Integrating of metal-organic framework UiO-66-NH2 and cellulose nanofibers mat for high-performance adsorption of dye rose bengal

Yuyao Han, Lei Xia, Xupin Zhuang, Yuxia Liang

PDF(162 KB)
PDF(162 KB)
Front. Chem. Sci. Eng. ›› 2022, Vol. 16 ›› Issue (9) : 1387-1398. DOI: 10.1007/s11705-022-2154-2
RESEARCH ARTICLE

Integrating of metal-organic framework UiO-66-NH2 and cellulose nanofibers mat for high-performance adsorption of dye rose bengal

Author information +
History +

Abstract

UiO-66-NH2 is an efficient material for removing pollutants from wastewater due to its high specific surface area, high porosity and water stability. However, recycling them from wastewater is difficult. In this study, the cellulose nanofibers mat deacetylated from cellulose acetate nanofibers were used to combine with UiO-66-NH2 by the method of in-situ growth to remove the toxic dye, rose bengal. Compared to previous work, the prepared composite could not only provide ease of separation of UiO-66-NH2 from the water after adsorption but also demonstrate better adsorption capacity (683 mg∙g‒1 (T = 25 °C, pH = 3)) than that of the simple UiO-66-NH2 (309.6 mg∙g‒1 (T = 25 °C, pH = 3)). Through the analysis of adsorption kinetics and isotherms, the adsorption for rose bengal is mainly suitable for the pseudo-second-order kinetic model and Freundlich model. Furthermore, the relevant research revealed that the main adsorption mechanism of the composite was electrostatic interaction, hydrogen bonding and π–π interaction. Overall, the approach depicts an efficient model for integrating metal-organic frameworks on cellulose nanofibers to improve metal-organic framework recovery performance with potentially broad applications.

Graphical abstract

Keywords

UiO-66-NH2 / cellulose nanofibers / rose bengal / adsorption / mechanism

Cite this article

Download citation ▾
Yuyao Han, Lei Xia, Xupin Zhuang, Yuxia Liang. Integrating of metal-organic framework UiO-66-NH2 and cellulose nanofibers mat for high-performance adsorption of dye rose bengal. Front. Chem. Sci. Eng., 2022, 16(9): 1387‒1398 https://doi.org/10.1007/s11705-022-2154-2

References

[1]
LeeL W, PaoS Y, PathakA, KangD Y, LuK L. Membrane adsorber containing a new Sm(III)-organic framework for dye removal. Environmental Science: Nano, 2019, 6( 4): 1067– 1076
CrossRef Google scholar
[2]
GuptaV K, MittalA, JhareD, MittalJ. Batch and bulk removal of hazardous colouring agent rose bengal by adsorption techniques using bottom ash as adsorbent. RSC Advances, 2012, 2( 22): 8381– 8389
CrossRef Google scholar
[3]
CriniG. Non-conventional low-cost adsorbents for dye removal: a review. Bioresource Technology, 2006, 97( 9): 1061– 1085
CrossRef Google scholar
[4]
McMullanG, MeehanC, ConneelyA, KirbyN, RobinsonT, NigamP, BanatI M, MarchantR, SmythW E. Microbial decolourisation and degradation of textile dyes. Applied Microbiology and Biotechnology, 2001, 56( 1-2): 81– 87
CrossRef Google scholar
[5]
FuF L, WangQ. Removal of heavy metal ions from wastewaters: a review. Journal of Environmental Management, 2011, 92( 3): 407– 418
CrossRef Google scholar
[6]
DabrowskiA. Adsorption—from theory to practice. Advances in Colloid and Interface Science, 2001, 93( 1-3): 135– 224
CrossRef Google scholar
[7]
RafatullahM, SulaimanO, HashimR, AhmadA. Adsorption of methylene blue on low-cost adsorbents: a review. Journal of Hazardous Materials, 2010, 177( 1-3): 70– 80
CrossRef Google scholar
[8]
KumarP, PournaraA, KimK H, BansalV, RaptiS, ManosM J. Metal-organic frameworks: challenges and opportunities for ion-exchange/sorption applications. Progress in Materials Science, 2017, 86 : 25– 74
CrossRef Google scholar
[9]
SchoeneckerP M, CarsonC G, JasujaH, FlemmingC J J, WaltonK S. Effect of water adsorption on retention of structure and surface area of metal-organic frameworks. Industrial & Engineering Chemistry Research, 2012, 51( 18): 6513– 6519
CrossRef Google scholar
[10]
YazaydinA O, BeninA I, FaheemS A, JakubczakP, LowJ J, WillisR R, SnurrR Q. Enhanced CO2 adsorption in metal-organic frameworks via occupation of open-metal sites by coordinated water molecules. Chemistry of Materials, 2009, 21( 8): 1425– 1430
CrossRef Google scholar
[11]
KumarP, DeepA, KimK H. Metal organic frameworks for sensing applications. Trends in Analytical Chemistry, 2015, 73 : 39– 53
CrossRef Google scholar
[12]
HaqueE, LoV, MinettA I, HarrisA T, ChurchT L. Dichotomous adsorption behaviour of dyes on an amino-functionalised metal-organic framework, amino-MIL-101(Al). Journal of Materials Chemistry A, 2014, 2( 1): 193– 203
CrossRef Google scholar
[13]
WangH, YuanX Z, WuY, ZengG M, ChenX H, LengL J, LiH. Synthesis and applications of novel graphitic carbon nitride/metal-organic frameworks mesoporous photocatalyst for dyes removal. Applied Catalysis B: Environmental, 2015, 174 : 445– 454
CrossRef Google scholar
[14]
AbdiJ, VossoughiM, MahmoodiN M, AlemzadehI. Synthesis of metal-organic framework hybrid nanocomposites based on GO and CNT with high adsorption capacity for dye removal. Chemical Engineering Journal, 2017, 326 : 1145– 1158
CrossRef Google scholar
[15]
PetersonG W, LeeD T, BartonH F, EppsT H III, ParsonsG N. Fibre-based composites from the integration of metal-organic frameworks and polymers. Nature Reviews Materials, 2021, 6( 7): 605– 621
CrossRef Google scholar
[16]
WangC H, ChengP, YaoY Y, YamauchiY, YanX, LiJ S, NaJ. In-situ fabrication of nanoarchitectured MOF filter for water purification. Journal of Hazardous Materials, 2020, 392 : 122164
CrossRef Google scholar
[17]
YangY Y, HuangW, GuoZ P, ZhangS Y, WuF, HuangJ J, YangH J, ZhouY S, XuW L, GuS J. Robust fluorine-free colorful superhydrophobic PDMS/NH2-MIL-125(Ti)@cotton fabrics for improved ultraviolet resistance and efficient oil-water separation. Cellulose, 2019, 26( 17): 9335– 9348
CrossRef Google scholar
[18]
LisM J, CaruziB B, GilG A, SamulewskiR B, BailA, ScacchettiF A P, MoisesM P, BezerraF M. In-situ direct synthesis of HKUST-1 in wool fabric for the improvement of antibacterial properties. Polymers, 2019, 11( 4): 713
CrossRef Google scholar
[19]
XiaL, JuJ G, XuW, DingC K, ChengB W. Preparation and characterization of hollow Fe2O3 ultra-fine fibers by centrifugal spinning. Materials & Design, 2016, 96 : 439– 445
CrossRef Google scholar
[20]
RenL Y, OzisikR, KothaS P, UnderhillP T. Highly efficient fabrication of polymer nanofiber assembly by centrifugal jet spinning: process and characterization. Macromolecules, 2015, 48( 8): 2593– 2602
CrossRef Google scholar
[21]
HuM R, WangY F, YanZ F, ZhaoG D, ZhaoY X, XiaL, ChengB W, DiY B, ZhuangX P. Hierarchical dual-nanonet of polymer nanofibers and supramolecular nanofibrils for air filtration with a high filtration efficiency, low air resistance and high moisture permeation. Journal of Materials Chemistry A, 2021, 9( 24): 14093– 14100
CrossRef Google scholar
[22]
RuJ, WangX M, WangF B, CuiX L, DuX Z, LuX Q. UiO series of metal-organic frameworks composites as advanced sorbents for the removal of heavy metal ions: synthesis, applications and adsorption mechanism. Ecotoxicology and Environmental Safety, 2021, 208 : 111577
CrossRef Google scholar
[23]
ButovaV V, SoldatovM A, GudaA A, LomachenkoK A, LambertiC. Metal-organic frameworks: structure, properties, methods of synthesis and characterization. Russian Chemical Reviews, 2016, 85( 3): 280– 307
CrossRef Google scholar
[24]
KalwarK, HuL, LiD L, ShanD. AgNPs incorporated on deacetylated electrospun cellulose nanofibers and their effect on the antimicrobial activity. Polymers for Advanced Technologies, 2018, 29( 1): 394– 400
CrossRef Google scholar
[25]
VahidiM, TavasoliA, RashidiA M. Preparation of amine functionalized UiO-66, mixing with aqueous N-methyldiethanolamine and application on CO2 solubility. Journal of Natural Gas Science and Engineering, 2016, 28 : 651– 659
CrossRef Google scholar
[26]
HasanZ, KhanN A, JhungS H. Adsorptive removal of diclofenac sodium from water with Zr-based metal-organic frameworks. Chemical Engineering Journal, 2016, 284 : 1406– 1413
CrossRef Google scholar
[27]
HashemT, IbrahimA H, WollC, AlkordiM H. Grafting zirconium-based metal-organic framework UiO-66-NH2 nanoparticles on cellulose fibers for the removal of Cr(VI) ions and methyl orange from water. ACS Applied Nano Materials, 2019, 2( 9): 5804– 5808
CrossRef Google scholar
[28]
PetersonG W, LuA X, EppsT H III. Tuning the morphology and activity of electrospun polystyrene/UiO-66-NH2 metal-organic framework composites to enhance chemical warfare agent removal. ACS Applied Materials & Interfaces, 2017, 9( 37): 32248– 32254
CrossRef Google scholar
[29]
WangJ L, GuoX. Adsorption kinetic models: physical meanings, applications, and solving methods. Journal of Hazardous Materials, 2020, 390 : 122156
CrossRef Google scholar
[30]
ZaboonS, AbidH R, YaoZ X, GubnerR, WangS B, BarifcaniA. Removal of monoethylene glycol from wastewater by using Zr-metal organic frameworks. Journal of Colloid and Interface Science, 2018, 523 : 75– 85
CrossRef Google scholar
[31]
GuoX, WangJ L. A general kinetic model for adsorption: theoretical analysis and modeling. Journal of Molecular Liquids, 2019, 288 : 111100
CrossRef Google scholar
[32]
WangJ L, GuoX. Adsorption isotherm models: classification, physical meaning, application and solving method. Chemosphere, 2020, 258 : 127279
CrossRef Google scholar
[33]
MohammadiN, KhaniH, GuptaV K, AmerehE, AgarwalS. Adsorption process of methyl orange dye onto mesoporous carbon material-kinetic and thermodynamic studies. Journal of Colloid and Interface Science, 2011, 362( 2): 457– 462
CrossRef Google scholar
[34]
LinS, ZhaoY F, YunY S. Highly effective removal of nonsteroidal anti-inflammatory pharmaceuticals from water by Zr(IV)-based metal- organic framework: adsorption performance and mechanisms. ACS Applied Materials & Interfaces, 2018, 10( 33): 28076– 28085
CrossRef Google scholar
[35]
PengY G, HuangH L, ZhangY X, KangC F, ChenS M, SongL, LiuD H, ZhongC L. A versatile MOF-based trap for heavy metal ion capture and dispersion. Nature Communications, 2018, 9( 1): 187
CrossRef Google scholar
[36]
ChenQ, HeQ Q, LvM M, XuY L, YangH B, LiuX T, WeiF Y. Selective adsorption of cationic dyes by UiO-66-NH2. Applied Surface Science, 2015, 327 : 77– 85
CrossRef Google scholar
[37]
YangD Q, HennequinB, SacherE. XPS demonstration of π-π interaction between benzyl mercaptan and multiwalled carbon nanotubes and their use in the adhesion of Pt nanoparticles. Chemistry of Materials, 2006, 18( 21): 5033– 5038
CrossRef Google scholar
[38]
TingH, ChiH Y, LamC H, ChanK Y, KangD Y. High-permeance metal-organic framework-based membrane adsorber for the removal of dye molecules in aqueous phase. Environmental Science Nano, 2017, 4( 11): 2205– 2214
CrossRef Google scholar
[39]
AhmedM A, AbdelbarN M, MohamedA A. Molecular imprinted chitosan-TiO2 nanocomposite for the selective removal of rose bengal from wastewater. International Journal of Biological Macromolecules, 2018, 107 : 1046– 1053
CrossRef Google scholar
[40]
NaushadM, AlothmanZ A, AwualM R, AlfadulS M, AhamadT. Adsorption of rose bengal dye from aqueous solution by amberlite Ira-938 resin: kinetics, isotherms, and thermodynamic studies. Desalination and Water Treatment, 2016, 57( 29): 13527– 13533
CrossRef Google scholar
[41]
CaiR, DuY P, PengS J, BiH C, ZhangW Y, YangD, ChenJ, LimT M, ZhangH, CaoY C, YanQ. Synthesis of porous, hollow metal MCO3 (M = Mn, Co, Ca) microstructures and adsorption properties thereof. Chemistry, 2014, 20( 2): 421– 425
CrossRef Google scholar
[42]
WangM, MaY F, SunY, HongS Y, LeeS K, YoonB, ChenL, CiL J, NamJ D, ChenX Y, SuhrJ. Hierarchical porous chitosan sponges as robust and recyclable adsorbents for anionic dye adsorption. Scientific Reports, 2017, 7( 1): 18054
CrossRef Google scholar

Acknowledgments

The authors gratefully acknowledge the financial support of the Tianjin Natural Science Foundation (Grant No. 18JCQNJC71900).

RIGHTS & PERMISSIONS

2022 Higher Education Press
AI Summary
PDF(162 KB)

Accesses

Citations

Detail

Sections
Recommended

/