Bamboo-like N-doped carbon nanotubes encapsulating M(Co, Fe)-Ni alloy for electrochemical production of syngas with potential-independent CO/H₂ ratios

Abstract

The electrochemical conversion of CO₂-H₂O into CO-H₂ using renewable energy is a promising technique for clean syngas production. Low-cost electrocatalysts to produce tunable syngas with a potential-independent CO/H₂ ratio are highly desired. Herein, a series of N-doped carbon nanotubes encapsulating binary alloy nanoparticles (M_xNi-NCNT, M= Fe, Co) were successfully fabricated through the co-pyrolysis of melamine and metal precursors. The M_xNi-NCNT samples exhibited bamboo-like nanotubular structures with a large specific surface area and high degree of graphitization. Their electrocatalytic performance for syngas production can be tuned by changing the alloy compositions and modifying the electronic structure of the carbon nanotube through the encapsulated metal nanoparticles. Consequently, syngas with a wide range of CO/H₂ ratios, from 0.5:1 to 3.4:1, can be produced on M_xNi-NCNT. More importantly, stable CO/H₂ ratios of 2:1 and 1.5:1, corresponding to the ratio to produce biofuels by syngas fermentation, could be realized on Co₁Ni-NCNT and Co₂Ni-NCNT, respectively, over a potential window of –0.8 to –1.2 V versus the reversible hydrogen electrode. Our work provides an approach to develop low-cost and potential-independent electrocatalysts to effectively produce syngas with an adjustable CO/H₂ ratio from electrochemical CO₂ reduction.

Graphical abstract

Keywords

electrochemical reduction of CO₂ / syngas / N-doped carbon nanotubes / encapsulated alloy nanoparticles / CO/H₂ ratio

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Acknowledgments

This research was funded by the National Natural Science Foundation of China (Grant Nos. 21873067 and 21206117). We are grateful to the analysis and test center of Tianjin University for providing physical characterizations (XRD, SEM, TEM, XPS).

Electronic Supplementary Material

Supplementary material is available in the online version of this article at https://dx.doi.org/10.1007/s11705-021-2082-6 and is accessible for authorized users.

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