Photocatalytic syngas synthesis from CO₂ and H₂O using ultrafine CeO₂-decorated layered double hydroxide nanosheets under visible-light up to 600 nm

Abstract

The rational design of photocatalyst that can effectively reduce CO₂ under visible light (l>400 nm), and simultaneously precise control of the products syngas (CO/H₂) ratio is highly desirable for the Fischer-Tropsch reaction. In this work, we synthesized a series of CeO₂-decorated layered double hydroxides (LDHs, Ce-x) samples for photocatalytic CO₂ reduction. It was found that the selectivity and productivity of CO and H₂ from photoreduction of CO₂ in conjunction with Ru-complex as photosensitizer performed an obvious “volcano-like” trend, with the highest point at Ce-0.15 and the CO/H₂ ratio can be widely tunable from 1/7.7 to 1/1.3. Furthermore, compared with LDH, Ce-0.15 also drove photocatalytic CO₂ to syngas under 600 nm irradiation. It implied that an optimum amount of CeO₂ modifying LDH promoted the photoreduction of CO₂ to syngas. This report gives the way to fully utilize the rare earth elements and provides a promising route to enhance the photo-response ability and charge injection efficiency of LDH-based photocatalysts in the synthesis of syngas with a tunable ratio under visible light irradiation.

Graphical abstract

Keywords

visible light catalysis / CO₂ conversion / layered double hydroxide / rare earth elements

References

[1] Li X, Yu J, Jaroniec M, Chen X. Cocatalysts for selective photoreduction of CO₂ into solar fuels. Chemical Reviews, 2019, 119(6): 3962–4179

[2] Li X, Sun Y, Xu J, Shao Y, Wu J, Xu X, Pan Y, Ju H, Zhu J, Xie Y. Selective visible-light-driven photocatalytic CO₂ reduction to CH₄ mediated by atomically thin CuIn₅S₈ layers. Nature Energy, 2019, 4(8): 690–699

[3] Zhao Y, Waterhouse G I N, Chen G, Xiong X, Wu L Z, Tung C H, Zhang T. Two-dimensional-related catalytic materials for solar-driven conversion of CO_x into valuable chemical feedstocks. Chemical Society Reviews, 2019, 48(7): 1972–2010

[4] Huang P P, Huang J H, Pantovich S A, Carl A D, Fenton T G, Caputo C A, Grimm R L, Frenkel A I, Li G H. Selective CO₂ reduction catalyzed by single cobalt sites on carbon nitride under visible-light irradiation. Journal of the American Chemical Society, 2018, 140(47): 16042–16047

[5] Kuriki R, Yamamoto M, Higuchi K, Yamamoto Y, Akatsuka M, Lu D L, Yagi S, Yoshida T, Ishitani O, Maeda K. Robust binding between carbon nitride nanosheets and a binuclear ruthenium(II) complex enabling durable, selective CO₂ reduction under visible light in aqueous solution. Angewandte Chemie International Edition, 2017, 56(17): 4867–4871

[6] Kuriki R, Sekizawa K, Ishitani O, Maeda K. Visible-light-driven CO₂ reduction with carbon nitride: Enhancing the activity of ruthenium catalysts. Angewandte Chemie International Edition, 2015, 54(8): 2406–2409

[7] Lee J S, Won D I, Jung W J, Son H J, Pac C, Kang S O. Widely controllable syngas production by a dye-sensitized TiO₂ hybrid system with Re(I) and Co(III) catalysts under visible-light irradiation. Angewandte Chemie International Edition, 2017, 56(4): 976–980

[8] Won D I, Lee J S, Ji J M, Jung W J, Son H J, Pac C, Kang S O. Highly robust hybrid photocatalyst for carbon dioxide reduction: Tuning and optimization of catalytic activities of Dye/TiO₂/Re(I) organic-inorganic ternary systems. Journal of the American Chemical Society, 2015, 137(42): 13679–13690

[9] Woolerton T W, Sheard S, Reisner E, Pierce E, Ragsdale S W, Armstrong F A. Efficient and clean photoreduction of CO₂ to CO by enzyme-modified TiO₂ nanoparticles using visible light. Journal of the American Chemical Society, 2010, 132(7): 2132–2133

[10] Chen X, Liu L, Yu P Y, Mao S S. Increasing solar absorption for photocatalysis with black hydrogenated titanium dioxide nanocrystals. Science, 2011, 331(6018): 746–750

[11] Li P, Zhou Y, Zhao Z, Xu Q, Wang X, Xiao M, Zou Z. Hexahedron prism-anchored octahedronal CeO₂: Crystal facet-based homojunction promoting efficient solar fuel synthesis. Journal of the American Chemical Society, 2015, 137(30): 9547–9550

[12] Aneggi E, Wiater D, de Leitenburg C, Llorca J, Trovarelli A. Shape-dependent activity of ceria in soot combustion. ACS Catalysis, 2014, 4(1): 172–181

[13] Tanaka A, Hashimoto K, Kominami H. Preparation of Au/CeO₂ exhibiting strong surface plasmon resonance effective for selective or chemoselective oxidation of alcohols to aldehydes or ketones in aqueous suspensions under irradiation by green light. Journal of the American Chemical Society, 2012, 134(35): 14526–14533

[14] Wang J, Xia T, Wang L, Zheng X, Qi Z, Gao C, Zhu J, Li Z, Xu H, Xiong Y. Enabling visible-light-driven selective CO₂ reduction by doping quantum dots: Trapping electrons and suppressing H₂ evolution. Angewandte Chemie International Edition, 2018, 57(50): 16447–16451

[15] Ulmer U, Dingle T, Duchesne P N, Morris R H, Tavasoli A, Wood T, Ozin G A. Fundamentals and applications of photocatalytic CO₂ methanation. Nature Communications, 2019, 10(1): 3169

[16] Bushuyev O S, De Luna P, Dinh C T, Tao L, Saur G, van de Lagemaat J, Kelley S O, Sargent E H. What should we make with CO₂ and how can we make it? Joule, 2018, 2(5): 825–832

[17] Schultz D M, Yoon T P. Solar synthesis: Prospects in visible light photocatalysis. Science, 2014, 343(6174): 1239176

[18] Yu J, Wang Q, O’Hare D, Sun L. Preparation of two dimensional layered double hydroxide nanosheets and their applications. Chemical Society Reviews, 2017, 46(19): 5950–5974

[19] Yin H, Tang Z. Ultrathin two-dimensional layered metal hydroxides: An emerging platform for advanced catalysis, energy conversion and storage. Chemical Society Reviews, 2016, 45(18): 4873–4891

[20] Fan G, Li F, Evans D G, Duan X. Catalytic applications of layered double hydroxides: Recent advances and perspectives. Chemical Society Reviews, 2014, 43(20): 7040–7066

[21] Gao R, Yan D. Layered host-guest long-after glow ultrathin nanosheets: High-efficiency phosphorescence energy transfer at 2D confined interface. Chemical Science (Cambridge), 2017, 8(1): 590–599

[22] Li T, Hao X, Bai S, Zhao Y, Song Y F. Controllable synthesis and scale-up production prospect of monolayer layered double hydroxide nanosheets. Acta Physico-chimica Sinica, 2020, 36: 1912005(in Chinese)

[23] Yin Q, Rao D, Zhang G, Zhao Y, Han J, Lin K, Zheng L, Zhang J, Zhou J, Wei M. CoFe-Cl layered double hydroxide: A new cathode material for high-performance chloride ion batteries. Advanced Functional Materials, 2019, 29(36): 1900983

[24] Arif M, Yasin G, Shakeel M, Mushtaq M A, Ye W, Fang X, Ji S, Yan D. Hierarchical CoFe-layered double hydroxide and g-C₃N₄ heterostructures with enhanced bifunctional photo/electrocatalytic activity towards overall water splitting. Materials Chemistry Frontiers, 2019, 3(3): 520–531

[25] Kumar S, Durndell L J, Manayil J C, Isaacs M A, Parlett C M A, Karthikeyan S, Douthwaite R E, Coulson B, Wilson K, Lee A F. Delaminated CoAl-layered double hydroxide@TiO₂ heterojunction nanocomposites for photocatalytic reduction of CO₂. Particle & Particle Systems Characterization, 2018, 35(1): 1700317

[26] Tonda S, Kumar S, Bhardwaj M, Yadav P, Ogale S. g-C₃N₄/NiAl-LDH 2D/2D hybrid heterojunction for high-performance photocatalytic reduction of CO₂ into renewable fuels. ACS Applied Materials & Interfaces, 2018, 10(3): 2667–2678

[27] Ahmed N, Shibata Y, Taniguchi T, Izumi Y. Photocatalytic conversion of carbon dioxide into methanol using zinc-copper-M(III) (M= aluminum, gallium) layered double hydroxides. Journal of Catalysis, 2011, 279(1): 123–135

[28] Teramura K, Iguchi S, Mizuno Y, Shishido T, Tanaka T. Photocatalytic conversion of CO₂ in water over layered double hydroxides. Angewandte Chemie International Edition, 2012, 51(32): 8008–8011

[29] Izumi Y. Recent advances in the photocatalytic conversion of carbon dioxide to fuels with water and/or hydrogen using solar energy and beyond. Coordination Chemistry Reviews, 2013, 257(1): 171–186

[30] Arif M, Yasin G, Luo L, Ye W, Mushtaq M A, Fang X, Xiang X, Ji S, Yan D. Hierarchical hollow nanotubes of NiFeV-layered double hydroxides@CoVP heterostructures towards efficient, pH-universal electrocatalytical nitrogen reduction reaction to ammonia. Applied Catalysis B: Environmental, 2020, 265: 118559

[31] Zhao Y, Jia X, Waterhouse G I N, Wu L Z, Tung C H, O’Hare D, Zhang T. Layered double hydroxide nanostructured photocatalysts for renewable energy production. Advanced Energy Materials, 2016, 6(6): 1501974

[32] Li J, Xu Y, Ding Z, Mahadi A H, Zhao Y, Song Y F. Photocatalytic selective oxidation of benzene to phenol in water over layered double hydroxide: A thermodynamic and kinetic perspective. Chemical Engineering Journal, 2020, 388: 124248

[33] Wang Q, Feng J, Zheng L, Wang B, Bi R, He Y, Liu H, Li D. Interfacial structure-determined reaction pathway and selectivity for 5-hydroxymethyl furfural hydrogenation over Cu-based catalysts. ACS Catalysis, 2020, 10(2): 1353–1365

[34] Bai S, Wang Z, Tan L, Waterhouse G I N, Zhao Y, Song Y F. 600 nm irradiation-induced efficient photocatalytic CO₂ reduction by ultrathin layered double hydroxide nanosheets. Industrial & Engineering Chemistry Research, 2020, 59(13): 5848–5857

[35] Silva C G, Bouizi Y, Forne’s V, Garcia H. Layered double hydroxides as highly efficient photocatalysts for visible light oxygen generation from water. Journal of the American Chemical Society, 2009, 131(38): 13833–13839

[36] Ren J, Ouyang S, Xu H, Meng X, Wang T, Wang D, Ye J. Targeting activation of CO₂ and H₂ over Ru-loaded ultrathin layered double hydroxides to achieve efficient photothermal CO₂ methanation in flow-type system. Advanced Energy Materials, 2017, 7(5): 1601657

[37] Wang X, Wang Z, Bai Y, Tan L, Xu Y, Hao X, Wang J, Mahadi A H, Zhao Y, Zheng L, Tuning the selectivity of photoreduction of CO₂ to syngas over Pd/layered double hydroxide nanosheets under visible-light up to 600 nm. Journal of Energy Chemistry, 2020, 46: 1–7

[38] Kipkorir P, Tan L, Ren J, Zhao Y, Song Y F. Intercalation effect in NiAl-layered double hydroxide nanosheets for CO₂ reduction under visible light. Chemical Research in Chinese Universities, 2020, 36(1): 127–133

[39] Tan L, Xu S M, Wang Z, Xu Y, Wang X, Hao X, Bai S, Ning C, Wang Y, Zhang W, Highly selective photoreduction of CO₂ with suppressing H₂ evolution over monolayer layered double hydroxide under irradiation above 600 nm. Angewandte Chemie International Edition, 2019, 58(34): 11860–11867

[40] Hao X, Tan L, Xu Y, Wang Z, Wang X, Bai S, Ning C, Zhao J, Zhao Y, Song Y F. Engineering active Ni sites in ternary layered double hydroxides nanosheets for a high selectivity photoreduction of CO₂ to CH₄ under irradiation above 500 nm. Industrial & Engineering Chemistry Research, 2020, 59(7): 3008–3015

[41] Montini T, Melchionna M, Monai M, Fornasiero P. Fundamentals and catalytic applications of CeO₂-based materials. Chemical Reviews, 2016, 116(10): 5987–6041

[42] Li Y, He X, Yin J J, Ma Y, Zhang P, Li J, Ding Y, Zhang J, Zhao Y, Chai Z, Zhang Z. Acquired superoxide-scavenging ability of ceria nanoparticles. Angewandte Chemie International Edition, 2015, 54(6): 1832–1835

[43] Ye T, Huang W, Zeng L, Li M, Shi J. CeO_2−x platelet from monometallic cerium layered double hydroxides and its photocatalytic reduction of CO₂. Applied Catalysis B: Environmental, 2017, 210: 141–148

[44] Zhang S, Chang C, Huang Z, Ma Y, Gao W, Li J, Qu Y. Visible-light-activated Suzuki-Miyaura coupling reactions of aryl chlorides over the multifunctional Pd/Au/porous nanorods of CeO₂ catalysts. ACS Catalysis, 2015, 5(11): 6481–6488

[45] Primo A, Marino T, Corma A, Molinari R, Garcia H. Efficient visible-light photocatalytic water splitting by minute amounts of gold supported on nanoparticulate CeO₂ obtained by a biopolymer templating method. Journal of the American Chemical Society, 2011, 133(18): 6930–6933

[46] Seftel E M, Puscasu M C, Mertens M, Cool P, Carja G. Assemblies of nanoparticles of CeO₂-ZnTi-LDHs and their derived mixed oxides as novel photocatalytic systems for phenol degradation. Applied Catalysis B: Environmental, 2014, 150-151: 157–166

[47] Valente J S, Tzompantzi F, Prince J. Highly efficient photocatalytic elimination of phenol and chlorinated phenols by CeO₂/MgAl layered double hydroxides. Applied Catalysis B: Environmental, 2011, 102(1-2): 276–285

[48] Iqbal K, Iqbal A, Kirillov A M, Wang B, Liu W, Tang Y. A new Ce-doped MgAl-LDH@Au nanocatalyst for highly efficient reductive degradation of organic contaminants. Journal of Materials Chemistry. A, Materials for Energy and Sustainability, 2017, 5(14): 6716–6724

[49] Chen Y, Lv S, Chen C, Qiu C, Fan X, Wang Z. Controllable synthesis of ceria nanoparticles with uniform reactive {100} exposure planes. Journal of Chemical Physics, 2014, 118(8): 4437–4443

[50] Gao C, Chen S, Wang Y, Wang J, Zheng X, Zhu J, Song L, Zhang W, Xiong Y. Heterogeneous single-atom catalyst for visible-light-driven high-turnover CO₂ reduction: The role of electron transfer. Advanced Materials, 2018, 30(13): 1704624

[51] Rao H, Schmidt L C, Bonin J, Robert M. Visible-light-driven methane formation from CO₂ with a molecular iron catalyst. Nature, 2017, 548(7665): 74–77

[52] Han B, Ou X, Deng Z, Song Y, Tian C, Deng H, Xu Y J, Lin Z. Nickel metal-organic frameworks monolayers for photoreduction of diluted CO₂: Metal-node-dependent activity and selectivity. Angewandte Chemie International Edition, 2018, 57(51): 16811–16815

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