Effect of hierarchical ZSM-5 zeolite crystal size on diffusion and catalytic performance of n-heptane cracking

Abstract

Hierarchical ZSM-5 zeolite aggregates with different sizes of nanocrystals were synthesized using different amounts of the mesoporogen 3-aminopropyltriethoxysilane. The effect of the crystal size on the catalytic cracking of n-heptane was investigated and the Thiele modulus and effectiveness factor were used to determine the reaction rate-limiting step. The crystal size affected the textual properties of the catalysts but not the acidic properties of the catalysts. The reaction rate was first order with respect to the n-heptane concentration. Cracking over hierarchical zeolites with nanocrystal sizes larger than about 50 nm took place under transition-limiting conditions, whereas the reaction over hierarchical zeolites with nanocrystal sizes of 15 or 30 nm proceeded under reaction control conditions. Hierarchical ZSM-5 zeolite aggregates with smaller nanocrystals had better selectivity for light olefins which can be ascribed to the shorter diffusion path lengths and lower diffusion resistance in these catalysts. Furthermore, these catalysts had lower coking levels which can be attributed to the substantial number of mesopores which prevent the formation of coke precursors.

Graphical abstract

Keywords

hierarchical ZSM-5 / crystal size / catalytic cracking / Thiele modulus / effectiveness factor

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Acknowledgements

The support from the National Key R & D Program of China (2016YFA0202900), the National Natural Science Foundation of China (91434123, 21622606), the Zhejiang Provincial Natural Science Foundation of China (LR18B060001) and the Fundamental Research Fund for Central Universities is greatly appreciated. Xiaohong Ren acknowledges financial support from the State Key Laboratory of Fine Chemicals (KF1516).

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