Synthesis of hydrophobic carbon nanotubes/reduced graphene oxide composite films by flash light irradiation

Kai Wang, Jinbo Pang, Liwei Li, Shengzhe Zhou, Yuhao Li, Tiezhu Zhang

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PDF(349 KB)
Front. Chem. Sci. Eng. ›› 2018, Vol. 12 ›› Issue (3) : 376-382. DOI: 10.1007/s11705-018-1705-z
RESEARCH ARTICLE
RESEARCH ARTICLE

Synthesis of hydrophobic carbon nanotubes/reduced graphene oxide composite films by flash light irradiation

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Abstract

Carbon nanotubes/graphene composites have superior mechanical, electrical and electrochemistry properties with carbon nanotubes as a hydrophobicity boosting agent. Their extraordinary hydrophobic performance is highly suitable for electrode applications in lithium ion batteries and supercapacitors which often employ organic electrolytes. Also the hydrophobic features enable the oil enrichment for the crude oil separation from seawater. The ever reported synthesis routes towards such a composite either involve complicated multi-step reactions, e.g., chemical vapor depositions, or lead to insufficient extrusion of carbon nanotubes in the chemical reductions of graphene oxide, e.g., fully embedding between the compact graphene oxide sheets. As a consequence, the formation of standalone carbon nanotubes over graphene sheets remains of high interests. Herein we use the facile flash light irradiation method to induce the reduction of graphene oxides in the presence of carbon nanotubes. Photographs, micrographs, X-ray diffraction, infrared spectroscopy and thermogravimetric analysis all indicate that graphene oxides has been reduced. And the contact angle tests confirm the excellent hydrophobic performances of the synthesized carbon nanotube/reduced graphene oxide composite films. This one-step treatment represents a straightforward and high efficiency way for the reduction of carbon nanotubes/graphene oxides composites.

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Keywords

carbon nanotubes / graphene composite / flash irradiation method / reduced graphene oxide / contact angles

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Kai Wang, Jinbo Pang, Liwei Li, Shengzhe Zhou, Yuhao Li, Tiezhu Zhang. Synthesis of hydrophobic carbon nanotubes/reduced graphene oxide composite films by flash light irradiation. Front. Chem. Sci. Eng., 2018, 12(3): 376‒382 https://doi.org/10.1007/s11705-018-1705-z

References

[1]
Mathew J P, Patel R N, Borah A, Vijay R, Deshmukh M M. Dynamical strong coupling and parametric amplification of mechanical modes of graphene drums. Nature Nanotechnology, 2016, 11(9): 747–751
CrossRef Google scholar
[2]
Levendorf M P, Kim C J, Brown L, Huang P Y, Havener R W, Muller D A, Park J. Graphene and boron nitride lateral heterostructures for atomically thin circuitry. Nature, 2012, 488(7413): 627–632
CrossRef Google scholar
[3]
Nien L W, Chen K, Dao T D, Ishii S, Hsueh C H, Nagao T. Far-field and near-field monitoring of hybridized optical modes from Au nanoprisms suspended on a graphene/Si nanopillar array. Nanoscale, 2017, 9(43): 16950–16959
CrossRef Google scholar
[4]
Johns J E, Hersam M C. Atomic covalent functionalization of graphene. Accounts of Chemical Research, 2013, 46(1): 77–86
CrossRef Google scholar
[5]
Wang K, Li L W, Zhang T Z, Liu Z F. Nitrogen-doped graphene for supercapacitor with long-term electrochemical stability. Energy, 2014, 70: 612–617
CrossRef Google scholar
[6]
Lu Y, Zhang N, Jiang S, Zhang Y, Zhou M, Tao Z, Archer L A, Chen J. High-capacity and ultrafast Na-ion storage of a self-supported 3D porous antimony persulfide-graphene foam architecture. Nano Letters, 2017, 17(6): 3668–3674
CrossRef Google scholar
[7]
Pang J, Mendes R G, Wrobel P S, Wlodarski M D, Ta H Q, Zhao L, Giebeler L, Trzebicka B, Gemming T, Fu L, . Self-terminating confinement approach for large-area uniform monolayer graphene directly over Si/SiOx by chemical vapor deposition. ACS Nano, 2017, 11(2): 1946–1956
CrossRef Google scholar
[8]
Rummeli M H, Gorantla S, Bachmatiuk A, Phieler J, Geissler N, Ibrahim I, Pang J B, Eckert J. On the role of vapor trapping for chemical vapor deposition (CVD) grown graphene over copper. Chemistry of Materials, 2013, 25(24): 4861–4866
CrossRef Google scholar
[9]
Pang J, Bachmatiuk A, Ibrahim I, Fu L, Placha D, Martynkova G S, Trzebicka B, Gemming T, Eckert J, Rümmeli M H. CVD growth of 1D and 2D sp2 carbon nanomaterials. Journal of Materials Science, 2015, 51(2): 640–667
CrossRef Google scholar
[10]
Pang J B, Bachmatiuk A, Fu L, Yan C L, Zeng M Q, Wang J, Trzebicka B, Gemming T, Eckert J, Rummeli M H. Oxidation as a means to remove surface contaminants on Cu foil prior to graphene growth by chemical vapor deposition. Journal of Physical Chemistry C, 2015, 119(23): 13363–13368
CrossRef Google scholar
[11]
Pang J B, Bachmatiuk A, Fu L, Mendes R G, Libera M, Placha D, Martynkova G S, Trzebicka B, Gemming T, Eckert J, . Direct synthesis of graphene from adsorbed organic solvent molecules over copper. RSC Advances, 2015, 5(75): 60884–60891
CrossRef Google scholar
[12]
Wang K, Li L W, Xue W, Zhou S Z, Lan Y, Zhang H W, Sui Z Q. Electrodeposition synthesis of PANI/MnO2/graphene composite materials and its electrochemical performance. International Journal of Electrochemical Science, 2017, 12(9): 8306–8314
[13]
Zhang L, Ji B C, Wang K, Song J Y. Synthesis of nitrogen-doped graphene via solid microwave method. Materials Science and Engineering B, 2014, 185: 129–133
CrossRef Google scholar
[14]
Hu H, Zhao Z, Wan W, Gogotsi Y, Qiu J. Ultralight and highly compressible graphene aerogels. Advanced Materials, 2013, 25(15): 2219–2223
CrossRef Google scholar
[15]
Hu H, Zhao Z B, Gogotsi Y, Qiu J S. Compressible carbon nanotube-graphene hybrid aerogels with superhydrophobicity and superoleophilicity for oil sorption. Environmental Science & Technology Letters, 2014, 1(3): 214–220
CrossRef Google scholar
[16]
Hu H, Zhao Z B, Zhang R, Bin Y Z, Qiu J S. Polymer casting of ultralight graphene aerogels for the production of conductive nanocomposites with low filling content. Journal of Materials Chemistry. A, Materials for Energy and Sustainability, 2014, 2(11): 3756–3760
CrossRef Google scholar
[17]
Yu L, Hu H, Wu H B, Lou X W. Complex hollow nanostructures: Synthesis and energy-related applications. Advanced Materials, 2017, 29(15): 1604563
CrossRef Google scholar
[18]
Hu H, Zhang J, Guan B, Lou X W. Unusual formation of CoSe@carbon nanoboxes, which have an inhomogeneous shell, for efficient lithium storage. Angewandte Chemie International Edition, 2016, 55(33): 9514–9518
CrossRef Google scholar
[19]
Wang K, Zhang L, Ji B C, Yuan J L. The thermal analysis on the stackable supercapacitor. Energy, 2013, 59: 440–444
CrossRef Google scholar
[20]
Wang K, Li L, Yin H, Zhang T, Wan W. Thermal modelling analysis of spiral wound supercapacitor under constant-current cycling. PLoS One, 2015, 10(10): e0138672
CrossRef Google scholar
[21]
Lin K X, Gomez-Bombarelli R, Beh E S, Tong L C, Chen Q, Valle A, Aspuru-Guzik A, Aziz M J, Gordon R G. A redox-flow battery with an alloxazine-based organic electrolyte. Nature Energy, 2016, 1(9): 16102
CrossRef Google scholar
[22]
Zhou H H, Peng Y T, Wu H B, Sun F, Yu H, Liu F, Xu Q J, Lu Y F. Fluorine-rich nanoporous carbon with enhanced surface affinity in organic electrolyte for high-performance supercapacitors. Nano Energy, 2016, 21: 80–89
CrossRef Google scholar
[23]
Markevich E, Salitra G, Chesneau F, Schmidt M, Aurbach D. Very stable lithium metal stripping-plating at a high rate and high areal capacity in fluoroethylene carbonate-based organic electrolyte solution. ACS Energy Letters, 2017, 2(6): 1321–1326
CrossRef Google scholar
[24]
Li Y, Luong D X, Zhang J, Tarkunde Y R, Kittrell C, Sargunaraj F, Ji Y, Arnusch C J, Tour J M. Laser-induced graphene in controlled atmospheres: From superhydrophilic to superhydrophobic surfaces. Advanced Materials, 2017, 29(27): 1700496
CrossRef Google scholar
[25]
Feng C, Yi Z, She F, Gao W, Peng Z, Garvey C J, Dumee L F, Kong L. Superhydrophobic and superoleophilic micro-wrinkled reduced graphene oxide as a highly portable and recyclable oil sorbent. ACS Applied Materials & Interfaces, 2016, 8(15): 9977–9985
CrossRef Google scholar
[26]
Zhang Y X, Zhang H, Wang Y K, Wu H X, Zeng B, Zhang Y J, Tian Q W, Yang S P. Hydrophilic graphene oxide/bismuth selenide nanocomposites for CT imaging, photoacoustic imaging, and photothermal therapy. Journal of Materials Chemistry. B, Materials for Biology and Medicine, 2017, 5(9): 1846–1855
CrossRef Google scholar
[27]
Sakai N, Kamanaka K, Sasaki T. Modulation of photochemical activity of titania nanosheets via heteroassembly with reduced graphene oxide. Enhancement of photoinduced hydrophilic conversion properties. Journal of Physical Chemistry C, 2016, 120(42): 23944–23950
CrossRef Google scholar
[28]
Wang W Y, Liu P L, Wu K, Tan S, Li W S, Yang Y Q. Preparation of hydrophobic reduced graphene oxide supported Ni-B-P-O and Co-B-P-O catalysts and their high hydrodeoxygenation activities. Green Chemistry, 2016, 18(4): 984–988
CrossRef Google scholar
[29]
Jeon Y, Han X G, Fu K, Dai J Q, Kim J H, Hu L B, Song T, Paik U. Flash-induced reduced graphene oxide as a Sn anode host for high performance sodium ion batteries. Journal of Materials Chemistry. A, Materials for Energy and Sustainability, 2016, 4(47): 18306–18313
CrossRef Google scholar
[30]
Higgins D, Zamani P, Yu A P, Chen Z W. The application of graphene and its composites in oxygen reduction electrocatalysis: A perspective and review of recent progress. Energy & Environmental Science, 2016, 9(2): 357–390
CrossRef Google scholar
[31]
Wan W C, Zhang R Y, Li W, Liu H, Lin Y H, Li L N, Zhou Y. Graphene-carbon nanotube aerogel as an ultra-light, compressible and recyclable highly efficient absorbent for oil and dyes. Environmental Science. Nano, 2016, 3(1): 107–113
CrossRef Google scholar
[32]
Chen J, Zhang Y, Zhang M, Yao B W, Li Y R, Huang L, Li C, Shi G Q. Water-enhanced oxidation of graphite to graphene oxide with controlled species of oxygenated groups. Chemical Science (Cambridge), 2016, 7(3): 1874–1881
CrossRef Google scholar
[33]
Wang J, Singh B, Maeng S, Joh H I, Kim G H. Assembly of thermally reduced graphene oxide nanostructures by alternating current dielectrophoresis as hydrogen-gas sensors. Applied Physics Letters, 2013, 103(8): 083112
CrossRef Google scholar
[34]
Hamid S B A, Teh S J, Lai C W, Perathoner S, Centi G. Applied bias photon-to-current conversion efficiency of ZnO enhanced by hybridization with reduced graphene oxide. Journal of Energy Chemistry, 2017, 26(2): 302–308
CrossRef Google scholar
[35]
Jana M, Kumar J S, Khanra P, Samanta P, Koo H, Murmu N C, Kuila T. Superior performance of asymmetric supercapacitor based on reduced graphene oxide-manganese carbonate as positive and sono-chemically reduced graphene oxide as negative electrode materials. Journal of Power Sources, 2016, 303: 222–233
CrossRef Google scholar
[36]
Church R B, Hu K W, Magnacca G, Cerruti M. Intercalated species in multilayer graphene oxide: Insights gained from in situ FTIR spectroscopy with probe molecule delivery. Journal of Physical Chemistry C, 2016, 120(40): 23207–23211
CrossRef Google scholar
[37]
Peng L, Xu Z, Liu Z, Wei Y, Sun H, Li Z, Zhao X, Gao C. An iron-based green approach to 1-h production of single-layer graphene oxide. Nature Communications, 2015, 6(1): 5716
CrossRef Google scholar
[38]
Cao N, Lyu Q, Li J, Wang Y, Yang B, Szunerits S, Boukherroub R. Facile synthesis of fluorinated polydopamine/chitosan/reduced graphene oxide composite aerogel for efficient oil/water separation. Chemical Engineering Journal, 2017, 326: 17–28
CrossRef Google scholar
[39]
Xiong C, Li T, Dang A, Zhao T, Li H, Lv H. Two-step approach of fabrication of three-dimensional MnO2-graphene-carbon nanotube hybrid as a binder-free supercapacitor electrode. Journal of Power Sources, 2016, 306: 602–610
CrossRef Google scholar
[40]
David L, Bhandavat R, Barrera U, Singh G. Silicon oxycarbide glass-graphene composite paper electrode for long-cycle lithium-ion batteries. Nature Communications, 2016, 7: 10998
CrossRef Google scholar

Acknowledgements

The work was supported by the Qingdao postdoctoral fund (No. 2015118) and Key research and development plan of Shandong Province (No. 2017GGX50114).

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2018 Higher Education Press and Springer-Verlag GmbH Germany, part of Springer Nature
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