Materials sustainability for environment: Red-mud treatment

Brajendra Mishra, Sumedh Gostu

PDF(409 KB)
PDF(409 KB)
Front. Chem. Sci. Eng. ›› 2017, Vol. 11 ›› Issue (3) : 483-496. DOI: 10.1007/s11705-017-1653-z
REVIEW ARTICLE
REVIEW ARTICLE

Materials sustainability for environment: Red-mud treatment

Author information +
History +

Abstract

Bayer’s process revolutionized the extraction of aluminum from the bauxite ores. However, the hydrothermal extraction of alumina is associated with the generation of a byproduct, red-mud consisting of undissolved solids composed of iron oxides, sodium alumino silicates, titania, silica and rare earth elements. The accumulation of red-mud (or bauxite residue) in the world is 30 billion metric tons produced at a rate of 125 million tons per annum (2013). Utilization of red-mud for constructional purposes, wastewater treatment, metallurgical products, and pigments are listed. Metallurgical processing efforts of red-mud to generate various value added products such as pig iron, direct reduced iron slag wool, magnetite, titania, iron carbides are presented in the article.

Graphical abstract

Keywords

red-mud processing / waste management / sustainability / valorization

Cite this article

Download citation ▾
Brajendra Mishra, Sumedh Gostu. Materials sustainability for environment: Red-mud treatment. Front. Chem. Sci. Eng., 2017, 11(3): 483‒496 https://doi.org/10.1007/s11705-017-1653-z

Full size|PPT slide

Dr. Brajendra Mishra is the Kenneth G. Merriam Distinguished Professor of Mechanical Engineering and Director of the Metal Processing Institute at the Worcester Polytechnic Institute [WPI]. Dr. Mishra is the Director of the National Science Foundation’s Industry/University Collaborative Research Center on Resource Recovery & Recycling. Brajendra received his Bachelor of Technology degree in Metallurgical Engineering from the Indian Institute of Technology in Kharagpur, India and his M.S. and Ph.D. in Materials Science from the University of Minnesota in Minneapolis. Prior to joining WPI, Mishra was a Professor of Corrosion and Physico-chemical Processing in Metallurgical & Materials Engineering at the Colorado School of Mines [CSM] where he now serves as a University Emeritus Professor. Dr. Mishra has over twenty seven years of research experience in materials recovery and recycling, molten salt pyrometallurgy and electrochemistry and has many contributions to the application of these technologies to materials development and processing. Dr. Mishra has authored over 500 technical publications in refereed journals and conference proceedings. He holds nine patents and has authored/edited 19 books. Dr. Mishra is a member of TMS, ASM International, and NACE. He is a Fellow of ASM (2001) and TMS (2016). Mishra received the Distinguished Service Award from the Minerals Metals & Materials Society (2010) and the highest award of Honorary Membership form the Indian Institute of Metals (2008). Brajendra served as the 2006 President of The Mineral, Metals & Materials Society (TMS) of AIME and the 2011 President of Amer. Institute of Mining, Metallurgical & Petroleum Engineers. Dr. Mishra received the Presidential Citation of AIME in 2015 and the Kenneth Andrew Roe Award from AAES (2016).

References

[1]
Habbashi F. Textbook of Hydrometallurgy. Métallurgie Extractive Québec, 1999
[2]
Edward J, Frary F, Jefferies Z. Aluminum and Its Production. Columbus: McGraw-Hill Book Company, Inc, 1930
[3]
Information from Company Websites of USGS. Alcoa. 2017
[4]
Bauxite Residue Management: Best Practice. World aluminum, European aluminum association, April 2013
[5]
Burkin A R. Production of Aluminum and Alumina. Society of Chemical Industry. Hoboken: John Wiley and Sons, 1987
[6]
Prasad P M, Singh M. Problems in the disposal and utilization of red muds. Banaras Metallurgist, 1997, 14-15: 127–140
[7]
Staley A K. An investigation into the Pyrometallurgical and electrometallurgical extraction of iron from red mud generated in the processing of bauxite ores. Dissertation for the Doctoral Degree. Colorado: Colorado School of Mines, 2002
[8]
Samal S, Ray A, Bandopadhyay A. Proposal for resources, utilization and processes of red mud in India: A review. International Journal of Mineral Processing, 2013, 118: 43–55
CrossRef Google scholar
[9]
Pontikes Y, Angelpoulos G. Bauxite residue in cement and cementitious applications: Current status and a possible way forward. Resources, Conservation and Recycling, 2013, 73: 53–63
CrossRef Google scholar
[10]
Singh M, Upadhyay S N, Prasad P M. Preparation of iron rich cements using red mud. Cement and Concrete Research, 1997, 27(7): 1037–1046
CrossRef Google scholar
[11]
Mishra C R, Yadav D, Sharma P S, Alli M M. Production of ordinary portland cement (OPC) from NALCO red mud. TMS (The Minerals, Metals and Materials Society). 2011, https://link.springer.com/chapter/10.1007%2F978-3-319-48160-9_17
[12]
Liu X, Zhang N. Utilization of red mud in cement production: A review. Waste Management & Research, 2010, 29(10): 1053–1063
CrossRef Google scholar
[13]
Liu Q, Xin R, Li C, Xu C, Yang J. Application of red mud as a basic catalyst for biodiesel production. Journal of Environmental Sciences (China), 2013, 25(4): 823–829
CrossRef Google scholar
[14]
Liang W, Couperthwaite S J, Kaur G, Yan C, Johnstone D W, Millar G J. Effect of strong acids on red mud structural and fluoride adsorption properties. Journal of Colloid and Interface Science, 2014, 423: 158–165
CrossRef Google scholar
[15]
Liu Z, Li H. Metallurgical process for valuable elements recovery from red mud: A review. Hydrometallurgy, 2015, 155: 29–43
CrossRef Google scholar
[16]
Hammond K, Mishra B, Apelian D, Blanpain B. CR3 Communication: Red mud — a resource or a waste? Journal of the Minerals Metals & Materials Society, 2013, 65(3): 340–341
CrossRef Google scholar
[17]
Liu W, Yang J, Xiao B. Review on treatment and utilization of bauxite residues in China. International Journal of Mineral Processing, 2009, 93(3-4): 220–231
CrossRef Google scholar
[18]
Liu W, Sun S, Zhang L, Jahanshahi S, Yang J. Experimental and simulative study on phase transformation in Bayer red mud soda-lime roasting system and recovery of Al, Na and Fe. Minerals Engineering, 2012, 39: 213–218
CrossRef Google scholar
[19]
Zhong L, Zhang Y, Yi Z. Extraction of alumina and sodium oxide from red mud by a mild hydro-chemical process. Journal of Hazardous Materials, 2009, 172(2-3): 1629–1634
CrossRef Google scholar
[20]
Li H, Hui J, Wang C, Bao W, Sun Z. Removal of sodium (Na2O) from alumina extracted fly ash by a mild hydrothermal process. Hydrometallurgy, 2015, 153: 1–5
CrossRef Google scholar
[21]
Vachon P, Tyagi R D, Auclair J C, Wilkinson K J. Chemical and biological leaching of aluminum from red mud. Environmental Science & Technology, 1994, 28(1): 26–30
CrossRef Google scholar
[22]
Bruckard W J, Calle C M, Davidson R H, Glenn A M, Jahanshahi S, Somerville M A, Sparrow G J, Zhang L. Smelting of bauxite residue to form a soluble sodium aluminum silicate phase to recover alumina and soda. Mineral Processing and Extractive Metallurgy Review, 2010, 119(1): 18–26
CrossRef Google scholar
[23]
Li X, Xiao W, Liu W, Liu G, Peng Z, Zhou Q, Qi T. Recovery of alumina and ferric oxide from Bayer red mud rich in iron by reduction sintering. Transactions of Nonferrous Metallurgical Society, 2009, 19(5): 1342–1347
CrossRef Google scholar
[24]
Zhou Q S, Fan K S, Li X B, Peng Z H, Liu G H. Alumina recovery from red mud with high iron by sintering process . Journal of Central South University Science and Technology, 2008, 39(1): 92–97 (in Chinese)
[25]
Raspopov N V, Korneev V P, Averin V, Lainer Y A, Zinoneev D V, Dyubanov V G. Reduction of iron oxides during the Pyrometallurgical processing or red mud. Russian Metallurgy (Metally), 2013, 1(1): 33–37
CrossRef Google scholar
[26]
Li G, Liu M, Rao M, Jiang T, Zhuang J, Zhang Y. Stepwise extraction of valuable components from red mud based on reductive roasting with sodium salts. Journal of Hazardous Materials, 2014, 280: 774–780
CrossRef Google scholar
[27]
Jamieson E, Jones A, Cooling D, Stockton N. Magnetic separation of red sand to produce value. Minerals Engineering, 2006, 19(15): 1603–1605
CrossRef Google scholar
[28]
Zhu D, Jun T, Chun J, Zhen P. Recovery of iron from high-iron red mud by reduction roasting with adding sodium salt. Journal of Iron and Steel Research International, 2012, 19(8): 1–5
[29]
Liu W, Yang J, Xiao B. Application of Bayer red mud for iron recovery and building material production from aluminosilicate residues. Journal of Hazardous Materials, 2009, 161(1): 474–478
CrossRef Google scholar
[30]
Piga L, Pochetti F, Stoppa L. Recovery of metals from red mud generated during alumina production. JOM, 1993, 45(11): 54–59
CrossRef Google scholar
[31]
Stickney W A, Butler M O, Mauser J E, Fursman O C. Utilization of red mud residues from alumina production. Washington: U.S. Department of Interior, Bureau of Mines, DC, 1970
[32]
Kumar R, Srivastava J P. Premchand. Utilization of iron values of red mud for metallurgical applications. Environmental and Waste Management, 1998, 108–119
[33]
Jayasankar K, Ray P K, Chaubey A K, Padhi A, Satapathy B K, Mukherjee P S. Production of pig iron from red mud waste fines using thermal plasma technology. International Journal of Minerals Metallurgy and Materials, 2012, 19(8): 679–684
CrossRef Google scholar
[34]
Laguna C, González F, García-Balboa C, Ballester A, Blázquez M L, Muñoz J A. Bioreduction of iron compounds as a possible clean environmental alternative for metal recovery. Minerals Engineering, 2011, 24(1): 10–18
CrossRef Google scholar
[35]
Zhong L, Zhang Y, Zhang Y. Extraction of alumina and sodium oxide from red mud by a mild hydro-chemical process. Journal of Hazardous Materials, 2009, 172(2-3): 1629–1634
CrossRef Google scholar
[36]
Guo Y, Guo J, Xu H, Zhao K, Shi X. Nuggests production by direct reduction of high iron red mud. Journal of Iron and Steel research, International, 2013, 20(5): 24–27
[37]
Samouhos M, Taxiarchou M, Tsakiridis P, Potiriadis K. Greek red mud residue: A study of microwave reductive roasting followed by magnetic separation for a metallic iron recovery process. Journal of Hazardous Materials, 2013, 254-255: 193–205
CrossRef Google scholar
[38]
Li G, Liu M, Rao M, Jiang T, Zhuang J, Zhang Y. Stepwise extraction of valuable components from red mud based on reductive roasting with sodium salts. Journal of Hazardous Materials, 2014, 280: 774–780
CrossRef Google scholar
[39]
Teplov O A, Lainer Y U. Rate of reduction of the iron oxides in red mud by hydrogen and converted gas. Russian Metallurgy (Metally), 2013, 1: 32–40
[40]
Caupain R. Low-temperature gas-phase carbidization of iron-bearing constituents in red mud. Dissertation for the Master Degree. Colorado: Colorado School of Mines, 2004
[41]
Strausta K H. DD Patent , 120185-A, 1976-06-05
[42]
Vereinigte A W. FR Patent, 2.117.930-A, 1971-12-07
[43]
Wang J, Zhao P. Method of dealkalizing red mud and recovering aluminum and iron. Google patents, 2013
[44]
Agatzini-Leonardou S, Oustadakis P, Tsakiridis P E, Markopoulos C. Titanium leaching from red mud by diluted sulfuric acid at atmospheric pressure. Journal of Hazardous Materials, 2008, 157(2-3): 579–586
CrossRef Google scholar
[45]
Erçağ E, Apak R. Furnace smelting and extractive metallurgy of red mud: Recovery of TiO2, Al2O3 and pig iron. Journal of Chemical Technology and Biotechnology (Oxford, Oxfordshire), 1997, 70(3): 241–246
CrossRef Google scholar
[46]
Mehta S, Patel S. Recovery of titania from the bauxite sludge. Journal of the American Chemical Society, 1951, 73(1): 226–227
CrossRef Google scholar
[47]
Xiang Q, Liang X, Schlesinger M, Watson J. Low-temperature reduction of ferric iron in red mud. TMS (The Minerals, Metals and Materials Society). 2001
[48]
Liu Y, Zhao B, Tang Y, Wan P, Chen Y, Lv Z. Recycling of iron from red mud by magnetic separation after co-roasting with pyrite. Thermochimica Acta, 2014, 588: 11–15
CrossRef Google scholar
[49]
Binnemans K, Jones P T, Blanpain B, Gerven T P, Pontikes Y. Towards zero waste valorization of rare earth-containing-industrial process residues: A critical review. Journal of Cleaner Production, 2015, 99: 17–38
CrossRef Google scholar
[50]
Wagh A S, Pinnock W R. Occurrence of scandium and rare earth elements in Jamaican Bauxite waste. Economic Geology and the Bulletin of the Society of Economic Geologists, 1987, 82(3): 757–761
CrossRef Google scholar
[51]
Borra C R, Pontikes Y, Binnemans K, Gerven T V. Leaching of rare earths from bauxite residue (red mud). Minerals Engineering, 2015, 76: 20–27
CrossRef Google scholar
[52]
Wang W, Cheng C Y. Separation and purification of scandium by solvent extraction and related technologies: A review. Journal of Chemistry and Biotechnology, 2011, 86(10): 1237–1246
CrossRef Google scholar
[53]
Yatsenko S P, Pyagai I N. Red mud pulp carbonization with scandium extraction during alumina production. Theoretical Foundations of Chemical Engineering, 2010, 44(4): 563–568
CrossRef Google scholar

RIGHTS & PERMISSIONS

2017 Higher Education Press and Springer-Verlag Berlin Heidelberg
AI Summary AI Mindmap
PDF(409 KB)

Accesses

Citations

Detail

Sections
Recommended

/