Combustion mechanism development and CFD simulation for the prediction of soot emission during flaring
Anan Wang , Helen H. Lou , Daniel Chen , Anfeng Yu , Wenyi Dang , Xianchang Li , Christopher Martin , Vijaya Damodara , Ajit Patki
Front. Chem. Sci. Eng. ›› 2016, Vol. 10 ›› Issue (4) : 459 -471.
Combustion mechanism development and CFD simulation for the prediction of soot emission during flaring
Industrial Flares are important safety devices to burn off the unwanted gas during process startup, shutdown, or upset. However, flaring, especially the associated smoke, is a symbol of emissions from refineries, oil gas fields, and chemical processing plants. How to simultaneously achieve high combustion efficiency (CE) and low soot emission is an important issue. Soot emissions are influenced by many factors. Flare operators tend to over-steam or over-air to suppress smoke, which results in low CE. How to achieve optimal flare performance remains a question to the industry and the regulatory agencies. In this paper, regulations in the US regarding flaring were reviewed. In order to determine the optimal operating window for the flare, different combustion mechanisms related to soot emissions were summarized. A new combustion mechanism (Vsoot) for predicting soot emissions was developed and validated against experimental data. Computational fluid dynamic (CFD) models combined with Vsoot combustion mechanism were developed to simulate the flaring events. It was observed that simulation results agree well with experimental data.
flare / soot emission / combustion mechanism / CFD simulation
| [1] |
|
| [2] |
|
| [3] |
U.S. EPA. 2009 Final Report: Integrated Science Assessment for Particulate Matter. 2009 |
| [4] |
United States Government Code of Federal Regulations‒Standards of Performance for New Stationary Sources, General Control Device and Work Practice Requirements, 40CFR § 60.18. Available at: lt;Date>accessed in April, 2016</Date>) |
| [5] |
U.S. EPA. 40 CFR Ch. I (7–1–09 Edition), Pt. 60, App. A–4, Meth. 9.: Method 9-Visual determination of the opacity of emissions from stationary sources. Available at: lt;Date>accessed in April, 2016</Date>) |
| [6] |
U.S. EPA Office of Air Quality Planning and Standards (OAQPS). Parameters for properly designed and operated flares, report for flare review panel, 2012. Available at: lt;Date>accessed in April, 2016</Date>) |
| [7] |
|
| [8] |
|
| [9] |
|
| [10] |
|
| [11] |
|
| [12] |
|
| [13] |
|
| [14] |
|
| [15] |
|
| [16] |
|
| [17] |
|
| [18] |
Fine Particulate Matter National Ambient Air Quality Standards. State Implementation Plan Requirements; Proposed Rule. Available at: lt;Date>accessed in April, 2016</Date>) |
| [19] |
|
| [20] |
2013 Emissions Inventory Guidelines. Available at: lt;Date>accessed in April, 2016</Date>) |
| [21] |
Fact sheet proposed petroleum refinery risk and technology review and new source performance standards. Available at: lt;Date>accessed in April, 2016</Date>) |
| [22] |
EPA’s strategy for reducing methane and ozone-forming pollution from the oil and natural gas industry. Available at: lt;Date>accessed in April, 2016</Date>) |
| [23] |
EPA. 40 CFR Parts 60 and 63. Petroleum Refinery Sector Risk and Technology Review and New Source Performance Standards. Available at: lt;Date>accessed in April, 2016</Date>) |
| [24] |
Guide, ANSYS FLUENT USER. Release 14.5, ANSYS. Inc., 2012 |
| [25] |
|
| [26] |
|
| [27] |
|
| [28] |
|
| [29] |
|
| [30] |
|
| [31] |
|
| [32] |
|
| [33] |
|
| [34] |
|
| [35] |
|
| [36] |
|
| [37] |
|
| [38] |
|
| [39] |
|
| [40] |
|
| [41] |
|
| [42] |
|
| [43] |
|
| [44] |
|
| [45] |
|
| [46] |
|
| [47] |
|
| [48] |
|
| [49] |
|
| [50] |
|
| [51] |
|
| [52] |
|
| [53] |
|
| [54] |
|
| [55] |
|
| [56] |
|
Higher Education Press and Springer-Verlag Berlin Heidelberg
/
| 〈 |
|
〉 |