Reduction of CeO₂ in composites with transition metal complex oxides under hydrogen containing atmosphere and its correlation with catalytic activity

Abstract

Reduction behavior of pure and doped CeO₂, the multi-phase La_0.6Sr_0.4CoO₃∙xCeO₂, La_0.8Sr_0.2MnO₃ ∙xCeO₂, and La_0.95Ni_0.6Fe_0.4O₃∙xCeO₂ composites, was studied under hydrogen containing atmosphere to address issues related to the improvement of electrochemical and catalytic performance of electrodes in fuel cells. The enhanced reduction of cerium oxide was observed initially at 800°C in all composites in spite of the presence of highly reducible transition metal cations that could lead to the increase in surface concentration of oxygen vacancies and generation of the electron enriched surface. Due to continuous reduction of cerium oxide in La_0.6Sr_0.4CoO₃∙xCeO₂ and La_0.8Sr_0.2MnO₃∙xCeO₂ (up to 10 h) composites the redox activity of the Ce⁴⁺/Ce³⁺ pair could be suppressed and additional measures are required for reversible spontaneous regeneration of Ce⁴⁺. After 3 h exposure to H₂-Ar at 800°C the reduction of cerium oxides and perovskite phases in La_0.95Ni_0.6Fe_0.4O₃∙xCeO₂ composites was diminished. The extent of cerium oxide involvement in the reduction process varies with time, and depends on its initial deviation from oxygen stoichiometry (that results in the larger lattice parameter and the longer pathway for O^2- transport through the fluorite lattice), chemical origin of transition metal cations in the perovskite, and phase diversity in multi-phase composites.

Keywords

reduction of cerium oxide / composites / perovskites / catalyst under hydrogen containing atmosphere

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Acknowledgments

The authors gratefully acknowledge Dr. S. M. Frances for XPS measurements and Prof. J. T. S. Irvine for his kind support.

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2014 Higher Education Press and Springer-Verlag Berlin Heidelberg