Effective regeneration of thermally deactivated commercial V-W-Ti catalysts

Abstract

An effective method for the regeneration of thermally deactivated commercial monolith SCR catalysts was investigated. Two types of regenerated solutions, namely NH₄Cl (1 mol/L) and dilute H₂SO₄ (0.5 mol/L), were employed to treat the used catalyst. The effects of temperature and the regeneration process on the structural and textural properties of the catalysts were determined by X-ray diffraction, scanning electron microscopy, N₂ adsorption/desorption, elemental analysis and Fourier transform infrared spectroscopy. The results suggest that the anatase phase of the used catalyst is maintained after exposure to high temperatures. Some of the catalytic activity was restored after regeneration. The catalyst regenerated by aqueous NH₄Cl had a higher activity than that of the catalyst treated by dilute H₂SO₄. The main reason is that the NH₃ generated from the decomposition of NH₄Cl at high temperatures can be adsorbed onto the catalyst which promotes the reaction. The aggregated V₂O₅ were partially re-dispersed during the regeneration process, and the intrinsic oxidation of ammonia with high concentrations of O₂ is a factor that suppresses the catalytic activity.

Keywords

V₂O₅-WO₃/TiO₂ catalysts / thermal deactivation / regeneration / NH₄Cl / dilute H₂SO₄ solution

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Acknowledgments

This research was financially supported by the National Key Technology Program of China (Grant No. 2008BAC32B03) and the Science Foundation of the Fujian Province (No. 2011J01060).

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2014 Higher Education Press and Springer-Verlag Berlin Heidelberg