Hydrogen production from methanol through dielectric barrier discharge
Baowei WANG, Xu ZHANG, Haiying BAI, Yijun LÜ, Shuanghui HU
Hydrogen production from methanol through dielectric barrier discharge
The hydrogen fuel cell is a promising option as a future energy resource and the production of hydrogen is mainly depended on fossil fuels now. In this paper, methanol reforming to produce H2 through dielectric-barrier discharge (DBD) plasma reaction was studied. Effects of the power supply parameters, reactor parameters and process conditions on conversion of methanol and distribution of products were investigated. The best reaction conditions were following: input power (45 W), material of inner electrode (stainless steel), discharge gap (3.40 mm), length of reaction zone (90.00 mm), dielectric thickness (1.25 mm), and methanol content (37.65%). The highest conversion of methanol and the yield of H2 were 82.38% and 27.43%, respectively.
methanol / dielectric-barrier discharge / hydrogen / plasma
[1] |
Jiménez M, Yubero C, Calzada M D. Study on the reforming of alcohols in a surface wave discharge (SWD) at atmospheric pressure. Journal of Physics D: Applied Physics, 2008, 41: 175–201
|
[2] |
Li X S, Zhu A M, Wang K J, Xu Y, Song Z M. Methane conversion to C2 hydrocarbons and hydrogen in atmospheric non-thermal plasmas generated by different electric discharge techniques. Catalysis Today, 2004, 98(4): 617–624
CrossRef
Google scholar
|
[3] |
Indarto A. Hydrogen production from methane in a dielectric barrier discharge using oxide zinc and chromium as catalyst. Journal of the Chinese Institute of Chemical Engineers, 2008, 39: 23–28
|
[4] |
Sá S, Silva H, Sousa J M, Mendes A.Hydrogen production by methanol steam reforming in a membrane reactor: Palladium vs carbon molecular sieve membranes. Journal of Membrane Science, 2009, 339(1-2): 160–170
CrossRef
Google scholar
|
[5] |
Zong C Y, Chen L, Wang H L. Hydrogen generation by glow discharge plasma electrolysis of methanol solutions. International Journal of Hydrogen Energy, 2009, 34(1): 48–55
CrossRef
Google scholar
|
[6] |
Chang F W, Roselin L S, Ou T C. Hydrogen production by partial oxidation of methanol over bimetallic Au-Ru/Fe2O3 catalysts. Applied Catalysis A, General, 2008, 334(1-2): 147–155
CrossRef
Google scholar
|
[7] |
Indarto A, Yang D R, Palgunadi J, Choi J W, Lee H, Song H K. Partial oxidation of methane with Cu-Zn-Al catalyst in a dielectric barrier discharge. Chemical Engineering and Processing, 2008, 47(5): 780–786
CrossRef
Google scholar
|
[8] |
Besancon B M, Hasanov V, Imbault-Lastapis R, Beneschb R, Barrio M, Mølnvikc M J. Hydrogen quality from decarbonized fossil fuels to fuel cells. International Journal of Hydrogen Energy, 2009, 34(5): 2350–2360
CrossRef
Google scholar
|
[9] |
Das D, Veziroğlu T N. Hydrogen production by biological processes: a survey of literature. International Journal of Hydrogen Energy, 2001, 26(1): 13–28
CrossRef
Google scholar
|
[10] |
Take T, Tsurutani K, Umeda M. Hydrogen production by methanol-water solution electrolysis. Journal of Power Sources, 2007, 164(1): 9–16
CrossRef
Google scholar
|
[11] |
Gondal M A, Hameed A, Yamani Z H. Hydrogen generation by laser transformation of methanol using n-type WO3 semiconductor catalyst. Journal of Molecular Catalysis A: Chemical, 2004, 222(1-2): 259–264
CrossRef
Google scholar
|
[12] |
Medinsky M A, Dorman D C. Recent developments in methanol toxicity. Toxicology Letters, 1995, 82-83: 707–711
CrossRef
Google scholar
|
[13] |
Li H Q, Zou J J, Zhang Y P, Liu C J. Plasma methanol decomposition using corona discharges. Journal of Industrial and Engineering Chemistry (China), 2004, 55: 1989–1993 (in Chinese)
|
[14] |
Deminsky M, Jivotov V, Potapkin B, Rusanov V. Plasma-assisted production of hydrogen from hydrocarbons. Pure and Applied Chemistry, 2002, 74(3): 413–418
CrossRef
Google scholar
|
[15] |
Li H Q, Zou J J, Liu C J. Progress in hydrogen generation using plasmas. Progress in Chem, 2005, 17: 69–77
|
[16] |
Zong C Y, Chen L, Wang H L. Hydrogen generation by glow discharge plasma electrolysis of methanol solutions. International Journal of Hydrogen Energy, 2009, 34(1): 48–55
CrossRef
Google scholar
|
[17] |
Wang B W, Cao X L, Yang K H, Xu G H. Conversion of methane through dielectric-barrier discharge plasma. Frontiers of Chemical Engineering in China, 2008, 2(4): 373–378
CrossRef
Google scholar
|
[18] |
Xu D J, Li Z H, Lv J, Wang B W, Xu G H. Conversion of methane to C2 hydrocarbons through dielectric-barrier discharge plasma at low temperature and atmospheric pressure. Chem Reaction Eng & Tech, 2006, 22: 356–360 (in Chinese)
|
[19] |
Zhang X, Wang B W, Liu Y W, Xu G H. Conversion of methane by steam reforming using dielectric-barrier discharge. Chinese Journal of Chemical Engineering, 2009, 17(4): 625–629
CrossRef
Google scholar
|
[20] |
Kogelschatz U. Advanced ozone generation. Process Technologies for Water Treatment. Stucki S ed. New York & London: Plenum, 1988, 87–120
|
/
〈 | 〉 |