Kinetic studies of xylan hydrolysis of corn stover in a dilute acid cycle spray flow-through reactor

Abstract

Xylan of corn stover was pretreated with 1%, 2% and 3% (w/w) sulfuric acid at relatively low temperatures (90°C, 95°C and 100°C) in a dilute acid cycle spray flow-through reactor (DCF). The hydrolysis of xylan to its monomeric xylose was modeled by a series of first-order reactions. Both biphasic and Saeman hydrolysis models were applied to fit the experimental data. The results confirmed that the kinetic data of xylan hydrolysis fitted a first-order irreversible reaction model and the experimental data. The reaction rates of xylose monomer formation and degradation were sensitive to catalyst concentration and temperature. Higher catalyst concentration and lower reaction temperature result in high xylose yield. The activation energy for xylose formation and degradation were determined to be 112.9 and 101.0 kJ·mol^-1, respectively. Over 90% theoretical xylose obtained from corn stover can be used to produce ethanol, xylitol and fumaric acid by fermentation.

Keywords

corn stover / xylan hydrolysis / biphasic model / Saeman model / cycle spray / kinetics

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Acknowledgments

This work was funded by China Petroleum & Chemical Corporation, the National Natural Science Foundation of China (Grant No. 20876078), the United Foundation of NSFC and Guangdong Province (No. U0733001), the National Hi-Tech Research and Development Program of China (No. 2009AA02Z208).

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2014 Higher Education Press and Springer-Verlag Berlin Heidelberg