Effect of potassium carbonate on catalytic synthesis of calcium carbide at moderate temperature

Abstract

Calcium carbide was successfully synthesized by carbothermal reduction of lime with coke at 1973 K for 1.5 h. The effect of potassium carbonate as additive on the composition and morphology of the product was investigated using X-ray diffraction and scanning electron microscope. Addition of potassium carbonate increased the yield of calcium carbide. The sample in the presence of potassium carbonate generated acetylene gas of 168.3 L/kg, which was 10% higher than that in the absence of potassium carbonate. This result confirmed the catalytic effect of potassium carbonate on the synthesis of calcium carbide. A possible mechanism of the above effects was that the additive, which was melted at the reduction temperature, dissolved CaO and so promoted the contact between CaO and carbon, which was essential for the solid-solid reaction to form calcium carbide.

Keywords

calcium carbide / synthesis / catalysis

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Acknowledgments

XRD and SEM analyses were completed with the assistance of the Centre for Instrumental Analysis at China University of Petroleum. The research was financially supported by the Science and Technology Department of Qinghai Province.

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2014 Higher Education Press and Springer-Verlag Berlin Heidelberg