Salt-assisted synthesis of tree-like oriented SnO₂ nanodendrite

Abstract

Tree-like SnO₂ nanodendrites in large amounts have been prepared through two-step reactions. The nanoparticles used as the precursors have taken aggregation forming tree-like or string of nanodendrtie. The samples were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM) and energy dispersive spectrometer (EDS), respectively. The results showed that molar ratio of the ethanol/distilled water is an important factor for formation of the different dendrite structures. There are different morphologies between tree-like SnO₂ nanowhiskers and bunch of SnO₂ nanorods. However, they are growing along the \left[\mathrm{11}\overline{\mathrm{2}}\right].

Keywords

crystal morphology / nano-structures / nanodendrite

References

[1] Ahmadi T S, Wang Z L, Green T C, Henglein A, El-Sayed M A. Shape-controlled synthesis of colloidal platinum nanoparticles. Science, 1996, 272(5270): 1924–1925

[2] Ma Y, Qi L, Ma J, Cheng H. Hierarchical, star-shaped PbS crystals formed by a simple solution route. Crystal Growth & Design, 2004, 4(2): 351–354

[3] Lijlma S. Helical microtubules of graphitic carbon. Nature, 1991, 354(7): 56–58

[4] Pan Z, Dai Z, Wang Z. Nanobelts of semiconducting oxides. Science, 2001, 291(5510): 1947–1949

[5] Ng H T, Li J, Smith M K, Nguyen P, Cassell A, Han J, Meyyappan M. Growth of epitaxial nanowires at the junctions of nanowalls. Science, 2003, 300(5623): 1249–1253

[6] Kong X Y, Ding Y, Yang R. Single-crystal nanorings formed by epitaxial self-coiling of polar nanobelts. Science, 2004, 303(5662): 1348–1351

[7] Corso M, Auwärter W, Muntwiler M, Tamai A, Greber T, Osterwalder J. Boron nitride nanomesh. Scinece, 2004, 303(5655): 217–220

[8] Wang W, Yan D, Bratton D, Howdle S M, Wang Q, Lecomte P. Charge transfer complex inimer: a facile route to dendritic materials. Advanced Materials (Deerfield Beach, Fla.), 2003, 15(16): 1348–1352

[9] Frechet J M J. Functional polymers and dendrimers: reactivity, molecular architecture, and interfacial energy. Science, 1994, 263(5154): 1710–1715

[10] Yin L W, Li M S, Liu Y X, Xu B, Sui J L, Qi Y X. Unique single-crystalline beta carbon nitride nanorods. Advanced Materials (Deerfield Beach, Fla.), 2003, 15: 720–726

[11] Lu Q, Gao F, Komarneni S. Biomolecule-assisted synthesis of highly ordered snowflake like structures of bismuth sulfide nanorods. Journal of the American Chemical Society, 2004, 126(1): 54–55

[12] Jian J K, Chen X L, Wang W J, Dai L, Xu Y P. Growth and morphologies of large-scale SnO₂ nanowires, nanobelts and nanodendrites. Applied Physics. A, Materials Science & Processing, 2003, 76: 291–294

[13] Cölfen H, Qi L, Mastai Y, Borger L. Formation of unusual 10-petal BaSO₄ structures in the presence of a polymeric additive. Crystal Growth & Design, 2002, 2(3): 191–196

[14] Amin N, Isaka T, Yamada A, Konagai M. Highly effcient 1μm thick CdTe solar cells with textured TCOs. Solar Energy Materials and Solar Cells, 2001, 67(1-4): 195–201

[15] Law M, Kind H, Messer B, Messer B, Kim F, Yang P. Photochemical sensing of NO₂ with SnO₂ nanoribbon nanosensors at room temperature. Angewandte Chemie International Edition, 2002, 41(13): 2405–2408

[16] Wang C, Hu Y, Qian Y, Zhao G. A novel method to prepare nanocrystalline SnO₂. Nanostructured Materials, 1996, 7(4): 421–427

[17] Nagano M. Growth of SnO₂ whiskers by VLS mechanism. Journal of Crystal Growth, 1984, 66(2): 377–379

[18] Liu Y K, Zheng C L, Wang W Z, Zhan Y J. Production of SnO₂ nanorods by redox reaction. Journal of Crystal Growth, 2001, 233(1-2): 8–12

[19] Xu C, Zhao X, Liu S, Wang G. Large-scale synthesis of rutile SnO₂ nanorods. Solid State Communications, 2003, 125(6): 301–304

[20] Zhang D F, Sun L D, Yin J L, Yan C H, Wang R M. Attachment-driven morphology evolvement of rectangular ZnO nanowires. Journal of Physical Chemistry B, 2005, 109(18): 8786–8790

[21] Zhu J, Lu Z, Aruna S T, Aurbach D, Gedanken A. Sonochemical synthesis of SnO₂ nanoparticles and their preliminary study as Li insertion electrodes. Chemistry of Materials, 2000, 12 (9): 2557–2566

[22] Wang W, Xu C, Wang G, Liu Y, Zheng C. Synthesis and Raman scattering study of rutile SnO₂ nanowires. Journal of Applied Physics, 2002, 92(5): 2740–2742

[23] Zheng M, Li G, Zhang X, Huang S, Lei Y, Zhang L. Fabrication and structural characterization of large-scale uniform SnO₂ nanowire array embedded in anodic alumina membrane. Chemistry of Materials, 2001, 13(11): 3859–3861

[24] Zhang D F, Sun L D, Yin J L, Yan C H. Low-temperature fabrication of highly crystalline SnO₂ nanorods. Advanced Materials (Deerfield Beach, Fla.), 2003, 15(12): 1022–1025

[25] Li F, Chen L, Chen Z, Xu J, Zhu J, Xin X. Two-step solid-state synthesis of tin oxide and its gas-sensing property. Materials Chemistry and Physics, 2002, 73(2-3): 335–338

[26] W J B, Kaner R B. Rapid solid-state precursor synthesis of materials. Science, 1992, 255(5048): 1093–1097

[27] Wu N L, Wang S Y, Rusakova I A. Inhibition of crystallite growth in the sol-gel synthesis of nanocrystalline metal oxides. Science, 1999, 285(5432): 1375–1377

[28] Penn R L, Banfield J F. Imperfect oriented attachment: dislocation generation in defect-free nanocrystals. Science, 1998, 281(5379): 969–971

[29] Ye X R, Jian D Z, Yu J Q, Xin X Q, Xue Z. One step solid-state reactions at ambient temperature—a novel approach to nanocrystal synthesis. Advanced Materials, 1999, 11(11): 941–942

[30] Tang Z Y, Kotov N A, Giersig M. Spontaneous organization of single CdTe nanoparticles into luminescent nanowires. Science, 2002, 297(5579): 237–240

Acknowledgments

This work was supported by grants from the Program of Science and Technology Bureau of Qingdao (NO. 08-1-3-14-JCH).

RIGHTS & PERMISSIONS

2014 Higher Education Press and Springer-Verlag Berlin Heidelberg