The effect of capping with natural and modified zeolites on the release of phosphorus and organic contaminants from river sediment

Abstract

A microcosm system that included river sediment, water and different zeolite capping materials (natural zeolite, surfactant-modified zeolite (SMZ), or aluminum modified zeolite (AMZ)) was designed to study the effect of capping on the release of phosphorus and three organic pollutants (phenol, pyridine, and pyrene) from the sediment to the overlying water over the course of three month. For the same amount of the three capping materials, the efficiency of phosphorus inactivation was in the order of SMZ>AMZ>natural zeolite. The inactivation of phosphorus was mainly caused by the covering effect, co-precipitation and adsorption by the capping materials. The different zeolites gave different results for the release of phenol, pyridine, and pyrene from the sediment. When natural zeolite was used as the capping material, there was no effect on the release of pyrene and pyridine, whereas capping the sediment with SMZ or AMZ inhibited the release of pyrene and pyridine but to different extents. However, for controlling the release of phenol from the sediment, aluminum modified zeolite was the most efficient material, whereas no effects were observed when natural zeolite or SMZ were used. The different capabilities of the zeolite materials for controlling the release of different organic pollutants are related to the differences in the electrical properties of these pollutants.

Keywords

sediment / capping / natural zeolite / modified zeolite / phosphorus

References

[1] Søndergaard M, Jensen J P, Jeppesen E. Internal phosphorus loading in shallow Danish lakes. Hydrobiologia, 1999, 408-409: 145–152

[2] McQueen D J, Lean D R S, Charlton M N. The effects of hypolimnetic aeration on iron-phosphorus interactions. Water Research, 1986, 20(9): 1129–1135

[3] Peterson S A. Lake restoration by sediment removal. Water Resources Bulletin, 1982, 18: 423–435

[4] Salonen V P, Varjo E. Gypsum treatment as a restoration method for sediments of eutrophied lakes—experiments from southern Finland. Environmental Geology, 2000, 39(3-4): 353–359

[5] Jaeger D. Effects of hypolimnetic water aeration and ironphosphate precipitation on the trophic level of Lake Krupunder. Hydrobiologia, 1994, 275-276(1): 433–444

[6] Reitzel K, Hansen J, Andersen F Ø, Hansen K S, Jensen H S. Lake restoration by dosing aluminum relative to mobile phosphorus in the sediment. Environmental Science & Technology, 2005, 39(11): 4134–4140

[7] Reitzel K, Hansen J, Jensen H S, Anderson F Ø, Hansen K S. Testing aluminum addition as a tool for lake restoration in shallow, eutrophic Lake Sønderby, Denmark. Hydrobiologia, 2003, 506-509(1-3): 781–787

[8] Jacobs P H, Förstner U. Concept of subaqueous capping of contaminated sediments with active barrier systems (ABS) using natural and modified zeolites. Water Research, 1999, 33(9): 2083–2087

[9] Ghiaci M, Kia R, Abbaspur A, Seyedeyn-Azad F. Adsorption of chromate by surfactant-modified zeolites and MCM-41 molecular sieve. Separation and Purification Technology, 2004, 40(3): 285–295

[10] Erdem E, Karapinar N, Donat R. The removal of heavy metal cations by natural zeolites. J Coll Int Sci, 2004, 280(2): 309–314

[11] Murayama N, Yoshida S, Takami Y, Yamamoto H, Shibata J. Simultaneous removal of NH4+ and PO43- in aqueous solution and its mechanism by using zeolites synthesized from coal fly ash. Separation Science and Technology, 2003, 38(1): 113–130

[12] Wild D, Kisliakova A, Siegrist H. P-fixation by Mg, Ca and zeolites during a stabilization of excess sludge from enhanced biological P-removal. Water Science and Technology, 1996, 34(1-2): 391–398

[13] Bowman R S. Applications of surfactant-modified zeolites to environmental remediation. Microporous and Mesoporous Materials, 2003, 61(1-3): 43–56

[14] Li Z, Roy S J, Zou Y, Bowman R S. Long-term chemical and biological stability of surfactant-modified zeolite. Environmental Science & Technology, 1998, 32(17): 2628–2632

[15] Institute of Soil Science, Chinese Academy of Sciences. Physico-Chemistry Analysis of Soil. Shanghai: Shanghai Science and Technology Publishing Company, 1978, 35–45 (in Chinese)

[16] Ruban V, Brigault S, Demare D, Philippe A M. An investigation of the origin and mobility of phosphorus in freshwater sediments from Bort-Les-Orgues Reservoir, France. Journal of Environmental Monitoring, 1999, 1(4): 403–407

[17] Tan K H. Soil Sampling, Preparation and Analysis. New York: Marcel Dekker, 1995, 138–142

[18] Haggerty G M, Bowman R S. Sorption of chromate and other inorganic anions by organo-zeolite. Environmental Science & Technology, 1994, 28(3): 452–458

[19] Li Z, Burt T, Bowman R S. Sorption of ionizable organic solutes by surfactant-modified zeolite. Environmental Science & Technology, 2000, 34(17): 3756–3760

[20] Zhang H, Zhou M, Shao K. Study on the removal of phosphate from water by modified zeolite. Environmental Pollution Control, 2005, 27(4): 137–138 (in Chinese)

[21] APHA. AWWA, WEF. Standard Methods for the Examination of Water and Wastewater, 19th ed. Washington DC: American Public Health Association, 1995, 4–113

[22] Wingenfelder U, Furrer G, Schulin R. Sorption of antimonate by HDTMA-modified zeolite. Microporous and Mesoporous Materials, 2006, 95(1-3): 265–271

[23] Komarowski S, Yu Q. Ammonium ion removal from wastewater using australian natural zeolite: batch equilibrium and kinetic studies. Environmental Technology, 1997, 18(11): 1085–1097

[24] Widiastuti N, Wu H, Ang H M, Zhang D. The potential application of natural zeolite for greywater treatment. Desalination, 2008, 218(1-3): 271–280

[25] Subramanyam B, Das A. Study of the adsorption of phenol by two soils based on kinetic and isotherm modeling analyses. Desalination, 2009, 249(3): 914–921

[26] Zhang J, Xie S, Ho Y S. Removal of fluoride ions from aqueous solution using modified attapulgite as adsorbent. Journal of Hazardous Materials, 2009, 165(1-3): 218–222

[27] Zhu L, Li Y, Zhang J. Sorption of organobentonites to some organic pollutants in water. Environmental Science & Technology, 1997, 31(5): 1407–1410

Acknowledgments

This study was supported by the National Natural Science Foundation of China (Grant Nos. 20677031, 20737002).

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2014 Higher Education Press and Springer-Verlag Berlin Heidelberg