Preparation of Cu/ZnO/Al₂O₃ catalyst under microwave irradiation for slurry methanol synthesis

Abstract

Cu/ZnO/Al₂O₃ catalysts with Cu/Zn/Al ratios of 6/3/1 were precipitated and aged by conventional and microwave heating methods and tested in the slurry phase reactor for methanol synthesis. The effect of technological condition of precipitation and aging process under microwave irradiation on the catalytic performance was investigated to optimize the preparing condition of Cu/ZnO/Al₂O₃ catalyst. The results showed that the microwave irradiation during precipitation process could improve the activity of the catalyst, but had little effect on the stability. While the microwave irradiation during aging process has a great benefit to both the activity and stability of the catalyst, the catalyst aged at 80°C for 1 h under microwave irradiation possessed higher methanol space time yield (STY) and more stable catalytic activity. The activity and stability of the catalyst was further enhanced when microwave irradiation was used in both precipitation and aging processes; the optimized condition for the catalyst precursor preparation was precipitation at 60°C and aging at 80°C under microwave irradiation.

Keywords

microwave irradiation / precipitation temperature / aging temperature / methanol synthesis / Cu/ZnO/Al₂O₃ catalyst

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Acknowledgments

This work was supported by the National Basic Research Program of China (Grant No. 2005CB221204).

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2014 Higher Education Press and Springer-Verlag Berlin Heidelberg