High-Performance Stable Hybrid Inorganic-Organic Light-Emitting Transistor

Huixue Huang , Zhagen Miao , Haikuo Gao , Jin Cao , Yanqiong Zheng , Can Gao , Xifeng Li , Guangcai Yuan , Huanli Dong

SmartMat ›› 2025, Vol. 6 ›› Issue (1) : e1321

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SmartMat ›› 2025, Vol. 6 ›› Issue (1) : e1321 DOI: 10.1002/smm2.1321
RESEARCH ARTICLE

High-Performance Stable Hybrid Inorganic-Organic Light-Emitting Transistor

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Abstract

Light-emitting transistors (LETs) as novel integrated optoelectronic devices demonstrate great potential applications in smart displays and visual intelligent perception. The construction of high-performance area-emission LETs with low power consumption and good reliability is urgently needed for advancing their applications, however, this integration has not been realized within a single device. Herein, we demonstrate a kind of planar-driven hybrid LET (PDHLET) that makes use of the unique advantages of high mobility and stability of inorganic and organic semiconductors in the same device. By incorporating an indium-zinc-gallium-oxide (InZnGeO) conducting layer and organic emissive layer, a high-performance stable blue-emissive PDHLET is constructed, giving a high Ion/Ioff ratio approaching 6.1 × 108 and a low Von of 5.5 V along with maximum brightness of 1264 cd/m2 as well as small VTH shift of 0.5 V after 1000 s positive stress bias. Finally, a systematic simulation, including charge concentration and Langevin recombination rate, is carried out on PDHLET for the first time, demonstrating good consistency with experimental results. This confirms the uniformity of high redistributed charge concentration in the InZnGeO conducting layer which thus enables good area emission. This study provides a new avenue for constructing high-performance stable LETs to advance various field applications.

Keywords

area emission / good stability / high performance / hybrid planar-driven structure / light-emitting transistor

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Huixue Huang, Zhagen Miao, Haikuo Gao, Jin Cao, Yanqiong Zheng, Can Gao, Xifeng Li, Guangcai Yuan, Huanli Dong. High-Performance Stable Hybrid Inorganic-Organic Light-Emitting Transistor. SmartMat, 2025, 6(1): e1321 DOI:10.1002/smm2.1321

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References

[1]

R. Capelli, S. Toffanin, G. Generali, H. Usta, A. Facchetti, and M. Muccini, “Organic Light-Emitting Transistors With an Efficiency That Outperforms the Equivalent Light-Emitting Diodes,” Nature Materials 9, no. 6 (2010): 496–503.

[2]

C. Zhang, P. Chen, and W. Hu, “Organic Light-Emitting Transistors: Materials, Device Configurations, and Operations,” Small 12, no. 10 (2016): 1252–1294.

[3]

C. F. Liu, X. Liu, W. Y. Lai, and W. Huang, “Organic Light-Emitting Field-Effect Transistors: Device Geometries and Fabrication Techniques,” Advanced Materials 30, no. 52 (2018): 1802466–1802500.

[4]

Z. Qin, H. Gao, H. Dong, and W. Hu, “Organic Light-Emitting Transistors Entering a New Development Stage,” Advanced Materials 33, no. 31 (2021): 2007149–2007166.

[5]

H. Yu, S. Ho, N. Barange, R. Larrabee, and F. So, “Semi-Transparent Vertical Organic Light-Emitting Transistors,” Organic Electronics 55, no. 55 (2018): 126–132.

[6]

H. Gao, Z. Miao, Z. Qin, et al., “Redistributed Current Density in Lateral Organic Light-Emitting Transistors Enabling Uniform Area Emission With Good Stability and Arbitrary Tunability,” Advanced Materials 34, no. 8 (2022): 2108795–2108804.

[7]

J. Liu, H. Zhang, H. Dong, et al., “High Mobility Emissive Organic Semiconductor,” Nature Communications 6, no. 1 (2015): 10032–10049.

[8]

Z. Qin, C. Gao, H. Gao, T. Wang, H. Dong, and W. Hu, “Molecular Doped, Color-Tunable, High-Mobility, Emissive, Organic Semiconductors for Light-Emitting Transistors,” Science Advances 8, no. 27 (2022): 8775–8783.

[9]

D. Liu, J. De, H. Gao, et al., “Organic Laser Molecule With High-Mobility, High Photoluminescence Quantum Yield and Deep-Blue Lasing Characteristics,” Journal of the American Chemical Society 142, no. 13 (2020): 6332–6339.

[10]

J. Deng, Z. Zhang, P. Sang, et al., “Organic Single-Crystal Light-Emitting Transistors With External Quantum Efficiency Over 20%,” Aggregate 4, no. 4 (2023): 313–319.

[11]

Y. Hu, L. Song, S. Zhang, et al., “Improving the Efficiency of Multilayer Organic Light-Emitting Transistors by Exploring the Hole Blocking Effect,” Advanced Materials Interfaces 7, no. 17 (2020): 2000657–2000665.

[12]

L. Liu, C. Cai, Z. Zhang, et al., “Lamellar Organic Light-Emitting Crystals Exhibiting Spectral Gain and 3.6% External Quantum Efficiency in Transistors,” ACS Materials Letters 3, no. 4 (2021): 428–432.

[13]

H. Gao, J. Liu, Z. Qin, et al., “High-Performance Amorphous Organic Semiconductor-Based Vertical Field-Effect Transistors and Light-Emitting Transistors,” Nanoscale 12, no. 35 (2020): 18371–18378.

[14]

M. A. McCarthy, B. Liu, E. P. Donoghue, et al., “Low-Voltage, Low-Power, Organic Light-Emittin. Transistors for Active Matrix Displays,” Science 332, no. 6029 (2011): 570–573.

[15]

Z. Wu, Y. Liu, E. Guo, et al., “Efficient and Low-Voltage Vertical Organic Permeable Base Light-Emitting Transistors,” Nature Materials 20, no. 7 (2021): 1007–1014.

[16]

Z. Miao, C. Gao, H. Gao, Z. Qin, W. Hu, and H. Dong, “High-Efficiency Area-Emissive White Organic Light-Emitting Transistor for Full-Color Display,” Advanced Materials 36, no. 1 (2023): 2306725–2306733.

[17]

Y. J. Park, A. Song, B. Walker, J. H. Seo, and K. Chung, “Hybrid ZnON-Organic Light Emitting Transistors With Low Threshold Voltage < 5 V,” Advanced Optical Materials 7, no. 7 (2019): 1801290–1801296.

[18]

P. He, L. Lan, C. Deng, J. Wang, J. Peng, and Y. Cao, “Highly Efficient and Stable Hybrid Quantum-Dot Light-Emitting Field-Effect Transistors,” Materials Horizons 7, no. 9 (2020): 2439–2449.

[19]

K. Muhieddine, M. Ullah, B. N. Pal, P. Burn, and E. B. Namdas, “All Solution-Processed, Hybrid Light Emitting Field-Effect Transistors,” Advanced Materials 26, no. 37 (2014): 6410–6415.

[20]

B. Walker, M. Ullah, G. J. Chae, et al., “High Mobility Solution-Processed Hybrid Light Emitting Transistors,” Applied Physics Letters 105, no. 18 (2014): 183302–183307.

[21]

M. Ullah, Y. H. Lin, K. Muhieddine, S. C. Lo, T. D. Anthopoulos, and E. B. Namdas, “Hybrid Light-Emitting Transistors Based on Low-Temperature Solution-Processed Metal Oxides and a Charge-Injecting Interlayer,” Advanced Optical Materials 4, no. 2 (2016): 231–237.

[22]

M. U. Chaudhry, K. Tetzner, Y. H. Lin, et al., “Low-Voltage Solution-Processed Hybrid Light-Emitting Transistors,” ACS Applied Materials & Interfaces 10, no. 22 (2018): 18445–18449.

[23]

A. Ablat, A. Kyndiah, A. Bachelet, et al., “Low Optical Turn-On Voltage in Solution Processed Hybrid Light Emitting Transistor,” Applied Physics Letters 115, no. 2 (2019): 023301–023306.

[24]

M. Nag, S. Steudel, A. Bhoolokam, et al., “High Performance a-IGZO Thin-Film Transistors With mf-PVD SiO2 as an Etch-Stop-Layer,” Journal of the Society for Information Display 22, no. 1 (2014): 23–28.

[25]

C. Peng, M. Xu, L. Chen, X. Li, and J. Zhang, “Improvement of Properties of Top-Gate IGZO TFT by Oxygen-Rich Ultrathin In Situ ITO Active Layer,” Japanese Journal of Applied Physics 61, no. 7 (2022): 070914–070918.

[26]

Y. Kim, M. Bae, W. Kim, et al., “Amorphous InGaZnO Thin-Film Transistors-Part I: Complete Extraction of Density of States Over the Full Subband-Gap Energy Range,” IEEE Transactions on Electron Devices 59, no. 10 (2012): 2689–2698.

[27]

T. H. Chiang, B. S. Yeh, and J. F. Wager, “Amorphous IGZO Thin-Film Transistors With Ultrathin Channel Layers,” IEEE Transactions on Electron Devices 62, no. 11 (2015): 3692–3696.

[28]

E. G. Lee, J. Park, S. E. Lee, et al., “Oxygen Radical Control Via Atmospheric Pressure Plasma Treatment for Highly Stable IGZO Thin-Film Transistors,” IEEE Transactions on Electron Devices 67, no. 8 (2020): 3135–3140.

[29]

Y. H. Joo, J. H. Wi, W. J. Lee, et al., “Work Function Tuning of Zinc-Tin Oxide Thin Films Using High-Density O2 Plasma Treatment,” Coatings 10, no. 11 (2020): 1026–1034.

[30]

C. Y. Lee, Y. H. Joo, M. P. Kim, D. S. Um, and C. I. Kim, “Etching Characteristics and Changes in Surface Properties of IGZO Thin Films by O2 Addition in CF4/Ar Plasma,” Coatings 11, no. 8 (2021): 906–916.

[31]

H. Kim, C. Han, D. Kim, and B. Choi, “Electrical Performance and Reliability Enhancement of a-IGZO TFTS Via Post-N2O Plasma Optimization,” IEEE Transactions on Electron Devices 70, no. 7 (2023): 3611–3616.

[32]

S. Knobelspies, A. Takabayashi, A. Daus, G. Cantarella, N. Münzenrieder, and G. Tröster, “Improvement of Contact Resistance in Flexible a-IGZO Thin-Film Transistors by CF4/O2 Plasma Treatment,” Solid-State Electronics 150, no. 150 (2018): 23–27.

[33]

A. Sharma, R. Abdur, D. Kim, et al., “Effect of Ge Doping on the Electrical Properties of Amorphous Zn-Sn-O Thin Films,” Current Applied Physics 20, no. 9 (2020): 1041–1048.

[34]

C. Peng, S. Yang, C. Pan, X. Li, and J. Zhang, “Effect of Two-Step Annealing on High Stability of a-IGZO Thin-Film Transistor,” IEEE Transactions on Electron Devices 67, no. 10 (2020): 4262–4268.

[35]

W. S. Liu, C. L. Huang, Y. H. Lin, C. H. Hsu, and Y. M. Chu, “Improving Device Characteristics of IGZO Thin-Film Transistors by Using Pulsed DC Magnetron Sputtering Deposition,” Semiconductor Science and Technology 35, no. 2 (2020): 025004–025031.

[36]

E. L. Ratcliff, A. K. Sigdel, M. R. Macech, et al., “Surface Composition, Work Function, and Electrochemical Characteristics of Gallium-Doped Zinc Oxide,” Thin Solid Films 520, no. 17 (2012): 5652–5663.

[37]

J. W. Shim, C. Fuentes-Hernandez, A. Dindar, Y. Zhou, T. M. Khan, and B. Kippelen, “Polymer Solar Cells With NiO Hole-Collecting Interlayers Processed by Atomic Layer Deposition,” Organic Electronics 14, no. 11 (2013): 2802–2808.

[38]

C. Oh, T. Kim, M. W. Ju, et al., “Influence of Channel Surface With Ozone Annealing and UV Treatment on the Electrical Characteristics of Top-Gate InGaZnO Thin-Film Transistors,” Materials 16, no. 18 (2023): 6161–6175.

[39]

J. Y. Lee, G. Tarsoly, S. G. Choi, H. G. Ryu, and S. J. Kim, “Influences of Oxygen Plasma Posttreatment on Electrical Characteristics of Amorphous Indium-Gallium-Zinc-Oxide Thin-Film Transistors,” Physica Status Solidi (A) 218, no. 19 (2021): 2100205–2100213.

[40]

R. N. Bukke, C. Avis, and J. Jang, “Solution-Processed Amorphous In-Zn-Sn Oxide Thin-Film Transistor Performance Improvement by Solution-Processed Y2O3 Passivation,” IEEE Electron Device Letters 37, no. 4 (2016): 433–436.

[41]

S. I. Cho, J. B. Ko, S. H. Lee, J. Kim, and S. H. K. Park, “Remarkably Stable High Mobility Self-Aligned Oxide TFT by Investigating the Effect of Oxygen Plasma Time During PEALD of SiO2 Gate Insulator,” Journal of Alloys and Compounds 893, no. 893 (2022): 162308–162317.

[42]

S. Choi, J. Park, S. H. Hwang, et al., “Excessive Oxygen Peroxide Model-Based Analysis of Positive-Bias-Stress and Negative-Bias-Illumination-Stress Instabilities in Self-Aligned Top-Gate Coplanar In-Ga-Zn-O Thin-Film Transistors,” Advanced Electronic Materials 8, no. 5 (2022): 2101062–2101071.

[43]

R. Kobayashi, T. Nabatame, T. Onaya, et al., “Influence of Adsorbed Oxygen Concentration on Characteristics of Carbon-Doped Indium Oxide Thin-Film Transistors Under Bias Stress,” Japanese Journal of Applied Physics 60, no. SC (2021): SCCM01–SCCM06.

[44]

G. Lin, H. Peng, L. Chen, et al., “Improving Electron Mobility of Tetraphenylethene-Based AIEgens to Fabricate Nondoped Organic Light-Emitting Diodes With Remarkably High Luminance and Efficiency,” ACS Applied Materials & Interfaces 8, no. 26 (2016): 16799–16808.

[45]

Y. J. Park, A. R. Song, K. B. Chung, T. Y. Kim, B. Walker, and J. H. Seo, “Highly Efficient Hybrid Light-Emitting Transistors Incorporating MoOx/Ag/MoOx Semi-Transparent Electrodes,” Journal of Materials Chemistry C 10, no. 3 (2022): 880–885.

[46]

K. Muhieddine, M. Ullah, F. Maasoumi, P. L. Burn, and E. B. Namdas, “Hybrid Area-Emitting Transistors: Solution Processable and With High Aperture Ratios,” Advanced Materials 27, no. 42 (2015): 6677–6682.

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