Due to extreme poison, strong corrosion, and complex precipitation and deposition of H2S in the reservoir, it is very difficult and risky to investigate and explore drilling, completion, production and gas transportation. In the course of production of fractured gas reservoir with high H2S content, formation pressure falls continually, which lead to decline of solubility of sulfur particles in gas phase. Sulfur particles which dissolve in gas phase originally in the formation should precipitate from gas phase after running up to saturation state and deposit at pore space and throat, sequentially resulting in formation porosity and permeability reduction. At present, the researches of sulfur deposition are mainly focused on the conventional gas reservoirs and sulfur deposition in the near wellbore region is generally estimated using Roberts' model. However, most of the gas reservoirs with high-content H2S are fractured gas reservoirs, classical damage model is no longer applicable to fractured gas reservoirs with high H2S content. In the present study, a sulfur deposition damage model is established. The refined model, based on non-Darcy flow, takes into consideration the effects of sulfur deposition, variation in gas properties and fracture. In addition, the effect of gas well production rate on formation permeability is also studied. The results show that formation permeability decreases with fracture aperture and gas well production rate increasing. The bigger gas well production rate is, the quicker sulfur precipitates. The sulfur deposition of fractured gas reservoir with high-content H2S is mainly in the near wellbore zone, and the fracture aperture has a significant impact on the formation permeability in the near wellbore zone.
Acknowledgments
This work was Supported by a Sichuan Youth Science and Technology Innovative Research Team of Safe and Efficient Development of Sour Gas Reservoir (2014TD0009).
| [1] |
Guo Xiao, Du Zhimin, Chen Xiaofan, et al., New advancement of percolation study on fractured acid gas reservoir, Nat. Gas Ind. 26 (1) (2006) 30-33.
|
| [2] |
Du Zhimin, Oversea experiences of acid gas reservoir development and their enlightenments, Nat. Gas Ind. 26 (12) (2006) 35-37.
|
| [3] |
Haiyan Mei, Maolin Zhang, Xuefeng Yang, The Effect of Sulfur Deposition on Gas Deliverability, SPE 99700, 2006.
|
| [4] |
Guo Xiao, Du Zhimin, Mei Haiyan, et al., EOS-related Mathematical Model to Predict Sulfur Deposition and Cost-effective Approach of Removing Sulfides from Sour Natural Gas, SPE106614, 2007.
|
| [5] |
C.H. Kuo, On the production of hydrogen sulfide-sulfur mixtures from deep formations, SPE 3838-PA, J. Pet. Technol. (1972) 1142-1146.
|
| [6] |
E. Brunner, et al., Solubility of sulfur in hydrogen sulfide and sour gases, SPE 8778-PA, SPE J. (1980) 377-384.
|
| [7] |
C.H. Kuo, P.J. Colsmann, Theoretical study of fluid flow accompanied by solid precipitation in porous media, AICHE J. 12 (1966) 995.
|
| [8] |
B.E. Roberts, The Effect of Sulfur Deposition on Gas Well Inflow Performance, SPE 36707, 1996, pp. 285-296.
|
| [9] |
J. Chrastil, Solubility of solids and liquids in supercritical gases, J. Phys. Chem. 86 (15) (1982) 3016-3021.
|
| [10] |
E. Brunner, W. Woll, Solubility of sulfur in hydrogen sulfide and sour gases, Soc. Pet. Eng. J. (Oct.1980) 377-384.
|
| [11] |
E. Brunner, M.C. Place Jr. W. H. Woll, Sulfur solubility in sour gas, J. Pet. Technol. (Dec. 1988) 1587-1592.
|
| [12] |
A. Fadairo, C. Ako, O. Falode, Elemental sulphur induced formation damage management in gas reservoir. In: SPE International Conference on Oilfield Scale Held in Aberdeen, UK,May 30-31, 2012 (SPE paper 154980).
|
| [13] |
M. Mahmoud, A. Al-Majed, New model to predict formation damage due to sulfur deposition in sour Gas Wells, In: North Africa Technical Conference and Exhibition Held in Cairo, Egypt, 2012; 20e22 (SPE paper 149535).
|
| [14] |
N. Hands, B. Oz, B. Roberts, P. Davis, Advances in the Prediction and Management of Elemental Sulfur Deposition Associated with Sour Gas Production from Fractured Carbonate Reservoir, SPE 77332, 2002, pp. 1-18.
|
| [15] |
J.H. Hu, S.L. He, X.D. Wang, et al., The modeling of sulfur deposition damage in the presence of natural fracture, Pet. Sci. Technol. 31 (2013) 80-87.
|
| [16] |
Manping Yang, Caizhen Peng, Cuinan Li, Study of sulfur deposition model and its application of sour gas fields, J. Southwest Pet. Inst. 06 (2004) 54-56.
|
| [17] |
C. Luis,A Study of grand water flow in jointed rock and its influence on the stability of rock masses, in: Rock, Mech. Res. Rep. 10, Imperial College, London, England, 1969.
|