Uranium Isotope Variations (234U/238U and 238U/235U) and Behavior of U−Pb Isotope System in the Vershinnoe Sandstone-Type Uranium Deposit, Vitim Uranium Ore District, Russia

V. N. Golubev, I. V. Chernyshev, B. T. Kochkin, N. N. Tarasov, G. V. Ochirova, A. V. Chugaev

Journal of Earth Science ›› 2022, Vol. 33 ›› Issue (2) : 317-324.

Journal of Earth Science ›› 2022, Vol. 33 ›› Issue (2) : 317-324. DOI: 10.1007/s12583-021-1436-9
Article

Uranium Isotope Variations (234U/238U and 238U/235U) and Behavior of U−Pb Isotope System in the Vershinnoe Sandstone-Type Uranium Deposit, Vitim Uranium Ore District, Russia

Author information +
History +

Abstract

The U-Pb isotope system and uranium isotope composition (235U/238U and 234U/238U) were studied in a number of samples from the vertical section of the uranium ore body at the Vershinnoe sandstone-type deposit, Vitim uranium ore district, Russia. These parameters were determined to broadly vary. Deviations of the 234U/238U ratio from the equilibrium value indicate that the uranium ore was not completely conserved during the postore stage, and uranium was determined to continue migrating at the deposit. Comparison of the U−Pb isotope age value and 234U/238U isotope ratio provides an insight into the migrate direction of uranium in the ore body. The broad variations (137.377–137.772) in the 238U/235U ratio over the vertical section of the ore body can be explained by the different settings of the samples relative to the ore deposition front and changes in the redox conditions when this front shifted. The fact that the δ238U and K234/238 values are correlated indicates that the transfer of the 234U isotope into the aqueous phase may have been coupled with isotope fractionation in the 238U−235U system during the postformation uranium migration within the orebody.

Keywords

sandstone-type uranium deposit / U-Pb age / uranium isotope composition / ore deposit geology

Cite this article

Download citation ▾
V. N. Golubev, I. V. Chernyshev, B. T. Kochkin, N. N. Tarasov, G. V. Ochirova, A. V. Chugaev. Uranium Isotope Variations (234U/238U and 238U/235U) and Behavior of U−Pb Isotope System in the Vershinnoe Sandstone-Type Uranium Deposit, Vitim Uranium Ore District, Russia. Journal of Earth Science, 2022, 33(2): 317‒324 https://doi.org/10.1007/s12583-021-1436-9

References

Andersen M B, Stirling C H, Weyer S. Uranium Isotope Fractionation. Reviews in Mineralogy and Geochemistry, 2017, 82(1): 799-850.
CrossRef Google scholar
Basu A, Sanford R A, Johnson T M, . Uranium Isotopic Fractionation Factors during U(VI) Reduction by Bacterial Isolates. Geochimica et Cosmochimica Acta, 2014, 136: 100-113.
CrossRef Google scholar
Basu A, Brown S T, Christensen J N, . Isotopic and Geochemical Tracers for U(VI) Reduction and U Mobility at an in situ Recovery U Mine. Environmental Science & Technology, 2015, 49(10): 5939-5947.
CrossRef Google scholar
Bopp C J IV, Lundstrom C C, Johnson T M, . Variations in 238U/235U in Uranium Ore Deposits: Isotopic Signatures of the U Reduction Process?. Geology, 2009, 37(7): 611-614.
CrossRef Google scholar
Bopp C J IV, Lundstrom C C, Johnson T M, . Uranium 238U/235U Isotope Ratios as Indicators of Reduction: Results from an in situ Biostimulation Experiment at Rifle, Colorado, USA. Environmental Science & Technology, 2010, 44(15): 5927-5933.
CrossRef Google scholar
Cheng H, Edwards R L, Shen C C, . Improvements in 230Th Dating, 230Th and 234U Half-Life Values, and U−Th Isotopic Measurements by Multi-Collector Inductively Coupled Plasma Mass Spectrometry. Earth and Planetary Science Letters, 2013, 371/372: 82-91.
CrossRef Google scholar
Cherdyntsev, V. V., 1971. Uranium-234. Israel Program for Scientific Translations, Jerusalem. 338
Chernyshev I V, Golubev V N, Chugaev A V, . 238U/235U Isotope Ratio Variations in Minerals from Hydrothermal Uranium Deposits. Geochemistry International, 2014, 52(12): 1013-1029.
CrossRef Google scholar
Chernyshev I V, Dubinina E O, Golubev V N. Fractionation Factor of 238U and 235U Isotopes in the Process of Hydrothermal Pitchblende Formation: A Numerical Estimate. Geology of Ore Deposits, 2014, 56(5): 315-321.
CrossRef Google scholar
Chernyshev I V, Golubev V N, Chugaev A V, . Behavior of the 238U, 235U, and 234U Isotopes at Weathering of Volcanic Rocks with U Mineralization: A Case Study at the Tulukuevskoe Deposit, Eastern Transbaikalia. Petrology, 2019, 27(4): 407-424.
CrossRef Google scholar
Doynikova O A, Tarasov N N, Mokhov A V. A New Phosphatic Type of Uranium Deposits in Russia. Doklady Earth Sciences, 2014, 457(2): 910-914.
CrossRef Google scholar
Golubev V N, Chernyshev I V, Chugaev A V, . U−Pb Systems and U Isotopic Composition of the Sandstone-Hosted Paleovalley Dybryn Uranium Deposit, Vitim Uranium District, Russia. Geology of Ore Deposits, 2013, 55(6): 399-410.
CrossRef Google scholar
Golubev V N, Dubinina E O, Chernyshev I V, . Behavior of Isotope (18O/16O, 234U/238U) Systems during the Formation of Uranium Deposits of the “Sandstone” Type. Doklady Earth Sciences, 2016, 466(1): 28-31.
CrossRef Google scholar
Hiess J, Condon D J, McLean N, . 238U/235U Systematics in Terrestrial Uranium-Bearing Minerals. Science, 2012, 335(6076): 1610-1614.
CrossRef Google scholar
Jemison N E, Bizjack M T, Johnson T M, . Influence of Physical and Chemical Hydrology on Bioremediation of a U-Contaminated Aquifer Informed by Reactive Transport Modeling Incorporating 238U/235U Ratios. Geochimica et Cosmochimica Acta, 2020, 269: 303-328.
CrossRef Google scholar
Kochkin B T, Tarasov N N, Velichkin V I, . Iron Redistribution during Postore Stage at Uranium Deposits of the Khiagda Ore Field, Vitim District. Geology of Ore Deposits, 2014, 56(2): 113-127.
CrossRef Google scholar
Kochkin B T, Tarasov N N, Andreeva O V, . Polygenetic and Polychronic Uranium Mineralization at Deposits of the Khiagda Ore Field, Buryatia. Geology of Ore Deposits, 2017, 59(2): 141-155.
CrossRef Google scholar
Kochkin B T, Solodov I N, Ganina N I, . Geochemical Features of the Ore-Bearing Medium in Uranium Deposits in the Khiagda Ore Field. Geology of Ore Deposits, 2017, 59(5): 341-353.
CrossRef Google scholar
Mandzhieva G V, Sadasyuk A S, Chernyshev I V, . High-Precision Determination of the 238U/235U Isotope Ratio in Rocks by Multicollector Inductively Coupled Plasma Mass Spectrometry. Journal of Analytical Chemistry, 2018, 73(14): 1334-1342.
CrossRef Google scholar
Mashkovtsev G A, Konstantinov A K, Miguta A K, . Uran Rossiiskikh Nedr (Uranium in Russian Subsurface), 2010, Moscow: VIMS, 850 (in Russian)
Murphy M J, Stirling C H, Kaltenbach A, . Fractionation of 238U/235U by Reduction during Low Temperature Uranium Mineralisation Processes. Earth and Planetary Science Letters, 2014, 388: 306-317.
CrossRef Google scholar
Placzek C J, Heikoop J M, House B, . Uranium Isotope Composition of Waters from South Texas Uranium Ore Deposits. Chemical Geology, 2016, 437: 44-55.
CrossRef Google scholar
Richter S, Eykens R, Kühn H, . New Average Values for the n (238U)/n(235U) Isotope Ratios of Natural Uranium Standards. International Journal of Mass Spectrometry, 2010, 295(1/2): 94-97.
CrossRef Google scholar
Rosholt J N, Shields W R, Garner E L. Isotopic Fractionation of Uranium in Sandstone. Science, 1963, 139(3551): 224-226.
CrossRef Google scholar
Schauble E A. Role of Nuclear Volume in Driving Equilibrium Stable Isotope Fractionation of Mercury, Thallium, and Other very Heavy Elements. Geochimica et Cosmochimica Acta, 2007, 71(9): 2170-2189.
CrossRef Google scholar
Schauble E A, Meheut M, Hill P S. Combining Metal Stable Isotope Fractionation Theory with Experiments. Elements, 2009, 5(6): 369-374.
CrossRef Google scholar
Stacey J S, Kramers J D. Approximation of Terrestrial Lead Isotope Evolution by a Two-Stage Model. Earth and Planetary Science Letters, 1975, 26(2): 207-221.
CrossRef Google scholar
Stirling C H, Andersen M B, Potter E K, . Low-Temperature Isotopic Fractionation of Uranium. Earth and Planetary Science Letters, 2007, 264(1/2): 208-225.
CrossRef Google scholar
Tarasov N N, Kochkin B T, Velichkin V I, . Deposits of the Hiagda Uranium Ore Field, Buryatia: Formation Conditions and Ore Control Factors. Geology of Ore Deposits, 2018, 60(4): 347-354.
CrossRef Google scholar
Thurber D L. Anomalous U234U238 in Nature. Journal of Geophysical Research Atmospheres, 1962, 67(11): 4518-4520.
CrossRef Google scholar
Uvarova Y A, Kyser T K, Geagea M L, . Variations in the Uranium Isotopic Compositions of Uranium Ores from Different Types of Uranium Deposits. Geochimica et Cosmochimica Acta, 2014, 146: 1-17.
CrossRef Google scholar
Vaks A, Gutareva O S, Breitenbach S F, . Speleothems Reveal 500 000-Year History of Siberian Permafrost. Science, 2013, 340(6129): 183-186.
CrossRef Google scholar
Weyer S, Anbar A D, Gerdes A, . Natural Fractionation of 238U/235U. Geochimica et Cosmochimica Acta, 2008, 72(2): 345-359.
CrossRef Google scholar

Accesses

Citations

Detail

Sections
Recommended

/