Geochronology and Ore Genesis of the Niujuan-Yingfang Pb-Zn-Ag Deposit in Fengning, Northern North China Craton: Constraints from Fluid Inclusions, H-O-S Isotopes and Fluorite Sr-Nd Isotopes

Abstract

The Niujuan-Yingfang Pb-Zn-Ag deposit in northern North China Craton (NCC) is hosted at the contact zone between Permian biotite monzogranite and Hongqiyingzi Group migmatitic gneiss. The orebodies are structurally controlled by NE-trending F₁ fault. Mineralization can be divided into three stages: (1) siliceous-chlorite-pyrite stage, (2) quartz-Ag-base metal stage, and (3) fluoritecalcite stage. Four types of fluid inclusions were identified, including: (1) liquid-rich aqueous inclusions, (2) vapor-rich inclusions, (3) liquid-rich, solid-bearing inclusions, and (4) CO₂-bearing inclusions. Microthermometric measurements reveal that from stage I to III, the homogenization temperatures range from 317 to 262 °C, from 297 to 192 °C, and from 248 to 151 °C, respectively, and the fluid salinities are in the ranges from 1.1 wt.% to 6.5 wt.%, 1.2 wt.% to 6.0 wt.% and 0.7 wt.% to 4.0 wt.% NaCl equivalents, respectively. Fluid boiling and cooling are the two important mechanisms for ore precipitation according to microthermometric data, and fluid-rock interaction is also indispensable. Laser Raman spectroscopic analyses indicate the fluid system of the deposit is composed of CO₂-NaCl-H₂O±N₂. Metallogenic fluorites yielded a Sm-Nd isochron age of 158±35 Ma. The δ³⁴S_V-CDT values of sulfides range from −1.3‰ to 6.3‰, suggesting that the sulfur may be inherited from the basement metamorphic igneous rocks. Hydrogen and oxygen isotopic compositions of quartz indicate a metamorphic origin for the ore-forming fluid, and the proportion of meteoric water increased during the ore-forming processes. Sr-Nd isotopes of fluorites show a crustal source for the ore-forming fluid, with primary metamorphic fluid mixed with meteoric water during ascent to lower crustal levels. Combined with the geological, metallogenic epoch, fluid inclusions, H-O-S and Sr-Nd isotopes characteristics of the deposit, we suggest that the Niujuan-Yingfang deposit belongs to the medium-low temperature hydrothermal vein-type Pb-Zn-Ag polymetallic deposit, with ore-forming fluids dominantly originated from metamorphic fluids.

Keywords

fluid inclusion / geochronology / H-O-S isotopes / fluorite Sr-Nd isotopes / Niujuan-Yingfang Pb-Zn-Ag deposit / NCC

References

Beaudoin G, Taylor B E, Sangster D F. Silver-Lead-Zinc Veins and Crustal Hydrology during Eocene Extension, Southeastern British Columbia, Canada. Geochimica et Cosmochimica Acta, 1992, 56(9): 3513-3529.

Bell K, Anglin C D, Franklin J M. Sm-Nd and Rb-Sr Isotope Systematics of Scheelites: Possible Implications for the Age and Genesis of Vein-Hosted Gold Deposits. Geology, 1989, 17(6): 500-504.

Bendezú R, Fontboté L. Cordilleran Epithermal Cu-Zn-Pb-(Au-Ag) Mineralization in the Colquijirca District, Central Peru: Deposit-Scale Mineralogical Patterns. Economic Geology, 2009, 104(7): 905-944.

Bodnar R J. Revised Equation and Table for Determining the Freezing Point Depression of H₂O-NaCl Solutions. Geochimica et Cosmochimica Acta, 1993, 57(3): 683-684.

Boutoux A, Verlaguet A, Bellahsen N, . Fluid Systems above Basement Shear Zones during Inversion of Pre-Orogenic Sedimentary Basins (External Crystalline Massifs, Western Alps). Lithos, 2014, 206: 435-453. 207

Catchpole H, Kouzmanov K, Bendezú A, . Timing of Porphyry (Cu-Mo) and Base Metal (Zn-Pb-Ag-Cu) Mineralisation in a Magmatic-Hydrothermal System—Morococha District, Peru. Mineralium Deposita, 2015, 50(8): 895-922.

Catchpole H, Kouzmanov K, Fontboté L, . Fluid Evolution in Zoned Cordilleran Polymetallic Veins—Insights from Microthermometry and LA-ICP-MS of Fluid Inclusions. Chemical Geology, 2011, 281(3): 293-304. 4

Cheilletz A, Levresse G, Gasquet D, . The Giant Imiter Silver Deposit: Neoproterozoic Epithermal Mineralization in the Anti-Atlas, Morocco. Mineralium Deposita, 2002, 37(8): 772-781.

Chen B, Jahn B M, Tian W. Evolution of the Solonker Suture Zone: Constraints from Zircon U-Pb Ages, Hf Isotopic Ratios and Whole-Rock Nd-Sr Isotope Compositions of Subduction- and Collision-Related Magmas and Forearc Sediments. Journal of Asian Earth Sciences, 2009, 34(3): 245-257.

Chen B, Jahn B M, Wilde S, . Two Contrasting Paleozoic Magmatic Belts in Northern Inner Mongolia, China: Petrogenesis and Tectonic Implications. Tectonophysics, 2000, 328(1): 157-182. 2

Chen W J, Liu H T, Zhang D H. Fluid Inclusion’s Characteristics of the Niujuan Silve Deposit in Fengning, Hebei, and Its Geological Significance. Mineral Resources and Geology, 2007, 21(1): 12-16. (in Chinese with English Abstract)

Chen Y J, Ni P, Fan H R, . Diagnostic Fluid Inclusions of Different Types Hydrothermal Gold Deposits. Acta Petrologica Sinica, 2007, 23(9): 2085-2108. (in Chinese with English Abstract)

Chen Y J, Sui Y H, Pirajno F. Exclusive Evidences for CMF Model and a Case of Orogenic Silver Deposits: Isotope Geochemistry of the Tieluping Silver Deposit, East Qinling Orogen. Acta Petrologica Sinica, 2003, 19(3): 551-568. (in Chinese with English Abstract)

Clayton R N, Mayeda T K. The Use of Bromine Pentafluoride in the Extraction of Oxygen from Oxides and Silicates for Isotopic Analysis. Geochimica et Cosmochimica Acta, 1963, 27(1): 43-52.

Clayton R N, O’Neil J R, Mayeda T K. Oxygen Isotope Exchange between Quartz and Water. Journal of Geophysical Research, 1972, 77(17): 3057-3067.

Collins P L F. Gas Hydrates in CO₂-Bearing Fluid Inclusions and the Use of Freezing Data for Estimation of Salinity. Economic Geology, 1979, 74(6): 1435-1444.

Cook N J, Ciobanu C L, Mao J W. Textural Control on Gold Distribution in As-Free Pyrite from the Dongping, Huangtuliang and Hougou Gold Deposits, North China Craton (Hebei Province, China). Chemical Geology, 2009, 264(1): 101-121. 2/3/4

Cooke D R, McPhail D C, Bloom M S. Epithermal Gold Mineralization, Acupan, Baguio District, Philippines: Geology, Mineralization, Alteration, and the Thermochemical Environment of Ore Deposition. Economic Geology, 1996, 91(2): 243-272.

Cunningham C G, Zartman R E, McKee E H, . The Age and Thermal History of Cerro Rico de Potosi, Bolivia. Mineralium Deposita, 1996, 31(5): 374-385.

Dai J Z, Mao J W, Yang F Q, . Geological Characteristics and Geodynamic Background of Molybdenum (Copper) Deposits along Yanshan-Liaoning Metallogenic Belt on Northern Margin of North China Block. Mineral Deposits, 2006, 25(5): 598-612. (in Chinese with English Abstract)

Ding S. The Diagenesis and Metallogenesis of Sinongduo Epithermal Ag-Pb-Zn deposit in Gangdese Belt, Tibet, 2017, Chengdu: Chengdu University of Technology, 1-167. (in Chinese with English Abstract)

Dong C Y, Wan Y S, Zhang Y H, . 3.3∼3.1 Ga Magmatism Recorded in an Outcrop of the Dongshan Complex in the Anshan Area, North China Craton: Evidence from Geochemistry and SHRIMP Zircon Dating. Acta Petrologica Sinica, 2013, 29(2): 414-420. (in Chinese with English Abstract)

Duan S G, Xue C J, Yan C H, . Comparison of Pb-Zn Metallogenic Characteristics between Northern and Southern Margins of North China Landmass. Mineral Deposits, 2008, 27(3): 383-398. (in Chinese with English Abstract)

Fan H R, Liu S, Hu F F, . Fluid Inclusions in the Ultra-High Pressure Metamorphic Rocks and High Pressure Metamorphic Veins at Taohang in the Sulu Terrane. Acta Petrologica Sinica, 2008, 24(9): 2003-2011. (in Chinese with English Abstract)

Fu C Y, Gao B L. The Structural and Geological Characteristics of Niuquan Silver-Gold Deposit, Fengning, Hebei Province. Journal of Geology and Mineral Resources of North China, 1998, 13(3): 55-60. (in Chinese with English Abstract)

Gammons C H, Barnes H L. The Solubility of Ag₂S in Near-Neutral Aqueous Sulfide Solutions at 25 to 300 °C. Geochimica et Cosmochimica Acta, 1989, 53(2): 279-290.

Gammons C H, Williams-Jones A E. Hydrothermal Geochemistry of Electrum; Thermodynamic Constraints. Economic Geology, 1995, 90(2): 420-432.

Gao H. Characteristics of Xiaoqinggou Ag, Mn Polymetal Ore Deposit, Lingqiu County, Shanxi Province and Study on Its Genesis. Contributions to Geology and Mineral Resources Research, 2004, 19(2): 87-91. (in Chinese with English Abstract)

Gao K B. Characteristics of Hydrogen and Oxygen Isotopes, Fluid Inclusions and Fluid Evolution of the Fengning Ag(Au) Deposit, Hebei Province: Comparing with Decratonic Gold Deposits, 2017, Beijing: China University of Geosciences, 1-64. (in Chinese with English Abstract)

Gao M, Gao F. Retrogressive Metamorphism of Archean Granulites and Evidence of Rb-Sr Isochron Age in Zhangjiakou and Xuanhua Regions. Journal of Hebei College of Geology, 1988, 11(4): 11-19. (in Chinese with English Abstract)

Guo G J, Wang S Q. REE Geochemistry of Xiaokouhuaying Silver-Manganese Deposit in Hebei Province. Acta Scientiarum Naturalium Universitis Pekinensis, 1998, 34(4): 98-106. (in Chinese with English Abstract)

Guo L N, Liu S S, Hou L, . Fluid Inclusion and H-O Isotope Geochemistry of the Phapon Gold Deposit, NW Laos: Implications for Fluid Source and Ore Genesis. Journal of Earth Science, 2019, 30(1): 80-94.

Guo L N, Zhang C, Song Y Z, . Hydrogen and Oxygen Isotopes Geochemistry of the Wang’ershan Gold Deposit, Jiaodong. Acta Petrologica Sinica, 2014, 30(9): 2481-2494. (in Chinese with English Abstract)

Halliday A N, Shepherd T J, Dickin A P, . Sm-Nd Evidence for the Age and Origin of a Mississippi Valley Type Ore Deposit. Nature, 1990, 344(6261): 54-56.

Han Q J, Shao J A, Zhou R. Petrology, Geochemistry and Petrogenesis of Early Mesozoic Diorites in Harqin Area, Inner Mongolia. Acta Petrologica Sinica, 2000, 16(3): 385-391. (in Chinese with English Abstract)

Hart C J, Goldfarb R J, Qiu Y M, . Gold Deposits of the Northern Margin of the North China Craton: Multiple Late Paleozoic-Mesozoic Mineralizing Events. Mineralium Deposita, 2002, 37(3): 326-351.

Hezarkhani A, Williams-Jones A E, Gammons C H. Factors Controlling Copper Solubility and Chalcopyrite Deposition in the Sungun Porphyry Copper Deposit, Iran. Mineralium Deposita, 1999, 34(8): 770-783.

Hu X D, Zhao J N, Li S B. Gold Minerallization in Archean Metamorphic Rocks, Zhangjiakou-Xuahua Area, Hebei Province. Bulletin of the Tianjin Institute of Geology and Mineral Resources, 1990, 9: 68-78. (in Chinese)

Hu X W, Zhang J M, Quan H. The Isotopic Ages of the Hongqiyingzi Group in Northern Hebei and Its Age Assignment. Regional Geology of China, 1996, 2: 186-192. (in Chinese with English Abstract)

Huang D H, Wu C Y, Zhang C J. Study on Stable Isotopic Geochemistry of Caijiaying Pb-Zn-Ag Deposit, Hebei Province, China. Geochimica, 1997, 26(4): 24-35. (in Chinese with English Abstract)

John T, Gussone N, Podladchikov Y Y, . Volcanic Arcs Fed by Rapid Pulsed Fluid Flow through Subducting Slabs. Nature Geoscience, 2012, 5(7): 489-492.

Kamenov G, Macfarlane A W, Riciputi L. Sources of Lead in the San Cristobal, Pulacayo, and Potosi Mining Districts, Bolivia, and a Reevaluation of Regional Ore Lead Isotope Provinces. Economic Geology, 2002, 97(3): 573-592

Ke L L, Zhang H Y, Liu J J, . Fluid Inclusion, H-O, S, Pb and Noble Gas Isotope Studies of the Aerhada Pb-Zn-Ag Deposit, Inner Mongolia, NE China. Ore Geology Reviews, 2017, 88: 304-316.

Li J F. Chengde Fengning Niujuan Silver Deposit Genesis Analysis, 2013, Shijiazhuang: Shijiazhuang University of Economics, 1-45. (in Chinese with English Abstract)

Li J M, Gong E P, Yao Y Z, . The Geological Geochemical Characteristics and Metallogeny of Fengning Silver Polymetallic Ore Deposit, North Hebei Province. Contributions to Geology and Mineral Resources Research, 2006, 21(4): 241-247. (in Chinese with English Abstract)

Li J M, Gong E P, Yao Y Z, . Discussion on the Metallogenetic Epoch and Ore-Forming Matter Source of the Silver Deposits in Yanshan Area. Geology and Resources, 2006, 15(3): 179-186. (in Chinese with English Abstract)

Li J P, Zhang D H. The Geological and Geochemical Characteristics and Discussion on the Genesis of the Daxigou Gold Deposit in Fengning, Hebei Province. Mineral Resources and Geology, 2011, 25(2): 109-114. (in Chinese with English Abstract)

Li S M, Han Y C, Wei M H, . Characteristics of Isotopic Compositions and Genesis of the Lianjiagou Polymetallic Ore Deposit in Chichen County, Zhangjiakou. Geology in China, 2016, 43(6): 2154-2162. (in Chinese with English Abstract)

Li S M, Wei M H, Li S W, . Rb-Sr and Sm-Nd Isochron Ages of the Liangjiagou Pb-Zn-Ag Ore Deposit in Chicheng County of Zhangjiakou City and Their Geological Implications. Geology in China, 2014, 41(2): 529-539. (in Chinese with English Abstract)

Li S R, Santosh M. Metallogeny and Craton Destruction: Records from the North China Craton. Ore Geology Reviews, 2014, 56: 376-414.

Li W B, Zhou W D, Chen S C, . Geological Characteristics of the Yindonggou Silver Deposit in Hubei Province and Its Implication for Ore Genesis. Earth Science Frontiers, 2010, 17(1): 177-185. (in Chinese with English Abstract)

Li Y G, Wang L X. The Study on Wall Rock Alteration of Niujuan Silver (Gold) Deposit, Hebei Province, China. Contributions to Geology and Mineral Resources Research, 2002, 17(4): 234-239. (in Chinese with English Abstract)

Li Y J. Metallogenic Process and Potential of the Silver-Polymetallic System in Fengning, Northern Hebei Province: Constraint of Geochronology, Geochemistry and Genetic Mineralogy, 2016, Beijing: China University of Geosciences, 1-145. (in Chinese with English Abstract)

Li Y J, Li S R, Santosh M, . Isotope Geochemistry and Geochronology of the Niujuan Silver Deposit, Northern North China Craton: Implications for Magmatism and Metallogeny in an Extensional Tectonic Setting. Ore Geology Reviews, 2017, 90: 36-51.

Li Z Y, Liu X Y, Li S M, . An Analysis of Geological Age and Materials Source of the Niujuan Ag-Au Polymetallic Deposit in Chengde. Geology in China, 2014, 41(3): 951-960. (in Chinese with English Abstract)

Liang J H, Gong E P, Yao Y Z, . The Geological Characteristics of Fengning Cryptoexplosive Breccia Silver Ploymetal Deposits in Hebei. Contributions to Geology and Mineral Resources Research, 2007, 22(1): 48-51. (in Chinese with English Abstract)

Liu C H, Nie F J, Bagas L. Geology and Ore Genesis of the Yu’erya Gold Deposit, Eastern Hebei Province, China. Ore Geology Reviews, 2016, 73: 270-283.

Liu C W, Gu Z F, Wei M H, . Metallogenic Characteristics and Formation Mechanism of the Xiangguang Mn-Ag Ore Deposit, Hebei. Mineral Exploration, 2012, 3(2): 165-170. (in Chinese with English Abstract)

Liu F S, Zhang G H. Genesis of Niujuan Hot-Spring Type Ag(Au) Deposit in Hebei Province. Journal of Precious Metallic Geology, 1996, 5(1): 48-58. (in Chinese with English Abstract)

Liu J M, Zhao Y, Sun Y L, . Recognition of the Latest Permian to Early Triassic Cu-Mo Mineralization on the Northern Margin of the North China Block and Its Geological Significance. Gondwana Research, 2010, 17(1): 125-134.

Liu Q M, Han Y C, Li S M. Metallogenic Epoch of the Wanquansi Silver-Gold Deposit in Zhangjiakou, Hebei Province, and Its Geological Significance. Acta Geoscientica Sinica, 2018, 39(4): 474-480. (in Chinese with English Abstract)

Liu S W, Tian W, Lv Y J, . Geochemistry, Nd Isotopic Characteristics of Metamorphic Complexes in Northern Hebei: Implications for Crustal Accretion. Acta Geologica Sinica: English Edition, 2006, 80(6): 807-818

Liu T, Xiong S F, Jiang S Y, . Genesis of the Zhijiadi Ag-Pb-Zn Deposit, Central North China Craton: Constraints from Fluid Inclusions and Stable Isotope Data. Geofluids, 2017, 2017(2): 1-23

Liu W H, Zhang X J, Zhang J, . Sphalerite Rb-Sr Dating and in situ Sulfur Isotope Analysis of the Daliangzi Lead-Zinc Deposit in Sichuan Province, SW China. Journal of Earth Science, 2018, 29(3): 573-586.

Ludwig K R. User’s Manual for Isoplot/Ex Rev. 3.00: A Geochronological Toolkit for Microsoft Excel. Berkeley Geochronology Center Special Publication, 2003, 4: 1-71.

Luo Z K, Miao L C, Guan K, . SHRIMP Chronological Study of the Shuiquangou Intrusive Body in Zhangjiakou Area, Hebei Province and Geochemical Significance. Geochimica, 2001, 30(2): 116-122. (in Chinese with English Abstract)

Ma Y, Jiang S Y, Chen R S, . Hydrothermal Evolution and Ore Genesis of the Zhaiping Ag-Pb-Zn Deposit in Fujian Province of Southeast China: Evidence from Stable Isotopes (H, O, C, S) and Fluid Inclusions. Ore Geology Reviews, 2019, 104: 246-265.

Mao D B, Chen Z H, Zhong C T, . The Re-Os Isotopic Age of Molybdenite from Beichagoumen Pb-Zn Deposit in the North China Platform. Geochimica, 2000, 29(2): 132-135. (in Chinese with English Abstract)

Mao D B, Zhong C T, Chen Z H, . On the Metollogenic Aspects of Pb-Zn-Ag Deposits in the Middle North Margin of North China Block. Progress in Precambrian Research, 2002, 25(2): 105-112. (in Chinese with English Abstract)

Mao D B, Zhong C T, Wu Y P, . Metallogenic Processes of Beichagoumen Lead-Zinc Polymetallic Deposit, North Hebei Province: Constrains from Geological and Geochemical Characteristics. Geological Survey and Research, 2005, 28(4): 228-239. (in Chinese with English Abstract)

Mao J W, Li X F, Zhang Z H, . Geology, Distribution, Types and Tectonic Settings of Mesozoic Epithermal Gold Deposits in East China. Geological Journal of China Universities, 2003, 9(4): 620-637. (in Chinese with English Abstract)

Mao J W, Xie G Q, Zhang Z H, . Mesozoic Large-Scale Metallogenic Pulses in North China and Corresponding Geodynamic Settings. Acta Petrologica Sinica, 2005, 21(1): 169-188. (in Chinese with English Abstract)

Mu B L, Shao J A, Chu Z Y, . Sm-Nd Age and Sr, Nd Isotopic Characteristics of the Fangshan Potassic Alkaline Ultramafic-Syenite Complex in Hebei Province, China. Acta Petrologica Sinica, 2001, 17(3): 358-365. (in Chinese with English Abstract)

Mu B L, Yan G H. Geochemistry of Triassic Alkaline or Subalkaline Igneous Complexes in the Yan-Liao Area and Their Significance. Acta Geologica Sinica, 1992, 66(2): 108-121. (in Chinese with English Abstract)

Munoz M, Premo W R, Courjault-Radé P C. Sm-Nd Dating of Fluorite from the Worldclass Montroc Fluorite Deposit, Southern Massif Central, France. Mineralium Deposita, 2005, 39(8): 970-975.

Nie F J. Type and Distribution of Gold Deposits along the Northern Margin of the North China Craton, People’s Republic of China. International Geology Review, 1997, 39(2): 151-180.

Nie F J, Jiang S H, Su X X, . Geological Features and Origin of Gold Deposits Occurring in the Baotou-Bayan Obo District, South-Central Inner Mongolia, People’s Republic of China. Ore Geology Reviews, 2002, 20(3): 139-169. 4

Nie F J, Zhang W Y, Jiang S H, . Discussion on the Time Limitation of Silver (Gold) Mineralization in the Niujuan Deposit, Northern Hebei Province. Earth Science Frontiers, 2007, 14(5): 167-176. (in Chinese with English Abstract)

Niu S Y, Luo D W, Ye D H, . Mantle-Branch Structure and Its Mineralization in North China, 1996, Beijing: Geological Publishing House, 1-124. (in Chinese)

Ohmoto H, Rye R. Barnes H L. Isotopes of Sulfur and Carbon. Geochemistry of Hydrothermal Ore Deposits, 1979, New York: Wiley, 505-567

Ouyang H G, Mao J W, Santosh M, . Geodynamic Setting of Mesozoic Magmatism in NE China and Surrounding Regions: Perspectives from Spatio-Temporal Distribution Patterns of Ore Deposits. Journal of Asian Earth Sciences, 2013, 78: 222-236.

Paiement J P, Beaudoin G, Paradis S, . Geochemistry and Metallogeny of Ag-Pb-Zn Veins in the Purcell Basin, British Columbia. Economic Geology, 2012, 107(6): 1303-1320.

Peng J T, Fu Y Z, Yuan S D, . Sm-Nd Isotope Dating of Some Ca-Bearing Minerals in Hydrothermal Deposits. Geological Review, 2006, 52(5): 662-667. (in Chinese with English Abstract)

Peng J T, Hu R Z, Jiang G H. Strontium Isotope Geochemistry of Fluorites from Qinglong Antimony Deposit in Guizhou Province. Geological Journal of China Universities, 2003, 9(2): 244-251. (in Chinese with English Abstract)

Qi J P, Chen Y J, Li Q Z. The Epithermal Deposits in the Northern Margin of North China Craton: Spatiotemporal Distribution and Tectonic Setting. Journal of Mineralogy and Petrology, 2004, 24(3): 82-92. (in Chinese with English Abstract)

Ren Y W. Evidence for Ore-Forming and Geological Characteristics of Silver Deposit at Yingfang, Hebei Province. Contributions to Geology and Mineral Resources Research, 1991, 6(4): 80-89. (in Chinese with English Abstract)

Ren Y W. Diagenetic Mechanism and Mineralization Characteristics of Cryptoexplosive Breccia in Yingfang Silver Deposit, Hebei Province. Mineral Resources and Geology, 1992, 6(3): 224-230. (in Chinese)

Ren Y W. A Study on Hongqiyingzi Group—The Source Bed of Pb-Zn-Ag Deposits in North Hebei. Journal of Geology and Mineral Resources of North China, 1997, 12(1): 44-51. (in Chinese with English Abstract)

Ren Y W, Cao Q W. Occurrence State and Enrichment Rule of Ag in Pb-Zn-Ag Deposit of Fengning Yingfang, Hebei Province. Journal of Geology and Mineral Resources of North China, 1995, 10(1): 77-86. (in Chinese with English Abstract)

Rice C M, Steele G B, Barfod D N, . Duration of Magmatic, Hydrothermal and Supergene Activity at Cerro Rico de Potosi, Bolivia. Economic Geology, 2005, 100(8): 1647-1656.

Robinson B W, Kusakabe M. Quantitative Preparation of Sulfur Dioxide, for ³⁴S/³²S Analyses, from Sulfides by Combustion with Cuprous Oxide. Analytical Chemistry, 1975, 47(7): 1179-1181.

Rottier B, Kouzmanov K, Casanova V, . Cyclic Dilution of Magmatic Metal-Rich Hypersaline Fluids by Magmatic Low-Salinity Fluid: A Major Process Generating the Giant Epithermal Polymetallic Deposit of Cerro de Pasco, Peru. Economic Geology, 2018, 113(4): 825-856.

Ruaya J R, Seward T M. The Stability of Chlorozinc(II) Complexes in Hydrothermal Solutions up to 350 °C. Geochimica et Cosmochimica Acta, 1986, 50(5): 651-661.

Rubinstein N A, Carrasquero S I, Gómez A L R, . Metallogeny of the Paramillos de Uspallata Pb-Zn-Ag Vein Deposit in the Cuyo Rift Basin, Argentina. Comptes Rendus Geoscience, 2018, 350(4): 164-172.

Sallet R, Moritz R, Fontignie D. Fluorite ⁸⁷Sr/⁸⁶Sr and REE Constraints on Fluid-Melt Relations, Crystallization Time Span and Bulk D^Sr of Evolved High-Silica Granites. Tabuleiro Granites, Santa Catarina, Brazil. Chemical Geology, 2000, 164(1): 81-92. 2

Santosh M, Zhao D P, Kusky T. Mantle Dynamics of the Paleoproterozoic North China Craton: A Perspective Based on Seismic Tomography. Journal of Geodynamics, 2010, 49(1): 39-53.

Seward T M. The Stability of Chloride Complexes of Silver in Hydrothermal Solutions up to 350 °C. Geochimica et Cosmochimica Acta, 1976, 40(11): 1329-1341.

Shang L B, Fan W L, Hu R Z, . A Thermodynamic Study on Paragenesis and Separation of Silver, Lead and Zinc in Hydrothermal Solutions. Acta Mineralogica Sinica, 2004, 24(1): 81-86. (in Chinese with English Abstract)

Shen L X, Li W S, Wang Z L, . Forecast for the Deep Mineralization of Niujuan Silver-Gold Deposit and Yingfang Silver-Lead-Zinc Deposit in Northern Hebei Province. Contributions to Geology and Mineral Resources Research, 2012, 27(4): 450-457. (in Chinese with English Abstract)

Sillitoe R H. Porphyry Copper Systems. Economic Geology, 2010, 105(1): 3-41.

Stefánsson A, Seward T M. Experimental Determination of the Stability and Stoichiometry of Sulphide Complexes of Silver(I) in Hydrothermal Solutions to 400 °C. Geochimica et Cosmochimica Acta, 2003, 67(7): 1395-1413.

Su R, Sun G S, Du M Y. Geochemical Characteristics of Biotites from Amphibolites in Jianping Group, Southeastern Chifeng and Their Geological Implications. Global Geology, 2015, 34(2): 307-311. (in Chinese with English Abstract)

Su W C, Hu R Z, Xia B, . Calcite Sm-Nd Isochron Age of the Shuiyindong Carlin-Type Gold Deposit, Guizhou, China. Chemical Geology, 2009, 258(3): 269-274. 4

Ulrich T, Günther D, Heinrich C A. The Evolution of a Porphyry Cu-Au Deposit, Based on LA-ICP-MS Analysis of Fluid Inclusions: Bajo de La Alumbrera, Argentina. Economic Geology, 2002, 97(8): 1889-1920.

Walther J V, Orville P M. Volatile Production and Transport in Regional Metamorphism. Contributions to Mineralogy and Petrology, 1982, 79(3): 252-257.

Wang F, Chen F K, Siebel W, . Zircon U-Pb Geochronology and Hf Isotopic Composition of the Hongqiyingzi Complex, Northern Hebei Province: New Evidence for Paleoproterozoic and Late Paleozoic Evolution of the Northern Margin of the North China Craton. Gondwana Research, 2011, 20(1): 122-136.

Wang H C, Zhao F Q, Li H M, . Zircon SHRIMP U-Pb Age of the Dioritic Rocks from Northern Hebei: the Geological Records of Late Paleozoic Magmatic Arc. Acta Petrologica Sinica, 2007, 23(3): 597-604. (in Chinese with English Abstract)

Wang M Y. Researches on Geological Characteristics and Metallogenic Regular in Daxigou Gold Deposit, Hebei Province, 2008, Beijing: China University of Geosciences, 1-69. (in Chinese with English Abstract)

Wang, Q. C., 1992. On the Age of Hongqiyingzi Group and Geological Thermal Events in Undergone. Scientia Geologica Sinica, S1: 17–24 (in Chinese with English Abstract)

Wang S Q, Liu X W. Geological Characteristics and Ore-Controlling Significance of the Cryptoexploed Breccia in Niujuan Silver Deposit, in Hebei Province. Contributions to Geology and Mineral Resources Research, 2009, 24(2): 139-141. (in Chinese with English Abstract)

Wang Y H. Study on the Genesis of the Niujuan Silver (Gold) Deposit in Hebei Province. Geological Survey and Research, 2010, 33(1): 35-41. (in Chinese with English Abstract)

Wang Z H. The Metallogenic Regularity and Prospecting Direction of Silver Polymetallic Ore Deposit in Chengde Cluster, 2015, Nanjing: Nanjing University, 1-79. (in Chinese with English Abstract)

Wang Z Q, Chen B, Yan X, . Characteristics of Hydrothermal Chlorite from the Niujuan Ag-Au-Pb-Zn Deposit in the North Margin of NCC and Implications for Exploration Tools for Ore Deposits. Ore Geology Reviews, 2018, 101: 398-412.

Wei X Y. Discussion on Structural Control Characteristics and Genesis of Yingfang-Niujuan Silver Deposit, Hebei. Contributions to Geology and Mineral Resources Research, 2000, 15(3): 261-266. (in Chinese with English Abstract)

Williams-Jones A E, Migdisov A A. Experimental Constraints on the Transport and Deposition of Metals in Ore-forming Hydrothermal Systems. Society of Economic Geologists, 2014, 18: 77-96.

Williams-Jones A E, Samson I M, Ault K M, . The Genesis of Distal Zinc Skarns: Evidence from the Mochito Deposit, Honduras. Economic Geology, 2010, 105(8): 1411-1440.

Wood S A, Samson I M. Solubility of Ore Minerals and Complexation of Ore Metals in Hydrothermal Solutions. In: Richards, J. P., Larson, P. B., eds., Techniques in Hydrothermal Ore Deposits Geology. Reviews in Economic Geology, 1998, 10: 33-80.

Xia Y B, Wu J H, Jiang S, . Geochronology, Geochemical Characteristics, and Genesis of Trachyte in Datan Basin, Northern Hebei. Geological Journal of China Universities, 2016, 22(4): 608-620. (in Chinese with English Abstract)

Xiao Y L, Yu C L, Wang Y Y, . Metamorphism and Fluid Inclusions: An Overview and Prospectives. Bulletin of Mineralogy, Petrology and Geochemistry, 2018, 37(3): 424-440. (in Chinese with English Abstract)

Xu C, Huang Z L, Liu C Q, . Indicator of Fluorite Sr and Nd Isotope to Mantle-Derived Ore-Forming Fluids in Maoniuping REE Deposit, Sichuan Province, China. Earth Science, 2003, 28(1): 41-46. (in Chinese with English Abstract)

Xu C, Huang Z L, Qi L, . Sr-Nd Isotope Geochemistry of Fluorites—A Review. Geology-Geochemistry, 2001, 29(4): 27-34. (in Chinese with English Abstract)

Xu W G, Fan H R, Hu F F, . Geochronology of the Guilaizhuang Gold Deposit, Luxi Block, Eastern North China Craton: Constraints from Zircon U-Pb and Fluorite-Calcite Sm-Nd Dating. Ore Geology Reviews, 2015, 65(1): 390-399.

Xu X F. Ore-Forming Model of the Niujuan Epithermal Silver-Gold Deposit in Fengning, Hebei Province. Nonferrous Geology of North China, 1991, 1: 1-10. (in Chinese)

Yan X, Chen B, Wang Z Q, . The Petrogenesis of the Two-Stage A-Type Granites from the Niujuan Silver Deposit in the Northern Margin of North China Craton and Their Tectonic Implications. Acta Petrologica Sinica, 2019, 35(2): 558-588. in Chinese with English Abstract)

Yang H, Ma W L, Wang R, . Factors Controlling Deposition of Metallic Minerals in the Meng’entaolegai Ag-Pb-Zn Deposit, Inner Mongolia, China: Evidence from Fluid Inclusions, Isotope Systematics, and Thermodynamic Model. Journal of Earth Science, 2020, 31(2): 271-286.

Yang J H, Wu F Y, Wilde S A. A Review of the Geodynamic Setting of Large-Scale Late Mesozoic Gold Mineralization in the North China Craton: An Association with Lithospheric Thinning. Ore Geology Reviews, 2003, 23(3): 125-152. 4

Yang M Z. Types of Ag Deposits in the North Hebei Province and Geology, Geochemistry, Geohistory Evolution Model, Ore-Searching Direction of the Ag Deposit. Contributions to Geology and Mineral Resources Research, 2000, 15(3): 193-203. (in Chinese with English Abstract)

Yang S D. Ore Forming Geological Characteristics and Scientific Prospecting for Silver Deposits in North Hebei Province, 2000, Guangzhou: Central South University of Technology, 1-84. (in Chinese with English Abstract)

Yang X Q, Li Z L. Fluid Characteristics of Late Paleozoic Ultrahigh-Temperature Granulites from the Altay Orogenic Belt, Northwestern China and Its Significance. Acta Petrologica Sinica, 2013, 29(10): 3446-3456. (in Chinese with English Abstract)

Yang Z X, Tian L C. Studies on the Metallogenisis of Lead-Zinc Deposits in Liaoning. Liaoning Geology, 1998, 1: 1-19. (in Chinese with English Abstract)

Zeng Q D, Liu J M, Chu S X, . Mesozoic Molybdenum Deposits in the East Xingmeng Orogenic Belt, Northeast China: Characteristics and Tectonic Setting. International Geology Review, 2012, 54(16): 1843-1869.

Zeng Q D, Wang Y B, Yang J H, . Spatial-Temporal Distribution and Tectonic Setting of Gold Deposits in the Northern Margin Gold Belt of the North China Craton. International Geology Review, 2020, 25(5): 1-32

Zhang C Q, Wu Y, Hou L, . Geodynamic Setting of Mineralization of Mississippi Valley-Type Deposits in World-Class Sichuan-Yunnan-Guizhou Zn-Pb Triangle, Southwest China: Implications from Age-Dating Studies in the Past Decade and the Sm-Nd Age of Jinshachang Deposit. Journal of Asian Earth Sciences, 2015, 103: 103-114.

Zhang D H. Some New Advances in Ore-forming Fluid Geochemistry on Boiling and Mixing of Fluids during the Processes of Hydrothermal Deposits. Advance in Earth Sciences, 1997, 12(6): 546-552. (in Chinese with English Abstract)

Zhang G H. Study on Fluid Inclusion of Niujuan Ag (Gold) Deposit. Bulletin of Mineralogy, Petrology and Geochemistry, 1995, 3: 153-154. (in Chinese)

Zhang, H. Q., 2014. Research on Metallization of Zhijiadi Epithermal-Type Ag-Pb-Zn Deposit in Shanxi, China: [Dissertation]. China University of Geosciences, Beijing. 1–124 (in Chinese with English Abstract)

Zhang S H, Zhao Y, Kröner A, . Early Permian Plutons from the Northern North China Block: Constraints on Continental Arc Evolution and Convergent Margin Magmatism Related to the Central Asian Orogenic Belt. International Journal of Earth Sciences, 2009, 98(6): 1441-1467.

Zhang S H, Zhao Y, Song B, . Contrasting Late Carboniferous and Late Permian-Middle Triassic Intrusive Suites from the Northern Margin of the North China Craton: Geochronology, Petrogenesis and Tectonic Implications. Geological Society of America Bulletin, 2009, 121(1): 181-200. 2

Zhang S H, Zhao Y, Song B, . Petrogenesis of the Middle Devonian Gushan Diorite Pluton on the Northern Margin of the North China Block and Its Tectonic Implications. Geological Magazine, 2007, 144(3): 553-568.

Zhang S H, Zhao Y, Song B, . Carboniferous Granitic Plutons from the Northern Margin of the North China Block: Implications for a Late Paleozoic Active Continental Margin. Journal of the Geological Society, 2007, 164(2): 451-463.

Zhang Y F, Wu J H, Jiang S, . SHRIMP U-Pb Geochronology, Geochemistry and Sr-Nd Isotopes of the Uranium-(Molybdenum) Related Rhyolite and Granitic Porphyry, Datan, Northern Hebei. Acta Petrologica Sinica, 2016, 32(1): 193-211. (in Chinese with English Abstract)

Zhao G C, Wilde S A, Cawood P A, . Archean Blocks and Their Boundaries in the North China Craton: Lithological, Geochemical, Structural and P-T Path Constraints and Tectonic Evolution. Precambrian Research, 2001, 107(1): 45-73. 2

Zhao Y, Chen B, Zhang S H, . Pre-Yanshanian Geological Events in the Northern Margin of the North China Craton and Its Adjacent Areas. Geology in China, 2010, 37(4): 900-915. (in Chinese with English Abstract)

Zhong R C, Yang Y F, Shi Y X, . Ore Characters and Ore Genesis of the Bairendaba Ag Polymetallic Ore Deposit in Keshiketeng Banner, Inner Mongolia. Geology in China, 2008, 35(6): 1274-1285. (in Chinese with English Abstract)

Zhu R X, Chen L, Wu F Y, . Timing, Scale and Mechanism of the Destruction of the North China Craton. Science China Earth Sciences, 2011, 54(6): 789-797.

Zhu R X, Fan H R, Li J W, . Decratonic Gold Deposits. Science China Earth Sciences, 2015, 58(9): 1523-1537.