Provenance of Lower Carboniferous Bauxite Deposits in Northern Guizhou, China: Constraints from Geochemistry and Detrital Zircon U-Pb Ages

Abstract

The Lower Carboniferous Jiujialu Formation bauxite deposits of northern Guizhou Province, China, are a Kazakhstan subtype of karst bauxite deposits. The provenance of the Jiujialu Formation has long been debated, with uncertainty about the formation of the bauxite deposits. Here we report new geochemical data that indicate the affinity between the Lower-Middle Ordovician clastic rocks and argillaceous dolostones and the overlying Carboniferous bauxite deposits, all of which are characterized by high Al₂O₃, K₂O, and ΣREE contents, flat post-Archean Australian shale (PAAS)-normalized REE patterns, and uniform immobile element ratios (TiO₂/Al₂O₃, Nb/TiO₂, and Zr/TiO₂). Their similar detrital zircon age distributions further indicate the link between the bauxite deposits and the clastic rocks and argillaceous dolostones. Zircon age spectra of clastic rocks of the Lower Silurian Hanchiatien Formation in northern Guizhou match those of the bauxite deposits, with a maximum age peak at ∼980 Ma and other secondary age peaks, suggesting these clastic rocks may represent the provenance of the bauxite deposits. The youngest detrital zircons (∼445 Ma) occur only in the bauxite deposits and are probably sourced from K-bentonite beds of the Ordovician-Silurian transition. Our analyses indicate that the source materials of the bauxite deposits in the Jiujialu Formation are of mixed provenance: Lower-Middle Ordovician aluminosilicate rocks and argillaceous dolostones of the underlying strata, and Lower Silurian clastic rocks and K-bentonite from adjacent areas. A comparison of Early Carboniferous bauxitic provenances in northern and central Guizhou indicates that paleotopography was the major factor controlling the provenance of these bauxite deposits.

Keywords

weathering / bauxitization / karstification / chemical weathering / Jiujialu Formation

References

Ahmadnejad F, Zamanian H, Taghipour B, . Mineralogical and Geochemical Evolution of the Bidgol Bauxite Deposit, Zagros Mountain Belt, Iran: Implications for Ore Genesis, Rare Earth Elements Fractionation and Parental Affinity. Ore Geology Reviews, 2017, 86: 755-783.

Bárdossy G. Karst Bauxites: Bauxite Deposits on Carbonate Rocks, 1982, Amsterdam: Elsevier, 441.

Bárdossy G. Carboniferous to Jurassic Bauxite Deposits as Paleoclimatic and Paleogeographic Indicators. Global Environments and Resources, 1994, 17: 283-293.

Bárdossy G, Combes P J. Karst Bauxites: Interfingering of Deposition and Palaeoweathering, 1999, Oxford: Blackwell Science, 189-206.

BGMRGZP Bureau of GeologicMineral Resource of Guizhou Province Regional Geology of China, Guizhou Province, 2017, Beijing: Geological Press House (in Chinese)

Bogatyrev B A, Zhukov V V, Tsekhovsky Y G. Formation Conditions and Regularities of the Distribution of Large and Superlarge Bauxite Deposits. Lithology and Mineral Resources, 2009, 44(2): 135-151.

Boni M, Reddy S M, Mondillo N, . A Distant Magmatic Source for Cretaceous Karst Bauxites of Southern Apennines (Italy), Revealed through SHRIMP Zircon Age Dating. Terra Nova, 2012, 24(4): 326-332.

Braun J J, Pagel M, Herbilln A, . Mobilization and Redistribution of REEs and Thorium in a Syenitic Lateritic Profile: A Mass Balance Study. Geochimica et Cosmochimica Acta, 1993, 57(18): 4419-4434.

Brimhall G H, Lewis C J, Ague J J, . Metal Enrichment in Bauxites by Deposition of Chemically Mature Aeolian Dust. Nature, 1988, 333(6176): 819-824.

Combes P J, Bárdossy G. Geodynamic of Bauxitic in the Tethyan Realm, 1995, Boston: Springer, 347-365.

Comer J B, Naeser C W, McDowell F W. Fission-Track Ages of Zircon from Jamaican Bauxite and Terra Rossa. Economic Geology, 1980, 75(1): 117-121.

D’Argenio B, Mindszenty A. Bauxites and Related Paleokarst: Tectonic and Climatic Event Markers at Regional Unconformities. Eclogae Geologicae Helvetiae, 1995, 88(3): 453-499.

Deng X, Yang K G, Liu Y L, . Characteristics and Tectonic Evolution of Qianzhong Uplift. Earth Science Frontiers, 2010, 17(3): 79-89. (in Chinese with English Abstract)

Du X B, Lu Y C, Duan D, . Was Volcanic Activity during the Ordovician-Silurian Transition in South China Part of a Global Phenomenon? Constraints from Zircon U-Pb Dating of Volcanic Ash Beds in Black Shales. Marine and Petroleum Geology, 2020, 114 104209

Esmaeily D, Rahimpour-Bonab H, Esna-Ashari A, . Petrography and Geochemistry of the Jajarm Karst Bauxite Ore Deposit, Ne Iran: Implications for Source Rock Material and Ore Genesis. Turkish Journal of Earth Sciences, 2010, 19(2): 267-284.

Greentree M R, Li Z X. The Oldest Known Rocks in South-Western China: SHRIMP U-Pb Magmatic Crystallisation Age and Detrital Provenance Analysis of the Paleoproterozoic Dahongshan Group. Journal of Asian Earth Sciences, 2008, 33(5): 289-302. 6

Gu J, Huang Z L, Fan H P, . Provenance of Lateritic Bauxite Deposits in the Wuchuan-Zheng’an-Daozhen Area, Northern Guizhou Province, China: LA-ICP-MS and SIMS U-Pb Dating of Detrital Zircons. Journal of Asian Earth Sciences, 2013, 70: 265-282. 71

He X Q, Xiao J F, Wang S Y. The Study on the Oianzhong Upheaval. Guizhou Geology, 2005, 22(2): 83-89. (in Chinese with English Abstract)

He Y Y, Niu Z J, Zhang Z Z, . Detrital Zircons of the Meitan Formation During Ordovician in Northeastern Guizhou, It’s Significance for Provenance-Tectonic and Implications for Metallogenic Chronology. Geology in China, 2020, 47(4): 1025-1040. (in Chinese with English Abstract)

Hofmann M H, Li X H, Chen J, . Provenance and Temporal Constraints of the Early Cambrian Maotianshan Shale, Yunnan Province, China. Gondwana Research, 2016, 37: 348-361.

Hoskin P W O, Schaltegger U. The Composition of Zircon and Igneous and Metamorphic Petrogenesis. Reviews in Mineralogy and Geochemistry, 2003, 53(1): 27-62.

Hou Y L, Zhong Y T, Xu Y G, . The Provenance of Late Permian Karstic Bauxite Deposits in SW China, Constrained by the Geochemistry of Interbedded Clastic Rocks, and U-Pb-Hf-O Isotopes of Detrital Zircons. Lithos, 2017, 278–281: 240-254.

Hu Y H, Zhou J B, Song B, . SHRIMP Zircon U-Pb Dating from K-Bentonite in the Top of Ordovician of Wangjiawan Section, Yichang, Hubei, China. Science in China Series D: Earth Sciences, 2008, 51(4): 493-498.

Huang X, Zhang X H, Du Y S, . Age of Bauxite Forming in Northern Guizhou. Geological Science and Technology Information, 2012, 31(3): 49-54. (in Chinese with English Abstract)

Jiang S Y, Pi D H, Heubeck C, . Early Cambrian Ocean Anoxia in South China. Nature, 2009, 459(7248): E5-E6.

Lan Z W, Li X H, Chu X L, . SIMS U-Pb Zircon Ages and Ni-Mo-PGE Geochemistry of the Lower Cambrian Niutitang Formation in South China: Constraints on Ni-Mo-PGE Mineralization and Stratigraphic Correlations. Journal of Asian Earth Sciences, 2017, 137: 141-162.

Li P G, Yu W C, Du Y S, . Influence of Geomorphology and Leaching on the Formation of Permian Bauxite in Northern Guizhou Province, South China. Journal of Geochemical Exploration, 2020, 210 106446

Li Z X, Li X H, Kinny P D, . Geochronology of Neoproterozoic Syn-Rift Magmatism in the Yangtze Craton, South China and Correlations with other Continents: Evidence for a Mantle Superplume that Broke up Rodinia. Precambrian Research, 2003, 122(1): 85-109. 2/3/4

Liao S F, Liang T R. Bauxite Geology in China, 1991, Guiyang: Science and Technology Publishing House of Guizhou, 277 (in Chinese)

Ling K Y, Zhu X Q, Tang H S, . Importance of Hydrogeological Conditions during Formation of the Karstic Bauxite Deposits, Central Guizhou Province, Southwest China: A Case Study at Lindai Deposit. Ore Geology Reviews, 2017, 82: 198-216.

Ling K Y, Zhu X Q, Tang H S, . Geology and Geochemistry of the Xiaoshanba Bauxite Deposit, Central Guizhou Province, SW China: Implications for the Behavior of Trace and Rare Earth Elements. Journal of Geochemical Exploration, 2018, 190: 170-186.

Liu B J, Xu X S. Atlas of the Palaeogeography of South China (Sinian-Triassic), 1994, Beijing: Geological Publishing House (in Chinese)

Liu P. The Initial Discussion on Guizhou Bauxite Deposit. Guizhou Geology, 1987, 4(1): 3-14. (in Chinese with English Abstract)

Liu P. Another Discussion on Guizhou Bauxite Deposits—A Study of Houcao Bauxite Material Resources According to Chemical Composition Features. Guizhou Geology, 1991, 8(4): 313-321. (in Chinese with English Abstract)

Liu P. Geochemical Characteristics of Carboniferous Bauxite Deposits in Central Guizhou-Southern Sichuan. Regional Geology of China, 1999, 18(2): 210-217. (in Chinese with English Abstract)

Liu P, Liao Y C. A Tentative Discussion on the Age of Bauxite-Bearing Rock Series in Central Guizhou-Southern Chongqing Area. Geology in China, 2012, 39(3): 661-682. (in Chinese with English Abstract)

Liu X F, Wang Q F, Feng Y W, . Genesis of the Guangou Karstic Bauxite Deposit in Western Henan, China. Ore Geology Reviews, 2013, 55: 162-175.

Liu Y S, Hu Z C, Gao S, . In situ Analysis of Major and Trace Elements of Anhydrous Minerals by LA-ICP-MS without Applying an Internal Standard. Chemical Geology, 2008, 257(1): 34-43. 2

Ludwig K R. Isoplot 3.70: A Geochronological Toolkit Formicrosoft Excel, 2008, Berkeley: Berkeley Geochronology Center Special Publication, 26-35.

MacLean W H. Mass Change Calculations in Altered Rock Series. Mineralium Deposita, 1990, 25(1): 44-49.

MacLean W H, Barrett T J. Lithogeochemical Techniques Using Immobile Elements. Journal of Geochemical Exploration, 1993, 48(2): 109-133.

MacLean W H, Bonavia F F, Sanna G. Argillite Debris Converted to Bauxite during Karst Weathering: Evidence from Immobile Element Geochemistry at the Olmedo Deposit, Sardinia. Mineralium Deposita, 1997, 32(6): 607-616.

MacLean W H, Kranidiotis P. Immobile Elements as Monitors of Mass Transfer in Hydrothermal Alteration; Phelps Dodge Massive Sulfide Deposit, Matagami, Quebec. Economic Geology, 1987, 82(4): 951-962.

Mameli P, Mongelli G, Oggiano G, . Geological, Geochemical and Mineralogical Features of Some Bauxite Deposits from Nurra (Western Sardinia, Italy): Insights on Conditions of Formation and Parental Affinity. International Journal of Earth Sciences, 2007, 96(5): 887-902.

McLennan S M. Rare Earth Elements in Sedimentary Rocks: Influence of Provenance and Sedimentary Processes, 1989, Washington, D.C.: Mineralogical Society of America, 170-200.

Mongelli G. Ce-Anomalies in the Textural Components of Upper Cretaceous Karst Bauxites from the Apulian Carbonate Platform (Southern Italy). Chemical Geology, 1997, 140(1): 69-79. 2

Mongelli G, Boni M, Buccione R, . Geochemistry of the Apulian Karst Bauxites (Southern Italy): Chemical Fractionation and Parental Affinities. Ore Geology Reviews, 2014, 63: 9-21.

Mongelli G, Buccione R, Gueguen E, . Geochemistry of the Apulian Allochthonous Karst Bauxite, Southern Italy: Distribution of Critical Elements and Constraints on Late Cretaceous Peri-Tethyan Palaeogeography. Ore Geology Reviews, 2016, 77: 246-259.

Nesbitt H W. Mobility and Fractionation of Rare Earth Elements during Weathering of a Granodiorite. Nature, 1979, 279(5710): 206-210.

Niu X S, Feng C M, Liu J. Formation Mechanism and Time of Qianzhong Uplift. Marine Origin Petroleum Geology, 2007, 12(2): 46-50. (in Chinese with English Abstract)

Okada Y, Sawaki Y, Komiya T, . New Chronological Constraints for Cryogenian to Cambrian Rocks in the Three Gorges, Weng’an and Chengjiang Areas, South China. Gondwana Research, 2014, 25(3): 1027-1044.

Price G D, Valdes P J, Sellwood B W. Prediction of Modern Bauxite Occurrence: Implications for Climate Reconstruction. Palaeogeography, Palaeoclimatology, Palaeoecology, 1997, 131(1): 1-13. 2

Rong J Y, Chen X, Wang Y. Northward Expansion of Central Guizhou Oldland through the Ordovician and Silurian Transition: Evidence and Implications. Sci. Sin. Terrae., 2011, 41: 1407-1415. (in Chinese with English Abstract)

Rubatto D. Zircon Trace Element Geochemistry: Partitioning with Garnet and the Link between U-Pb Ages and Metamorphism. Chemical Geology, 2002, 184(1): 123-138. 2

Shi X, Yu J X, Chen B, . Palynology of the Lower Permian Dazhuyuan and Liangshan Formations in Wuchuan-Zheng’an-Daozhen Area, Northern Guizhou Province. Journal of Paleogeography, 2014, 16(2): 217-226. (in Chinese with English Abstract)

Spencer C J, Kirkland C L, Taylor R J M. Strategies Towards Statistically Robust Interpretations of in situ U-Pb Zircon Geochronology. Geoscience Frontiers, 2016, 7(4): 581-589.

Su W B, He L Q, Wang Y B. K-Bentonite Beds and High-Resolution Integrated Stratigraphy of the Uppermost Ordovician Wufeng and the Lowest Silurian Longmaxi Formations in South China. Science in China (Series D), 2003, 46(11): 1121-1133.

Su W B, Huff W D, Ettensohn F R, . K-Bentonite, Black-Shale and Flysch Successions at the Ordovician-Silurian Transition, South China: Possible Sedimentary Responses to the Accretion of Cathaysia to the Yangtze Block and Its Implications for the Evolution of Gondwana. Gondwana Research, 2009, 15(1): 111-130.

Sun W H, Zhou M F, Gao J F, . Detrital Zircon U-Pb Geochronological and Lu-Hf Isotopic Constraints on the Precambrian Magmatic and Crustal Evolution of the Western Yangtze Block, SW China. Precambrian Research, 2009, 172(1): 99-126. 2

Sun W H, Zhou M F, Yan D P, . Provenance and Tectonic Setting of the Neoproterozoic Yanbian Group, Western Yangtze Block (SW China). Precambrian Research, 2008, 167(1): 213-236. 2

Vermeesch P. On the Visualisation of Detrital Age Distributions. Chemical Geology, 2012, 312: 190-194. 313

Wang L J, Yu J H, O’Reilly S Y, . Grenvillian Orogeny in the Southern Cathaysia Block: Constraints from U-Pb Ages and Lu-Hf Isotopes in Zircon from Metamorphic Basement. Science Bulletin, 2008, 53(19): 3037-3050.

Wang Q F, Deng J, Liu X F, . Discovery of the REE Minerals and Its Geological Significance in the Quyang Bauxite Deposit, West Guangxi, China. Journal of Asian Earth Sciences, 2010, 39(6): 701-712.

Wang Q F, Deng J, Liu X F, . Provenance of Late Carboniferous Bauxite Deposits in the North China Craton: New Constraints on Marginal Arc Construction and Accretion Processes. Gondwana Research, 2016, 38: 86-98.

Wang Q S. A Discussion on Metallogenic Conditions and Origin of Zunyi Bauxite Deposits. Guizhou Geology, 1988, 5(2): 28-36. (in Chinese with English Abstract)

Wang R X, Wang Q F, Huang Y X, . Combined Tectonic and Paleogeographic Controls on the Genesis of Bauxite in the Early Carboniferous to Permian Central Yangtze Island. Ore Geology Reviews, 2018, 101: 468-480.

Wang X M, Jiao Y Q, Du Y S, . REE Mobility and Ce Anomaly in Bauxite Deposit of WZD Area, Northern Guizhou, China. Journal of Geochemical Exploration, 2013, 133: 103-117.

Weng S F, Lei Z Y, Zhao S, . Relation between Richening, Preserving and Paleokarst Landform of Xianrenyan Bauxite Deposit in Zunyi. Guizhou Geology, 2011, 28(4): 260-264. (in Chinese with English Abstract)

Weng S F, Yu W C, Algeo T J, . Giant Bauxite Deposits of South China: Multistage Formation Linked to Late Paleozoic Ice Age (LPIA) Eustatic Fluctuations. Ore Geology Reviews, 2019, 104: 1-13.

Wu L, Jia D, Li H B, . Provenance of Detrital Zircons from the Late Neoproterozoic to Ordovician Sandstones of South China: Implications for Its Continental Affinity. Geological Magazine, 2010, 147(6): 974-980.

Xia X P, Nie X S, Lai C K, . Where Was the Ailaoshan Ocean and when did It Open: A Perspective Based on Detrital Zircon U-Pb Age and Hf Isotope Evidence. Gondwana Research, 2016, 36: 488-502.

Xiong C, Chen H D, Niu Y L, . Provenance, Depositional Setting, and Crustal Evolution of the Cathaysia Block, South China: Insights from Detrital Zircon U-Pb Geochronology and Geochemistry of Clastic Rocks. Geological Journal, 2018, 54(2): 897-912.

Yang S C, Hu W X, Wang X L, . Duration, Evolution, and Implications of Volcanic Activity across the Ordovician-Silurian Transition in the Lower Yangtze Region, South China. Earth and Planetary Science Letters, 2019, 518(15): 13-25.

Yang S J, Wang Q F, Zhang Q Z, . Terrestrial Deposition Processes of Quaternary Gibbsite Nodules in the Yongjiang Basin, Southeastern Margin of Tibet, and Implication for the Genesis of Ancient Karst Bauxite. Sedimentary Geology, 2018, 373: 292-306.

Yu J H, O’Reilly S Y, Wang L J, . Where Was South China in the Rodinia Supercontinent?. Precambrian Research, 2008, 164(1): 1-15. 2

Yu J H, O’Reilly S Y, Wang L J, . Components and Episodic Growth of Precambrian Crust in the Cathaysia Block, South China: Evidence from U-Pb Ages and Hf Isotopes of Zircons in Neoproterozoic Sediments. Precambrian Research, 2010, 181(1–4): 97-114.

Yu J H, O’Reilly Y S, Wang L J, . Finding of Ancient Materials in Cathaysia and Implication for the Formation of Precambrian Crust. Chinese Science Bulletin, 2007, 52(1): 13-22.

Yu W C, Algeo T J, Du Y S, . Mixed Volcanogenic-Lithogenic Sources for Permian Bauxite Deposits in Southwestern Youjiang Basin, South China, and Their Metallogenic Significance. Sedimentary Geology, 2016, 341: 276-288.

Yu W C, Algeo T J, Yan J X, . Climatic and Hydrologic Controls on Upper Paleozoic Bauxite Deposits in South China. Earth-Science Reviews, 2019, 189: 159-176.

Yu W C, Du Y S, Cawood P A, . Detrital Zircon Evidence for the Reactivation of an Early Paleozoic Syn-Orogenic Basin along the North Gondwana Margin in South China. Gondwana Research, 2015, 28(2): 769-780.

Yu W C, Du Y S, Zhou Q, . Palaeoclimate of the Early Permian: Evidence from Characteristics of Bauxite Beds in Wuchuan-Zheng’an-Daozhen Area, Northern Guizhou Province. Journal of Paleogeography, 2014, 16(1): 30-40. (in Chinese with English Abstract)

Zamanian H, Ahmadnejad F, Zarasvandi A. Mineralogical and Geochemical Investigations of the Mombi Bauxite Deposit, Zagros Mountains, Iran. Geochemistry, 2016, 76(1): 13-37.

Zhang Y B, Zhou Z Y, Zhang J M. Sedimentary Differentiation during the Latest Early Ordovician—Earliest Darriwilian in the Yangtze Block. Journal of Stratigraphy, 2002, 26(4): 302-314. (in Chinese with English Abstract)

Zhao G C, Cawood P A. Precambrian Geology of China. Precambrian Research, 2012, 222: 13-54. 223

Zhao L H, Liu X F. Metallogenic and Tectonic Implications of Detrital Zircon U-Pb, Hf Isotopes, and Detrital Rutile Geochemistry of Late Carboniferous Karstic Bauxite on the Southern Margin of the North China Craton. Lithos, 2019, 350 105222 351

Zhao X F, Zhou M F, Li J W, . Late Paleoproterozoic to Early Mesoproterozoic Dongchuan Group in Yunnan, SW China: Implications for Tectonic Evolution of the Yangtze Block. Precambrian Research, 2010, 182(1): 57-69. 2

Zhao Y L, Li J Y, Rong K F, . The Effect of Karstification in the Palaeogeographic Study: A Supplement and Discussion About the Article “a Discussion on Several Principles in the Paiaeogeographic Study. Guizhou Geology, 1989, 1(6): 60-64. (in Chinese with English Abstract)

Zheng Y F, Zhang S B, Zhao Z F, . Contrasting Zircon Hf and O Isotopes in the Two Episodes of Neoproterozoic Granitoids in South China: Implications for Growth and Reworking of Continental Crust. Lithos, 2007, 96(1): 127-150. 2

Zhou M F, Ma Y X, Yan D P, . The Yanbian Terrane (Southern Sichuan Province, SW China): A Neoproterozoic Arc Assemblage in the Western Margin of the Yangtze Block. Precambrian Research, 2006, 144(1): 19-38. 2

Zhou M F, Yan D P, Kennedy A K, . SHRIMP U-Pb Zircon Geochronological and Geochemical Evidence for Neoproterozoic Arc-Magmatism along the Western Margin of the Yangtze Block, South China. Earth and Planetary Science Letters, 2002, 196(1): 51-67. 2

Zhou W L, Liu Y P. Characteristics of Basement Strata in Bauxite Deposits of Guizhou Province and Their Relationships to Regional Mineralization. Geology and Exploration, 2016, 52(3): 462-471. (in Chinese with English Abstract)