The effect of SiO₂ nanoparticles derived from hydrothermal solutions on the performance of portland cement based materials

Abstract

The nanoparticles of SiO₂ were used in cement systems to modify the rheological behavior, to enhance the reactivity of supplementary cementitious materials, and also to improve the strength and durability. In this research, low-cost nano-SiO₂ particles from natural hydrothermal solutions obtained by membrane ultrafiltration and, optionally, by cryochemical vacuum sublimation drying, were evaluated in portland cement based systems. ƒThe SiO₂-rich solutions were obtained from the wells of Mutnovsky geothermal power station (Far East of Russia). The constant nano-SiO₂ dosage of 0.25% (as a solid material by weight of cementitious materials) was used to compare the cement systems with different nanoparticles against a reference mortar and a commercially available nano-SiO₂. Nanoparticles were characterized by X-Ray Diffraction (XRD), BET Surface Area, Scanning Electron Microscope (SEM) and Fourier Transform Infrared (FTIR) spectroscopy techniques. It was demonstrated that the addition of polycarboxylate ether superplasticizer and the dispersion treatment using an ultrasound processor can be used to facilitate the distribution of nano-SiO₂ particles in the mixing water. The effect of nano-SiO₂ particles in portland cement mortars was investigated by evaluating the flow, heat of hydration and compressive strength development. It was demonstrated that the use of nano-SiO₂ particles can reduce the segregation and improve strength properties.

Key words： ultrafiltration; cryochemical vacuum sublimation drying; nanoparticles; portland cement; heat of hydration; surface area; compressive strength

Acknowledgments

The authors acknowledge the donation of materials by the Lafarge Cement Company, EKA Chemicals, AKZO Nobel and Handy Chemicals. The research team acknowledges the financial support from BRICS STI Framework Programme, PCA, WisDOT and We Energies.

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