Perovskite oxides and heterojunctions have attracted much attention due to their multifunctional properties of electricity and optics and magnetic as well as the very good chemical and thermal stability. In this brief review, we describe the novel progress of researches in the optical characteristic, including ultrafast photoelectric effects of picosecond order in perovskite oxide single crystals, thin-films and heterojunctions, high-sensitive photovoltages, the enhanced transient lateral photovoltages in perovskite oxide thin-films and heterojunctions, and the high-sensitive ultraviolet (UV) photodetectors based on perovskite oxides. The recent advances present in this paper not only could stimulate theoretical studies on the mechanism but also would open up the possibilities in the developments of optoelectronic devices based on perovskite oxides and heterojunctions.
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