Advances in self-assembled ultrathin polyoxomolybdates multilayers
Received date: 24 Oct 2008
Accepted date: 21 Nov 2008
Published date: 05 Mar 2009
Copyright
The research on the assembly and function of organized molecular films has gained more and more interest. Electrostatic interactions can be employed to assemble polyoxomolybdates in surface confined multilayers. Ultrathin multilayer films of polyoxomolybdates and organic molecules by the self-assembly method have been reviewed. At the same time, self-assemblies in aqueous solution are also reported, such as wheel-shaped clusters (Mo154), hollow spherical “blackberry”-like vesicles (Mo72Fe30) and Keggin structures. Polyoxomolybdate multilayers are promising candidates for diverse applications including electrocatalytic, photo- and electro-chromic systems. The development in this particular field of materials science may be highlighted in the future.
Key words: polyoxomolybdates; multilayer films; self-assembled
Liang-bao YANG , Xiu-fang WANG , An-jian XIE , Gang HU , Yu-hua SHEN . Advances in self-assembled ultrathin polyoxomolybdates multilayers[J]. Frontiers of Materials Science, 2009 , 3(1) : 1 -8 . DOI: 10.1007/s11706-009-0019-y
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