Frontiers of Materials Science >
Facile solvothermal synthesis of NiFe2O4 nanoparticles for high-performance supercapacitor applications
Received date: 12 Dec 2019
Accepted date: 06 Feb 2020
Published date: 15 Jun 2020
Copyright
We report a green and facile approach for the synthesis of NiFe2O4 (NF) nanoparticles with good crystallinity. The prepared materials are studied by various techniques in order to know their phase structure, crystallinity, morphology and elemental state. The BET analysis revealed a high surface area of 80.0 m2·g−1 for NF possessing a high pore volume of 0.54 cm3·g−1, also contributing to the amelioration of the electrochemical performance. The NF sample is studied for its application in supercapacitors in an aqueous 2 mol·L−1 KOH electrolyte. Electrochemical properties are studied both in the three-electrode method and in a symmetrical supercapacitor cell. Results show a high specific capacitance of 478.0 F·g−1 from the CV curve at an applied scan rate of 5 mV·s−1 and 368.0 F·g−1 from the GCD analysis at a current density of 1 A·g−1 for the NF electrode. Further, the material exhibited an 88% retention of its specific capacitance after continuous 10000 cycles at a higher applied current density of 8 A·g−1. These encouraging properties of NF nanoparticles suggest the practical applicability in high-performance supercapacitors.
Meenaketan SETHI, U. Sandhya SHENOY, Selvakumar MUTHU, D. Krishna BHAT. Facile solvothermal synthesis of NiFe2O4 nanoparticles for high-performance supercapacitor applications[J]. Frontiers of Materials Science, 2020, 14(2): 120-132. DOI: 10.1007/s11706-020-0499-3
1 |
Sudhakar Y N, Selvakumar M, Bhat D K. Biopolymer Electrolytes: Fundamentals and Applications in Energy Storage. Elsevier, 2018
|
2 |
Sadiq M M J, Shenoy S U, Bhat D K. Novel NRGO–CoWO4–Fe2O3 nanocomposite as an efficient catalyst for dye degradation and reduction of 4-nitrophenol. Materials Chemistry and Physics, 2018, 208: 112–122
|
3 |
Peng H, Dai X, Sun K,
|
4 |
Dutta S, Pal S, De S. Mixed solvent exfoliated transition metal oxides nanosheets based flexible solid state supercapacitor devices endowed with high energy density. New Journal of Chemistry, 2019, 43(31): 12385–12395
|
5 |
Sethi M, Bhat D K. Facile solvothermal synthesis and high supercapacitor performance of NiCo2O4 nanorods. Journal of Alloys and Compounds, 2019, 781: 1013–1020
|
6 |
Pan C, Liu Z, Li W,
|
7 |
Gao H, Wang X, Wang G,
|
8 |
Aparna M L, Grace A N, Sathyanarayanan P,
|
9 |
Kumar P R, Mitra S. Nickel ferrite as a stable, high capacity and high rate anode for Li-ion battery applications. RSC Advances, 2013, 3(47): 25058–25064
|
10 |
Gao X, Wang W, Bi J,
|
11 |
Bandgar S B, Vadiyar M M, Ling Y C,
|
12 |
Hua M, Xu L, Cui F,
|
13 |
Bhojane P, Sharma A, Pusty M,
|
14 |
Anwar S, Muthu K S, Ganesh V,
|
15 |
Zhang X, Zhang Z, Sun S,
|
16 |
Sethi M, Bantawal H, Shenoy U S,
|
17 |
Subramanya B, Bhat D K. Novel eco-friendly synthesis of graphene directly from graphite using 2,2,6,6-tetramethylpiperidine 1-oxyl and study of its electrochemical properties. Journal of Power Sources, 2015, 275: 90–98
|
18 |
Giannozzi P, Baroni S, Bonini N,
|
19 |
Perdew J P, Burke K, Ernzerhof M. Generalized gradient approximation made simple. Physical Review Letters, 1996, 77(18): 3865–3868 doi:10.1103/PhysRevLett.77.3865
|
20 |
Shenoy U S, Bantawal H, Bhat D K. Band engineering of SrTiO3: Effect of synthetic technique and site occupancy of doped rhodium. The Journal of Physical Chemistry C, 2018, 122(48): 27567–27574
|
21 |
Sadiq M M J, Shenoy U S, Bhat D K. Enhanced photocatalytic performance of N-doped RGO–FeWO4/Fe3O4 ternary nanocomposite in environmental applications. Materials Today Chemistry, 2017, 4: 133–141
|
22 |
Zhao Y, Xu L, Yan J,
|
23 |
Sadiq M M J, Shenoy S U, Bhat D K. NiWO4–ZnO–NRGO ternary nanocomposite as an efficient photocatalyst for degradation of methylene blue and reduction of 4-nitro phenol. Journal of Physics and Chemistry of Solids, 2017, 109: 124–133
|
24 |
Wu F, Wang X, Li M,
|
25 |
Cao N, Zou X, Huang Y,
|
26 |
Liu L, Sun L, Liu J,
|
27 |
Subramanya B, Bhat D K. Novel one-pot green synthesis of graphene in aqueous medium under microwave irradiation using a regenerative catalyst and the study of its electrochemical properties. New Journal of Chemistry, 2015, 39(1): 420–430
|
28 |
Zhang Z, Li L, Qing Y,
|
29 |
Bhat D K, Shenoy U S. Zn: a versatile resonant dopant for SnTe thermoelectrics. Materials Today Chemistry, 2019, 11: 100158 doi:10.1016/j.mtphys.2019.100158
|
30 |
Shenoy U S, Bhat D K. Electronic structure engineering of tin telluride through co-doping of bismuth and indium for high performance thermoelectrics: a synergistic effect leading to a record high room temperature ZT in tin telluride. Journal of Materials Chemistry C: Materials for Optical and Electronic Devices, 2019, 7(16): 4817–4821
|
31 |
Shenoy U S, Bhat D K. Bi and Zn co-doped SnTe thermoelectrics: interplay of resonance levels and heavy hole band dominance leading to enhanced performance and a record high room temperature ZT. Journal of Materials Chemistry C: Materials for Optical and Electronic Devices, 2020, 8(6): 2036–2042 doi:10.1039/c9tc06490g
|
32 |
Kumar N, Kumar A, Huang G M,
|
33 |
Foo C Y, Lim H N, Mahdi M A B,
|
34 |
Zhang X, Zhu M, Ouyang T,
|
35 |
Cai Y Z, Cao W Q, Zhang Y L,
|
36 |
Zhang X, Zhang Z, Sun S,
|
37 |
Fu M, Chen W, Zhu X,
|
38 |
Sharma V, Biswas S, Sundaram B,
|
/
〈 |
|
〉 |