Nitrogen-doped carbon-coated hollow SnS₂/NiS microflowers for high-performance lithium storage

Abstract

Nitrogen-doped carbon-coated hollow SnS₂/NiS (SnS₂/NiS@N–C) microflowers were obtained using NiSn(OH)₆ nanospheres as the template via a solvent-thermal method followed by the polydopamine coating and carbonization process. When served as an anode material for lithium-ion batteries, such hollow SnS₂/NiS@N–C microflowers exhibited a capacity of 403.5 mAh·g⁻¹ at 2.0 A·g⁻¹ over 200 cycles and good rate performance. The electrochemical reaction kinetics of this anode was analyzed, and the morphologies and structures of anode materials after the cycling test were characterized. The high stability and good rate performance were mainly due to bimetallic synergy, hollow micro/nanostructure, and nitrogen-doped carbon layers. The revealed excellent electrochemical energy storage properties of hollow SnS₂/NiS@N–C microflowers in this study highlight their potential as the anode material.

Graphical abstract

Keywords

SnS ₂ / NiS / microflower / hollow structure / nitrogen-doped carbon / anode / lithium-ion battery

References

[1] Ding Y, Cai P, Wen Z . Electrochemical neutralization energy: from concept to devices.Chemical Society Reviews, 2021, 50(3): 1495–1511

[2] Pang Z Y, Zhang H Z, Wang L, . Towards safe lithium‒sulfur batteries from liquid-state electrolyte to solid-state electrolyte.Frontiers of Materials Science, 2023, 17(1): 230630

[3] Ma Z Y, Wang Q B, Wang Y H, . High lithium storage performance of Ni_0.5Fe_0.5O_1−xN_x thin film with NiO-type crystal structure.Frontiers of Materials Science, 2022, 16(4): 220624

[4] Zhou Y Y, Zhang Z Y, Zhang H Z, . Progress and perspective of vanadium-based cathode materials for lithium ion batteries.Tungsten, 2021, 3(3): 279–288

[5] Inamdar A I, Hou B, Chavan H S, . Copper cobalt tin sulphide (Cu₂CoSnS₄) anodes synthesised using a chemical route for stable and efficient rechargeable lithium-ion batteries.Dalton Transactions, 2022, 51(38): 14535–14544

[6] Wei X J, Zhang Y B, Zhang B K, . Yolk–shell-structured zinc‒cobalt binary metal sulfide @ N-doped carbon for enhanced lithium-ion storage.Nano Energy, 2019, 64: 103899

[7] Yang X X, He C J, Hou Y L, . In-situ growth engineering of nano-sheets SnS₂ on S-doped reduced graphene oxide for high lithium/sodium storage capacity.Journal of Electroanalytical Chemistry, 2022, 904: 115947

[8] Dong X, Deng Z P, Huo L H, . Large-scale synthesis of NiS@N and S co-doped carbon mesoporous tubule as high performance anode for lithium-ion battery.Journal of Alloys and Compounds, 2019, 788: 984–992

[9] Yu L Q, Zhao S X, Wu Q L, . Strengthening the interface between flower-like VS₄ and porous carbon for improving its lithium storage performance.Advanced Functional Materials, 2020, 30(16): 2000427

[10] Zhao Z J, Chao Y G, Wang F, . Intimately coupled WS₂ nanosheets in hierarchical hollow carbon nanospheres as the high-performance anode material for lithium-ion storage.Rare Metals, 2022, 41(4): 1245–1254

[11] Zhang S P, Wang G, Wang B B, . 3D carbon nanotube network bridged hetero-structured Ni–Fe–S nanocubes toward high-performance lithium, sodium, and potassium storage.Advanced Functional Materials, 2020, 30(24): 2001592

[12] Fang Y, Luan D, Gao S, . Rational design and engineering of one-dimensional hollow nanostructures for efficient electrochemical energy storage.Angewandte Chemie International Edition, 2021, 60(37): 20102–20118

[13] Zhang Y, Wang P X, Yin Y Y, . Carbon coated amorphous bimetallic sulfide hollow nanocubes towards advanced sodium ion battery anode.Carbon, 2019, 150: 378–387

[14] Lin Y M, Qiu Z Z, Li D Z, . NiS₂@CoS₂ nanocrystals encapsulated in N-doped carbon nanocubes for high performance lithium/sodium ion batteries.Energy Storage Materials, 2018, 11: 67–74

[15] Fang G Z, Wu Z X, Zhou J, . Observation of pseudocapacitive effect and fast ion diffusion in bimetallic sulfides as an advanced sodium-ion battery anode.Advanced Energy Materials, 2018, 8(19): 1703155

[16] Wen Z Y, Gu C P, Yin Y J, . Ultra-thin N-doped carbon coated SnO₂ nanotubes as anode material for high performance lithium-ion batteries.Applied Surface Science, 2021, 568: 150969

[17] Liu H, Lei W, Tong Z, . Enhanced diffusion kinetics of Li ions in double-shell hollow carbon fibers.ACS Applied Materials & Interfaces, 2021, 13(21): 24604–24614

[18] Xue L, Li Y, Lin W, . Electrochemical properties and facile preparation of hollow porous V₂O₅ microspheres for lithium-ion batteries.Journal of Colloid and Interface Science, 2023, 638: 231–241

[19] Huang J R, Dai Q S, Wu Q A, . Preparation of hollow SnO₂@N‒C nanospheres for high performance lithium-ion battery.Journal of Electroanalytical Chemistry, 2022, 922: 116741

[20] Zhang W L, Huang Z Y, Zhou H H, . Facile synthesis of ZnS nanoparticles decorated on defective CNTs with excellent performances for lithium-ion batteries anode material.Journal of Alloys and Compounds, 2020, 816: 152633

[21] Han X Y, Zhao D L, Meng W J, . Hollow tremella-like graphene sphere/SnO₂ composite for high performance Li-ion battery anodes.Ceramics International, 2019, 45(13): 16244–16250

[22] Li W, Huang B, Liu Z, . NiS₂ wrapped into graphene with strong Ni–O interaction for advanced sodium and potassium ion batteries.Electrochimica Acta, 2021, 369: 137704

[23] Ji Y L, Lu X M, Luo F Y, . Improved SnO₂/C composite anode enabled by well-designed heterogeneous nanospheres decoration.Chemical Physics Letters, 2021, 763: 138242

[24] Chen F M, Chen Z L, Dai Z Y, . Self-templating synthesis of carbon-encapsulated SnO₂ hollow spheres: a promising anode material for lithium-ion batteries.Journal of Alloys and Compounds, 2020, 816: 152495

[25] Guan S, Wang T, Fu X, . Coherent SnS₂/NiS₂ hetero-nanosheet arrays with fast charge transfer for enhanced sodium-ion storage.Applied Surface Science, 2020, 508: 145241

[26] Khan N A, Rashid N, Junaid M, . NiO/NiS heterostructures: an efficient and stable electrocatalyst for oxygen evolution reaction.ACS Applied Energy Materials, 2019, 2(5): 3587–3594

[27] Xue L C, Chen F M, Zhang Z B, . Fast charge transfer kinetics enabled by carbon-coated, heterostructured SnO₂/SnS_x arrays for robust, flexible lithium-ion batteries.Chem Electro Chem, 2022, 9(2): e202101327

[28] Xue L, Li Y, Lin W, . Electrochemical properties and facile preparation of hollow porous V₂O₅ microspheres for lithium-ion batteries.Journal of Colloid and Interface Science, 2023, 638: 231–241

[29] Wang C P, Zhang Y Y, Li Y S, . Construction of uniform SnS₂/ZnS heterostructure nanosheets embedded in graphene for advanced lithium-ion batteries.Journal of Alloys and Compounds, 2020, 820: 153147

[30] Zhang R, Lu C X, Shi Z L, . Hexagonal phase NiS octahedrons co-modified by 0D-, 1D-, and 2D carbon materials for high performance supercapacitor.Electrochimica Acta, 2019, 311: 83–91

[31] Wang X, Li X, Li Q, . Improved electrochemical performance based on nanostructured SnS₂@CoS₂‒rGO composite anode for sodium-ion batteries.Nano-Micro Letters, 2018, 10(3): 46

[32] Zhang D L, Mou H Y, Lu F, . A novel strategy for 2D/2D NiS/graphene heterostructures as efficient bifunctional electrocatalysts for overall water splitting.Applied Catalysis B: Environmental, 2019, 254: 471–478

[33] Li W L, Chen Z, Hou J M, . SnO₂ nano-crystals anchored on N-doped porous carbon with enhanced lithium storage properties.Applied Surface Science, 2020, 515: 145902

[34] Xiang M, Li J, Feng S, . Synergistic capture and conversion of polysulfides in cathode composites with multidimensional framework structures.Journal of Colloid and Interface Science, 2022, 624: 471–481

[35] Li J J, Li X Y, Fan X, . Holey graphene anchoring of the monodispersed nano-sulfur with covalently-grafted polyaniline for lithium sulfur batteries.Carbon, 2022, 188: 155–165

[36] Ren Y J, Zhang G Q, Huo J H, . Flower-like TiO₂ hollow microspheres with mixed-phases for high-pseudocapacitive lithium storage.Journal of Alloys and Compounds, 2022, 902: 163730

[37] Feng S Q, Wang J F, Gao N S, . Heterogeneous interface of Ni–Mn composite Prussian blue analog-coated structure modulates the adsorption and conversion of polysulfides in lithium‒sulfur batteries.Electrochimica Acta, 2022, 433: 141218

[38] Deepalakshmi T, Nguyen T T, Kim N H, . Rational design of ultrathin 2D tin nickel selenide nanosheets for high-performance flexible supercapacitors.Journal of Materials Chemistry A: Materials for Energy and Sustainability, 2019, 7(42): 24462–24476

[39] Dai H H, Zhao Y, Zhang Z, . Ostwald ripening and sulfur escaping enabled chrysanthemum-like architectures composed of NiS₂/NiS@C heterostructured petals with enhanced charge storage capacity and rate capability.Journal of Electroanalytical Chemistry, 2022, 921: 116671

[40] Yu X L, Chen C M, Li R X, . Construction of SnS₂@MoS₂@rGO heterojunction anode and their half/full sodium ion storage performances.Journal of Alloys and Compounds, 2022, 896: 162784

[41] Li S, Zhao Z, Li C, . SnS₂@C hollow nanospheres with robust structural stability as high-performance anodes for sodium ion batteries.Nano-Micro Letters, 2019, 11(1): 14

[42] Zhang L S, Huang Y P, Zhang Y F, . Flexible electrospun carbon nanofiber@NiS core/sheath hybrid membranes as binder-free anodes for highly reversible lithium storage.Advanced Materials Interfaces, 2016, 3(2): 1500467–1500476

[43] Huang S J, Li H P, Xu G B, . Porous N-doped carbon sheets wrapped MnO in 3D carbon networks as high-performance anode for Li-ion batteries.Electrochimica Acta, 2020, 342: 136115

[44] Xiang M, Zhang H Y, Feng S Q, . Nitrogen-doped carbon–cobalt-modified MnO nanowires as cathodes for high-performance lithium sulfur batteries.Journal of Electroanalytical Chemistry, 2021, 900: 115721

[45] Pei Y R, Zhao M, Zhu Y P, . VN nanoparticle-assembled hollow microspheres/N-doped carbon nanofibers: an anode material for superior potassium storage.Nano Materials Science, 2022, 4(2): 104–112

[46] Han D D, Xiao N R, Liu B, . One-pot synthesis of core/shell structured NiS@onion-like carbon nanocapsule as a high-performance anode material for lithium-ion batteries.Materials Letters, 2017, 196: 119–122

[47] Li H, He Y Y, Dai Y X, . Bimetallic SnS₂/NiS₂@S‒rGO nanocomposite with hierarchical flower-like architecture for superior high rate and ultra-stable half/full sodium-ion batteries.Chemical Engineering Journal, 2022, 427: 131784

[48] Ou X, Cao L, Liang X, . Fabrication of SnS₂/Mn₂SnS₄/carbon heterostructures for sodium-ion batteries with high initial coulombic efficiency and cycling stability.ACS Nano, 2019, 13(3): 3666–3676

[49] Miao Y, Zhao X, Wang X, . Flower-like NiCo₂S₄ nanosheets with high electrochemical performance for sodium-ion batteries.Nano Research, 2020, 13(11): 3041–3047

[50] Jia Z Q, Cui Z H, Tan Y B, . Bimetal-organic frameworks derived ternary metal sulphide nanoparticles embedded in porous carbon spheres/carbon nanotubes as high-performance lithium storage materials.Chemical Engineering Journal, 2019, 370: 89–97

[51] Su L W, Zhou Z, Qin X, . CoCO₃ submicrocube/graphene composites with high lithium storage capability.Nano Energy, 2013, 2(2): 276–282

[52] Yin L, Cheng R, Song Q, . Construction of nanoflower SnS₂ anchored on g-C₃N₄ nanosheets composite as highly efficient anode for lithium ion batteries.Electrochimica Acta, 2019, 293: 408–418

[53] Deng W, Chen X, Liu Z, . Three-dimensional structure-based tin disulfide/vertically aligned carbon nanotube arrays composites as high-performance anode materials for lithium ion batteries.Journal of Power Sources, 2015, 277: 131–138

[54] Liu S, Zhang X, Yan P, . Dual bond enhanced multidimensional constructed composite silicon anode for high-performance lithium ion batteries.ACS Nano, 2019, 13(8): 8854–8864

[55] Pan Q, Xie J, Liu S Y, . Facile one-pot synthesis of ultrathin NiS nanosheets anchored on graphene and the improved electrochemical Li-storage properties.RSC Advances, 2013, 3(12): 3899–3906

[56] Li J, Xu X, Yu X, . Monodisperse CoSn and NiSn nanoparticles supported on commercial carbon as anode for lithium- and potassium-ion batteries.ACS Applied Materials & Interfaces, 2020, 12(4): 4414–4422

[57] Peng H, Li R, Hu J, . Core‒shell Sn‒Ni‒Cu-alloy@carbon nanorods to array as three-dimensional anode by nano electrodeposition for high-performance lithium ion batteries.ACS Applied Materials & Interfaces, 2016, 8(19): 12221–12227

[58] Nguyen T L, Kim D S, Hur J, . Ni–Sn-based hybrid composite anodes for high-performance lithium-ion batteries.Electrochimica Acta, 2018, 278: 25–32

[59] Zhang Y, Wang P, Yin Y, . Heterostructured SnS‒ZnS@C hollow nanoboxes embedded in graphene for high performance lithium and sodium ion batteries.Chemical Engineering Journal, 2019, 356: 1042–1051

[60] Xu C X, Manukyan K V, Adams R A, . One-step solution combustion synthesis of CuO/Cu₂O/C anode for long cycle life Li-ion batteries.Carbon, 2019, 142: 51–59

[61] Ding Y, Wang W W, Bi M F, . CoTe nanorods/rGO composites as a potential anode material for sodium-ion storage.Electrochimica Acta, 2019, 313: 331–340

[62] Cao B K, Liu Z Q, Xu C Y, . High-rate-induced capacity evolution of mesoporous C@SnO₂@C hollow nanospheres for ultra-long cycle lithium-ion batteries.Journal of Power Sources, 2019, 414: 233–241

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