A review of Pt-based electrocatalysts for oxygen reduction reaction
Received date: 16 Jan 2017
Accepted date: 26 Mar 2017
Published date: 07 Sep 2017
Copyright
Development of active and durable electrocatalyst for oxygen reduction reaction (ORR) remains one challenge for the polymer electrolyte membrane fuel cell (PEMFC) technology. Pt-based nanomaterials show the greatest promise as electrocatalyst for this reaction among all current catalytic structures. This review focuses on Pt-based ORR catalyst material development and covers the past achievements, current research status and perspectives in this research field. In particular, several important categories of Pt-based catalytic structures and the research advances are summarized. Key factors affecting the catalyst activity and durability are discussed. An outlook of future research direction of ORR catalyst research is provided.
Changlin ZHANG , Xiaochen SHEN , Yanbo PAN , Zhenmeng PENG . A review of Pt-based electrocatalysts for oxygen reduction reaction[J]. Frontiers in Energy, 2017 , 11(3) : 268 -285 . DOI: 10.1007/s11708-017-0466-6
1 |
NarayananR, El-Sayed M A. Shape-dependent catalytic activity of platinum nanoparticles in colloidal solution.Nano Letters, 2004, 4(7): 1343–1348
|
2 |
PyaytA L, WileyB, XiaY, Chen A, DaltonL . Integration of photonic and silver nanowire plasmonic waveguides.Nature Nanotechnology, 2008, 3(11): 660–665
|
3 |
StewartM E, Anderton C R, ThompsonL B , MariaJ, GrayS K, RogersJ A, Nuzzo R G. Nanostructured plasmonic sensors.Chemical Reviews, 2008, 108(2): 494–521
|
4 |
TaoA R, HabasS, YangP. Shape control of colloidal metal nanocrystals.Small, 2008, 4(3): 310–325
|
5 |
ChngL L, Erathodiyil N, YingJ Y . Nanostructured catalysts for organic transformations.Accounts of Chemical Research, 2013, 46(8): 1825–1837
|
6 |
LinicS, Christopher P, XinH , MarimuthuA. Catalytic and photocatalytic transformations on metal nanoparticles with targeted geometric and plasmonic properties.Accounts of Chemical Research, 2013, 46(8): 1890–1899
|
7 |
LuJ, ElamJ W, StairP C. Synthesis and stabilization of supported metal catalysts by atomic layer deposition.Accounts of Chemical Research, 2013, 46(8): 1806–1815
|
8 |
WuJ, YangH. Platinum-based oxygen reduction electrocatalysts.Accounts of Chemical Research, 2013, 46(8): 1848–1857
|
9 |
ZhangH, JinM, XiongY, Lim B, XiaY . Shape-controlled synthesis of Pd nanocrystals and their catalytic applications.Accounts of Chemical Research, 2013, 46(8): 1783–1794
|
10 |
CuenyaB R. Synthesis and catalytic properties of metal nanoparticles: size, shape, support, composition, and oxidation state effects.Thin Solid Films, 2010, 518(12): 3127–3150
|
11 |
GuoS, WangE. Noble metal nanomaterials: controllable synthesis and application in fuel cells and analytical sensors.Nano Today, 2011, 6(3): 240–264
|
12 |
GuJ, ZhangY W, TaoF. Shape control of bimetallic nanocatalysts through well-designed colloidal chemistry approaches.Chemical Society Reviews, 2012, 41(24): 8050–8065
|
13 |
ZhangL, NiuG, LuN, WangJ, TongL, Wang L, KimM J , XiaY. Continuous and scalable production of well-controlled noble-metal nanocrystals in milliliter-sized droplet reactors.Nano Letters, 2014, 14(11): 6626–6631
|
14 |
ChiM, WangC, LeiY, Wang G, LiD , MoreK L, LupiniA, AllardL F, Markovic N M, StamenkovicV R . Surface faceting and elemental diffusion behaviour at atomic scale for alloy nanoparticles during in situ annealing.Nature Communication, 2015, 6: 1–9
|
15 |
ElmerT, WorallM, WuS, RiffatS B. Fuel cell technology for domestic built environment applications: state-of-the-art review.Renewable & Sustainable Energy Reviews, 2015, 42: 913–931
|
16 |
WangX, ZhangH, LinH, Gupta S, WangC , TaoZ, FuH, WangT, Zheng J, WuG , LiX. Directly converting Fe-doped metal–organic frameworks into highly active and stable Fe-NC catalysts for oxygen reduction in acid.Nano Energy, 2016, 25: 110–119
|
17 |
TianX, LuoJ, NanH, Zou H, ChenR , ShuT, LiX, LiY, SongH, LiaoS, Adzic R R. Transition metal nitride coated with atomic layers of pt as a low-cost, highly stable electrocatalyst for the oxygen reduction reaction.Journal of the American Chemical Society, 2016, 138(5): 1575–1583
|
18 |
WangY J, ZhaoN, FangB, Li H, BiX T , WangH. Carbon-supported pt-based alloy electrocatalysts for the oxygen reduction reaction in polymer electrolyte membrane fuel cells: particle size, shape, and composition manipulation and their impact to activity.Chemical Reviews, 2015, 115(9): 3433–3467
|
19 |
NiuG, Ruditskiy A, VaraM , XiaY. Toward continuous and scalable production of colloidal nanocrystals by switching from batch to droplet reactors.Chemical Society Reviews, 2015, 44(16): 5806–5820
|
20 |
ChungD Y, JunS W, YoonG, Kwon S G, ShinD Y , SeoP, YooJ M, ShinH, Chung Y H, KimH , MunB S, LeeK S, LeeN S, Yoo S J, LimD H , KangK, SungY E, HyeonT. Highly durable and active PtFe nanocatalyst for electrochemical oxygen reduction reaction.Journal of the American Chemical Society, 2015, 137(49): 15478–15485
|
21 |
LototskyyM V, DavidsM W, ToljI, Klochko Y V, SekharB S , ChidzivaS, SmithF, SwanepoelD, Pollet B G. Metal hydride systems for hydrogen storage and supply for stationary and automotive low temperature PEM fuel cell power modules.International Journal of Hydrogen Energy, 2015, 40(35): 11491–11497
|
22 |
AlaswadA, Baroutaji A, OlabiA . Application of fuel cell technologies in the transport sector: current challenges and developments.State of the Art on Energy Developments, 2015, 11: 251
|
23 |
DebeM K. Electrocatalyst approaches and challenges for automotive fuel cells.Nature, 2012, 486(7401): 43–51
|
24 |
JiaoL, ZhangL, WangX, Diankov G, DaiH . Narrow graphene nanoribbons from carbon nanotubes.Nature, 2009, 458(7240): 877–880
|
25 |
MaiyalaganT, JarvisK A, ThereseS, Ferreira P J, ManthiramA . Spinel-type lithium cobalt oxide as a bifunctional electrocatalyst for the oxygen evolution and oxygen reduction reactions.Nature Communications, 2014, 5: 1–8
|
26 |
TianN, ZhouZ Y, SunS G, Ding Y, WangZ L . Synthesis of tetrahexahedral platinum nanocrystals with high-index facets and high electro-oxidation activity.Science, 2007, 316(5825): 732–735
|
27 |
ZhaoZ, XiaZ. Design principles for dual-element-doped carbon nanomaterials as efficient bifunctional catalysts for oxygen reduction and evolution reactions.ACS Catalysis, 2016, 6(3): 1553–1558
|
28 |
ENERGY. GOV Office of Energy Efficiency & Renewable Energy. The U.S. Department of Energy (DOE) Technical Plan—Fuel cell technologies office multi-year research, development and demonstration plan. https://energy.gov/eere/fuelcells/downloads/fuel-cell-technologies-office-multi-year-research-development-and-22,2017-02
|
29 |
StamenkovicV R, FowlerB, MunB S, Wang G, RossP N , LucasC A, Marković N M. Improved oxygen reduction activity on Pt3Ni(111) via increased surface site availability.Science, 2007, 315(5811): 493–497
|
30 |
GreeleyJ, Stephens I, BondarenkoA , JohanssonT P, HansenH A, JaramilloT, Rossmeisl J, ChorkendorffI , NørskovJ K. Alloys of platinum and early transition metals as oxygen reduction electrocatalysts.Nature Chemistry, 2009, 1(7): 552–556
|
31 |
StamenkovicV R, MunB S, ArenzM, Mayrhofer K J J, LucasC A , WangG, RossP N, MarkovicN M . Trends in electrocatalysis on extended and nanoscale Pt-bimetallic alloy surfaces.Nature Materials, 2007, 6(3): 241–247
|
32 |
SunS, MurrayC B, WellerD, Folks L, MoserA . Monodisperse FePt nanoparticles and ferromagnetic FePt nanocrystal superlattices.Science, 2000, 287(5460): 1989–1992
|
33 |
CuiC, GanL, HeggenM, Rudi S, StrasserP . Compositional segregation in shaped Pt alloy nanoparticles and their structural behaviour during electrocatalysis.Nature Materials, 2013, 12(8): 765–771
|
34 |
ZhangC, HwangS Y, TroutA, Peng Z. Solid-state chemistry-enabled scalable production of octahedral Pt–Ni alloy electrocatalyst for oxygen reduction reaction.Journal of the American Chemical Society, 2014, 136(22): 7805–7808
|
35 |
ChoiS I, LeeS U, KimW Y, Choi R, HongK , NamK M, HanS W, ParkJ T. Composition-controlled PtCo alloy nanocubes with tuned electrocatalytic activity for oxygen reduction.ACS Applied Materials & Interfaces, 2012, 4(11): 6228–6234
|
36 |
OezaslanM, Hasché F, StrasserP . PtCu3, PtCu and Pt3Cu alloy nanoparticle electrocatalysts for oxygen reduction reaction in alkaline and acidic media.Journal of the Electrochemical Society, 2012, 159(4): B444–B454
|
37 |
JeonM K, ZhangY, McGinnP J. A comparative study of PtCo, PtCr, and PtCoCr catalysts for oxygen electro-reduction reaction.Electrochimica Acta, 2010, 55(19): 5318–5325
|
38 |
KoffiR C, Coutanceau C, GarnierE , LégerJ M, Lamy C. Synthesis, characterization and electrocatalytic behaviour of non-alloyed PtCr methanol tolerant nanoelectrocatalysts for the oxygen reduction reaction (ORR).Electrochimica Acta, 2005, 50(20): 4117–4127
|
39 |
KangY, MurrayC B. Synthesis and electrocatalytic properties of cubic Mn-Pt nanocrystals (nanocubes).Journal of the American Chemical Society, 2010, 132(22): 7568–7569
|
40 |
DaiY, OuL, LiangW, Yang F, LiuY , ChenS. Efficient and superiorly durable Pt-Lean electrocatalysts of Pt-W alloys for the oxygen reduction reaction.Journal of Physical Chemistry C, 2011, 115(5): 2162–2168
|
41 |
HuangX, ZhaoZ, CaoL, Chen Y, ZhuE , LinZ, LiM, YanA, Zettl A, WangY M , DuanX, Mueller T, HuangY . High-performance transition metal–doped Pt3Ni octahedra for oxygen reduction reaction.Science, 2015, 348(6240): 1230–1234
|
42 |
WangC, LiD, ChiM, Pearson J, RankinR B , GreeleyJ, DuanZ, WangG, van der VlietD, MoreK L, MarkovicN M , StamenkovicV R. Rational development of ternary alloy electrocatalysts.Journal of Physical Chemistry Letters, 2012, 3(12): 1668–1673
|
43 |
ZhangC, Sandorf W, PengZ . Octahedral Pt2CuNi uniform alloy nanoparticle catalyst with high activity and promising stability for oxygen reduction reaction.ACS Catalysis, 2015, 5(4): 2296–2300
|
44 |
Escudero-EscribanoM, Malacrida P, HansenM H , Vej-HansenU G, Velázquez-Palenzuela A, TripkovicV , SchiøtzJ, Rossmeisl J, StephensI E , ChorkendorffI. Tuning the activity of Pt alloy electrocatalysts by means of the lanthanide contraction.Science, 2016, 352(6281): 73–76
|
45 |
ShaoM, PelesA, ShoemakerK. Electrocatalysis on platinum nanoparticles: particle size effect on oxygen reduction reaction activity.Nano Letters, 2011, 11(9): 3714–3719
|
46 |
NesselbergerM, AshtonS, MeierJ C, Katsounaros I, MayrhoferK J , ArenzM. The particle size effect on the oxygen reduction reaction activity of Pt catalysts: influence of electrolyte and relation to single crystal models.Journal of the American Chemical Society, 2011, 133(43): 17428–17433
|
47 |
LiD, WangC, StrmcnikD S , TripkovicD V, SunX, KangY, Chi M, SnyderJ D , van der VlietD, TsaiY, StamenkovicV R , SunS, Markovic N M. Functional links between Pt single crystal morphology and nanoparticles with different size and shape: the oxygen reduction reaction case.Energy & Environmental Science, 2014, 7(12): 4061–4069
|
48 |
LeontyevI, Belenov S, GutermanV , Haghi-AshtianiP, Shaganov A, DkhilB . Catalytic activity of carbon-supported Pt nanoelectrocatalysts. Why reducing the size of Pt nanoparticles is not always beneficial?Journal of Physical Chemistry C, 2011, 115(13): 5429–5434
|
49 |
WeiG F, LiuZ P. Optimum nanoparticles for electrocatalytic oxygen reduction: the size, shape and new design.Physical Chemistry Chemical Physics, 2013, 15(42): 18555–18561
|
50 |
LiuY, ZhangL, WillisB G, Mustain W. Importance of particle size and distribution in achieving high-activity, high-stability oxygen reduction catalysts.ACS Catalysis, 2015, 5(3): 1560–1567
|
51 |
ViswanathanV, WangF Y F. Theoretical analysis of the effect of particle size and support on the kinetics of oxygen reduction reaction on platinum nanoparticles.Nanoscale, 2012, 4(16): 5110–5117
|
52 |
TripkovićV, Cerri I, BligaardT , RossmeislJ. The influence of particle shape and size on the activity of platinum nanoparticles for oxygen reduction reaction: a density functional theory study.Catalysis Letters, 2014, 144(3): 380–388
|
53 |
ZhangC, HwangS Y, PengZ. Size-dependent oxygen reduction property of octahedral Pt-Ni nanoparticle electrocatalysts.Journal of Materials Chemistry A, Materials for Energy and Sustainability, 2014, 2(46): 19778–19787
|
54 |
DengY J, Tripkovic V, RossmeislJ , ArenzM. Oxygen reduction reaction on Pt overlayers deposited onto a gold film: ligand, strain, and ensemble effect.ACS Catalysis, 2016, 6(2): 671–676
|
55 |
ZhaoX, ChenS, FangZ, Ding J, SangW , WangY, ZhaoJ, PengZ, Zeng J. Octahedral Pd@Pt1.8Ni core-shell nanocrystals with ultrathin PtNi alloy shells as active catalysts for oxygen reduction reaction.Journal of the American Chemical Society, 2015, 137(8): 2804–2807
|
56 |
LiQ, WuL, WuG, SuD, LvH, ZhangS, ZhuW, Casimir A, ZhuH , Mendoza-GarciaA, Sun S. New approach to fully ordered fct-FePt nanoparticles for much enhanced electrocatalysis in acid.Nano Letters, 2015, 15(4): 2468–2473
|
57 |
ChenC, KangY, HuoZ, Zhu Z, HuangW , XinH L, SnyderJ D, LiD, HerronJ A, MavrikakisM , ChiM, MoreK L, LiY, Markovic N M, SomorjaiG A , YangP, Stamenkovic V R. Highly crystalline multimetallic nanoframes with three-dimensional electrocatalytic surfaces.Science, 2014, 343(6177): 1339–1343
|
58 |
LiM, ZhaoZ, ChengT, Fortunelli A, ChenC Y , YuR, ZhangQ, GuL, Merinov B, LinZ , ZhuE, YuT, JiaQ, Guo J, ZhangL , GoddardW III, Huang Y, DuanX . Ultrafine jagged platinum nanowires enable ultrahigh mass activity for the oxygen reduction reaction.Science, 2016, 354(6318): 1414–1419
|
59 |
AhmadiT S, WangZ L, GreenT C, Henglein A, El-SayedM A . Shape-controlled synthesis of colloidal platinum nanoparticles.Science, 1996, 272(5270): 1924–1925
|
60 |
DengL, HuW, DengH, Xiao S, TangJ . Au–Ag bimetallic nanoparticles: surface segregation and atomic-scale structure.Journal of Physical Chemistry C, 2011, 115(23): 11355–11363
|
61 |
DevivaraprasadR, Kar T, ChakrabortyA , SinghR K, Neergat M. Reconstruction and dissolution of shape-controlled Pt nanoparticles in acidic electrolytes.Physical Chemistry Chemical Physics, 2016, 18(16): 11220–11232
|
62 |
GanL, CuiC, HeggenM, Dionigi F, RudiS , StrasserP. Element-specific anisotropic growth of shaped platinum alloy nanocrystals.Science, 2014, 346(6216): 1502–1506
|
63 |
GanL, HeggenM, CuiC, Strasser P. HeggenM,CuiC,StrasserP.Thermal facet healing of concave octahedral Pt–Ni nanoparticles imaged in situ at the atomic scale: implications for the rational synthesis of durable high-performance ORR electrocatalysts.ACS Catalysis, 2016, 6(2): 692–695
|
64 |
LeeK S, El-Sayed M A. Gold and Silver nanoparticles in sensing and imaging: sensitivity of plasmon response to size, shape, and metal composition.Journal of Physical Chemistry B, 2006, 110(39): 19220–19225
|
65 |
LiaoH G, CuiL, WhitelamS, Zheng H. Real-time imaging of Pt3Fe nanorod growth in solution.Science, 2012, 336(6084): 1011–1014
|
66 |
LiaoH G, Zherebetskyy D, XinH , CzarnikC, ErciusP, ElmlundH, Pan M, WangL W , ZhengH. Facet development during platinum nanocube growth.Science, 2014, 345(6199): 916–919
|
67 |
MohantyA, GargN, JinR. A universal approach to the synthesis of noble metal nanodendrites and their catalytic properties.Angewandte Chemie International Edition, 2010, 49(29): 4962–4966
|
68 |
PanY T, WuJ, YinX, Yang H. In situ ETEM study of composition redistribution in Pt-Ni octahedral catalysts for electrochemical reduction of oxygen.AIChE Journal, 2016, 62(2): 399–407
|
69 |
PengL, RingeE, van DuyneR P , MarksL D. Segregation in bimetallic nanoparticles.Physical Chemistry Chemical Physics, 2015, 17(42): 27940–27951
|
70 |
QiY, WuJ, ZhangH, Jiang Y, JinC , FuM, YangH, YangD. Facile synthesis of Rh–Pd alloy nanodendrites as highly active and durable electrocatalysts for oxygen reduction reaction.Nanoscale, 2014, 6(12): 7012–7018
|
71 |
ChoiS I, XieS, ShaoM, Odell J H, LuN , PengH C, Protsailo L, GuerreroS , ParkJ, XiaX, WangJ, Kim M J, XiaY . Synthesis and characterization of 9 nm Pt–Ni octahedra with a record high activity of 3.3 A/mgPt for the oxygen reduction reaction.Nano Letters, 2013, 13(7): 3420–3425
|
72 |
WuJ, QiL, YouH, Gross A, LiJ , YangH. Icosahedral platinum alloy nanocrystals with enhanced electrocatalytic activities.Journal of the American Chemical Society, 2012, 134(29): 11880–11883
|
73 |
CoronaB, HowardM, ZhangL, Henkelman G. Computational screening of core@ shell nanoparticles for the hydrogen evolution and oxygen reduction reactions.Journal of Chemical Physics, 2016, 145(24): 244708
|
74 |
OezaslanM, Hasché F, StrasserP . Pt-based core–shell catalyst architectures for oxygen fuel cell electrodes.Journal of Physical Chemistry Letters, 2013, 4(19): 3273–3291
|
75 |
StricklerA L, Jackson A, JaramilloT F . Active and stable Ir@ Pt core–shell catalysts for electrochemical oxygen reduction.ACS Energy Letters, 2017, 2(1): 244–249
|
76 |
ShenL L, ZhangG R, MiaoS, Liu J, XuB Q . Core-shell nanostructured Au@ Nim Pt2 electrocatalysts with enhanced activity and durability for oxygen reduction reaction.ACS Catalysis, 2016, 6(3): 1680–1690
|
77 |
StrasserP. Free electrons to molecular bonds and back: closing the energetic oxygen reduction (ORR)–oxygen evolution (OER) cycle using core–shell nanoelectrocatalysts.Accounts of Chemical Research, 2016, 49(11): 2658–2668
|
78 |
StrasserP, Kühl S. Dealloyed Pt-based core-shell oxygen reduction electrocatalysts.Nano Energy, 2016, 29: 166–177
|
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