A review of Pt-based electrocatalysts for oxygen reduction reaction
Changlin ZHANG, Xiaochen SHEN, Yanbo PAN, Zhenmeng PENG
A review of Pt-based electrocatalysts for oxygen reduction reaction
Development of active and durable electrocatalyst for oxygen reduction reaction (ORR) remains one challenge for the polymer electrolyte membrane fuel cell (PEMFC) technology. Pt-based nanomaterials show the greatest promise as electrocatalyst for this reaction among all current catalytic structures. This review focuses on Pt-based ORR catalyst material development and covers the past achievements, current research status and perspectives in this research field. In particular, several important categories of Pt-based catalytic structures and the research advances are summarized. Key factors affecting the catalyst activity and durability are discussed. An outlook of future research direction of ORR catalyst research is provided.
oxygen reduction reaction (ORR) / electrocatalysis / platinum catalyst / activity / durability
[1] |
NarayananR, El-Sayed M A. Shape-dependent catalytic activity of platinum nanoparticles in colloidal solution.Nano Letters, 2004, 4(7): 1343–1348
CrossRef
Google scholar
|
[2] |
PyaytA L, WileyB, XiaY, Chen A, DaltonL . Integration of photonic and silver nanowire plasmonic waveguides.Nature Nanotechnology, 2008, 3(11): 660–665
CrossRef
Google scholar
|
[3] |
StewartM E, Anderton C R, ThompsonL B , MariaJ, GrayS K, RogersJ A, Nuzzo R G. Nanostructured plasmonic sensors.Chemical Reviews, 2008, 108(2): 494–521
CrossRef
Google scholar
|
[4] |
TaoA R, HabasS, YangP. Shape control of colloidal metal nanocrystals.Small, 2008, 4(3): 310–325
CrossRef
Google scholar
|
[5] |
ChngL L, Erathodiyil N, YingJ Y . Nanostructured catalysts for organic transformations.Accounts of Chemical Research, 2013, 46(8): 1825–1837
CrossRef
Google scholar
|
[6] |
LinicS, Christopher P, XinH , MarimuthuA. Catalytic and photocatalytic transformations on metal nanoparticles with targeted geometric and plasmonic properties.Accounts of Chemical Research, 2013, 46(8): 1890–1899
CrossRef
Google scholar
|
[7] |
LuJ, ElamJ W, StairP C. Synthesis and stabilization of supported metal catalysts by atomic layer deposition.Accounts of Chemical Research, 2013, 46(8): 1806–1815
CrossRef
Google scholar
|
[8] |
WuJ, YangH. Platinum-based oxygen reduction electrocatalysts.Accounts of Chemical Research, 2013, 46(8): 1848–1857
CrossRef
Google scholar
|
[9] |
ZhangH, JinM, XiongY, Lim B, XiaY . Shape-controlled synthesis of Pd nanocrystals and their catalytic applications.Accounts of Chemical Research, 2013, 46(8): 1783–1794
CrossRef
Google scholar
|
[10] |
CuenyaB R. Synthesis and catalytic properties of metal nanoparticles: size, shape, support, composition, and oxidation state effects.Thin Solid Films, 2010, 518(12): 3127–3150
CrossRef
Google scholar
|
[11] |
GuoS, WangE. Noble metal nanomaterials: controllable synthesis and application in fuel cells and analytical sensors.Nano Today, 2011, 6(3): 240–264
CrossRef
Google scholar
|
[12] |
GuJ, ZhangY W, TaoF. Shape control of bimetallic nanocatalysts through well-designed colloidal chemistry approaches.Chemical Society Reviews, 2012, 41(24): 8050–8065
CrossRef
Google scholar
|
[13] |
ZhangL, NiuG, LuN, WangJ, TongL, Wang L, KimM J , XiaY. Continuous and scalable production of well-controlled noble-metal nanocrystals in milliliter-sized droplet reactors.Nano Letters, 2014, 14(11): 6626–6631
CrossRef
Google scholar
|
[14] |
ChiM, WangC, LeiY, Wang G, LiD , MoreK L, LupiniA, AllardL F, Markovic N M, StamenkovicV R . Surface faceting and elemental diffusion behaviour at atomic scale for alloy nanoparticles during in situ annealing.Nature Communication, 2015, 6: 1–9
|
[15] |
ElmerT, WorallM, WuS, RiffatS B. Fuel cell technology for domestic built environment applications: state-of-the-art review.Renewable & Sustainable Energy Reviews, 2015, 42: 913–931
CrossRef
Google scholar
|
[16] |
WangX, ZhangH, LinH, Gupta S, WangC , TaoZ, FuH, WangT, Zheng J, WuG , LiX. Directly converting Fe-doped metal–organic frameworks into highly active and stable Fe-NC catalysts for oxygen reduction in acid.Nano Energy, 2016, 25: 110–119
CrossRef
Google scholar
|
[17] |
TianX, LuoJ, NanH, Zou H, ChenR , ShuT, LiX, LiY, SongH, LiaoS, Adzic R R. Transition metal nitride coated with atomic layers of pt as a low-cost, highly stable electrocatalyst for the oxygen reduction reaction.Journal of the American Chemical Society, 2016, 138(5): 1575–1583
CrossRef
Google scholar
|
[18] |
WangY J, ZhaoN, FangB, Li H, BiX T , WangH. Carbon-supported pt-based alloy electrocatalysts for the oxygen reduction reaction in polymer electrolyte membrane fuel cells: particle size, shape, and composition manipulation and their impact to activity.Chemical Reviews, 2015, 115(9): 3433–3467
CrossRef
Google scholar
|
[19] |
NiuG, Ruditskiy A, VaraM , XiaY. Toward continuous and scalable production of colloidal nanocrystals by switching from batch to droplet reactors.Chemical Society Reviews, 2015, 44(16): 5806–5820
CrossRef
Google scholar
|
[20] |
ChungD Y, JunS W, YoonG, Kwon S G, ShinD Y , SeoP, YooJ M, ShinH, Chung Y H, KimH , MunB S, LeeK S, LeeN S, Yoo S J, LimD H , KangK, SungY E, HyeonT. Highly durable and active PtFe nanocatalyst for electrochemical oxygen reduction reaction.Journal of the American Chemical Society, 2015, 137(49): 15478–15485
CrossRef
Google scholar
|
[21] |
LototskyyM V, DavidsM W, ToljI, Klochko Y V, SekharB S , ChidzivaS, SmithF, SwanepoelD, Pollet B G. Metal hydride systems for hydrogen storage and supply for stationary and automotive low temperature PEM fuel cell power modules.International Journal of Hydrogen Energy, 2015, 40(35): 11491–11497
CrossRef
Google scholar
|
[22] |
AlaswadA, Baroutaji A, OlabiA . Application of fuel cell technologies in the transport sector: current challenges and developments.State of the Art on Energy Developments, 2015, 11: 251
|
[23] |
DebeM K. Electrocatalyst approaches and challenges for automotive fuel cells.Nature, 2012, 486(7401): 43–51
CrossRef
Google scholar
|
[24] |
JiaoL, ZhangL, WangX, Diankov G, DaiH . Narrow graphene nanoribbons from carbon nanotubes.Nature, 2009, 458(7240): 877–880
CrossRef
Google scholar
|
[25] |
MaiyalaganT, JarvisK A, ThereseS, Ferreira P J, ManthiramA . Spinel-type lithium cobalt oxide as a bifunctional electrocatalyst for the oxygen evolution and oxygen reduction reactions.Nature Communications, 2014, 5: 1–8
CrossRef
Google scholar
|
[26] |
TianN, ZhouZ Y, SunS G, Ding Y, WangZ L . Synthesis of tetrahexahedral platinum nanocrystals with high-index facets and high electro-oxidation activity.Science, 2007, 316(5825): 732–735
CrossRef
Google scholar
|
[27] |
ZhaoZ, XiaZ. Design principles for dual-element-doped carbon nanomaterials as efficient bifunctional catalysts for oxygen reduction and evolution reactions.ACS Catalysis, 2016, 6(3): 1553–1558
CrossRef
Google scholar
|
[28] |
ENERGY. GOV Office of Energy Efficiency & Renewable Energy. The U.S. Department of Energy (DOE) Technical Plan—Fuel cell technologies office multi-year research, development and demonstration plan. https://energy.gov/eere/fuelcells/downloads/fuel-cell-technologies-office-multi-year-research-development-and-22,2017-02
|
[29] |
StamenkovicV R, FowlerB, MunB S, Wang G, RossP N , LucasC A, Marković N M. Improved oxygen reduction activity on Pt3Ni(111) via increased surface site availability.Science, 2007, 315(5811): 493–497
CrossRef
Google scholar
|
[30] |
GreeleyJ, Stephens I, BondarenkoA , JohanssonT P, HansenH A, JaramilloT, Rossmeisl J, ChorkendorffI , NørskovJ K. Alloys of platinum and early transition metals as oxygen reduction electrocatalysts.Nature Chemistry, 2009, 1(7): 552–556
CrossRef
Google scholar
|
[31] |
StamenkovicV R, MunB S, ArenzM, Mayrhofer K J J, LucasC A , WangG, RossP N, MarkovicN M . Trends in electrocatalysis on extended and nanoscale Pt-bimetallic alloy surfaces.Nature Materials, 2007, 6(3): 241–247
CrossRef
Google scholar
|
[32] |
SunS, MurrayC B, WellerD, Folks L, MoserA . Monodisperse FePt nanoparticles and ferromagnetic FePt nanocrystal superlattices.Science, 2000, 287(5460): 1989–1992
CrossRef
Google scholar
|
[33] |
CuiC, GanL, HeggenM, Rudi S, StrasserP . Compositional segregation in shaped Pt alloy nanoparticles and their structural behaviour during electrocatalysis.Nature Materials, 2013, 12(8): 765–771
CrossRef
Google scholar
|
[34] |
ZhangC, HwangS Y, TroutA, Peng Z. Solid-state chemistry-enabled scalable production of octahedral Pt–Ni alloy electrocatalyst for oxygen reduction reaction.Journal of the American Chemical Society, 2014, 136(22): 7805–7808
CrossRef
Google scholar
|
[35] |
ChoiS I, LeeS U, KimW Y, Choi R, HongK , NamK M, HanS W, ParkJ T. Composition-controlled PtCo alloy nanocubes with tuned electrocatalytic activity for oxygen reduction.ACS Applied Materials & Interfaces, 2012, 4(11): 6228–6234
CrossRef
Google scholar
|
[36] |
OezaslanM, Hasché F, StrasserP . PtCu3, PtCu and Pt3Cu alloy nanoparticle electrocatalysts for oxygen reduction reaction in alkaline and acidic media.Journal of the Electrochemical Society, 2012, 159(4): B444–B454
CrossRef
Google scholar
|
[37] |
JeonM K, ZhangY, McGinnP J. A comparative study of PtCo, PtCr, and PtCoCr catalysts for oxygen electro-reduction reaction.Electrochimica Acta, 2010, 55(19): 5318–5325
CrossRef
Google scholar
|
[38] |
KoffiR C, Coutanceau C, GarnierE , LégerJ M, Lamy C. Synthesis, characterization and electrocatalytic behaviour of non-alloyed PtCr methanol tolerant nanoelectrocatalysts for the oxygen reduction reaction (ORR).Electrochimica Acta, 2005, 50(20): 4117–4127
CrossRef
Google scholar
|
[39] |
KangY, MurrayC B. Synthesis and electrocatalytic properties of cubic Mn-Pt nanocrystals (nanocubes).Journal of the American Chemical Society, 2010, 132(22): 7568–7569
CrossRef
Google scholar
|
[40] |
DaiY, OuL, LiangW, Yang F, LiuY , ChenS. Efficient and superiorly durable Pt-Lean electrocatalysts of Pt-W alloys for the oxygen reduction reaction.Journal of Physical Chemistry C, 2011, 115(5): 2162–2168
CrossRef
Google scholar
|
[41] |
HuangX, ZhaoZ, CaoL, Chen Y, ZhuE , LinZ, LiM, YanA, Zettl A, WangY M , DuanX, Mueller T, HuangY . High-performance transition metal–doped Pt3Ni octahedra for oxygen reduction reaction.Science, 2015, 348(6240): 1230–1234
CrossRef
Google scholar
|
[42] |
WangC, LiD, ChiM, Pearson J, RankinR B , GreeleyJ, DuanZ, WangG, van der VlietD, MoreK L, MarkovicN M , StamenkovicV R. Rational development of ternary alloy electrocatalysts.Journal of Physical Chemistry Letters, 2012, 3(12): 1668–1673
CrossRef
Google scholar
|
[43] |
ZhangC, Sandorf W, PengZ . Octahedral Pt2CuNi uniform alloy nanoparticle catalyst with high activity and promising stability for oxygen reduction reaction.ACS Catalysis, 2015, 5(4): 2296–2300
CrossRef
Google scholar
|
[44] |
Escudero-EscribanoM, Malacrida P, HansenM H , Vej-HansenU G, Velázquez-Palenzuela A, TripkovicV , SchiøtzJ, Rossmeisl J, StephensI E , ChorkendorffI. Tuning the activity of Pt alloy electrocatalysts by means of the lanthanide contraction.Science, 2016, 352(6281): 73–76
CrossRef
Google scholar
|
[45] |
ShaoM, PelesA, ShoemakerK. Electrocatalysis on platinum nanoparticles: particle size effect on oxygen reduction reaction activity.Nano Letters, 2011, 11(9): 3714–3719
CrossRef
Google scholar
|
[46] |
NesselbergerM, AshtonS, MeierJ C, Katsounaros I, MayrhoferK J , ArenzM. The particle size effect on the oxygen reduction reaction activity of Pt catalysts: influence of electrolyte and relation to single crystal models.Journal of the American Chemical Society, 2011, 133(43): 17428–17433
CrossRef
Google scholar
|
[47] |
LiD, WangC, StrmcnikD S , TripkovicD V, SunX, KangY, Chi M, SnyderJ D , van der VlietD, TsaiY, StamenkovicV R , SunS, Markovic N M. Functional links between Pt single crystal morphology and nanoparticles with different size and shape: the oxygen reduction reaction case.Energy & Environmental Science, 2014, 7(12): 4061–4069
CrossRef
Google scholar
|
[48] |
LeontyevI, Belenov S, GutermanV , Haghi-AshtianiP, Shaganov A, DkhilB . Catalytic activity of carbon-supported Pt nanoelectrocatalysts. Why reducing the size of Pt nanoparticles is not always beneficial?Journal of Physical Chemistry C, 2011, 115(13): 5429–5434
CrossRef
Google scholar
|
[49] |
WeiG F, LiuZ P. Optimum nanoparticles for electrocatalytic oxygen reduction: the size, shape and new design.Physical Chemistry Chemical Physics, 2013, 15(42): 18555–18561
CrossRef
Google scholar
|
[50] |
LiuY, ZhangL, WillisB G, Mustain W. Importance of particle size and distribution in achieving high-activity, high-stability oxygen reduction catalysts.ACS Catalysis, 2015, 5(3): 1560–1567
CrossRef
Google scholar
|
[51] |
ViswanathanV, WangF Y F. Theoretical analysis of the effect of particle size and support on the kinetics of oxygen reduction reaction on platinum nanoparticles.Nanoscale, 2012, 4(16): 5110–5117
CrossRef
Google scholar
|
[52] |
TripkovićV, Cerri I, BligaardT , RossmeislJ. The influence of particle shape and size on the activity of platinum nanoparticles for oxygen reduction reaction: a density functional theory study.Catalysis Letters, 2014, 144(3): 380–388
CrossRef
Google scholar
|
[53] |
ZhangC, HwangS Y, PengZ. Size-dependent oxygen reduction property of octahedral Pt-Ni nanoparticle electrocatalysts.Journal of Materials Chemistry A, Materials for Energy and Sustainability, 2014, 2(46): 19778–19787
CrossRef
Google scholar
|
[54] |
DengY J, Tripkovic V, RossmeislJ , ArenzM. Oxygen reduction reaction on Pt overlayers deposited onto a gold film: ligand, strain, and ensemble effect.ACS Catalysis, 2016, 6(2): 671–676
CrossRef
Google scholar
|
[55] |
ZhaoX, ChenS, FangZ, Ding J, SangW , WangY, ZhaoJ, PengZ, Zeng J. Octahedral Pd@Pt1.8Ni core-shell nanocrystals with ultrathin PtNi alloy shells as active catalysts for oxygen reduction reaction.Journal of the American Chemical Society, 2015, 137(8): 2804–2807
CrossRef
Google scholar
|
[56] |
LiQ, WuL, WuG, SuD, LvH, ZhangS, ZhuW, Casimir A, ZhuH , Mendoza-GarciaA, Sun S. New approach to fully ordered fct-FePt nanoparticles for much enhanced electrocatalysis in acid.Nano Letters, 2015, 15(4): 2468–2473
CrossRef
Google scholar
|
[57] |
ChenC, KangY, HuoZ, Zhu Z, HuangW , XinH L, SnyderJ D, LiD, HerronJ A, MavrikakisM , ChiM, MoreK L, LiY, Markovic N M, SomorjaiG A , YangP, Stamenkovic V R. Highly crystalline multimetallic nanoframes with three-dimensional electrocatalytic surfaces.Science, 2014, 343(6177): 1339–1343
CrossRef
Google scholar
|
[58] |
LiM, ZhaoZ, ChengT, Fortunelli A, ChenC Y , YuR, ZhangQ, GuL, Merinov B, LinZ , ZhuE, YuT, JiaQ, Guo J, ZhangL , GoddardW III, Huang Y, DuanX . Ultrafine jagged platinum nanowires enable ultrahigh mass activity for the oxygen reduction reaction.Science, 2016, 354(6318): 1414–1419
CrossRef
Google scholar
|
[59] |
AhmadiT S, WangZ L, GreenT C, Henglein A, El-SayedM A . Shape-controlled synthesis of colloidal platinum nanoparticles.Science, 1996, 272(5270): 1924–1925
CrossRef
Google scholar
|
[60] |
DengL, HuW, DengH, Xiao S, TangJ . Au–Ag bimetallic nanoparticles: surface segregation and atomic-scale structure.Journal of Physical Chemistry C, 2011, 115(23): 11355–11363
CrossRef
Google scholar
|
[61] |
DevivaraprasadR, Kar T, ChakrabortyA , SinghR K, Neergat M. Reconstruction and dissolution of shape-controlled Pt nanoparticles in acidic electrolytes.Physical Chemistry Chemical Physics, 2016, 18(16): 11220–11232
CrossRef
Google scholar
|
[62] |
GanL, CuiC, HeggenM, Dionigi F, RudiS , StrasserP. Element-specific anisotropic growth of shaped platinum alloy nanocrystals.Science, 2014, 346(6216): 1502–1506
CrossRef
Google scholar
|
[63] |
GanL, HeggenM, CuiC, Strasser P. HeggenM,CuiC,StrasserP.Thermal facet healing of concave octahedral Pt–Ni nanoparticles imaged in situ at the atomic scale: implications for the rational synthesis of durable high-performance ORR electrocatalysts.ACS Catalysis, 2016, 6(2): 692–695
CrossRef
Google scholar
|
[64] |
LeeK S, El-Sayed M A. Gold and Silver nanoparticles in sensing and imaging: sensitivity of plasmon response to size, shape, and metal composition.Journal of Physical Chemistry B, 2006, 110(39): 19220–19225
CrossRef
Google scholar
|
[65] |
LiaoH G, CuiL, WhitelamS, Zheng H. Real-time imaging of Pt3Fe nanorod growth in solution.Science, 2012, 336(6084): 1011–1014
CrossRef
Google scholar
|
[66] |
LiaoH G, Zherebetskyy D, XinH , CzarnikC, ErciusP, ElmlundH, Pan M, WangL W , ZhengH. Facet development during platinum nanocube growth.Science, 2014, 345(6199): 916–919
CrossRef
Google scholar
|
[67] |
MohantyA, GargN, JinR. A universal approach to the synthesis of noble metal nanodendrites and their catalytic properties.Angewandte Chemie International Edition, 2010, 49(29): 4962–4966
CrossRef
Google scholar
|
[68] |
PanY T, WuJ, YinX, Yang H. In situ ETEM study of composition redistribution in Pt-Ni octahedral catalysts for electrochemical reduction of oxygen.AIChE Journal, 2016, 62(2): 399–407
CrossRef
Google scholar
|
[69] |
PengL, RingeE, van DuyneR P , MarksL D. Segregation in bimetallic nanoparticles.Physical Chemistry Chemical Physics, 2015, 17(42): 27940–27951
CrossRef
Google scholar
|
[70] |
QiY, WuJ, ZhangH, Jiang Y, JinC , FuM, YangH, YangD. Facile synthesis of Rh–Pd alloy nanodendrites as highly active and durable electrocatalysts for oxygen reduction reaction.Nanoscale, 2014, 6(12): 7012–7018
CrossRef
Google scholar
|
[71] |
ChoiS I, XieS, ShaoM, Odell J H, LuN , PengH C, Protsailo L, GuerreroS , ParkJ, XiaX, WangJ, Kim M J, XiaY . Synthesis and characterization of 9 nm Pt–Ni octahedra with a record high activity of 3.3 A/mgPt for the oxygen reduction reaction.Nano Letters, 2013, 13(7): 3420–3425
CrossRef
Google scholar
|
[72] |
WuJ, QiL, YouH, Gross A, LiJ , YangH. Icosahedral platinum alloy nanocrystals with enhanced electrocatalytic activities.Journal of the American Chemical Society, 2012, 134(29): 11880–11883
CrossRef
Google scholar
|
[73] |
CoronaB, HowardM, ZhangL, Henkelman G. Computational screening of core@ shell nanoparticles for the hydrogen evolution and oxygen reduction reactions.Journal of Chemical Physics, 2016, 145(24): 244708
CrossRef
Google scholar
|
[74] |
OezaslanM, Hasché F, StrasserP . Pt-based core–shell catalyst architectures for oxygen fuel cell electrodes.Journal of Physical Chemistry Letters, 2013, 4(19): 3273–3291
CrossRef
Google scholar
|
[75] |
StricklerA L, Jackson A, JaramilloT F . Active and stable Ir@ Pt core–shell catalysts for electrochemical oxygen reduction.ACS Energy Letters, 2017, 2(1): 244–249
CrossRef
Google scholar
|
[76] |
ShenL L, ZhangG R, MiaoS, Liu J, XuB Q . Core-shell nanostructured Au@ Nim Pt2 electrocatalysts with enhanced activity and durability for oxygen reduction reaction.ACS Catalysis, 2016, 6(3): 1680–1690
CrossRef
Google scholar
|
[77] |
StrasserP. Free electrons to molecular bonds and back: closing the energetic oxygen reduction (ORR)–oxygen evolution (OER) cycle using core–shell nanoelectrocatalysts.Accounts of Chemical Research, 2016, 49(11): 2658–2668
CrossRef
Google scholar
|
[78] |
StrasserP, Kühl S. Dealloyed Pt-based core-shell oxygen reduction electrocatalysts.Nano Energy, 2016, 29: 166–177
CrossRef
Google scholar
|
/
〈 | 〉 |