Theoretical study on flow and radiation in tubular solar photocatalytic reactor

Qingyu WEI, Yao WANG, Bin DAI, Yan YANG, Haijun LIU, Huaijie YUAN, Dengwei JING, Liang ZHAO

PDF(3514 KB)
PDF(3514 KB)
Front. Energy ›› 2021, Vol. 15 ›› Issue (3) : 687-699. DOI: 10.1007/s11708-021-0773-9
RESEARCH ARTICLE
RESEARCH ARTICLE

Theoretical study on flow and radiation in tubular solar photocatalytic reactor

Author information +
History +

Abstract

In this paper, based on the mixture flow model, an optimized six-flux model is first established and applied to the tubular solar photocatalytic reactor. Parameters influencing photocatalyst distribution and radiation distribution at the reactor outlet, viz. catalyst concentration and circulation speed, are also analyzed. It is found that, at the outlet of the reactor, the optimized six-flux model has better performances (the energy increase by 1900% and 284%, respectively) with a higher catalyst concentration (triple) and a lower speed (one third).

Graphical abstract

Keywords

photocatalytic hydrogen photoreactor / nume- rical simulation / solar energy / flow model / radiation model

Cite this article

Download citation ▾
Qingyu WEI, Yao WANG, Bin DAI, Yan YANG, Haijun LIU, Huaijie YUAN, Dengwei JING, Liang ZHAO. Theoretical study on flow and radiation in tubular solar photocatalytic reactor. Front. Energy, 2021, 15(3): 687‒699 https://doi.org/10.1007/s11708-021-0773-9

References

[1]
Chen X, Shen S, Guo L, . Semiconductor-based photocatalytic hydrogen generation. Chemical Reviews, 2010, 110(11): 6503–6570
CrossRef Google scholar
[2]
Grätzel M. Photoelectrochemical cells. Nature, 2001, 414(6861): 338–344
CrossRef Google scholar
[3]
Lewis N S. Light work with water. Nature, 2001, 414(6864): 589–590
CrossRef Google scholar
[4]
Lewis N S. Toward cost-effective solar energy use. Science, 2007, 315(5813): 798–801
CrossRef Google scholar
[5]
Lewis N S, Crabtree G. Basic research needs for solar energy utilization. Report of the Basic Energy Sciences Workshop on Solar Energy Utilization. Washington DC, Office of Basic Energy Science, US Department of Energy, 2005
[6]
Walter M G, Warren E L, McKone J R, . Solar water splitting cells. Chemical Reviews, 2010, 110(11): 6446–6473
CrossRef Google scholar
[7]
Züttel A, Borgschulte A, Schlapbach L. Hydrogen as a Future Energy Carrier. Wiley-VCH Verlag GmbH & Co. KGaA, 2008
[8]
Chornet E, Czernik S. Harnessing hydrogen. Nature, 2002, 418(6901): 928–929
CrossRef Google scholar
[9]
Schlapbach L. Hydrogen-fueled vehicles. Nature, 2009, 460(7257): 809–811
CrossRef Google scholar
[10]
Xia Z. Solar-powered hydrogen production clean energy supply system. Solar Energy, 1994, (3): 31 (in Chinese)
[11]
Kumar J, Bansal A. Photocatalytic degradation in annular reactor: modelization and optimization using computational fluid dynamics (CFD) and response surface methodology (RSM). Journal of Environmental Chemical Engineering, 2013, 1(3): 398–405
CrossRef Google scholar
[12]
Ren Y, Jing D. Study on particle and photonic flux distributions in a magnetically stirred photocatalytic reactor. Journal of Photonics for Energy, 2015, 5(1): 052097
CrossRef Google scholar
[13]
Ren Y, Zhao L, Jing D, . Investigation and modeling of CPC based tubular photocatalytic reactor for scaled-up hydrogen production. International Journal of Hydrogen Energy, 2016, 41(36): 16019–16031
CrossRef Google scholar
[14]
Casado C, Marugán J, Timmers R, . Comprehensive multiphysics modeling of photocatalytic processes by computational fluid dynamics based on intrinsic kinetic parameters determined in a differential photoreactor. Chemical Engineering Journal, 2017, 310: 368–380
CrossRef Google scholar
[15]
Acosta-Herazo R, Monterroza-Romero J, Mueses M Á, . Coupling the six flux absorption-scattering model to the henyey-greenstein scattering phase function: evaluation and optimization of radiation absorption in solar heterogeneous photoreactors. Chemical Engineering Journal, 2016, 302: 86–96
CrossRef Google scholar
[16]
Moreno-SanSegundo J, Casado C, Marugán J. Enhanced numerical simulation of photocatalytic reactors with an improved solver for the radiative transfer equation. Chemical Engineering Journal, 2020, 388: 124183
CrossRef Google scholar
[17]
Peralta Muniz Moreira R, Li Puma G. Multiphysics computational fluid-dynamics (CFD) modeling of annular photocatalytic reactors by the discrete ordinates method (DOM) and the six-flux model (SFM) and evaluation of the contaminant intrinsic kinetics constants. Catalysis Today, 2021, 361: 77–84
CrossRef Google scholar
[18]
Ramírez-Cabrera M A, Valadés-Pelayo P J, Arancibia-Bulnes C A, . Validity of the six-flux model for photoreactors. Chemical Engineering Journal, 2017, 330: 272–280
CrossRef Google scholar
[19]
Cassano A E, Alfano O M. Reaction engineering of suspended solid heterogeneous photocatalytic reactors. Catalysis Today, 2000, 58(2–3): 167–197
CrossRef Google scholar
[20]
Roupp G B, Nico J A, Annangi S, . Two-flux radiation-field model for an annular packed-bed photocatalytic oxidation reactor. AIChE Journal, 1997, 43(3): 792–801
CrossRef Google scholar
[21]
Cao F, Li H, Chao H, . Optimization of the concentration field in a suspended photocatalytic reactor. Energy, 2014, 74(5): 140–146
CrossRef Google scholar
[22]
Romero R L, Alfano O M, Cassano A E. Cylindrical photocatalytic reactors. Radiation absorption and scattering effects produced by suspended fine particles in an annular space. Industrial & Engineering Chemistry Research, 1997, 36(8): 3094–3109
CrossRef Google scholar
[23]
Jing D, Jing L, Liu H, . Photocatalytic hydrogen production from refinery gas over a fluidized-bed reactor II: parametric study. Industrial & Engineering Chemistry Research, 2013, 52(5): 1992–1999
CrossRef Google scholar
[24]
Brucato A, Cassano A E, Grisafi F, . Estimating radiant fields in flat heterogeneous photoreactors by the six-flux model. AIChE Journal, 2006, 52(11): 3882–3890
CrossRef Google scholar
[25]
Marinangeli R E, Ollis D F. Photoassisted heterogeneous catalysis with optical fibers: I. Isolated single fiber. AIChE Journal, 1977, 23(4): 415–426
CrossRef Google scholar
[26]
Cabrera M I, Alfano O M, Cassano A E. Absorption and scattering coefficients of titanium dioxide particulate suspensions in water. Journal of Physical Chemistry, 1996, 100(51): 20043–20050
CrossRef Google scholar
[27]
Wei Q, Yang Y, Liu H, . Experimental study on direct solar photocatalytic water splitting for hydrogen production using surface uniform concentrators. International Journal of Hydrogen Energy, 2018, 43(30): 13745–13753
CrossRef Google scholar
[28]
Colina-Márquez J, Machuca-Martínez F, Puma G L. Radiation absorption and optimization of solar photocatalytic reactors for environmental applications. Environmental Science & Technology, 2010, 44(13): 5112–5120
CrossRef Google scholar

Acknowledgments

This work was supported by the National Key Research and Development Program of China (No. 2018YFB1502005), the National Natural Science Foundation of China (Grant Nos. 51961130386 and 51506043), the Royal Society-Newton Advanced Fellowship grant (NAF/R1/191163), the National High Technology Research and Development Program of China (No. 2012AA051501), and the Foundation of the State Key Laboratory of Multiphase Flow in Power Engineering, Xi’an Jiaotong University, China.

RIGHTS & PERMISSIONS

2021 Higher Education Press
AI Summary AI Mindmap
PDF(3514 KB)

Accesses

Citations

Detail

Sections
Recommended

/