Nano-modifiers enhance the performance of natural ester transformer oils: challenges and future directions

Deliang Guo , Zhuqi Xue , Yiming Yin , Haitao Duan , Xinru Wang , Linlin Duan , Sheng Han

Front. Chem. Sci. Eng. ›› 2025, Vol. 19 ›› Issue (6) : 45

PDF (2662KB)
Front. Chem. Sci. Eng. ›› 2025, Vol. 19 ›› Issue (6) : 45 DOI: 10.1007/s11705-025-2556-z
REVIEW ARTICLE

Nano-modifiers enhance the performance of natural ester transformer oils: challenges and future directions

Author information +
History +
PDF (2662KB)

Abstract

Natural esters exhibit excellent flame retardant and biodegradability, which help minimize power accidents and reduce environmental impact. These qualities make natural esters a promising alternative to conventional transformer insulating oils. However, the practical applications of natural esters in power equipment have been significantly restricted by their inherent limitations, including elevated viscosity, high dielectric loss, and poor oxidative stability. Nano-modification technologies present a novel methodological approach to solve these inherent constraints. A systematic analysis of the latest research developments in nano-modified natural ester transformer oils is provided in this review. The properties of various natural esters are examined, and their suitability as base fluids is evaluated, while the modification effects and mechanisms of typical nano-additives are comprehensively reviewed. The key role of nano-modification technology in improving the overall performance of natural esters is elucidated through detailed analysis of how nanoparticles influence physical properties, dielectric properties, and oxidative stability. In addition, the practical challenges facing nano-modification technology are addressed, providing valuable theoretical guidance for future developments in this field.

Graphical abstract

Keywords

transformer oil / natural ester / insulating oil / nanoparticles / dielectric properties

Cite this article

Download citation ▾
Deliang Guo, Zhuqi Xue, Yiming Yin, Haitao Duan, Xinru Wang, Linlin Duan, Sheng Han. Nano-modifiers enhance the performance of natural ester transformer oils: challenges and future directions. Front. Chem. Sci. Eng., 2025, 19(6): 45 DOI:10.1007/s11705-025-2556-z

登录浏览全文

4963

注册一个新账户 忘记密码

References

[1]

Metwally I A . Failures, monitoring, and new trends of power transformers. IEEE Potentials, 2011, 30(3): 36–43

[2]

Zhang S , Zhao J , Zhang Q , Zhang J , Jiang H . Experimental study and numerical analysis of thermal hazard for fire accident in converter transformers. Thermal Science and Engineering Progress, 2023, 45: 102108

[3]

Li S , Yu S , Feng Y . Progress in and prospects for electrical insulating materials. High Voltage, 2016, 1(3): 122–129

[4]

Okabe S , Kohtoh M , Amimoto T . Suppression of increase in electrostatic charging tendency of insulating oil by aging used for power transformer insulation. IEEE Transactions on Dielectrics and Electrical Insulation, 2010, 17(1): 294–301

[5]

Zdanowski M . Streaming electrification phenomenon of electrical insulating oils for power transformers. Energies, 2020, 13(12): 3225

[6]

Kim Y J , Jeong M , Park Y G , Ha M Y . A numerical study of the effect of a hybrid cooling system on the cooling performance of a large power transformer. Applied Thermal Engineering, 2018, 136: 275–286

[7]

Liao R , Feng D , Hao J , Yang L , Li J , Wang Q , Zhang S . Thermal and electrical properties of a novel 3-element mixed insulation oil for power transformers. IEEE Transactions on Dielectrics and Electrical Insulation, 2019, 26(2): 610–617

[8]

Kaplan I R , Rasco J , Lu S T . Chemical characterization of transformer mineral-insulating oils. Environmental Forensics, 2010, 11(1-2): 117–145

[9]

Madavan R , Saroja S , Karthick A , Murugesan S , Mohanavel V , Velmurugan P , Al Obaid S , Alfarraj S , Sivakumar S . Performance analysis of mixed vegetable oil as an alternative for transformer insulation oil. Biomass Conversion and Biorefinery, 2025, 15(2): 1939–1944

[10]

Siddique A , Yaqoob M , Aslam W , Zaffar F , Atiq S , Usama Shahid M . A systematic review on promising development of cost-effective, biodegradable, and environment friendly vegetable based nanofluids as a future resource for green transformer insulation oil. Journal of Molecular Liquids, 2024, 403: 124836

[11]

Karthik M , Narmadhai N . Transformer insulation-based vegetable seed oil for power system analysis. Biomass Conversion and Biorefinery, 2024, 14(17): 21565–21578

[12]

Mohd N K , Wen-Huei L , Hassan N A A , Shoot-Kian Y . Potential application of palm oil products as electrical insulating medium in oil-immersed transformers. Environmental Progress & Sustainable Energy, 2021, 40(6): e13728

[13]

Rafiq M , Lv Y Z , Zhou Y , Ma K B , Wang W , Li C R , Wang Q . Use of vegetable oils as transformer oils: a review. Renewable & Sustainable Energy Reviews, 2015, 52: 308–324

[14]

Ab Ghani S , Muhamad N A , Noorden Z A , Zainuddin H , Abu Bakar N , Talib M A . Methods for improving the workability of natural ester insulating oils in power transformer applications: a review. Electric Power Systems Research, 2018, 163: 655–667

[15]

Wei X , Wang Z , Guo J . Reliability assessment of transformer insulating oil using accelerated life testing. Scientific Reports, 2022, 12(1): 21669

[16]

Oparanti S O , Fofana I , Jafari R , Zarrougui R . A state-of-the-art review on green nanofluids for transformer insulation. Journal of Molecular Liquids, 2024, 396: 124023

[17]

Shukla G , Aiyer H . Thermal conductivity enhancement of transformer oil using functionalized nanodiamonds. IEEE Transactions on Dielectrics and Electrical Insulation, 2015, 22(4): 2185–2190

[18]

Qin J , Peng X , Qiu Q , Tang C . A new type of nano APTES-hBN modified palm oil as natural ester insulating oil with upgraded thermal aging characteristics. Renewable Energy, 2022, 200: 743–750

[19]

Zhang T , Chen M , Zhou H , Shi G , Fan X , Wu Q . Study on the anti-aging performance of different nano-modified natural ester insulating oils based on molecular dynamics. Nanomaterials, 2023, 13(4): 653

[20]

Masra S M W , Arief Y Z , Sahari S K , Muhammad M S , Rigit A R H , Rahman M R . A systematic review on promising development of palm oil and its nanofluid as a biodegradable oil insulation alternative. IEEE Transactions on Dielectrics and Electrical Insulation, 2022, 29(1): 302–318

[21]

Shazly R I E , El-Sheshtawy H S , Ahmed N S , Nassar A M . Synthesis and biodegradation testing of some synthetic oils based on ester. Scientific Reports, 2024, 14(1): 3416

[22]

Rozga P , Stuchala F , Rao Ungarala M , Jaya Sree T . Assessing the lightning performance of sustainable GTL type dielectric liquids versus mineral oils and synthetic ester in a non-uniform electric field. Measurement, 2025, 242: 116089

[23]

Moumine I , Gosse B , Gosse J P , Clavreul R , Hantouche C . Vegetable oil as an impregnant in HV AC capacitors. In: Proceedings of 1995 IEEE 5th International Conference on Conduction and Breakdown in Solid Dielectrics. Leicester: IEEE, 1995, 611–615

[24]

McShane C P . Vegetable-oil-based dielectric coolants. IEEE Industry Applications Magazine, 2002, 8: 34–41

[25]

Chiesa M , Das S K . Experimental investigation of the dielectric and cooling performance of colloidal suspensions in insulating media. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2009, 335: 88–97

[26]

Jariyanurat K , Pattanadech N , Potivejkul S , Chotigo S . Dielectric properties of natural ester based nanofluid. In: Proceedings of 2017 IEEE 19th International Conference on Dielectric Liquids (ICDL). Manchester: IEEE, 2017, 1–4

[27]

R M , Kumar S S , Iruthyarajan M W . A comparative investigation on effects of nanoparticles on characteristics of natural esters-based nanofluids. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2018, 556: 30–36

[28]

Olmo C , Méndez C , Quintanilla P J , Ortiz F , Renedo C J , Ortiz A . Mineral and ester nanofluids as dielectric cooling liquid for power transformers. Nanomaterials, 2022, 12: 2723

[29]

IEA. Average annual material needs for power transformers in the Net Zero Scenario, 2012–2050. Paris: International Energy Agency, 2023

[30]

Toorani M R , Farhoosh R , Golmakani M , Sharif A . Antioxidant activity and mechanism of action of sesamol in triacylglycerols and fatty acid methyl esters of sesame, olive, and canola oils. Lebensmittel Wissenschaft Technologie, 2019, 103: 271–278

[31]

Nitbani F O , Tjitda P J P , Nurohmah B A , Wogo H E . Preparation of fatty acid and monoglyceride from vegetable oil. Journal of Oleo Science, 2020, 69(4): 277–295

[32]

Razavi R , Bemani A , Baghban A , Mohammadi A H , Habibzadeh S . An insight into the estimation of fatty acid methyl ester based biodiesel properties using a LSSVM model. Fuel, 2019, 243: 133–141

[33]

Mostafaei M . Prediction of biodiesel fuel properties from its fatty acids composition using ANFIS approach. Fuel, 2018, 229: 227–234

[34]

Oparanti S O , Fofana I , Jafari R , Zarrougui R , Abdelmalik A A . Canola oil: a renewable and sustainable green dielectric liquid for transformer insulation. Industrial Crops and Products, 2024, 215: 118674

[35]

Bakrutheen M , Iruthayarajan M W , Narayani A . Statistical failure reliability analysis on edible and non edible natural esters based liquid insulation for the applications in high voltage transformers. IEEE Transactions on Dielectrics and Electrical Insulation, 2018, 25(5): 1579–1586

[36]

Oparanti S O , Khaleed A A , Abdelmalik A A . Nanofluid from palm kernel oil for high voltage insulation. Materials Chemistry and Physics, 2021, 259: 123961

[37]

Durango-Giraldo G , Zapata-Hernandez C , Santa J F , Buitrago-Sierra R . Palm oil as a biolubricant: literature review of processing parameters and tribological performance. Journal of Industrial and Engineering Chemistry, 2022, 107: 31–44

[38]

Tokunaga J , Koide H , Mogami K , Hikosaka T . Comparative studies on the aging of thermally upgraded paper insulation in palm fatty acid ester, mineral oil, and natural ester. IEEE Transactions on Dielectrics and Electrical Insulation, 2016, 23(1): 258–265

[39]

Sajeeb A , Rajendrakumar P K . Comparative evaluation of lubricant properties of biodegradable blend of coconut and mustard oil. Journal of Cleaner Production, 2019, 240: 118255

[40]

Katim N I A , Ishak M T , Mohamad Amin N A , Abdul Hamid M H , Amali Ahmad K , Azis N . Lightning breakdown voltage evaluation of palm oil and coconut oil as transformer oil under quasi-uniform field conditions. Energies, 2018, 11(10): 2676

[41]

Das A K , Shill D C , Chatterjee S . Potential of coconut oil as a dielectric liquid in distribution transformers. IEEE Electrical Insulation Magazine, 2020, 36(6): 36–46

[42]

Matharage H M S Y B S . Fernando R M M A, Bandara A P M A, Jayantha G A, Kalpage C S. Performance of coconut oil as an alternative transformer liquid insulation. IEEE Transactions on Dielectrics and Electrical Insulation, 2013, 20(3): 887–898

[43]

Das A K Ch , Ch Shill D , Chatterjee S . Coconut oil for utility transformers: environmental safety and sustainability perspectives. Renewable & Sustainable Energy Reviews, 2022, 164: 112572

[44]

Suryani S , Sariani S , Earnestly F , Marganof M , Rahmawati R , Sevindrajuta S , Mahlia T M I , Fudholi A . A comparative study of virgin coconut oil, coconut oil, and palm oil in terms of their active ingredients. Processes, 2020, 8(4): 402

[45]

He Z , Xiong L , Liu J , Han S , Hu J , Xu X , Shen M . Tribological property study of mercaptobenzothiazole-containing borate derivatives and its synergistic antioxidative effects with N-phenyl-α-naphthylamine. Lubrication Science, 2019, 31(6): 239–251

[46]

Xiong L , He Z , Xie F , Hu J , Liu J , Han S , Yang S . Study of tribological synergistic effect of N-containing heterocyclic borate ester with tricresyl phosphate as rapeseed oil additive. Tenside, Surfactants, Detergents, 2020, 57(2): 175–184

[47]

Zhou Z , Kai L , Tao W , Xu H , Hui Q , Bing F . Rapid determination of oxidation stability for transformer oils with antioxidant. IEEE Transactions on Dielectrics and Electrical Insulation, 2012, 19(5): 1604–1608

[48]

Wang Y , Lin X , Wang R , Li J , Li X , Xue X , Wang M , Jiancuo S . Molecular ionization potentials of triglycerides and mechanism analysis of streamer discharge in vegetable insulating oil. Journal of Molecular Liquids, 2023, 391: 123376

[49]

SoučekJHornakJSvobodaMGuttenMKoltunowiczT. Comparison of the electrical properties of canola oil with commercially available mineral oil. In: Proceedings of 16th International Scientific Conference on Electric Power Engineering (EPE). Kouty nad Desnou: IEEE, 2015, 634–637

[50]

Unge M , Singha S , Van Dung N , Linhjell D , Ingebrigtsen S , Lundgaard L E . Enhancements in the lightning impulse breakdown characteristics of natural ester dielectric liquids. Applied Physics Letters, 2013, 102(17): 172905

[51]

Abdulla R , Chan E S , Ravindra P . Biodiesel production from Jatropha curcas: a critical review. Critical Reviews in Biotechnology, 2011, 31(1): 53–64

[52]

Makkar H P S , Becker K . A promising crop for the generation of biodiesel and value-added coproducts. European Journal of Lipid Science and Technology, 2009, 111(8): 773–787

[53]

Wu J , Zhang J . Research and development of natural vegetable insulating oil based on jatropha curcas seed oil. Energies, 2020, 13(17): 4319

[54]

Beltrán N , Palacios E , Blass G . Potential of Jatropha curcas oil as a dielectric fluid for power transformers. IEEE Electrical Insulation Magazine, 2017, 33(2): 8–15

[55]

Sitorus H B H , Setiabudy R , Bismo S , Beroual A . Jatropha curcas methyl ester oil obtaining as vegetable insulating oil. IEEE Transactions on Dielectrics and Electrical Insulation, 2016, 23(4): 2021–2028

[56]

Kumar A , Sharma S . An evaluation of multipurpose oil seed crop for industrial uses (Jatropha curcas L.): a review. Industrial Crops and Products, 2008, 28(1): 1–10

[57]

Joshi S , Gogate P R , Moreira P F Jr , Giudici R . Intensification of biodiesel production from soybean oil and waste cooking oil in the presence of heterogeneous catalyst using high speed homogenizer. Ultrasonics Sonochemistry, 2017, 39: 645–653

[58]

Módenes A N , Sanderson K , Trigueros D E G , Schuelter A R , Espinoza-Quiñones F R , Neves C V , Zanão L A , Kroumov A D . Insights on the criteria of selection of vegetable and mineral dielectric fluids used in power transformers on the basis of their biodegradability and toxicity assessments. Chemosphere, 2018, 199: 312–319

[59]

Karthik M , Nuvvula R S S , Dhanamjayulu C , Khan B . Appropriate analysis on properties of various compositions on fluids with and without additives for liquid insulation in power system transformer applications. Scientific Reports, 2024, 14(1): 17814

[60]

Zhu X , Yun Z , Gui X . Preparation of silicon-based soybean base oil by modified soybean oil by transesterification and hydrosilation. Canadian Journal of Chemical Engineering, 2022, 100(2): 254–260

[61]

Das A K . Statistical evaluation of the AC breakdown voltages of vegetable oil exposed to direct sunlight. Materials Chemistry and Physics, 2022, 285: 126106

[62]

Hu X , Cong H , Wang Y , Zhang X , Du Y , Li Q , Yu Z . Experimental research on deterioration effect of transition metals on natural ester. IEEE Transactions on Dielectrics and Electrical Insulation, 2024, 31(1): 477–484

[63]

Zeng M , Chen C , Cai S , Shao M , Yin J , Li H , Guo H , Chen J , Yin G . Oxidative stability of soybean oil under accelerated transformer conditions: comprehensive mechanistic studies. Industrial & Engineering Chemistry Research, 2019, 58(19): 7742–7751

[64]

Mohan Rao U , Fofana I , Jaya T , Rodriguez-Celis E M , Jalbert J , Picher P . Alternative dielectric fluids for transformer insulation system: progress, challenges, and future prospects. IEEE Access: Practical Innovations, Open Solutions, 2019, 7: 184552–184571

[65]

Rao U M , Sood Y R , Jarial R K . Ester dielectrics: current perspectives and future challenges. IETE Technical Review, 2017, 34(4): 448–459

[66]

Fofana I . 50 years in the development of insulating liquids. IEEE Electrical Insulation Magazine, 2013, 29(5): 13–25

[67]

Fernández I , Ortiz A , Delgado F , Renedo C , Pérez S . Comparative evaluation of alternative fluids for power transformers. Electric Power Systems Research, 2013, 98: 58–69

[68]

Hussain M R , Khan Q , Khan A A , Refaat S S , Abu-Rub H . Dielectric performance of magneto-nanofluids for advancing oil-immersed power transformer. IEEE Access: Practical Innovations, Open Solutions, 2020, 8: 163316–163328

[69]

Johns R W , Blemker M A , Azzaro M S , Heo S , Runnerstrom E L , Milliron D J , Roberts S T . Charge carrier concentration dependence of ultrafast plasmonic relaxation in conducting metal oxide nanocrystals. Journal of Materials Chemistry C: Materials for Optical and Electronic Devices, 2017, 5(23): 5757–5763

[70]

Beheshti A , Shanbedi M , Heris S Z . Heat transfer and rheological properties of transformer oil-oxidized MWCNT nanofluid. Journal of Thermal Analysis and Calorimetry, 2014, 118(3): 1451–1460

[71]

Raymon A , Sakthibalan S , Cinthal C , Subramaniaraja R , Yuvaraj M . Enhancement and comparison of nano-ester insulating fluids. IEEE Transactions on Dielectrics and Electrical Insulation, 2016, 23(2): 892–900

[72]

Koutras K N , Naxakis I A , Antonelou A E , Charalampakos V P , Pyrgioti E C , Yannopoulos S N . Dielectric strength and stability of natural ester oil based TiO2 nanofluids. Journal of Molecular Liquids, 2020, 316: 113901

[73]

Wu Y , Yang J , Zhang L , Tang C . Effect of amino-modified SiO2 nanoparticles on micro-water diffusion behaviour in soybean oil-based natural ester oil-paper insulation system. Journal of Molecular Liquids, 2023, 389: 122888

[74]

Wu Y , Chen R , Zhang J , Tang C . The influence of doping with different surface modified SiO2 nanoparticles on the dielectric properties of natural ester insulating oil. Renewable Energy, 2024, 228: 120671

[75]

Raj R A , Samikannu R , Yahya A , Mosalaosi M . Investigation of survival/hazard rate of natural ester treated with Al2O3 nanoparticle for power transformer liquid dielectric. Energies, 2021, 14(5): 1510

[76]

Khaled U , Beroual A . DC breakdown voltage of natural ester oil-based Fe3O4, Al2O3, and SiO2 nanofluids. Alexandria Engineering Journal, 2020, 59(6): 4611–4620

[77]

Khelifa H , Vagnon E , Beroual A . Effect of fullerene and graphene nanoparticles on the AC dielectric strength of natural ester. Energies, 2023, 16(4): 1995

[78]

Neouze M A , Schubert U . Surface modification and functionalization of metal and metal oxide nanoparticles by organic ligands. Monatshefte für Chemie, 2008, 139(3): 183–195

[79]

Makmud M Z H , Illias H A , Chee C Y , Sarjadi M S . Influence of conductive and semi-conductive nanoparticles on the dielectric response of natural ester-based nanofluid insulation. Energies, 2018, 11(2): 333

[80]

Shah G M , Amin M , Shahid M , Ahmad I , Khalid S , Abbas G , Imran M , Naeem M A , Shahid N . Toxicity of ZnO and Fe2O3 nano-agro-chemicals to soil microbial activities, nitrogen utilization, and associated human health risks. Environmental Sciences Europe, 2022, 34(1): 106

[81]

Chen R , Qiu Q , Peng X , Tang C . Surface modified h-BN towards enhanced electrical properties and thermal conductivity of natural ester insulating oil. Renewable Energy, 2023, 204: 185–196

[82]

Costa A L R , Gomes A , Cunha R L . One-step ultrasound producing O/W emulsions stabilized by chitosan particles. Food Research International, 2018, 107: 717–725

[83]

Al-Jumaili A , Mulvey P , Kumar A , Prasad K , Bazaka K , Warner J , Jacob M V . Eco-friendly nanocomposites derived from geranium oil and zinc oxide in one step approach. Scientific Reports, 2019, 9(1): 5973

[84]

Siddique A , Adnan M , Aslam W , Murtaza Qamar H G , Aslam M N , Alqahtani S A . Up-gradation of the dielectric, physical & chemical properties of cottonseed-based, non-edible green nanofluids as sustainable alternatives for high-voltage equipment’s insulation fluids. Heliyon, 2024, 10(7): e28352

[85]

Mehta B , Subhedar D , Panchal H , Said Z . Synthesis, stability, thermophysical properties, and heat transfer applications of nanofluid: a review. Journal of Molecular Liquids, 2022, 364: 120034

[86]

Yu W , Xie H . A Review on nanofluids: preparation, stability mechanisms, and applications. Journal of Nanomaterials, 2012, 2012(1): 435873

[87]

Rafiq M , Shafique M , Azam A , Ateeq M . The impacts of nanotechnology on the improvement of liquid insulation of transformers: emerging trends and challenges. Journal of Molecular Liquids, 2020, 302: 112482

[88]

Siddique A , Tanzeela W , Aslam S . Upgradation of highly efficient and profitable eco-friendly nanofluid-based vegetable oil prepared by green synthesis method for the insulation and cooling of transformer. Clean Technologies and Environmental Policy, 2024 (in press),

[89]

Ali H M , Babar H , Shah T R , Sajid M U , Qasim M A , Javed S . Preparation techniques of TiO2 nanofluids and challenges: a review. Applied Sciences, 2018, 8(4): 587

[90]

Ahmad F , Khan A A , Khan Q , Hussain M R . State-of-art in nano-based dielectric oil: a review. IEEE Access: Practical Innovations, Open Solutions, 2019, 7: 13396–13410

[91]

Induranga A , Galpaya C , Vithanage V , Koswattage K R . Thermal properties of TiO2 nanoparticle-treated transformer oil and coconut oil. Energies, 2024, 17(1): 49

[92]

Zhang W , Yuan W , Zhang X , Coronado M . Predicting the dynamic and kinematic viscosities of biodiesel-diesel blends using mid- and near-infrared spectroscopy. Applied Energy, 2012, 98: 122–127

[93]

Ansari K , Goga G , Mohan R . Performance and emission characteristics of mahua blended biodiesel. Materials Today: Proceedings, 2022, 71: 293–299

[94]

D0045–18, Standard Test Method for Kinematic Viscosity of Transparent and Opaque Liquids (and Calculation of Dynamic Viscosity). West Conshohocken: ASTM International, 2019

[95]

Oparanti S O , Rao U M , Fofana I . Natural esters for green transformers: challenges and keys for improved serviceability. Energies, 2023, 16(1): 61

[96]

Sippola M , Sepponen R E . Accurate prediction of high-frequency power-transformer losses and temperature rise. IEEE Transactions on Power Electronics, 2002, 17(5): 835–847

[97]

Ramaian Thirugnanam A R P , Maria Siluvairaj W I , Karthik R . Performance studies on dielectric and physical properties of eco-friendly based natural ester oils using semi-conductive nanocomposites for power transformer application. IET Science, Measurement & Technology, 2018, 12(3): 323–327

[98]

Dombek G , Nadolny Z , Marcinkowska A . Effects of nanoparticles materials on heat transfer in electro-insulating liquids. Applied Sciences, 2018, 8(12): 2538

[99]

Das A K . Investigation of electrical breakdown and heat transfer properties of coconut oil-based nanofluids. Industrial Crops and Products, 2023, 197: 116545

[100]

Chen B , Yang J , Li H , Su Z , Chen R , Tang C . Electrical properties enhancement of natural ester insulating oil by interfacial interaction between KH550-TiO2 and oil molecules. Surfaces and Interfaces, 2023, 42: 103441

[101]

Olmo C , Méndez C , Ortiz F , Delgado F , Ortiz A . Titania nanofluids based on natural ester: cooling and insulation properties assessment. Nanomaterials, 2020, 10(4): 603

[102]

Olmo C , Méndez C , Ortiz F , Delgado F , Valiente R , Werle P . Maghemite nanofluid based on natural ester: cooling and insulation properties assessment. IEEE Access: Practical Innovations, Open Solutions, 2019, 7: 145851–145860

[103]

Khan S A , Tariq M , Khan A A , Alamri B , Mihet-Popa L . Assessment of thermophysical performance of ester-based nanofluids for enhanced insulation cooling in transformers. Electronics, 2022, 11(3): 376

[104]

Dessouky S S , Mansour D E A , Shaban M , Abdelwahab S A M . Insulation performance enhancement of aged current transformers using nanofluids. International Journal of Electrical Power & Energy Systems, 2021, 126: 106613

[105]

Yin X , Kou G , Xu A , Fu T , Zhu J . Effects of TiO2 nanoparticles on thermal conductivity of heat transfer oil. Journal of Central South University, 2019, 26(8): 2129–2135

[106]

Leong K Y , Ku Ahmad K Z , Ong H C , Ghazali M J , Baharum A . Synthesis and thermal conductivity characteristic of hybrid nanofluids: a review. Renewable & Sustainable Energy Reviews, 2017, 75: 868–878

[107]

Siddique Z B , Basu S , Basak P . Dielectric behavior of natural ester based mineral oil blend dispersed with TiO2 and ZnO nanoparticles as insulating fluid for transformers. Journal of Molecular Liquids, 2021, 339: 116825

[108]

Wu Z , Zhou X , Liu X , Ni Y , Zhao K , Peng F , Yang L . Investigation on the dependence of flash point of diesel on the reduced pressure at high altitudes. Fuel, 2016, 181: 836–842

[109]

Mehta D M , Kundu P , Chowdhury A , Lakhiani V K , Jhala A S . A review on critical evaluation of natural ester vis-a-vis mineral oil insulating liquid for use in transformers: Part 1. IEEE Transactions on Dielectrics and Electrical Insulation, 2016, 23(2): 873–880

[110]

KulkarniS VKhapardeS A. Transformer Engineering: Design, Technology, and Diagnostics. 2nd ed. Boca Raton: CRC Press, 2017

[111]

Gülüm M , Bilgin A . Density, flash point, and heating value variations of corn oil biodiesel-diesel fuel blends. Fuel Processing Technology, 2015, 134: 456–464

[112]

Khoirudin K B , Sukarman A A , Santoso B , Wijayanta A T , Aziz M . Flash point improvement of mineral oil utilizing nanoparticles to reduce fire risk in power transformers: a review. Fire, 2024, 7(9): 305

[113]

Jacob J , Preetha P , Sindhu T K . Stability analysis and characterization of natural ester nanofluids for transformers. IEEE Transactions on Dielectrics and Electrical Insulation, 2020, 27(5): 1715–1723

[114]

Raghu P , Murugesan M . Molecular interactions of the antioxidant in the coolant oil for energy transformers: dielectric and simulation studies. Journal of Molecular Liquids, 2024, 411: 125795

[115]

Hamid M H A , Ishak M T , Suhaimi N S , Adnan J , Hashim N I , Ariffin M , Katim N I A , Abd Rahman R . Electrical properties of palm oil and rice bran oil under AC stress for transformer application. Alexandria Engineering Journal, 2022, 61(11): 9095–9105

[116]

ASTM D97–17b(2022), Standard Test Method for Pour Point of Petroleum Products. West Conshohocken: ASTM International, 2022

[117]

Syahruddin S , Yuliati L , Widhiyanuriyawan D , Wardana I N G . The role of activated carbon nanoparticles on hydro-degumming non-edible vegetable oils. Alexandria Engineering Journal, 2022, 61(6): 4729–4739

[118]

Furqan Hameed M , Hussain G A , Qayyum Gill Y , Mahmood F , Yousaf A . Enhancement of physical and electrical properties of mustard oil by adding TiO2 nanotubes for power transformers. IEEE Access: Practical Innovations, Open Solutions, 2024, 12: 95461–95471

[119]

Al-Shboul T , Sagala F , Nassar N N . Role of surfactants, polymers, nanoparticles, and its combination in inhibition of wax deposition and precipitation: a review. Advances in Colloid and Interface Science, 2023, 315: 102904

[120]

Xiao M , Du B X . Effects of high thermal conductivity on temperature rise of epoxy cast winding for power transformer. IEEE Transactions on Dielectrics and Electrical Insulation, 2016, 23(4): 2413–2420

[121]

Taha-Tijerina J , Narayanan T N , Gao G , Rohde M , Tsentalovich D A , Pasquali M , Ajayan P M . Electrically insulating thermal nano-oils using 2D fillers. ACS Nano, 2012, 6(2): 1214–1220

[122]

Atiya E G , Mansour D E A , Khattab R M , Azmy A M . Dispersion behavior and breakdown strength of transformer oil filled with TiO2 nanoparticles. IEEE Transactions on Dielectrics and Electrical Insulation, 2015, 22(5): 2463–2472

[123]

Wanatasanappan V V , Rezman M , Abdullah M Z . Thermophysical properties of vegetable oil-based hybrid nanofluids containing Al2O3-TiO2 nanoparticles as insulation oil for power transformers. Nanomaterials, 2022, 12(20): 3621

[124]

Srivastava M , Goyal S K , Saraswat A . Ester oil as an alternative to mineral transformer insulating liquid. Materials Today: Proceedings, 2021, 43: 2850–2854

[125]

Lundgaard L E , Liu Q , Lesaint O , Madshaven I . Dielectric performance of transformer liquids: summary of a CIGRE study. IEEE Electrical Insulation Magazine, 2023, 39(5): 7–16

[126]

Miao J , Dong M , Ren M , Wu X , Shen L , Wang H . Effect of nanoparticle polarization on relative permittivity of transformer oil-based nanofluids. Journal of Applied Physics, 2013, 113(20): 204103

[127]

Risos A , Gouws G . In-situ aging monitoring of transformer oil via the relative permittivity and DC conductivity using novel interdigitated dielectrometry sensors (IDS). Sensors and Actuators B: Chemical, 2019, 287: 602–610

[128]

Szcześniak D , Przybylek P . Oxidation stability of natural ester modified by means of fullerene nanoparticles. Energies, 2021, 14(2): 490

[129]

Wu Y , Zhang J , Chen B , Li H , Tang C . Two-element mixed natural ester insulation oil doped with KH550-TiO2 nanoparticles for enhanced antiaging properties. ACS Applied Nano Materials, 2024, 7(5): 4721–4730

[130]

Farade R A , Wahab N I B A , Mansour D E A , Azis N B , Jasni J , Banapurmath N R , Soudagar M E M . Investigation of the dielectric and thermal properties of non-edible cottonseed oil by infusing h-BN nanoparticles. IEEE Access: Practical Innovations, Open Solutions, 2020, 8: 76204–76217

[131]

Khan S A , Tariq M , Khan A A , Alamri B . Effect of iron/titania-based nanomaterials on the dielectric properties of mineral oil, natural, and synthetic esters as transformers insulating fluid. IEEE Access: Practical Innovations, Open Solutions, 2021, 9: 168971–168980

[132]

Nadolny Z . Determination of dielectric losses in a power transformer. Energies, 2022, 15(3): 993

[133]

Maina R , Tumiatti V , Pompili M , Bartnikas R . Dielectric loss characteristics of copper-contaminated transformer oils. IEEE Transactions on Power Delivery, 2010, 25(3): 1673–1677

[134]

Fernández I , Valiente R , Ortiz F , Renedo C J , Ortiz A . Effect of TiO2 and ZnO nanoparticles on the performance of dielectric nanofluids based on vegetable esters during their aging. Nanomaterials, 2020, 10(4): 692

[135]

Oparanti S O , Khaleed A A , Abdelmalik A A . AC breakdown analysis of synthesized nanofluids for oil-filled transformer insulation. International Journal of Advanced Manufacturing Technology, 2021, 117(5): 1395–1403

[136]

Umar S , Abdelmalik A A , Sadiq U . Synthesis and characterization of a potential bio-based dielectric fluid from neem oil seed. Industrial Crops and Products, 2018, 115: 117–123

[137]

Shah Z H , Tahir Q A . Dielectric properties of vegetable oils. Journal of Scientific Research, 2011, 3(3): 481–492

[138]

Farade R A , Wahab N I A , Mansour D E A . The effect of nano-additives in natural ester dielectric liquids: a comprehensive review on dielectric properties. IEEE Transactions on Dielectrics and Electrical Insulation, 2023, 30(4): 1502–1516

[139]

Amizhtan S K , Amalanathan A J , Sarathi R , Srinivasan B , Gardas R L , Edin H , Taylor N . Impact of surfactants on the electrical and rheological aspects of silica based synthetic ester nanofluids. IEEE Access: Practical Innovations, Open Solutions, 2022, 10: 18192–18200

[140]

Lv Y Z , Ge Y , Sun Z , Wang L , Niu M K , Huang M , Li C R , Qi B , Yuan J S . Effects of additives on dielectric strength of naphthenic transformer oil. Journal of Molecular Liquids, 2018, 271: 1–7

[141]

Cong H , Shao H , Du Y , Hu X , Zhao W , Li Q . Influence of nanoparticles on long-term thermal stability of vegetable insulating oil. IEEE Transactions on Dielectrics and Electrical Insulation, 2022, 29(5): 1642–1650

[142]

Katiyar A , Dhar P , Nandi T , Das S K . Effects of nanostructure permittivity and dimensions on the increased dielectric strength of nano insulating oils. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2016, 509: 235–243

[143]

ASTM D877/D877M–13, Standard Test Method for Dielectric Breakdown Voltage of Insulating Liquids Using Disk Electrodes. West Conshohocken: ASTM International, 2019

[144]

ASTM D664–18E2, Standard Test Method for Acid Number of Petroleum Products by Potentiometric Titration. West Conshohocken: ASTM International, 2022

[145]

Shen M , Almallahi R , Rizvi Z , Gonzalez-Martinez E , Yang G , Robertson M L . Accelerated hydrolytic degradation of ester-containing biobased epoxy resins. Polymer Chemistry, 2019, 10(23): 3217–3229

[146]

Xu Y , Qian S , Liu Q , Wang Z D . Oxidation stability assessment of a vegetable transformer oil under thermal aging. IEEE Transactions on Dielectrics and Electrical Insulation, 2014, 21(2): 683–692

[147]

Zou P , Li J , Sun C X , Zhang Z T , Liao R J . Dielectric properties and electrodynamic process of natural ester-based insulating nanofluid. Modern Physics Letters B, 2011, 25(25): 2021–2031

[148]

Koutras K N , Antonelou A E , Naxakis I A , Charalampakos V P , Pyrgioti E C , Yannopoulos S N . In-situ high temperature study of the long-term stability and dielectric properties of nanofluids based on TiO2 and SiC dispersions in natural ester oil at various concentrations. Journal of Molecular Liquids, 2022, 359: 119284

[149]

Thakur S , Sarathi R , Danikas M G . Investigation on thermal ageing impact on dielectric properties of natural ester oil. Electrical Engineering, 2019, 101(3): 1007–1018

[150]

Li S , Wang X , Jiang S , Han S , Wang C . Tribological mechanisms of the synergistic effect between phosphate based ionic liquids and metal-organic frameworks. Wear, 2024, 558–559: 205565

[151]

Wang H , Xia W , Yu H , Chen H , Pan Y , Sun Y , Li S , Han S . A theoretical investigation on the transformer oil pyrolysis mechanism and the effect of the small molecule acid in oils. Fuel, 2024, 361: 130522

[152]

Wang H , Chen H , Yu H , Pan Y , Sun Y , Li S , Han S . A reactive molecular dynamics simulation on the mechanism of the transformer oil pyrolysis at the high temperature. Research on Chemical Intermediates, 2024, 50(1): 373–395

RIGHTS & PERMISSIONS

Higher Education Press

AI Summary AI Mindmap
PDF (2662KB)

539

Accesses

0

Citation

Detail

Sections
Recommended

AI思维导图

/