Direct pyrolysis to convert biomass to versatile 3D carbon nanotubes/mesoporous carbon architecture: conversion mechanism and electrochemical performance

Abstract

The massive conversion of resourceful biomass to carbon nanomaterials not only opens a new avenue to effective and economical disposal of biomass, but provides a possibility to produce highly valued functionalized carbon-based electrodes for energy storage and conversion systems. In this work, biomass is applied to a facile and scalable one-step pyrolysis method to prepare three-dimensional (3D) carbon nanotubes/mesoporous carbon architecture, which uses transition metal inorganic salts and melamine as initial precursors. The role of each employed component is investigated, and the electrochemical performance of the attained product is explored. Each component and precise regulation of their dosage is proven to be the key to successful conversion of biomass to the desired carbon nanomaterials. Owing to the unique 3D architecture and integration of individual merits of carbon nanotubes and mesoporous carbon, the as-synthesized carbon nanotubes/mesoporous carbon hybrid exhibits versatile application toward lithium-ion batteries and Zn-air batteries. Apparently, a significant guidance on effective conversion of biomass to functionalized carbon nanomaterials can be shown by this work.

Graphical abstract

Keywords

biomass / direct pyrolysis / 3D CNTs/MC hybrid / lithium-ion batteries / Zn-air batteries

References

[1] Titirici M, White J, Brun N, Budarin L, Su S, del Monte F, MacLachlan J. Sustainable carbon materials. Chemical Society Reviews, 2015, 44(1): 250–290

[2] Liu X, Dai L. Carbon-based metal-free catalysts. Nature Reviews Materials, 2016, 1(11): 16064

[3] Yan J, Wang Q, Wei T, Fan Z. Recent advances in design and fabrication of electrochemical supercapacitors with high energy densities. Advanced Energy Materials, 2014, 4(4): 1300816

[4] Zhang Q, Cheng X, Huang J, Peng H, Wei F. Review of carbon materials for advanced lithium−sulfur batteries. Carbon, 2015, 81: 850

[5] Liu H, Liu X, Li W, Guo X, Wang Y, Wang G, Zhao D. Porous carbon composites for next generation rechargeable lithium batteries. Advanced Energy Materials, 2017, 7(24): 1700283

[6] Zheng M, Chi Y, Hu Q, Tang H, Jiang X, Zhang L, Xu Q. Carbon nanotube-based materials for lithium−sulfur batteries. Journal of Materials Chemistry A: Materials for Energy and Sustainability, 2019, 7(29): 17204–17241

[7] Dai L, Chang W, Baek B, Lu W. Carbon nanomaterials for advanced energy conversion and storage. Small, 2012, 8(8): 1130–1166

[8] Kim M, Park T, Wang C, Tang J, Lim H, Hossain M, Konarova M, Yi J, Na J, Kim J, Yamauchi Y. Tailored nanoarchitecturing of microporous ZIF-8 to hierarchically porous double-shell carbons and their intrinsic electrochemical property. ACS Applied Materials & Interfaces, 2020, 12(30): 34065–34073

[9] Kim M, Xu X, Xin R, Earnshaw J, Ashok A, Kim J, Park T, Nanjundan A K, El-Said W A, Yi J, Na J, Yamauchi Y. KOH-activated hollow ZIF-8 derived porous carbon: nanoarchitectured control for upgraded capacitive deionization and supercapacitor. ACS Applied Materials & Interfaces, 2021, 13(44): 52034–52043

[10] Gupta N, Gupta M, Sharma K. Carbon nanotubes: synthesis, properties and engineering applications. Carbon Letters, 2019, 29(5): 419–447

[11] Moothi K, Iyuke S, Meyyappan M, Falcon R. Coal as a carbon source for carbon nanotube synthesis. Carbon, 2012, 50(8): 2679–2690

[12] Hoang V C, Hassan M, Gomes V G. Coal derived carbon nanomaterials recent advances in synthesis and applications. Applied Materials Today, 2018, 12: 342–358

[13] Zhang G, Liu X, Wang L, Fu H. Recent advances of biomass derived carbon-based materials for efficient electrochemical energy devices. Journal of Materials Chemistry A: Materials for Energy and Sustainability, 2022, 10(17): 9277–9307

[14] Zhang S, Jiang F, Huang B C, Shen X C, Chen W J, Zhou T P, Yu H Q. Sustainable production of value-added carbon nanomaterials from biomass pyrolysis. Nature Sustainability, 2020, 3(9): 753–760

[15] Voloshin R A, Rodionova M V, Zharmukhamedov K, Nejat Veziroglu T, Allakhverdiev S I. Review: biofuel production from plant and algal biomass. International Journal of Hydrogen Energy, 2016, 41(39): 17257–17273

[16] Osman A I, Mehta N, Elgarahy A M, Al Hinai A, Al Muhtaseb A H, Rooney D W. Conversion of biomass to biofuels and life cycle assessment: a review. Environmental Chemistry Letters, 2021, 19(6): 4075–4118

[17] Alper K, Tekin K, Karagöz S, Ragauskas A J. Sustainable energy and fuels from biomass: a review focusing on hydrothermal biomass processing. Sustainable Energy & Fuels, 2020, 4(9): 4390–4414

[18] Wang Z, Shen D, Wu C, Gu S. State-of-the-art on the production and application of carbon nanomaterials from biomass. Green Chemistry, 2018, 20(22): 5031–5057

[19] Reina A, Jia X, Ho J, Nezich D, Son H, Bulovic V, Kong J. Large area, few-layer graphene films on arbitrary substrates by chemical vapor deposition. Nano Letters, 2009, 9(1): 30–35

[20] Bi Z, Kong Q, Cao Y, Sun G, Su F, Wei X, Chen M. Biomass-derived porous carbon materials with different dimensions for supercapacitor electrodes: a review. Journal of Materials Chemistry A: Materials for Energy and Sustainability, 2019, 7(27): 16028–16045

[21] Balahmar N, Mitchell A C, Mokaya R. Generalized mechanochemical synthesis of biomass-derived sustainable carbons for high performance CO₂ storage. Advanced Energy Materials, 2015, 5(22): 1500867

[22] Wang Y, Zhang M, Shen X, Wang H, Wang H, Xia K, Yin Z, Zhang Y. Biomass-derived carbon materials: controllable preparation and versatile applications. Small, 2021, 17(40): 2008079

[23] Yin J, Zhang W, Alhebshi N, Salah N, Alshareef H. Synthesis strategies of porous carbon for supercapacitor applications. Small Methods, 2020, 4(3): 1900853

[24] Lyu L, Seong K, Ko D, Choi J, Lee C, Hwang T, Cho Y, Jin X, Zhang W, Pang H, Piao Y. Recent development of biomass-derived carbons and composites as electrode materials for supercapacitors. Materials Chemistry Frontiers, 2019, 3(1): 2543–2570

[25] Zhang M, Zhang J, Ran S, Sun W, Zhu Z. Biomass-derived sustainable carbon materials in energy conversion and storage applications: status and opportunities. A mini review. Electrochemistry Communications, 2022, 138: 107283

[26] Yang W, Liu X, Yue X, Jia J, Guo S. Bamboo-like carbon nanotube/Fe₃C nanoparticle hybrids and their highly efficient catalysis for oxygen reduction. Journal of the American Chemical Society, 2015, 137(4): 1436–1439

[27] Kang J, Duan X, Wang C, Sun H, Tan X, Tade M O, Wang S. Nitrogen-doped bamboo-like carbon nanotubes with Ni encapsulation for persulfate activation to remove emerging contaminants with excellent catalytic stability. Chemical Engineering Journal, 2018, 332: 398–408

[28] Chen S, Bao P, Wang G. Synthesis of Fe₂O₃-CNT-graphene hybrid materials with an open three-dimensional nanostructure for high capacity lithium storage. Nano Energy, 2013, 2(3): 425–434

[29] Yan N, Zhou X, Li Y, Wang F, Zhong H, Wang H, Chen Q. Fe₂O₃ nanoparticles wrapped in multi-walled carbon nanotubes with enhanced lithium storage capability. . Scientific Reports, 2013, 3(1): 3392

[30] Zhang B, Li T, Huang L, Ren Y, Sun D, Pang H, Tang Y. In situ immobilization of Fe/Fe₃C/Fe₂O₃ hollow hetero-nanoparticles onto nitrogen-doped carbon nanotubes towards high-efficiency electrocatalytic oxygen reduction. Nanoscale, 2021, 13(10): 5400–5409

[31] Bistamam M S A, Azam M A. Tip-growth of aligned carbon nanotubes on cobalt catalyst supported by alumina using alcohol catalytic chemical vapor deposition. Results in Physics, 2014, 4: 105–106

[32] Gohier A, Ewels C P, Minea T M, Djouadi M A. Carbon nanotube growth mechanism switches from tip- to base-growth with decreasing catalyst particle size. Carbon, 2008, 46(10): 1331–1338

[33] Behan J A, Mates Torres E, Stamatin S N, Domínguez C, Iannaci A, Fleischer K, Colavita P E. Oxygen reduction reaction: untangling cooperative effects of pyridinic and graphitic nitrogen sites at metal-free N-doped carbon electrocatalysts for the oxygen reduction reaction. Small, 2019, 15(48): 1970256

[34] Li J, Zhang Y, Zhang X, Han J, Wang Y, Gu L, Song B. Direct transformation from graphitic C₃N₄ to nitrogen-doped graphene: an efficient metal-free electrocatalyst for oxygen reduction reaction. ACS Applied Materials & Interfaces, 2015, 7(35): 19626–19634

[35] Yang L, Huang N, Lu C, Yu H, Sun P, Lv X, Sun X. Atomically dispersed and nanoscaled Co species embedded in micro-/mesoporous carbon nanosheet/nanotube architecture with enhanced oxygen reduction and evolution bifunction for Zn-air batteries. Chemical Engineering Journal, 2021, 404: 127112

[36] Biemolt J, Rothenberg G, Yan N. Understanding the roles of amorphous domains and oxygen-containing groups of nitrogen-doped carbon in oxygen reduction catalysis: toward superior activity. Inorganic Chemistry Frontiers, 2020, 7(1): 177–185

[37] Cheng J, Wu D, Wang T. N-doped carbon nanosheet supported Fe₂O₃/Fe₃C nanoparticles as efficient electrode materials for oxygen reduction reaction and supercapacitor application. Inorganic Chemistry Communications, 2020, 117: 107952

[38] Tian Y, Xu L, Qian J, Bao J, Yan C, Li H, Zhang S. Fe₃C/Fe₂O₃ heterostructure embedded in N-doped graphene as a bifunctional catalyst for quasi-solid-state zinc-air batteries. Carbon, 2019, 146: 763–771

[39] Zhang J, Zhang M, Zeng Y, Chen J, Qiu L, Zhou H, Zhu Z. Single Fe atom on hierarchically porous S, N-co doped nanocarbon derived from porphyra enable boosted oxygen catalysis for rechargeable Zn-air batteries. Small, 2019, 15(24): 1900307

[40] Han J, Bao H, Wang J Q, Zheng L, Sun S, Wang Z L, Sun C. 3D N-doped ordered mesoporous carbon supported single-atom Fe-N-C catalysts with superior performance for oxygen reduction reaction and zinc-air battery. Applied Catalysis B: Environmental, 2021, 280: 119411

[41] Wang X R, Liu J Y, Liu Z W, Wang W C, Luo J, Han X P, Yang J. Identifying the key role of pyridinic-N-co bonding in synergistic electrocatalysis for reversible ORR/OER. Advanced Materials, 2018, 30(23): 1800005

[42] Takeyasu K, Furukawa M, Shimoyama Y, Singh S K, Nakamura J. Role of pyridinic nitrogen in the mechanism of the oxygen reduction reaction on carbon electrocatalysts. Angewandte Chemie International Edition, 2021, 60(10): 5121–5124

[43] Gu S, Christensen T, Hsieh C T, Mallick B C, Gandomi Y A, Li J, Chang J K. Improved lithium storage capacity and high rate capability of nitrogen-doped graphite-like electrode materials prepared from thermal pyrolysis of graphene quantum dots. Electrochimica Acta, 2020, 354: 136642

[44] He B, Li G, Chen L, Chen Z, Jing M, Zhou M, Hou Z. A facile N doping strategy to prepare mass-produced pyrrolic N-enriched carbon fibers with enhanced lithium storage properties. Electrochimica Acta, 2018, 278: 106–113

[45] Li X F, Lian K Y, Liu L, Wu Y, Qiu Q, Jiang J, Luo Y. Unraveling the formation mechanism of graphitic nitrogen-doping in thermally treated graphene with ammonia. Scientific Reports, 2016, 6(1): 23495

[46] Lai Q, Zheng L, Liang Y, He J, Zhao J, Chen J. Metal−organic-framework-derived Fe-N/C electrocatalyst with five-coordinated Fe-N_x sites for advanced oxygen reduction in acid media. ACS Catalysis, 2017, 7(3): 1655–1663

[47] Chen L, Li Z, Li G, Zhou M, He B, Ouyang J, Hou Z. A facile self-catalyzed CVD method to synthesize Fe₃C/N-doped carbon nanofibers as lithium storage anode with improved rate capability and cyclability. Journal of Materials Science and Technology, 2020, 44: 229–236

[48] Xu C, Chen L, Wen Y, Qin S, Li H, Hou Z, Kuang Y. A co-operative protection strategy to synthesize highly active and durable Fe/N co-doped carbon towards oxygen reduction reaction in Zn-air batteries. Materials Today Energy, 2021, 21: 100721

[49] Xu J, Wu C, Yu Q, Zhao Y, Li X, Guan L. Ammonia defective etching and nitrogen-doping of porous carbon toward high exposure of heme-derived Fe-N_x site for efficient oxygen reduction. ACS Sustainable Chemistry & Engineering, 2018, 6(1): 551–560

[50] Liu Y, Li X, Haridas A K, Sun Y, Heo J, Ahn J H, Lee Y. Biomass-derived graphitic carbon encapsulated Fe/Fe₃C composite as an anode material for high-performance lithium ion batteries. Energies, 2020, 13(4): 827

[51] Zheng J, Kong F, Tao S, Qian B A. Fe₂O₃-Fe₃C heterostructure encapsulated into a carbon matrix for the anode of lithium-ion batteries. Chemical Communications, 2021, 57(70): 8818–8821

[52] Kim M, Fernando J F, Wang J, Nanjundan A K, Na J, Hossain M S A, Nara H, Martin D, Sugahara Y, Golberg D, Yamauchi Y. Efficient lithium-ion storage using a heterostructured porous carbon framework and its in situ transmission electron microscopy study. Chemical Communications, 2022, 58(6): 863–866

[53] Chen X, Cheng X, Liu Z. High sulfur-doped hard carbon anode from polystyrene with enhanced capacity and stability for potassium-ion storage. Journal of Energy Chemistry, 2022, 68: 688–698

[54] Kim M, Fernando J F, Li Z, Alowasheeir A, Ashok A, Xin R, Martin D, Nanjundan A K, Golberg D, Yamauchi Y, Amiralian N, Li J. Ultra-stable sodium ion storage of biomass porous carbon derived from sugarcane. Chemical Engineering Journal, 2022, 445: 136344

Acknowledgements

This work was financially supported by the National Key Research and Development Program of China (Grant No. 2019YFC1907900), Science & Technology Talents Lifting Project of Hunan Province (Grant No. 2022TJ-N16) and the Scientific Research Fund of Hunan Provincial Education Department, China (Grant No. 21A0392).

Electronic Supplementary Material

Supplementary material is available in the online version of this article at https://dx.doi.org/10.1007/s11705-022-2266-8 and is accessible for authorized users.

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