Interlayer-confined two-dimensional manganese oxide-carbon nanotube catalytic ozonation membrane for efficient water purification

Dean Xu, Tong Ding, Yuqing Sun, Shilong Li, Wenheng Jing

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Front. Chem. Sci. Eng. ›› 2022, Vol. 16 ›› Issue (5) : 731-744. DOI: 10.1007/s11705-021-2110-6
RESEARCH ARTICLE

Interlayer-confined two-dimensional manganese oxide-carbon nanotube catalytic ozonation membrane for efficient water purification

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Abstract

Catalytic ozonation technology has attracted copious attention in water purification owing to its favorable oxidative degradation of pollutants and mitigation of membrane fouling capacity. However, its extensive industrial application has been restricted by the low ozone utilization and limited mass transfer of the short-lived radical species. Interlayer space-confined catalysis has been theoretically proven to be a viable strategy for achieving high catalytic efficiency. Here, a two-dimensional MnO2-incorporated ceramic membrane with tunable interspacing, which was obtained via the intercalation of a carbon nanotube, was designed as a catalytic ozonation membrane reactor for degrading methylene blue. Benefiting from the abundant catalytic active sites on the surface of two-dimensional MnO2 as well as the ultralow mass transfer resistance of fluids due to the nanolayer confinement, an excellent mineralization effect, i.e., 1.2 mg O3(aq) mg–1 TOC removal (a total organic carbon removal rate of 71.5%), was achieved within a hydraulic retention time of 0.045 s of pollutant degradation. Further, the effects of hydraulic retention time and interlayer spacing on methylene blue removal were investigated. Moreover, the mechanism of the catalytic ozonation employing catalytic ozonation membrane was proposed based on the contribution of the Mn(III/IV) redox pair to electron transfer to generate the reactive oxygen species. This innovative two-dimensional confinement catalytic ozonation membrane could act as a nanoreactor and separator to efficiently oxidize organic pollutants and enhance the control of membrane fouling during water purification.

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Keywords

catalytic membrane reactor / catalytic ozonation / nanoconfinement / two-dimensional manganese oxide

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Dean Xu, Tong Ding, Yuqing Sun, Shilong Li, Wenheng Jing. Interlayer-confined two-dimensional manganese oxide-carbon nanotube catalytic ozonation membrane for efficient water purification. Front. Chem. Sci. Eng., 2022, 16(5): 731‒744 https://doi.org/10.1007/s11705-021-2110-6

References

[1]
Nguyen T A, Juang R. Treatment of waters and wastewaters containing sulfur dyes: a review. Chemical Engineering Journal, 2013, 219: 109–117
CrossRef Google scholar
[2]
Katheresan V, Kansedo J, Lau S Y. Efficiency of various recent wastewater dye removal methods: a review. Journal of Environmental Chemical Engineering, 2018, 6(4): 4676–4697
CrossRef Google scholar
[3]
Spagni A, Casu S, Grilli S. Decolourisation of textile wastewater in a submerged anaerobic membrane bioreactor. Bioresource Technology, 2012, 117: 180–185
CrossRef Google scholar
[4]
García-Montaño J, Torrades F, García-Hortal J A, Domènech X, Peral J. Combining photo-Fenton process with aerobic sequencing batch reactor for commercial hetero-bireactive dye removal. Applied Catalysis B: Environmental, 2006, 67(1–2): 86–92
CrossRef Google scholar
[5]
Paździor K, Bilińska L, Ledakowicz S. A review of the existing and emerging technologies in the combination of AOPs and biological processes in industrial textile wastewater treatment. Chemical Engineering Journal, 2019, 376: 120597
CrossRef Google scholar
[6]
Nawrocki J, Kasprzyk-Hordern B. The efficiency and mechanisms of catalytic ozonation. Applied Catalysis B: Environmental, 2010, 99(1–2): 27–42
CrossRef Google scholar
[7]
Harman B I, Koseoglu H, Yigit N O, Beyhan M, Kitis M. The use of iron oxide-coated ceramic membranes in removing natural organic matter and phenol from waters. Desalination, 2010, 261(1–2): 27–33
CrossRef Google scholar
[8]
Byun S, Davies S H, Alpatova A L, Corneal L M, Baumann M J, Tarabara V V, Masten S J. Mn oxide coated catalytic membranes for a hybrid ozonation-membrane filtration: comparison of Ti, Fe and Mn oxide coated membranes for water quality. Water Research, 2011, 45(1): 163–170
CrossRef Google scholar
[9]
Lee W J, Bao Y, Guan C, Hu X, Lim T. Ce/TiOx-functionalized catalytic ceramic membrane for hybrid catalytic ozonation-membrane filtration process: fabrication, characterization and performance evaluation. Chemical Engineering Journal, 2021, 410: 128307
CrossRef Google scholar
[10]
Wang J, Wu Z, Li T, Ye J, Shen L, She Z, Liu F. Catalytic PVDF membrane for continuous reduction and separation of p-nitrophenol and methylene blue in emulsified oil solution. Chemical Engineering Journal, 2018, 334: 579–586
CrossRef Google scholar
[11]
Ma J, Graham N J D. Degradation of atrazine by manganese-catalysed ozonation: influence of humic substances. Water research (Oxford), 1999, 33(3): 785–793
[12]
Sun Q, Wang Y, Li L, Bing J, Wang Y, Yan H. Mechanism for enhanced degradation of clofibric acid in aqueous by catalytic ozonation over MnO/SBA-15. Journal of Hazardous Materials, 2015, 286: 276–284
CrossRef Google scholar
[13]
Zhao Y, Chang C, Teng F, Zhao Y, Chen G, Shi R, Waterhouse G I N, Huang W, Zhang T. Defect-engineered ultrathin δ-MnO2 nanosheet arrays as bifunctional electrodes for efficient overall water splitting. Advanced Energy Materials, 2017, 7(18): 1700005
CrossRef Google scholar
[14]
Rong S, Zhang P, Wang J, Liu F, Yang Y, Yang G, Liu S. Ultrathin manganese dioxide nanosheets for formaldehyde removal and regeneration performance. Chemical Engineering Journal, 2016, 306: 1172–1179
CrossRef Google scholar
[15]
Liu J, Wei Y, Li P, Zhang P, Su W, Sun Y, Zou R, Zhao Y. Experimental and theoretical investigation of mesoporous MnO2 nanosheets with oxygen vacancies for high-efficiency catalytic DeNOx. ACS Catalysis, 2018, 8(5): 3865–3874
CrossRef Google scholar
[16]
Zhu L, Chen M, Dong Y, Tang C Y, Huang A, Li L. A low-cost mullite-titania composite ceramic hollow fiber microfiltration membrane for highly efficient separation of oil-in-water emulsion. Water Research, 2016, 90: 277–285
CrossRef Google scholar
[17]
Liu Z, Xu K, Sun H, Yin S. One-step synthesis of single-layer MnO2 nanosheets with multi-role sodium dodecyl sulfate for high-performance pseudocapacitors. Small, 2015, 11(18): 2182–2191
CrossRef Google scholar
[18]
Tan X, Wan Y, Huang Y, He C, Zhang Z, He Z, Hu L, Zeng J, Shu D. Three-dimensional MnO2 porous hollow microspheres for enhanced activity as ozonation catalysts in degradation of bisphenol A. Journal of Hazardous Materials, 2017, 321: 162–172
CrossRef Google scholar
[19]
Cui L, Huang H, Ding P, Zhu S, Jing W, Gu X. Cogeneration of H2O2 and •OH via a novel Fe3O4/MWCNTs composite cathode in a dual-compartment electro-Fenton membrane reactor. Separation and Purification Technology, 2020, 237: 116380
CrossRef Google scholar
[20]
Lee W J, Bao Y, Hu X, Lim T. Hybrid catalytic ozonation-membrane filtration process with CeOx and MnOx impregnated catalytic ceramic membranes for micropollutants degradation. Chemical Engineering Journal, 2019, 378: 121670
CrossRef Google scholar
[21]
Chiou C, Mariñas B J, Adams J Q. Modified indigo method for gaseous and aqueous ozone analyses. Ozone Science and Engineering, 1995, 17(3): 329–344
CrossRef Google scholar
[22]
Kai K, Yoshida Y, Kageyama H, Saito G, Ishigaki T, Furukawa Y, Kawamata J. Room-temperature synthesis of manganese oxide monosheets. Journal of the American Chemical Society, 2008, 130(47): 15938–15943
CrossRef Google scholar
[23]
Wang X, Li Y. Synthesis and formation mechanism of manganese dioxide nanowires/nanorods. Chemistry (Weinheim an der Bergstrasse, Germany), 2003, 9(1): 300–306
CrossRef Google scholar
[24]
Devaraj S, Munichandraiah N. Effect of crystallographic structure of MnO2 on its electrochemical capacitance properties. Journal of Physical Chemistry C, 2008, 112(11): 4406–4417
CrossRef Google scholar
[25]
Rong S, Zhang P, Liu F, Yang Y. Engineering crystal facet of α-MnO2 nanowire for highly efficient catalytic oxidation of carcinogenic airborne formaldehyde. ACS Catalysis, 2018, 8(4): 3435–3446
CrossRef Google scholar
[26]
Sinha A K, Pradhan M, Pal T. Morphological evolution of two-dimensional MnO2 nanosheets and their shape transformation to one-dimensional ultralong MnO2 nanowires for robust catalytic activity. Journal of Physical Chemistry C, 2013, 117(45): 23976–23986
CrossRef Google scholar
[27]
Yang D S, Wang M K. Syntheses and characterization of well-crystallized birnessite. Chemistry of Materials, 2001, 13(8): 2589–2594
CrossRef Google scholar
[28]
Xu J, Li Y, Qian M, Pan J, Ding J, Guan B. Amino-functionalized synthesis of MnO2-NH2-GO for catalytic ozonation of cephalexin. Applied Catalysis B: Environmental, 2019, 256: 117797
CrossRef Google scholar
[29]
Nawaz F, Cao H, Xie Y, Xiao J, Chen Y, Ghazi Z A. Selection of active phase of MnO2 for catalytic ozonation of 4-nitrophenol. Chemosphere, 2017, 168: 1457–1466
CrossRef Google scholar
[30]
Zhao H, Dong Y, Jiang P, Wang G, Zhang J, Li K, Feng C. An α-MnO2 nanotube used as a novel catalyst in ozonation: performance and the mechanism. New Journal of Chemistry, 2014, 38(4): 1175–1743
CrossRef Google scholar
[31]
Li G, Lu Y, Lu C, Zhu M, Zhai C, Du Y, Yang P. Efficient catalytic ozonation of bisphenol-A over reduced graphene oxide modified sea urchin-like α-MnO2 architectures. Journal of Hazardous Materials, 2015, 294: 201–208
CrossRef Google scholar
[32]
Qi F, Chen Z, Xu B, Shen J, Ma J, Joll C, Heitz A. Influence of surface texture and acid-base properties on ozone decomposition catalyzed by aluminum (hydroxyl) oxides. Applied Catalysis B: Environmental, 2008, 84(3–4): 684–690
CrossRef Google scholar
[33]
Sui M, Liu J, Sheng L. Mesoporous material supported manganese oxides (MnOx/MCM-41) catalytic ozonation of nitrobenzene in water. Applied Catalysis B: Environmental, 2011, 106: 197–203
CrossRef Google scholar
[34]
Turan-Ertas T, Gurol M D. Oxidation of diethylene glycol with ozone and modified Fenton processes. Chemosphere, 2002, 47(3): 293–301
CrossRef Google scholar
[35]
Zhang S, Quan X, Zheng J, Wang D. Probing the interphase “HO·zone” originated by carbon nanotube during catalytic ozonation. Water Research, 2017, 122: 86–95
CrossRef Google scholar
[36]
Wang Y, Chen L, Chen C, Xi J, Cao H, Duan X, Xie Y, Song W, Wang S. Occurrence of both hydroxyl radical and surface oxidation pathways in N-doped layered nanocarbons for aqueous catalytic ozonation. Applied Catalysis B: Environmental, 2019, 254: 283–291
CrossRef Google scholar
[37]
Zhang J, Wu Y, Qin C, Liu L, Lan Y. Rapid degradation of aniline in aqueous solution by ozone in the presence of zero-valent zinc. Chemosphere, 2015, 141: 258–264
CrossRef Google scholar
[38]
Huang K, Liu G, Lou Y, Dong Z, Shen J, Jin W. A graphene oxide membrane with highly selective molecular separation of aqueous organic solution. Angewandte Chemie International Edition, 2014, 53(27): 6929–6932
CrossRef Google scholar
[39]
Rana M, Sai Avvaru V, Boaretto N, de la Peña O’Shea V A, Marcilla R, Etacheri V, Vilatela J J. High rate hybrid MnO2@CNT fabric anodes for Li-ion batteries: properties and a lithium storage mechanism study by in situ synchrotron X-ray scattering. Journal of Materials Chemistry. A, Materials for Energy and Sustainability, 2019, 7(46): 26596–26606
CrossRef Google scholar
[40]
Lu K, Hu Z, Xiang Z, Ma J, Song B, Zhang J, Ma H. Cation intercalation in manganese oxide nanosheets: effects on lithium and sodium storage. Angewandte Chemie International Edition, 2016, 55(35): 10448–10452
CrossRef Google scholar
[41]
Byun S, Cho S H, Yoon J, Geissen S U, Vogelpohl A, Kim S M. Influence of mass transfer on the ozonation of wastewater from the glass fiber industry. Water Science and Technology, 2004, 49(4): 31–36
CrossRef Google scholar
[42]
Saroj D P, Kumar A, Bose P, Tare V, Dhopavkar Y. Mineralization of some natural refractory organic compounds by biodegradation and ozonation. Water Research, 2005, 39(9): 1921–1933
CrossRef Google scholar
[43]
Rosal R, Rodríguez A, Perdigón-Melón J A, Mezcua M, Hernando M D, Letón P, García-Calvo E, Agüera A, Fernández-Alba A R. Removal of pharmaceuticals and kinetics of mineralization by O3/H2O2 in a biotreated municipal wastewater. Water Research, 2008, 42(14): 3719–3728
CrossRef Google scholar
[44]
Chen Y, Zhang G, Liu H, Qu J. Confining free radicals in close vicinity to contaminants enables ultrafast Fenton-like processes in the interspacing of MoS2 membranes. Angewandte Chemie International Edition, 2019, 58(24): 8134–8138
CrossRef Google scholar
[45]
Biswas S, Pal A. Visible light assisted Fenton type degradation of methylene blue by admicelle anchored alumina supported rod shaped manganese oxide. Journal of Water Process Engineering, 2020, 36: 101272
CrossRef Google scholar
[46]
Xu A, Li X, Xiong H, Yin G. Efficient degradation of organic pollutants in aqueous solution with bicarbonate-activated hydrogen peroxide. Chemosphere, 2011, 82(8): 1190–1195
CrossRef Google scholar
[47]
Luo X, Liang H, Qu F, Ding A, Cheng X, Tang C Y, Li G. Free-standing hierarchical α-MnO2@CuO membrane for catalytic filtration degradation of organic pollutants. Chemosphere, 2018, 200: 237–247
CrossRef Google scholar

Acknowledgments

This study was financially supported by the National Natural Science Foundation of China (Grant Nos. 21838005 and 21676139) and the Key Scientific Research and Development Projects of Jiangsu Province (Grant No. BE201800901). The authors would like to thank Shiyanjia Laboratory for the language editing service.

Electronic Supplementary Material

Supplementary material is available in the online version of this article at https://dx.doi.org/10.1007/s11705-021-2110-6 and is accessible for authorized users.

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