Preparation of a Pb loaded gas diffusion electrode and its application to CO₂ electroreduction

Abstract

A Pb loaded gas diffusion electrode was fabricated and used for the electroreduction of CO₂ to formic acid. The Pb/C catalyst was prepared by isometric impregnation. The crystal structure and morphology of the Pb/C catalyst were characterized by X-ray diffraction (XRD) and transmission electron microscope (TEM). The preparation conditions of the gas diffusion electrode were optimized by adjusting the amounts of polytetrafluoroethylene (PTFE) in the gas diffusion layer and acetylene black in the catalytic layer. The electrochemical performance of the as-prepared gas diffusion electrode was studied by chronoamperometry and cyclic voltammetry. The optimized gas diffusion electrode showed good catalytic performance for the electroreduction of CO₂. The current efficiency of formic acid after 1 h of operation reached a maximum of 22% at -2.0 V versus saturated calomel electrode (SCE).

Keywords

electroreduction / carbon dioxide / lead catalyst / gas diffusion electrode / formic acid

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Acknowledgments

The work was supported by the National Natural Science Foundation of China (Grant No. 21076152), the Special Research Fund for the Doctoral Program of Higher Education of China (No. 2100032110018), the Program of Introducing Talents of Discipline to Universities, China (No. B06006) and the Engineering Education Fund of Tianjin University.

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