Removal of copper by modified chitosan adsorptive membrane
Xiaoshuai LIU, Zihong CHENG, Wei MA
Removal of copper by modified chitosan adsorptive membrane
In this study, a novel adsorptive membrane was prepared from chitosan as the functional polymer and some additive blend solutions by solution casting method. The modified chitosan membrane was characterized by FTIR and its Water Swelling Ratio (WSR). The adsorption of copper ions on the adsorptive membrane was investigated in batch experiments. The results obtained from the experiments indicated that the membrane had a good adsorption capacity for copper ions, the optimal ionic strength and pH were 0.1 and 5-6, respectively. Compared with the Langmuir isotherm model, the experimental data were found to be following the Freundlich model.
chitosan / adsorptive membrane / copper removal / environmental engineering / heavy metal / isotherm model
[1] |
Beppu M M, Arruda E J, Vieira R S, Santos N N. Adsorption of Cu(II) on porous chitosan membranes functionalized with histidine. J Membr Sci. 2004, 240: 227-235
CrossRef
Google scholar
|
[2] |
Peniche C, Monal W A, Davidenko N, Sastre R, Gallardo A, Román J S. Self-curing membranes of chitosan/PAA IPNs obtained by radical polymerization: preparation, characterization and interpolymer complexation. Biomater, 1999, 20: 1869-1878
CrossRef
Google scholar
|
[3] |
Bueno S M A, Haupy K, Vijayalakshmi M A. In vitro removal of human lgG by pseudo-specific affinity membrane filtration on a large scale. A preliminary report. Int J Artif Organs, 1995, 18: 392-398
|
[4] |
Liu C X, Bai R B. Adsorptive removal of copper ions with highly porous chitosan/cellulose acetate blend hollow fiber membranes. J Membr Sci. 2006, 284: 313-322
CrossRef
Google scholar
|
[5] |
Wang X S, Qin Y. Equilibrium sorption isotherms for of Cu2+on rice bran. Process Biochem, 2005, 40: 677-680
CrossRef
Google scholar
|
[6] |
Bhattacharyya K G, Gupta S S. Pb(II) uptake by kaolinite and montmorillonite in aqueous medium: Influence of acid activation of the clays. Colloids Surf, A, 2006, 277: 191-200
CrossRef
Google scholar
|
[7] |
Noeline B F, Manohar D M. Kinetic and equilibrium modeling of lead (II) sorption from water and wastewater by polymerized banana stem in a batch reactor. Sep Purif Tech, 2005, 45: 131-140
CrossRef
Google scholar
|
/
〈 | 〉 |