Study on a green synthetic method of TRPPMCl (M= Fe, Mn, Co)

Abstract

A green synthetic method using mixted solvents of di-methyl formamide(DMF) and acids instead of single DMF to synthesize metalloporphyrins(TRPPMCl) from TRPPH₂ and MCl₂ metallization was proposed in this paper. A series of TRPPMCl (M= Fe, Mn, Co) were synthesized through this innovative synthetic method, and these complexes were characterized with various spectroscopic techniques, including IR and UV-Vis spectroscopy. The results showed that the metallization time was markedly reduced from about 10 h to 0.5 h in contrast with the conventional synthetic methods.

Keywords

TRPPMCl metalloporphyrins / green synthesis / acid

References

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (Grant Nos. 20776003, 20576005) and the Key Project of Natural Science Foundation of Beijing (No. 2061001).

RIGHTS & PERMISSIONS

2014 Higher Education Press and Springer-Verlag Berlin Heidelberg