Synergistic scale inhibition of polyaspartic acid composite with magnetic field

Abstract

Polyaspartic acid (PASP) composite, a scale inhibitor, was prepared from PASP, itaconic acid–acrylic acid–acrylic ester (IA-AA-AE) terpolymer and 2-phosphonobutane- 1,2,4-tricarboxylic acid (PBTCA). The scale inhibition of PASP composite and the effect of its synergism with a magnetic field on scale inhibition were investigated. Calcium carbonate crystals in scale samples were characterized by means of SEM and XRD. The static and dynamic experiments show that the chelating function of PASP composite for Ca²⁺ can be enhanced by synergism with a magnetic field. Under Ca²⁺ 650 mg/L, HCO₃^- 1,300 mg/L and PASP composite 4 mg/L, the scale inhibition rate of PASP composite in magnetic water can increase by 10% in static state and by 20% in dynamic experiments. Scanning electron microscope (SEM) and X-ray diffraction (XRD) results show that calcite and aragonite can be completely transformed into vaterite by using PASP composite.

Keywords

polyaspartic acid, itaconic acid, acrylic acid, acrylic ester, 2-phosphonobutane- 1,2,4-tricarboxylic acid, composite, magnetic field, scale inhibition