Wellbore strengthening through rock consolidation using diammonium phosphate
Mahmoud Desouky , Murtada Saleh Aljawad , Murtadha J. AlTammar , Hector J. Gonzalez-Perez , Ahmed Alqroos
Petroleum ›› 2026, Vol. 12 ›› Issue (2) : 254 -262.
Wellbore instability in chalk formations poses significant challenges during drilling and production due to low rock strength, fluid sensitivity, and creep. This study investigates the efficacy of diammonium phosphate (DAP) as a chemical consolidating agent to enhance chalk mechanical properties under simulated reservoir conditions. Austin Chalk core samples were treated with a 1 M DAP solution at 75 °C and 1000 psi confining pressure for 72 h to promote hydroxyapatite precipitation. Triaxial loading tests compared the treated and untreated specimens. Results demonstrated that the DAP treatment improved the confined compressive strength by 16%–8% across confining pressures (400–1600 psi). Mohr-Coulomb failure envelopes revealed a cohesion increase from 600 psi (untreated) to 1350 psi (treated), with unconfined compressive strength doubling to 3200 psi. These enhancements, attributed to hydroxyapatite cementation, indicate DAP’s potential to mitigate wellbore failure by strengthening the formation itself. The findings advance chemical stabilization strategies for chalk, offering a novel solution to reduce non-productive time and improve long-term well integrity in carbonate reservoirs.
Wellbore instability / Failure envelope / Carbonate consolidation / Chalk / Diammonium phosphate
| [1] |
|
| [2] |
|
| [3] |
|
| [4] |
|
| [5] |
R. Risnes, M.V. Madland, M. Hole, N.K. Kwabiah, Water weakening of Chalk-mechanical effects of water-glycol mixtures, J. Pet. Sci. Eng. 48 (1-2) (2005) 21-36, https://doi.org/10.1016/j.petrol.2005.04.004. |
| [6] |
Gaurina-Međimurec, N.; Simon, K.; Matanović, D. Laboratory investigations of silicate mud contamination with calcium. vol. 16. |
| [7] |
|
| [8] |
|
| [9] |
E. Van Oort, D. Ripley, I. Ward, J.W. Chapman, R. Williamson, M. Aston, Silicate-based drilling fluids: competent, cost-effective and benign solutions to wellbore stability problems, in: IADC/SPE Drilling Conference; SPE, New Orleans, Louisiana, 1996, https://doi.org/10.2118/35059-MS. SPE-35059-MS. |
| [10] |
Alford, S.; Dzialowski, A.; Jiang, P.; Ullmann, H. Research Into Lubricity, Formation Damage Promises to Expand Applications for Silicate Drilling Fluids. |
| [11] |
|
| [12] |
F. Jroundi, M.T. Gonzalez-Munoz, C. Rodriguez-Navarro, Protection and consolidation of stone heritage by bacterial carbonatogenesis, in: E. Joseph (Ed.), Microorganisms in the Deterioration and Preservation of Cultural Heritage, Springer International Publishing, Cham, 2021, pp. 281-299, https://doi.org/10.1007/978-3-030-69411-1_13. |
| [13] |
E. Sassoni, E. Franzoni, Sugaring marble in the monumental cemetery in Bologna (Italy): characterization of naturally and artificially weathered samples and first results of consolidation by hydroxyapatite, Appl. Phys. A 117 (4) (2014) 1893-1906, https://doi.org/10.1007/s00339-014-8629-3. |
| [14] |
M. Martino, G. Milazzo, P. Livreri, M.J. Mosquera, R. Giarrusso, Evaluation of ammonium phosphates as consolidating agent for carbonatic stone used in sicily, in: M.J. Mosquera, M.L. Almoraima Gil (Eds.), Conserving Cultural Heritage, CRC Press, 2018, pp. 33-35, https://doi.org/10.1201/9781315158648-8. |
| [15] |
E. Sassoni, G. Ugolotti, M. Nanolime Pagani, Nanosilica or ammonium phosphate? Laboratory and field study on consolidation of a byzantine marble sarcophagus, Constr. Build. Mater. 262 (2020) 120784, https://doi.org/10.1016/j.conbuildmat.2020.120784. |
| [16] |
B. Sena Da Fonseca, A.P. Ferreira Pinto, S. Piçarra, M.F. Montemor, Alkoxysilane-based sols for consolidation of carbonate stones: proposal of methodology to support the design and development of new consolidants, J. Cult. Herit. 43 (2020) 51-63, https://doi.org/10.1016/j.culher.2019.11.003. |
| [17] |
G. Graziani, E. Sassoni, E. Franzoni, Consolidation of porous carbonate stones by an innovative phosphate treatment: mechanical strengthening and physical-microstructural compatibility in comparison with TEOS-based treatments, Herit. Sci. 3 (1) (2015) 1, https://doi.org/10.1186/s40494-014-0031-0. |
| [18] |
|
| [19] |
E. Possenti, C. Colombo, C. Conti, L. Gigli, M. Merlini, J.R. Plaisier, M. Realini, D. Sali, G.D. Gatta, Diammonium hydrogenphosphate for the consolidation of building materials. Investigation of newly-formed calcium phosphates, Constr. Build. Mater. 195 (2019) 557-563, https://doi.org/10.1016/j.conbuildmat.2018.11.077. |
| [20] |
Y. Samarkin, M. Aljawad, A. Amao, T. Sølling, K. Al-Ramadan, S. Abu-Khamsin, S. Patil, M. AlTammar, K. Alruwaili, Hydraulic fracture conductivity sustenance in carbonate formations through rock strengthening by DAP solution, in: Day 3 Wed, Saudi Arabia, IPTC: Riyadh, 2022 D032S171R001, https://doi.org/10.2523/IPTC-22496-MS. (Accessed 23 February 2022). |
| [21] |
E. Sassoni, E. Franzoni, B. Pigino, G.W. Scherer, S. Naidu, Consolidation of calcareous and siliceous sandstones by hydroxyapatite: Comparison with a TEOS-based consolidant, J. Cult. Herit. 14 (3) (2013) e103-e108, https://doi.org/10.1016/j.culher.2012.11.029. |
| [22] |
B. Sena da Fonseca, A.P. Ferreira Pinto, S. Piçarra, B. Caldeira, M.F. Montemor, Consolidating efficacy of diammonium hydrogen phosphate on artificially aged and naturally weathered coarse-grained marble, J. Cult. Herit. 51 (2021) 145-156, https://doi.org/10.1016/j.culher.2021.08.003. |
| [23] |
Y. Samarkin, A.O. Amao, M.S. Aljawad, M. Borji, N. Scott, M.J. AlTammar, K.M. Alruwaili, In-Situ Micro-CT scanning and compressive strength assessment of diammonium hydrogen phosphate (DAP) treated chalk, Sci. Rep. 13 (1) (2023) 16806, https://doi.org/10.1038/s41598-023-43609-6. |
| [24] |
H. Pasco, S. Naidu, B. Lothenbach, E. Sassoni, Enhancement of surface properties of cementitious materials by phosphate treatments, Cem. Concr. Compos. 141 (2023) 105124, https://doi.org/10.1016/j.cemconcomp.2023.105124. |
| [25] |
E. Sassoni, G. Graziani, E. Franzoni, Repair of sugaring marble by ammonium phosphate: Comparison with ethyl silicate and ammonium oxalate and pilot application to historic artifact, Mater. Des. 88 (2015) 1145-1157, https://doi.org/10.1016/j.matdes.2015.09.101. |
| [26] |
M. Desouky, M.S. Aljawad, A. Abduljamiu, T. Solling, D. Al-Shehri, M.J. AlTammar, K.M. Alruwaili, Temperature, pressure, and duration impacts on the optimal stiffening of carbonates aged in diammonium phosphate solution, Sci. Rep. 14 (1) (2024) 6444. |
| [27] |
Y. Samarkin, A. Amao, M.S. Aljawad, T. Solling, K. Al-Ramadan, M.J. AlTammar, K.M. Alruwaili, Conductivity enhancement of fractured carbonates through high-temperature diammonium hydrogen phosphate consolidation: a preliminary study, SPE J. (2023) 1-17, https://doi.org/10.2118/214657-PA. |
| [28] |
|
| [29] |
|
| [30] |
Y. Samarkin, A. Amao, M.S. Aljawad, T.I. Sølling, K. Norrman, K. Al-Ramadan, M.J. AlTammar, K.M. Alruwaili, Hardness enhancement of carbonate rocks by formation of smithsonite and fluorite, Rock Mech. Rock Eng. 55 (2) (2022) 1001-1012, https://doi.org/10.1007/s00603-021-02701-x. |
| [31] |
|
| [32] |
|
| [33] |
E. Papamichos, M. Brignoli, F.J. Santarelli, An experimental and theoretical study of a partially saturated collapsible rock, Mech. Cohesive-Frict. Mater. 2 (3) (1997) 251-278, https://doi.org/10.1002/(SICI)1099-1484(199707)2:3%253C251::AID-CFM33%253E3.0.CO;2-%2523. |
| [34] |
|
| [35] |
Collin, F.; Cui, Y. J.; Schroeder, C.; Charlier, R. Mechanical Behaviour of Chalk Reservoir: Numerical Modelling of Water Sensitivity and Time Dependence Effects. |
| [36] |
J. Zhao, Applicability of mohr-coulomb and hoek-brown strength criteria to the dynamic strength of brittle rock, Int. J. Rock Mech. Min. Sci. 37 (7) (2000) 1115-1121, https://doi.org/10.1016/S1365-1609(00)00049-6. |
| [37] |
K. Runesson, M. Ristinmaa, L. Mahler, A comparison of viscoplasticity formats and algorithms, Mech. Cohesive-Frict. Mater. 4 (1) (1999) 75-98, https://doi.org/10.1002/(SICI)1099-1484(199901)4:1%253C75::AID-CFM60%253E3.0.CO;2-4. |
| [38] |
M. Desouky, M.S. Aljawad, A. Abduljamiu, T. Solling, A. Abdulraheem, M.J. AlTammar, K.M. Alruwaili, Enhancing fracture conductivity in soft chalk formations with diammonium phosphate treatment: a study at high temperature, pressure, and stresses, SPE J. (2023) 1-11, https://doi.org/10.2118/215857-PA. |
| [39] |
|
| [40] |
Fuchs, K.; Clauss, B. Borehole Breakout Method for Stress Determination - Theory and Practice -. |
/
| 〈 |
|
〉 |