Novel thermochemical fracturing: A breakthrough in sustainable and efficient enhanced geothermal systems (EGS)

Ahmed Al-Ghamdi , Amjed Hassan , Mohamed Mahmoud , Talal Al-Shafloot

Petroleum ›› 2025, Vol. 11 ›› Issue (5) : 613 -623.

PDF (16843KB)
Petroleum ›› 2025, Vol. 11 ›› Issue (5) :613 -623. DOI: 10.1016/j.petlm.2025.07.004
Full Length Article
research-article
Novel thermochemical fracturing: A breakthrough in sustainable and efficient enhanced geothermal systems (EGS)
Author information +
History +
PDF (16843KB)

Abstract

Enhanced geothermal systems (EGS) are crucial for accessing earth's vast geothermal potential, particularly in low-permeability formations. However, conventional EGS stimulation via hydraulic fracturing often entails high operational costs, substantial water consumption, potential environmental impacts, and risks of induced seismicity. This study presents a novel thermochemical fracturing approach to enhance EGS performance and sustainability while addressing these limitations. The in-situ exothermic reaction of sodium nitrite (NaNO2) and ammonium chloride (NH4Cl) was applied to a 12-inch carbonate rock sample. A specialized core flooding apparatus enabled real-time evaluation of temperature profiles, permeability, and heat transfer enhancements. The thermochemical stimulation increased permeability by 109% (from 19.01 to 39.70 mD) and enhanced heat transfer by 530%. These improvements stem from an extensive micro-fracture network generated by high-pressure nitrogen gas pulses, contrasting with larger planar fractures from hydraulic fracturing. Notably, this was achieved with only a 3.3% increase in porosity, indicating preserved rock integrity. The exothermic reaction prevented core cooling during ambient-temperature stimulation fluid injection, avoiding thermal shock. The thermochemical stimulation primarily generates nitrogen gas (N2) and a brine solution as byproducts. The generated N2 offers the additional benefit of providing well lifting energy, simplifying flowback operations. The novel application of thermochemical stimulation in EGS represents a promising, eco-friendly, and operationally efficient alternative to conventional EGS stimulation techniques.

Keywords

Energy sustainability / Enhanced geothermal systems / Thermochemical fluids / Fracturing treatment / Novel method

Cite this article

Download citation ▾
Ahmed Al-Ghamdi, Amjed Hassan, Mohamed Mahmoud, Talal Al-Shafloot. Novel thermochemical fracturing: A breakthrough in sustainable and efficient enhanced geothermal systems (EGS). Petroleum, 2025, 11(5): 613-623 DOI:10.1016/j.petlm.2025.07.004

登录浏览全文

4963

注册一个新账户 忘记密码

CRediT authorship contribution statement

Ahmed Al-Ghamdi: Methodology, Validation, Formal analysis, Writing-original draft, Investigation, Data curation. Amjed Hassan: Writing-review & editing, Supervision, Investigation, Data curation, Validation, Methodology, Conceptualization, Writing-original draft, Formal analysis. Mohamed Mahmoud: Visualization, Investigation, Writing-review & editing, Validation, Formal analysis, Conceptualization, Supervision, Data curation. Talal Al-Shafloot: Writing-review & editing, Data curation, Investigation, Supervision, Formal analysis, Conceptualization.

Declaration of competing interest

The Authors declare that they have not conflict of interest.

Acknowledgements

The College of Petroleum and Geoscience (CPG) at King Fahd University of Petroleum and Minerals (KFUPM) is acknowledged for the support and permission to publish this work.

References

[1]

P. Olasolo, M.C. Juárez, M.P. Morales, S. Damico, I.A. Liarte, Enhanced geothermal systems (EGS): a review, Renew. Sustain. Energy Rev. (2016), https://doi.org/10.1016/j.rser.2015.11.031.

[2]

L.C.A. Gutiérrez-Negrín,Evolution of worldwide geothermal power2020-2023, Geoth. Energy 12 (2024), https://doi.org/10.1186/s40517-024-00290-w.

[3]

J. Zhang, M. Zhao, G. Wang, Effects of heat transfer fluid and boundary conditions on temperature field of enhanced geothermal system, Petroleum 8 (3) (2022) 436-445, https://doi.org/10.1016/j.petlm.2021.06.006.

[4]

I.G.A. Irena t. Global Geothermal Market and Technology Assessmen, 2023.

[5]

K. Breede, K. Dzebisashvili, X. Liu, G. Falcone, A systematic review of enhanced (or engineered) geothermal systems: past, present and future, Geoth. Energy (2013), https://doi.org/10.1186/2195-9706-1-4.

[6]

Y. Kang, P. Li, W. Cao, M. Che, L. You, J. Liu, Z. Lai, Investigation of pore structure alteration and permeability enhancement of shale matrix by supercritical water treatment after hydraulic fracturing, Petroleum 10 (2) (2024) 265-274, https://doi.org/10.1016/j.petlm.2022.05.002.

[7]

H. Hofmann, G. Blöcher, N. Börning, N. Maronde, N. Pastrik, G. Zimmermann, Potential for enhanced geothermal systems in low permeability limestones - stimulation strategies for the Western Malm karst (Bavaria), Geothermics 51 (2014) 351-367, https://doi.org/10.1016/j.geothermics.2014.03.003.

[8]

G. Zimmermann, A. Reinicke, Hydraulic stimulation of a deep sandstone reservoir to develop an Enhanced Geothermal System: laboratory and field experiments, Geothermics 39 (2010) 70-77, https://doi.org/10.1016/j.geothermics.2009.12.003.

[9]

Y. Zhao, Y. Zhang, P. He, Hydraulic Fracturing and Rock Mechanics, Springer, 2023, https://doi.org/10.1007/978-981-99-2540-7.

[10]

J. Fink, Hydraulic Fracturing Chemicals and Fluids Technology, Gulf Professional Publishing, 2020, https://doi.org/10.1016/B978-0-12-822071-9.00008-6.

[11]

F.R. Spellman, Environmental Impacts of Hydraulic Fracturing, CRC Press, 2012, https://doi.org/10.1201/9781032622118.

[12]

E.L. Majer, R. Baria, M. Stark, S. Oates, J. Bommer, B. Smith, H. Asanuma, Induced seismicity associated with Enhanced Geothermal Systems, Geothermics 36 (2007) 185-222, https://doi.org/10.1016/j.geothermics.2007.03.003.

[13]

A. Mignan, D. Landtwing, P. Kästli, B. Mena, S. Wiemer, Induced seismicity risk analysis of the 2006 Basel, Switzerland, Enhanced Geothermal System project: influence of uncertainties on risk mitigation, Geothermics 53 (2015) 133-146, https://doi.org/10.1016/j.geothermics.2014.05.007.

[14]

X. Yin, Changsheng Jiang, F. Yin, H. Zhai, Y. Zheng, H. Wu, X. Niu, Y. Zhang, Cong Jiang, J. Li, Assessment and optimization of maximum magnitude forecasting models for induced seismicity in enhanced geothermal systems: the gonghe EGS project in Qinghai, China, Tectonophysics 886 (2024), https://doi.org/10.1016/j.tecto.2024.230438.

[15]

A. Ghassemi, S. Tarasovs, A.H.-D. Cheng, A 3-D study of the effects of thermomechanical loads on fracture slip in enhanced geothermal reservoirs, Int. J. Rock Mech. Min. Sci. 44 (2007) 1132-1148, https://doi.org/10.1016/j.ijrmms.2007.07.016.

[16]

G. Izadi, D. Elsworth, Reservoir stimulation and induced seismicity: roles of fluid pressure and thermal transients on reactivated fractured networks, Geothermics 51 (2014) 368-379, https://doi.org/10.1016/j.geothermics.2014.01.014.

[17]

U. Mital, M. Hu, Y. Guglielmi, J. Brown, J. Rutqvist, Modeling injection-induced fault slip using long short-term memory networks, J. Rock Mech. Geotech. Eng. (2024), https://doi.org/10.1016/j.jrmge.2024.09.006.

[18]

S. Andrés, D. Santillán, J.C. Mosquera, L. Cueto-Felgueroso, Hydraulic stimulation of geothermal reservoirs: numerical simulation of induced seismicity and thermal decline, Water (Basel) 14 (2022) 3697, https://doi.org/10.3390/w14223697.

[19]

Z. Liu, M. Wu, H. Zhou, L. Chen, X. Wang, Performance evaluation of enhanced geothermal systems with intermittent thermal extraction for sustainable energy production, J. Clean. Prod. 434 (2024), https://doi.org/10.1016/j.jclepro.2023.139954.

[20]

Z. Tariq, M. Mahmoud, A. Abdulraheem, A. Al-Nakhli, M. BaTaweel, An experimental study to reduce the breakdown pressure of the unconventional carbonate rock by cyclic injection of thermochemical fluids, J. Pet. Sci. Eng. 187 (2020), https://doi.org/10.1016/j.petrol.2019.106859.

[21]

A. Hassan, M. Mahmoud, A. Al-Majed, M. Elsayed, A. Al-Nakhli, M. BaTaweel, Performance analysis of thermochemical fluids in removing the gas condensate from different gas formations, J. Nat. Gas Sci. Eng. 78 (2020), https://doi.org/10.1016/j.jngse.2020.103333.

[22]

I. Gomaa, M. Mahmoud, Stimulating illitic sandstone reservoirs using in-situ generated HF with the aid of thermochemicals, J. Pet. Sci. Eng. 190 (2020), https://doi.org/10.1016/j.petrol.2020.107089.

[23]

A. Mustafa, M. Mahmoud, A. Abdulraheem, Z. Tariq, A. Al-Nakhli, Improvement of petrophysical properties of tight sandstone and limestone reservoirs using thermochemical fluids, Petrophysics-SPWLA J. Formation Evaluation and Reserv. Desc. 61 (2020) 363-382, https://doi.org/10.30632/PJV61N4-2020a3.

[24]

M.S. Aljawad, M. Mahmoud, S.A. Abu-Khamsin, Mass and heat transfer of thermochemical fluids in a fractured porous medium, Molecules 25 (2020), https://doi.org/10.3390/molecules25184179.

[25]

A.H. Gowida, S.A. Abu-Khamsin, M.A. Mahmoud, M.S. Aljawad, S.F. Alafnan, Accelerated low-temperature oxidation for sand consolidation and production control, J. Pet. Sci. Eng. 214 (2022), https://doi.org/10.1016/j.petrol.2022.110567.

[26]

F.J.S. Bispo, V. Kartnaller, J. Cajaiba, pH-Based control of the kinetics and process safety of the highly exothermic reaction between ammonium chloride and sodium nitrite for flow-assurance applications, SPE J. 26 (2021) 3634-3642, https://doi.org/10.2118/205389-PA.

[27]

W. Xiuyu, C. Yuqiao, L. Chang, Z. Ya, Improved kinetic equations for a NaNO2/NH4Cl heat generating system and their implications in oil production, Chem. Technol. Fuels Oils 55 (2019) 623-634, https://doi.org/10.1007/s10553-019-01075-9.

[28]

A. Hassan, M. Abdalla, M. Mahmoud, G. Glatz, A. Al-Majed, A. Al-Nakhli, Condensate-banking removal and gas-production enhancement using thermochemical injection: a field-scale simulation, Processes 8 (2020) 727, https://doi.org/10.3390/pr8060727.

[29]

A. Hassan, M. Mahmoud, A. Al-Majed, A. Al-Nakhli, New chemical treatment for permanent removal of condensate banking from different gas reservoirs, ACS Omega 4 (2019) 22228-22236, https://doi.org/10.1021/acsomega.9b03685.

[30]

Amjed M. Hassan, M.A. Mahmoud A.A. Al-Majed A.R. Al-Nakhli M. A. Bataweel, Water blockage removal and productivity index enhancement by injecting thermochemical fluids in tight sandstone formations, J. Pet. Sci. Eng. 182 (2019), https://doi.org/10.1016/j.petrol.2019.106298.

[31]

D.A. Nguyen, M.A. Iwaniw, H.S. Fogler, Kinetics and mechanism of the reaction between ammonium and nitrite ions: experimental and theoretical studies, Chem. Eng. Sci. 58 (2003) 4351-4362, https://doi.org/10.1016/S0009-2509(03)00317-8.

[32]

D.A. Nguyen, H.S. Fogler, S. Chavadej, Fused chemical reactions. 2. Encapsulation: application to remediation of paraffin plugged pipelines, Ind. Eng. Chem. Res. 40 (2001) 5058-5065, https://doi.org/10.1021/ie0009886.

[33]

P. Singh, H.S. Fogler, Fused chemical reactions: the use of dispersion to delay reaction time in tubular reactors, Ind. Eng. Chem. Res. 37 (1998) 2203-2207, https://doi.org/10.1021/ie9706020.

[34]

A.A. Al-Taq, M.S. Aljawad, O.S. Alade, M. Mahmoud, A. Alrustum, Thermally activated nitrogen/heat generating reaction: a kinetic study, ACS Omega 8 (2023) 10139-10147, https://doi.org/10.1021/acsomega.2c07466.

[35]

F. Al Balushi, Q. Zhang, A. Dahi Taleghani, On the impact of proppants shape, size distribution, and friction on adaptive fracture conductivity in EGS, Geoenergy Sci. Eng. 241 (2024) 213115, https://doi.org/10.1016/j.geoen.2024.213115.

[36]

U.C. Iyare, L.P. Frash, B. K C, M. Meng, W. Li, Y. Madenova, S.K. Peterson, M. R. Gross, M.M. Smith, K.A. Kroll, Experimental investigation of shear in granite fractures at Utah FORGE: implications for EGS reservoir stimulation, Geothermics 131 (2025) 103344, https://doi.org/10.1016/j.geothermics.2025.103344.

[37]

T. Kneafsey, P. Dobson, D. Blankenship, P. Schwering, M. White, J.P. Morris, L. Huang, T. Johnson, J. Burghardt, E. Mattson, G. Neupane, C. Strickland, H. Knox, V. Vermuel, J. Ajo-Franklin, P. Fu, W. Roggenthen, T. Doe, M. Schoenball, C. Hopp, V.R. Tribaldos, M. Ingraham, Y. Guglielmi, C. Ulrich, T. Wood, L. Frash, T. Pyatina, G. Vandine, M. Smith, R. Horne, M. McClure, A. Singh, J. Weers, M. Robertson, The EGS collab project: outcomes and lessons learned from hydraulic fracture stimulations in crystalline rock at 1.25 and 1.5 km depth, Geothermics 126 (2025) 103178, https://doi.org/10.1016/j.geothermics.2024.103178.

[38]

Z. Liu, N. Qi, P. Jiang, A. Li, X. Li, Developments of acid fracturing technology for enhanced geothermal systems: a review, Appl. Energy 388 (2025) 125650, https://doi.org/10.1016/j.apenergy.2025.125650.

[39]

M.A. Grant, P.F. Bixley, Geothermal Reservoir Engineering, Elsevier, 2011, https://doi.org/10.1016/B978-0-12-383880-3.10001-0.

[40]

A. Watson, Geothermal Engineering Fundamentals and Applications, Springer, 2013, https://doi.org/10.1007/978-1-4614-8569-8.

[41]

S. Morsy, J.J. Sheng, M.Y. Soliman,Improving hydraulic fracturing of shale formations by acidizing, in: SPE Eastern Regional Meeting, SPE, 2013, https://doi.org/10.2118/165688-MS.

[42]

Z. Tariq, M. Aljawad, M. Mahmoud, A. Abdulraheem, A.R. Al-Nakhli, Thermochemical acid fracturing of tight and unconventional rocks: experimental and modeling investigations, J. Nat. Gas Sci. Eng. 83 (2020), https://doi.org/10.1016/j.jngse.2020.103606.

[43]

A. Kamali, M. Pournik, Fracture closure and conductivity decline modeling-application in unpropped and acid etched fractures, J. Unconv.l Oil Gas Resour. 14 (2016) 44-55, https://doi.org/10.1016/j.juogr.2016.02.001.

[44]

H. Liu, B. Baletabieke, G. Wang, J. Guo, F. Xia, Z. Chen, Influences of real-time acid-rock reaction heat on etched fracture dimensions during acid fracturing of carbonate reservoirs and field applications, Heliyon 8 (2022) e11659, https://doi.org/10.1016/j.heliyon.2022.e11659.

[45]

H. Jia, H. Pu, J. Li, J. Wang, X. Chen, J. Mou, B. Gao, Acid-etched fracture conductivity with in situ-generated acid in ultra-deep, high-temperature carbonate reservoirs, Processes 12 (2024) 1792, https://doi.org/10.3390/pr12091792.

[46]

P. Liu, H. Hu, X. Chen, J. Du, J. Liu, F. Liu, W. Chen, Y. Jia, The influencing parameters and improve methods of acid-etched fracture conductivity: a review, Geoenergy Sci. Eng. 238 (2024) 212844, https://doi.org/10.1016/j.geoen.2024.212844.

PDF (16843KB)

0

Accesses

0

Citation

Detail

Sections
Recommended

/