Type-II topological metals

Si Li , Zhi-Ming Yu , Yugui Yao , Shengyuan A. Yang

Front. Phys. ›› 2020, Vol. 15 ›› Issue (4) : 43201

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Front. Phys. ›› 2020, Vol. 15 ›› Issue (4) :43201 DOI: 10.1007/s11467-020-0963-7
TOPICAL REVIEW
Type-II topological metals
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Abstract

Topological metals (TMs) are a kind of special metallic materials, which feature nontrivial band crossings near the Fermi energy, giving rise to peculiar quasiparticle excitations. TMs can be classified based on the characteristics of these band crossings. For example, according to the dimensionality of the crossing, TMs can be classified into nodal-point, nodal-line, and nodal-surface metals. Another important property is the type of dispersion. According to degree of the tilt of the local dispersion around the crossing, we have type-I and type-II dispersions. This leads to significant distinctions in the physical properties of the materials, owing to their contrasting Fermi surface topologies. In this article, we briefly review the recent advances in this research direction, focusing on the concepts, the physical properties, and the material realizations of the type-II nodal-point and nodal-line TMs.

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type-II / nodal point / nodal line / topological metals

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Si Li, Zhi-Ming Yu, Yugui Yao, Shengyuan A. Yang. Type-II topological metals. Front. Phys., 2020, 15 (4) : 43201 DOI:10.1007/s11467-020-0963-7

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1 Introduction

Topological metals (TMs) (including semimetals) have been attracting tremendous interest in current condensed-matter physics research [1-5]. In TM materials, the electronic band structures possess nontrivial band crossings near the Fermi energy, such that the low-energy quasiparticles behave distinctly from the conventional Schrödinger-type fermions, leading to unusual physical properties.

TMs are classified based on the characteristics of these band crossings. For example, according to the dimensionality of the band crossing, which (for a 3D material) can be 0D, 1D, and 2D, we respectively have nodal-point, nodal-line, and nodal-surface TMs. TMs can also be classified by the degree of degeneracy of the band crossing. For example, a Weyl semimetal refers to a TM with twofold degenerate nodal points [6, 7], whereas in a Dirac semimetal, the nodal points have fourfold degeneracy [8-10]. Nodal features with other degrees of degeneracy, such as threefold, sixfold, or even eightfold, have also been discussed [11-19]. Meanwhile, the classification can also be according to the dispersion around the band crossing. This is evidently an important characteristic, because it directly affects the properties of the low-energy excitations. The dispersion may have different leading order terms, e.g., with linear, quadratic, or cubic dispersions. Recent works have revealed the existence of stable quadratic and cubic nodal points as well as nodal lines [20-25]. Here, in this article, we focus on the classification based on another aspect of the dispersion, which is specific for linear band crossings, namely, the signs of slopes of the crossing bands.

This classification scheme was initially proposed for nodal points in 2015 [26, 27]. The dispersion around a conventional (type-I) Weyl point shows an up-right conical shape in the energy-momentum space [see Fig. 1(a)]. In comparison, for the proposed type-II Weyl point, the cone is tipped over (i.e., the two crossing bands have the same sign for their slopes along certain directions in the k-space), as shown in Fig. 1(b). The difference is crucial, because it leads to distinct Fermi surface topologies, which in turn determines many physical properties. In 2017, Li et al. [28] extended the scheme to nodal lines, proposing the concepts of type-II and hybrid nodal lines. These works have attracted great attention. Subsequent studies have revealed many interesting properties of these new TM phases, and have identified several realistic materials candidates.

In this article, we will briefly review the concepts, the physical properties, and the material realizations of the type-II nodal-point and nodal-line TMs. The very relevant concept of hybrid nodal-line TM and the speculation on the type-II nodal-surface TM will also be discussed. The field of TMs is still under rapid development. We hope this short review can serve its purpose to provide the readers with the background and to stimulate their interest to dive into this fascinating research field.

2 Type-II nodal point

We start by discussing the nodal-point TMs. The proposal of the type-II nodal point was first made for Weyl points [26, 27], and later extended to Dirac points [29, 30]. In this section, we first review the concept. Then we discuss several interesting physical properties of the type-II nodal-point TMs. Finally, we review the material candidates that have been identified. It should be noted that the distinction between type-I and type-II is on the dispersion. They actually share the same kind of topology/symmetry protection. Here, we will not cover the fundamentals pertinent to the topology/symmetry aspects. The readers who are interested in these are suggested to consult the previous review articles in Refs. [1-5].

2.1 Concept

The concept of type-II dispersion was first introduced in the context of Weyl points. Here, we will follow the discussion in Ref. [26] by Soluyanov et al. The most general model describing an isolated Weyl point can be written as

(1)H(k)=∑i=x,y,zj=0,x,y,zkivijσj,

where the energy and the wave vector k are measured from the Weyl point, ki are the components of k, vij are the Fermi velocities, σ0 is the 2×2 unit matrix, and σj (j=x,y,z) are the three Pauli matrices. The energy dispersion around the point can be expressed as

(2)E±(k)=∑i=x,y,zkivi0±∑j=x,y,z(∑i=x,y,zkivij)2=T(k)±U(k).

Here, ± corresponds to the two crossing bands. The two terms T(k) and U(k) both are linear in k. One notes that without the T term, the spectrum has a chiral symmetry, i.e., it is symmetric with respect to E=0, as shown in Fig. 1(a) where we have an up-right Weyl cone. A finite T(k) term will tilt the spectrum. When the tilt is so strong such that T dominates over U along a certain direction in k-space, the Weyl cone will be tipped over, and we will have a dramatically different situation, as shown in Fig. 1(b). This is defined as the type-II Weyl point.

One observes that the transition from the conventional (type-I) Weyl point in Fig. 1(a) to the type-II Weyl point in Fig. 1(b) represents a Lifshitz transition: the Fermi surface for the former case is a point (the Weyl point), whereas for the latter case it consists of finite electron and hole pockets touching at the Weyl point. Since many physical properties are connected with the Fermi surface topology, one naturally expects that the type-II Weyl TMs would exhibit distinct physics from their type-I counterparts. This is the rationale behind the definition of type-II dispersion.

A more intuitive criterion for distinguishing type-I and type-II points is as follows. For a type-I point, along all directions in k-space, the two crossing bands always have slopes with opposite signs. In contrast, for a type-II point, there must exist a direction k^, along which the two bands have slopes with the same sign. For example, in Fig. 1(b), the two bands both have negative slopes along the kx direction, and hence the Weyl cone is tipped over along this direction. It should be noted that along other directions [such as the ky direction in Fig. 1(b)], the two bands may still have slopes with opposite signs. This indicates that the type-II points intrinsically have a very strong anisotropy.

The concept can be naturally extended to Dirac points with preserved PT symmetry [29, 30], where P and T refer to the inversion and time reversal symmetries, respectively. Most discovered Dirac TM materials indeed have this symmetry (some exceptions have also been found [31, 32]). With PT symmetry, each band is doubly degenerate, so the dispersion around a Dirac point is just like that for a Weyl point, and the above discussion directly applies.

2.2 Physical property

As mentioned above, the type-II nodal point is associated with a distinct Fermi surface topology from the type-I case. For the type-I case, we have a single Fermi point (when the Fermi energy is exactly at the nodal point) or a single carrier pocket, whereas for the type-II case, we have coexisting electron and hole pockets close to each other. This distinction leads to marked differences in their physical properties.

The Fermi surface topology will directly affect the magnetic response. Under an applied magnetic field, the electrons in solids will form cyclotron orbits. In k-space, these orbits are located on equi-energy surfaces and are within planes perpendicular to the field direction. Thus, the magnetic response is sensitive to the Fermi surface and offers an well established tool for probing the Fermi surface property. In Ref. [33], Yu et al. compared the Landau spectra for type-I and type-II points (see Fig. 2). They found that the tilt [the T term in Eq. (2)] tends to squeeze the Landau levels in energy. For a type-II point, there exists a critical angle between the B field and the tilt direction, at which the squeezing becomes so strong such that the Landau levels collapses onto each other, leading to a huge peak in the density of states. Remarkably, this effect happens regardless of the magnetic field strength. Similar Landau level collapse effect was also predicted for graphene [34], but in that case, a huge in-plane electric field is also required, which proves to be challenging to achieve in experiment. In comparison, the effect is much more accessible for type-II TMs. It can manifest in the scanning tunneling spectroscopy (STS) and the magneto-transport measurements. Indeed, promising evidences have been reported in experiment on the type-II Weyl TM material WTe2 [35].

Before the Landau level collapse (i.e., below the critical angle), there also exist distinct features in the magneto-optical response. As discussed in Refs. [33, 36, 37], these features include the invariable presence of intraband absorption peaks at low frequencies, the absence of absorption tails (as evidenced by the appearance of absorption gaps in Fig. 3), and the special anisotropic field dependence. Especially, when reversing the B field direction, all the peaks are unchanged except for the first interband peak (which involves the chiral Landau band). This difference is illustrated in Fig. 3, and is unique for the type-II points. In Ref. [36], Tchoumakov et al. further emphasized the existence of new types of optical transitions beyond the unusual dipolar ones. These features should be detectable by using the magneto-optical spectroscopy.

A celebrated effect discussed in the context of Weyl semimetals is the chiral anomaly [38, 39]. Under a magnetic field, there appears a special chiral Landau band around an original Weyl point, which is gapless and has its sign of slope determined by the chirality of the Weyl point. In a non-interacting lattice model, the Weyl points come in pairs of opposite chirality. This is known as the Nielson–Ninomiya no-go theorem [40, 41] (one way to circumvent this theorem was recently proposed in Ref. [42]). As a result, with B field, the chiral Landau bands must also appear in pairs with slopes of opposite signs. If we further apply an electric field parallel to the magnetic field, the electrons can be pumped through these chiral Landau bands from Weyl points of one chirality to those with the opposite chirality. This non-conservation of chirality corresponds to the chiral anomaly originally discussed in high energy physics. In condensed matter, this effect leads to a positive contribution to the longitudinal magneto-conductivity [38, 39]. (However, positive longitudinal magneto-conductivity cannot be regarded as a smoking-gun evidence for the Weyl TM phase, because there exist other possible mechanisms even in the absence of nontrivial band topology [43, 44].) In Ref. [26], Soluyanov et al. pointed out that the chiral anomaly has a strong dependence on the magnetic field direction. It occurs only when angle between the B field and the tilt is less than the critical angle mentioned above (or equivalently, when |T(k)|>|U(k)| for k along the field direction). Later, in Ref. [37], by calculations on a lattice model for a type-II Weyl metal, it was shown that an inversion-asymmetric over-tilting can create an imbalance in the number of chiral Landau bands with positive and negative slopes. This is clearly observed in Fig. 4(c), where the two chiral Landau bands both have negative slopes. So far, it is still not clear whether such chiral bands can generate any measurable signals in transport experiment.

The energy spectrum under a magnetic field can usually be well captured by the semiclassical picture, involving the semiclassical cyclontron orbits quantized by the Bohr–Sommerfeld quantization condition [46-48]. This is also explicitly demonstrated for the Weyl model case [33]. One quantum effect going beyond this theory is the magnetic breakdown, referring to the field-induced tunneling between the semiclassical orbits. As we have mentioned above, a type-II nodal point is a contact point between an electron pocket and a hole pocket. Hence, one can naturally expect that there could exists strong tunneling between the electron and hole orbits. This effect has been studied in detail in Refs. [45, 49]. As shown in Fig. 5, the tunneling leads to hybridized 8-shaped orbits. O’Brien et al. [45] made an insightful comparison of this effect with the Klein tunneling at a p–n junction in real space, and showed that as the energy approaches the Weyl point, the tunneling probability approaches unity even with vanishing B field strength. This magnetic breakdown can manifest as an additional low frequency component in the magnetic oscillations. Koshino [49] showed that the 8-shaped orbits also lead to a factor of two difference in the resonance peaks for the optical conductivities along two orthogonal directions normal to the B field.

In general relativity and astrophysics, it is known that the light-cone is tilted by the effects of gravity. And inside the event horizon of a black hole, the light-cone is tipped over, just like the type-II case here. This had inspired the early proposals to realize artificial black holes in the superfluid Helium [50, 51], via controlling vortices and background superfluid flow which are challenging in experiment. Now, the type-II TMs offer a new possibility. In Ref. [52], Guan et al. proposed to achieve several astrophysical analogues in strained Weyl/Dirac TMs, including the black/white hole event horizons, gravitational lens, and Hawking radiation. It was shown that an event horizon can be created as a domain wall between type-I and type-II regions [see Fig. 6(a)]. A simple formula for estimating the Hawking radiation temperature was also presented.

Finally, for conventional type-I Weyl semimetals with broken T symmetry, it has been shown that there exists a finite intrinsic anomalous Hall effect with magnitude proportional to the separation between the Weyl points [53]. Zyuzin and Tiwari [54] found that for the type-II case, the anomalous Hall conductivity has a sensitive dependence on the tilt. Moreover, the conductivity remains finite even when the separation between the Weyl points vanishes, if the tilts of the Weyl points are not identical.

2.3 Material realization

The first example of the type-II Weyl TM was found by Soluyanov et al. in the layered material WTe2 [26]. Subsequently, a number of type-II Weyl TMs have been identified, including MoTe2 [55-58], MoxW1-xTe2 [59-61], TaIrTe4 [62, 63], LaAlGe [64], XP2 (X=Mo, W) [65, 66], Ta3S2 [67], and YbMnBi2 [68, 69]. Figure 7 shows the example of MoTe2. Although Weyl cones are completely tipped over along a certain direction. Type-II dispersion does not affect the topological charge of the Weyl point. Thus, a type-II Weyl TM also possesses Fermi arc surface states, as shown in Fig. 7(b) for MoTe2 [58].

Many TMs with type-II Dirac points have also been discovered to date, such as PtTe2 [70], PtSe2 [29, 71], PdTe2 [72, 73], MA3 (M=V, Nb, Ta; A=Al, Ga, In) [30], YPd2Sn class [74], LaAlO3/LaNiO3/LaAlO3 quantum well [75], high-temperature cuprate superconductor La2−xSrxCuO4 and Eu2−xSrxNiO4 [76], Heusler compounds XInPd2 (X=Ti, Zr, Hf) [77], and NiTe2 [78]. The crystal structure and the band structure of Val3 are shown in Fig. 8. In Fig. 8(c), one can clearly observe that the type-II crossing point on the Z–Γpath. Here, each band has a double degeneracy due to the PT symmetry, so that the point is a type-II Dirac point.

All the above mentioned type-II Dirac points are in non-magnetic materials. Recently, the first example of a magnetic type-II Dirac point was found in TaCoTe2 [79]. This material is antiferromagnetic in its ground state, with the magnetic configuration shown in Fig. 9(a). Again the system has a composite PT symmetry, so each band is doubly degenerate. In its band structure, one finds a type-II Dirac point slightly below the Fermi level, as indicated by the red arrow in Fig. 9(b) Importantly, this Dirac point is robust against spin–orbit coupling.

3 Type-II nodal line

A nodal line can be viewed as consisting of many nodal points. Since the dispersion of a nodal point can be classified as type-I or type-II, the following question naturally arises: can the classification be generalized to nodal lines? This question was first investigated by Li et al. in 2017 [28].

3.1 Concept

We first introduce the concept of a type-II nodal line. The discussion here follows that in Ref. [28]. Consider a nodal line formed by the linear crossing between two bands in a 3D system. For any point P on the line, the general low-energy effective model around P can be expressed as

(3)H(q)=v1q1σx+v2q2σy+w⋅q.

Here, the wave-vector q is measured from P, qi (i=1, 2) are the components of q along the two orthogonal transverse directions [see Fig. 10(a)], and vi are the Fermi velocities. The last term in Eq. (3) represents the local tilt of the spectrum at P. The energy spectrum is given by

(4)E±(q)=w⋅q±v12q12+v22q22.

It should be noted that in the q1–q2 plane, the tilt is most effective along the w⊥=(w1,w2,0) direction, where w⊥ is the projection of w onto the q1–q2 plane. When |w⊥| is small, the slopes of two bands have opposite signs for all directions in the q1–q2 plane and it is the conventional dispersion [Fig. 10(b)], and the point P can be defined as type-I. However, when |w⊥| is large enough and satisfies the relationship |w⊥|2>v12w12+v22w22, the spectrum becomes completely tipped along the w⊥ direction [Fig. 10(c)] and the slopes of the two crossing bands have the same sign. Such a dispersion (and the point P) can be referred to as type-II. Now, we can define a type-II (type-I) nodal line to be the one on which all the points are of type-II (type-I) dispersion. Generically, a type-I nodal line is formed by the crossing of an electron-like band and a hole-like band, whereas a type-II nodal line is formed by the crossing of two electron-like (or hole-like) bands. Hence, such a classification makes physical sense.

Ref. [28] also presented the following minimal model for a type-II nodal line,

(5)H(k)=12mkρ2+12η(kρ2−k02)σx+vzkzσy,

where kρ=kx2+ky2, m, η, and k0 are model parameters. This model describes a nodal loop with radius k0 in the kz=0 plane. Evidently, model (3) can be regarded as its low-energy model via identifying q1 to be along the k^ρ direction, q2 to be along k^z-direction, with the correspondences that v1=k0/η, and w=k0/mk^ρ. One finds that the model (5) describes a type-II (type-I) nodal loop when |η/m|>1 (<1). For the type-II case (with |η/m|>1), the tilt term [first term in Eq. (5)] dominates, making both bands electron-like or hole-like along the radial direction depending on the sign of m, and their intersection makes the type-II nodal loop. This model can be used as a start point for theoretical studies of the properties of type-II nodal lines.

3.2 Physical property

Type-II and type-I nodal loops differ in their energy dispersions. Most importantly, they have different kinds of constant energy surfaces. As shown in Figs. 11(a,b) in the q1–q2 plane for model (kρ–kz plane for model), for type-I line, the equi-energy contours are closed ellipses, whereas for type-II line, the equi-energy contours become hyperbolas. This qualitative difference will manifest in a variety of physical properties. For example, under a magnetic field, electrons orbit around constant energy surfaces, the different types of orbits will produce contrasting signals in magneto-oscillations [45, 80, 81] (such as de Haas-van Alphen oscillations); and the transition from elliptic to hyperbolic type orbits, e.g., by varying the magnetic field direction for a type-II nodal loop, would typically be accompanied by the Landau level collapse effect [33] as discussed in Section 2.2.

In Figs. 11(a,b), one also observes that the positive and negative energy contours have a much less overlap for a type-II nodal line than for a type-I nodal line. This is a natural consequence of both bands being electron-like (or hole-like), and could lead to marked difference in their optical response. In Figs. 11(c,d), the joint density of states (JDOS): D(ω)=1V∑kδ(Ec,k−Ev,k−ω), and the optical energy absorption rate: R(ω)=2πω∑k|Mcv|2δ(Ec,k−Ev,k−ω) are presented for the type-II and type-I nodal loops. Here Mcv is the optical transition matrix element and the model in Eq. (5) is used for the calculation. One indeed observes that both quantities are much suppressed for the type-II nodal line.

For carrier transport in the plane of a nodal loop, the type-II loop should have a higher mobility than the type-I loop. This is because the low-energy states near a point on the type-II loop are propagating roughly in the same direction, while the opposite-propagating states are located at the other end of the loop (see Fig. 10), thus momentum relaxation by scattering would be less effective as compared with the type-I case [52].

In addition, Chen et al. [82] found that under light-irridiation, a type-II nodal loop shows interesting transformations into several Floquet Weyl semimetal states, with features distinct from a type-I loop.

3.3 Material realization

The first material example with a type-II nodal line was predicted in the crystalline compound K4P3 [28]. The material has the W3CoB3-type orthorhombic structure with space group No. 63 (Cmcm) [see Fig. 12(a)]. Figure 12(b) shows the band structure of K4P3, in which one can observe a linear band crossing point along the Γ–X paths very close to the Fermi level, as indicated in Fig. 12(b). This linear crossing point is not isolated, but belongs to a nodal loop traversing the Brillouin zone (such a shape features a nontrivial ℤ3 index as discussed in Ref. [28]), as illustrated in Fig. 12(c,d). Furthermore, the dispersion in Fig. is of type-II. One can use the model (3) to fit the DFT band structure. The fitted parameters are shown in Fig. 12(e). One observes that |w|>|v1| for the whole loop, which confirms that the loop is type-II.

Subsequently, type-II nodal lines have also been found in a few other materials, such as Mg3Bi2 [83, 84] and strained Na3N [85]. Figure 13 shows the band structure results of Mg3Bi2. The type-II nodal loop in Mg3Bi2 has been verified by the angle-resolved photoemission spectroscopy (ARPES) measurement [84].

4 Hybrid nodal line

Besides type-I and type-II lines, there exists a remaining possibility for a nodal line: the line could be composed of both type-I and type-II points. This is defined as a hybrid nodal line. On a hybrid nodal line, the tilt dominates only part of the line.

A minimal model for a hybrid nodal line is presented in Ref. [86]:

(5)H(k)=αxkx2+αyky2+(βxkx2+βyky2−M)σx+vzkzσy.

Here, αi,βi,M, and vz are model parameters. Assuming βx(y)>0, when M>0, the model describes a nodal loop lies in the kx−ky plane, and around each point on the loop, the expanded low-energy model takes the form in Eq. (3). One can verify that when |αi|/|βi|<1(>1)(i=x,y), the loop is type I (type II); and when (|αx|−|βx|)(|αy|−|βy|)<0, a hybrid loop is realized.

The band structures as well as the Fermi surfaces for the type-I, type-II, and hybrid nodal lines are schematically illustrated in Fig. 14. A hybrid loop would typically occur when one of the crossing bands has a saddle-type dispersion [see Fig. 14(c)]. This leads to two important features. The first feature is that a hybrid loop generally has energy variation along the loop, i.e., it spans a range of energy. The second features is that when the Fermi energy is located in that energy range, the Fermi surface would consist of coexisting electron and hole pockets that are connected by isolated nodal points on the loop. These features can give rise to interesting magnetic responses, such as the zero-field magnetic breakdown (see Fig. 15) and peculiar anisotropy in the cyclotron resonance [86].

Several hybrid nodal-line materials have also been proposed, such as the Bernal-stacked graphite [87, 88], ScCd-type transition-metal intermetallic materials [28], Ca2As [86], certain 3D carbon allotropes [89, 90], and B2Si [91]. The results for Ca2As and a 3D carbon allotrope are shown in Fig. 16.

5 Summary and outlook

In this article, we have briefly reviewed the concepts and some recent developments of type-II topological TMs. These materials offer a fertile playground for exploring novel types of emergent fermions.

Regarding the concept, some studies used the terminology of “type-III” nodal point. It refers to a special case where one of the crossing bands is flat along the maximally tilted direction. Such a state is not a stable phase, rather, it is a critical point between the type-I and type-II phases, corresponding to the event horizon as discussed in Ref. [52].

Looking to the future, there are many interesting questions and directions to be explored.

First, the study can be extended to other kinds of nodal points, such as the triply degenerate nodal points and the Dirac points without the PT symmetry. The latter case is also known as the birefringent Dirac point [31, 92, 93], for which the four crossing bands would generally split along an arbitrary direction. One expects that there could be rich Fermi surface topologies depending on the dispersions around the nodal points.

Second, the classification can also be directly extended to nodal surfaces [94-97]. Depending on the dispersion around each point on the surface, we can naturally have type-I, type-II, and hybrid nodal surfaces, similar to the case for nodal lines. In Ref. [97], the nodal surfaces are classified based on their protecting mechanisms. The Class-I nodal surfaces have chiral symmetry, so they must belong to type-I. On the other hand, the Class-II surfaces do not have this constraint, so type-II and hybrid types may appear for the Class-II surfaces.

Third, the physical properties of these novel nodal features (including the type-II and hybrid nodal surfaces), especially the interplay between the dispersion and the band topology, still need to be explored. These includes systematic studies on the electric, magnetic, optical, and transport properties. In addition, as discussed in Ref. [52], the close analogy with astrophysics can offer intriguing possibility to study astrophysical effects in condensed matter settings.

Last but not least, we need to identify ideal material candidates for these new phases [98]. The desired ones are those with a clean low-energy band structure, with the target nodal feature close to the Fermi level, and with a sufficiently large linear-dispersion region. These requirements are important for experimental studies and for future applications based on these materials.

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