1 Introduction
The strongly interacting particles of the Standard Model are colored quarks and gluons. In contrast, the strongly interacting particles in nature are color-singlet (i.e., white) mesons and baryons. In the theory, quarks and gluons are related to mesons and baryons by the long-distance regime of Quantum Chromodynamics (QCD), which remains the least understood aspect of the theory. Since first-principle lattice-QCD (LQCD) calculations are still not practical for most long-distance phenomena, a number of models motivated by the color structure of QCD have been proposed. However, so far at least, predictions of these QCD-motivated models that pertain to the spectrum of hadrons have not had great success.
For example, it is well known that combining a light-quark triplet with a antiquark antitriplet gives the familiar meson octet of flavor-. Using similar considerations based on QCD, two quark triplets can be combined to form a “diquark” antitriplet of antisymmetric states and a sextet of symmetric states as illustrated in Fig. 1(a). In QCD, these diquarks have color: combining a red triplet with a blue triplet – as shown in the figure – produces a magenta (anti-green) diquark and, for the antisymmetric triplet configurations, the color force between the two quarks is expected to be attractive. Likewise, green-red and blue-green diquarks form yellow (anti-blue) and cyan (anti-red) antitriplets as shown in Fig. 1(b).
Since these diquarks are not color-singlets, they cannot exist as free particles but, on the other hand, the anticolored diquark antitriplets should be able to combine with other colored objects in a manner similar to antiquark antitriplets, thereby forming multiquark color-singlet states with a more complex substructure than the
mesons and
baryons of the original quark model [
1]. These so-called “exotic” states include pentaquark baryons, six-quark
H-dibaryons and tetraquark mesons, as illustrated in Fig. 1(c). Other proposed exotic states are glueballs, which are mesons made only from gluons, hybrids formed from a
q,
and a gluon, and deuteron-like bound states of color-singlet “normal” hadrons, commonly referred to as molecules. These are illustrated in Fig. 1(d). Glueball and hybrid mesons are motivated by QCD; molecules are a generalization of classical nuclear physics to systems of subatomic partics.
2 Pentaquarks and H-dibaryons
All of the above-mentioned candidates for exotic states have been the subject of numerous theoretical and experimental investigations during the four decades that have elapsed since QCD was first formulated. This activity peaked in 2003 when the LEPS experiment at the SPring-8 electron ring in Japan reported the observation of a peak in the
invariant mass distribution in
reactions on a carbon target [
2], with properties close to those that had been predicted for the
pentaquark [
3]. This created a lot of excitement at the time [
4] but subsequent, high-statistics experiments [
5,
6] did not confirm the LEPS result and, instead, gave negative results. The current “conventional wisdom” is that pentaquarks do not exist [
7], or at least have yet to be found.
The six-quark
H-dibaryon, subsequently referred to as
H, was predicted by Jaffee in 1977 to be a doubly strange, tightly bound six-quark structure
with isospin zero and
[
8]. An
state with baryon number
and mass below
could only decay via weak interactions and, thus, would be long-lived. Although Jaffe’s original prediction that the
H would be
MeV below the
threshold was ruled out by the observation of double-
hypernuclei, most notably the famous “Nagara” event [
9] that limited the allowed
H region to masses above
MeV, the theoretical case for an
H-dibaryon with mass near
continues to be strong, and has been recently strengthened by two independent LQCD calculations, both of which find an
H-dibaryon state with mass near
[
10,
11].
2.1 Belle H-dibaryon search
The Belle experiment recently reported results of a search for production of an
-dibaryon with mass near
in inclusive
and
decays [
12]. Decays of narrow
bottomonium
resonances are particularly well suited for searches for multiquark states with non-zero strangeness. The
states are flavor-
singlets that primarily decay via annihilation into three gluons. The gluons materialize into
,
and
pairs with nearly equal probabilities, plus additional gluons that also subsequently materialize as
pairs. This creates final states with a high density of quarks and antiquarks in a limited volume of phase space. A benchmark rate for multiquark-state production in these decays is set by the measured inclusive decay branching fractions to antideuterons (
)
†:
and
[
13]. If the six-quark
-dibaryon is produced at a rate that is similar to that for six-quark antideuterons, there should be many thousands of them in the 102 million
and 158 million
event samples collected by Belle.
For masses below , Belle searched for (& ) signals in the inclusive invariant mass distribution. For masses above , the (& mode was used. Figure 2 shows the measured (a) & (b) invariant mass spectra for masses below and the (c) and (d) mass spectra for masses above . Here results from the and data samples are combined. No signal is observed. The solid red curves show results of a background-only fit to the data; the dashed curve shows the MC expectations for an H-dibaryon produced at th of the antideuteron rate. Upper limits on the inclusive branching ratios that are at least a factor of twenty below that for antideuterons are set over the entire MeV mass interval.
Neither pentaquarks nor the
H-dibaryon are seen in spite of the stong theoretical motivation for their existence. The absence of pentaquarks led Wilczek to remark “
The story of the pentaquark shows how poorly we understand QCD” [
14]. The absence of any evidence for the
H-dibaryon (among other things) led Jaffe to observe that “
The absence of exotics is one of the most obvious features of QCD” [
15].
3 What we do see
Although forty years of experimental searches has failed to come up with compelling evidence for specifically QCD-motivated exotic hadrons, strong evidence for mesons that do not fit into the simple
scheme of the original quark model has been steadily accumulating during the past decade. These include a candidate for a bound state of a proton and antiproton from the BESII experiment [
16], so-called “baryonium”, an idea that has been around for a long, long time [
17], and the
XYZ mesons, charmoniumlike and bottomoniumlike states that do not fit into any of the remaining unfilled states in the
- and
-meson level schemes [
18].
3.1 Baryonium in radiative decays?
In 2003, the BESII experiment reported the observation of a dramatic near-threshold mass enhancement in the
invariant mass spectrum in radiative
decays, shown in the top panel of Fig. 3(a) [
16]. The lower panel in Fig. 3(a) shows the
spectrum with the effects of phase-space divided out (assuming an
S-wave
system). It seems apparent from the phase-space-corrected plot that the dynamical source for this enhancement, whatever it may be, is at or below the
mass threshold. A fit with a Breit–Wigner (BW) line shape modified by a kinematic threshold factor yielded a peak mass of
MeV, about 18 MeV below
, and an upper limit of
MeV on the width
†. It was subsequently pointed out that the BW form used by BESII should be modified to include the effect of final-state-interactions on the shape of the
mass spectrum [
19,
20]. When this was done, it was found that the effects of FSI are not sufficient to explain the observed structure and the peak mass of the BW term shifted downward, from 1859 MeV to
MeV while the range of allowed widths increased to
MeV.
Soon after the BESII publication appeared, Yan and Ding proposed a Skyrme-like model for proton-antiproton interactions in which the BESII
mass-threshold enhancement is an
S-wave
bound state with binding energy around 20 MeV [
21]. Since the
p and the
in such a system would annihilate whenever they came within close proximity of each other, such a state would have a finite width, creating a situation illustrated by the cartoon in panel (b) of Fig. 3: for masses above the
threshold, the state would decay essentially 100% of the time by “falling apart” into a
p and
; for masses below
, the decay would proceed via
annihilation into mesons. Since a preferred channel for low-energy
S-wave
annihlation is
, Yan and Ding advocated a search for
decays of this same state in radiative
decays. A subsequent BESII study of
decays found a distinct peak at
MeV and width
MeV as shown in panel (c) of Fig. 3 [
22], in good agreement with the mass and width results from the FSI-corrected fit to the
mass spectrum.
The
mass-threshold enhancement was confirmed at the same mass with much higher statistics by BESIII [
23]. The signal, shown in panel (d) of Fig. 3, has a significance that is
†. The large BESIII event sample permitted the application of a partial wave analysis (PWA) that established the
quantum number assignment, in agreement with baryonium expectations. The
peak in
decays was also confirmed and the production-angle distribution was found to be consistent with a
assignment. However, the situation still remains unclear. The BESIII measurements find a much larger width for the
peak than that found for the
peak in the BESIII partial wave analysis:
MeV versus
MeV. Another puzzling feature is the lack of any evidence for the
threshold enhancement in any other channels, such as
[
25],
[
26] or in
B decays [
27]. BESIII is actively looking at various other radiative
decay channels for evidence for or against other signs of resonance behaviour near 1835 MeV [
28].
3.2 The XYZ mesons
The XYZ mesons are a class of (somewhat haphazardly named) hadrons that are seen to decay to final states that contain a heavy quark and a heavy antiquark, i.e., Q and , where Q is either a c or b quark, but cannot be easily accommodated in an unassigned level. Since the c and b quarks are heavy, their production from the vacuum in the fragmentation process is heavily suppressed and, thus, any heavy quarks seen among the decay products of a hadron must have been present among its original constituents. In addition, the heavy quarks in conventional “quarkonium” mesons are slow and can be described reasonably well by non-relativistic quantum mechanics. Indeed it was the success of non-relativistic charmonium potential-model descriptions of the ψ and states in the mid-1970’s that led to the general acceptance of the reality of quarks and the validity of the quark model. Quarkonium models specify the allowed states of a system; if a meson decays to a final state containing a Q and a but does not match the expected properties of any of the unfilled levels in the associated spectrum, it is necessarily exotic.
3.2.1 Charmoniumlike mesons
Charmoniumlike
XYZ mesons were first observed starting in 2003 and continue to be found at a rate of about one or more new ones every year. There is a huge theoretical and experimental literature on this subject that will not be repeated here [
29,
30]. Instead I restrict myself to a few remark on subsets of the measurements and outstanding issues.
Figure 4 shows the current state of the charmonium and charmoniumlike meson spectrum below 4500 MeV. Here the yellow boxes indicate established charmonium states. All of the (narrow) states below the open-charm threshold have been established and found to have properties that are well described by the charmonium model. In addition, all of the states above the open-charm threshold have also been identified. The gray boxes show the remaining predicted, but still unassigned, charmonium states. The red boxes show electrically neutral X and Y mesons and the purple boxes show the charged Z mesons, aligned according to my best guess at their quantum numbers. In the following, I briefly comment on each of the XYZ entries in (roughly) clockwise order, starting at the left with the and .
X(3940) and X(4160) The
was first seen by Belle [
31] as a peak in the distribution of masses (
MX) recoiling against a
in inclusive
annihilations at
GeV shown in panel (a) of Fig. 5. In this figure, there are four distinct peaks: the lower three are due to the exclusive processes
,
and
. The fourth peak near 3940 MeV cannot be associated with any known or expected charmonium state and has been named the
. The curve shows results of a fit that includes the three known charmonium states plus a fourth state; the fit returned a mass
MeV and an upper limit on the total width of
MeV.
Belle also did a study of exclusive
decays in the same energy region. Here, to compensate for the low detetction efficiency for
D and
mesons, a partial reconstruction technique was used that required the reconstruction of the
and only one
D or
meson
†, and determined the presence of the
or
from energy momentum conservation [
32]. With this technique, the
was seen in the
invariant mass distribution in
annihilations [
32], as can be seen in the lower panel of Fig. 5(b) and the upper panel in Fig. 5(c). Here the fits shown in the plots return a mass and width of
MeV and
MeV. The
study uncovered another, higher mass state decaying to
as can be seen in the lower panel of Fig. 5(c). The fitted mass and width of this state, which is called the
, is
MeV and
MeV [
32].
Neither the
nor the
show up in the
invariant mass distribution for exclusive
at the same energies. Instead, the
spectrum exhibits a broad excess of events over an equally broad background as shown in the upper panel of Fig. 5(b). A fit to a resonant shape, shown as a curve in the figure, returns a signal of marginal significance (
) with a peak mass of
MeV and a width
MeV. Since the fitted values are unstable under variations of the background shape parameterization and the bin size, Belle makes no claims about this distribution other than that it is inconsistent with phase space or pure background. On the other hand, Chao [
33] suggests that this may be the
, which is discussed below in conjunction with the
.
The absence of signals for any of the known spin non-zero charmonium states in the inclusive spectrum of Fig. 5(a) provides circumstantial evidence for
assignments for the
and
. The
decay mode then ensures that its
values are
. The absence of any signal for
decay supports a
assignment for this state as well. In both cases, the measured masses are far below expectations for the only available
charmonium levels: the
and
. Since there are no strong reasons to doubt the generally accepted identifications of the
peak seen in the inclusive cross section for
hadrons as the
and the
peak as the
[
34,
35], these assignments would imply hyperfine
mass splittings that increase from the measured value of
MeV for
[
13], to
MeV for
and
MeV for
[
33]. This pattern conflicts with expectations from potential models, where hyperfine splittings are proportional to the square of the radial wavefunction at
and decrease with increasing
n [
36].
Y(4260), Y(4360) and Y(4660): BaBar discovered the
as a peak near 4260 MeV in the
distribution from initial-state-radiation
events [
37] shown in the upper panel of Fig. 6(a), and the
in the
system produced via
[
38], shown in the upper panel of Fig. 6(b). These states were confirmed by Belle, as shown in the lower panels of the same figures [
39,
40]. Belle found another peak, the
, at higher mass in the
distribution. There is no sign of the
in the
distributions: the expected shape for
is shown as a dashed curve in the upper panel of Fig. 6(b). Neither is there any sign of the
or
in the
distributions of Fig. 6(a).
These states have to be considered exotic because their production mechanism ensures that
and all of the
states near their masses have already been assigned. Moreover, there is no evidence for them in any exclusive [
41–
44] or the inclusive [
34,
35] charmed-meson production cross section, where there is a pronounced dip at
GeV and no striking feature near 4.36 GeV, as can be seen in BESII cross section data shown in Fig. 6(c) [
34,
35]. This implies large partial decay widths to
; for example: a specific analysis for the
finds
MeV [
45], which is huge by charmonium standards. Some authors have proposed that the
is a
-gluon hybrid state [
46,
47] while others have suggested that it is a molecule-like
bound-state [
48]. The
is discussed in more detail below.
The electrically charged Zc(3900), Zc(4020), Z1(4050), Z2(4250) and Z(4430) states: Since the
[
49,
50],
[
51,
52],
[
53],
[
53] and
[
54] are electrically charged and decay to hidden charm final states, their minimal quark structure is a
four-quark combination and, therefore, if they are mesons, they must be exotic.
The
Z(4430): The first electrically charged, charmoniumlike state to be reported was the
, which was found by Belle in 2008 in a study of
decays [
54]. An
vs.
Dalitz plot for these decays is shown in Fig. 7(a). There, the most prominent feature is a strong vertical band near
GeV
2 corresonding to
decays. A second vertical band near
GeV
2 corresponds to
. To reduce the influence of these structures, Belle studied events with
more than 100 MeV away from the
and
peak mass values (the
veto). The
invariant mass distribution in
decay events that survive this
veto, shown an open histogram in Fig. 7(b), exhibits a distinct peak near
GeV. A fit to a smooth background plus a BW signal function to describe the peak returns a mass and width of
MeV and
MeV; the statistical significance of the peak is
. However, a 2009 analysis by BaBar failed to confirm the Belle signal [
55]. Figure 7(c), taken from the BaBar paper, presents a direct comparison between the Belle and BaBar results with the same
veto requirements. A BW fit by BaBar that used Belle’s
mass and width values found a signal with a statistical significance of only
.
One concern about the
was that neither the BaBar nor the 2008 Belle analysis considered the possibility of interference between
and
amplitudes. Because of this, Belle did two subsequent analyses that explicitly accounted for the possibility of such interference [
56,
57]. The decay chain
;
can be completely described by four variables
†, which can be taken as
,
, the
helicity angle
θ and the angle between the
and
planes in the
B rest frame
φ. Belle’s first amplitude analysis integrated over
θ and
φ and only considered the
and
masses [
56]; the second analysis used all four variables [
57]. Both amplitude analyses found strong signals (
in both cases) for a resonance in the
channel, with a somewhat higher peak mass and much broader width than that reported in the 2008 Belle paper; the four-dimensional analysis, based on
signal events, reported
MeV and
MeV. These amplitude analyses show strong interference between the
and
channels, as is evident in Fig. 8(a) where the
distribution for the data surviving the
veto (points with errors) are shown with projections of the four-dimensional fit results superimposed
†. The fit that includes the
resonance is shown as a solid histogram and the best fit with no
resonance is shown as a dashed curve. For masses below the
resonance peak, the intereference is constructive and there is a clear positive enhancement; for masses above the peak the interference is destructive and produces a depletion of events. The original Belle result, which was based on a one-dimensional fit to the
distribution, only fit the low-mass positive lobe and this resulted in a lower mass and a narrower width. The four-dimensional analysis strongly favored the
quantum number assignment for the
.
In 2014, the LHCb experiment repeated the Belle four-dimensional analysis with a sample of more than 25 K
decays [
58] and confirmed the Belle signal with a significance greater than
. A comparison of their
data distribution with projections of their fit results superimposed is shown in Fig. 8(b), where strong interference effects, similar in character to those reported by Belle, are apparent. The LHCb results for the mass, width and
JP values,
MeV,
MeV and
, agree well with the Belle four-dimensional fit results but with smaller errors. With their ten-fold larger event sample, the LHCb group was able to relax the assumption of a BW form for the
amplitude and directly measure the real and imaginary parts of the amplitude as a function of mass. The results are shown as data points in Fig. 8(c). There the phase motion near the resonance peak agrees well with expectations for a BW amplitude as indicated by the nearly circular red curve superimposed on the plot. This rapid phase motion is a clear signature for a BW-like resonance behavior but, by itself, does not necessarily rule out explanations of the
structure as being due to a rescattering process [
59,
60].
The Belle and LHCb product branching fractions for production in decays are
the weighted average is
There is no experimental value for
, although we expect that it cannot be larger than
, for which BaBar has set a 90% CL upper limit of
[
61]. This seems reasonable because the leading quark-line diagram for
is a “factorizable” weak interaction process that is favored in
meson decays, while the leading-order diagram for producing a charged charmoniumlike state is “non-factorizable”, and expected to be suppressed in
meson decays [
63–
65]. Thus, it is probably safe to expect that
. In that case, the Belle-LHCb average given above give a
lower limit
that, when coupled with our average of the Belle and LHCb measurements of the
total width (
MeV), gives a lower limit on the partial width
MeV, which is very large by charmonium standards: for example, the largest measured hadronic transition width between well established charmonium states is
keV [
13]
†.
Another striking feature of the
is that its
partial decay width is much stronger than that for
. In 2009, BaBar reported
, an order of magnitude lower than the Belle-LHCb average value for
. Belle recently reported the first observation of the
decay mode in
decays with a product branching fraction of
[
62], which is near the BaBar upper limit and about an order of magnitude smaller than the corresponding rate for
production in the
channel.
The Z1(4050)
and Z2(4250): The
and
are resonances in the
channel that were found by Belle in a two-dimensional (
vs.
) amplitude analysis of
decays [
53]. Figure 9(a) shows the
distribution for events with
(upper) and
GeV (lower) with the best fit for a model with all known
resonances but no resonance in the
channel. Figure 9(b) shows the same data with a fit that includes one resonance in the
channel. Here the fit quality improves substantially; the statistical significance of the
term is more than
. The use of different parameterizations of the
scalar amplitude or the inclusion of an additional
or
resonance with a mass and width left as free parameters do not reduce the significance of the
term to below
.
It is evident in Fig. 9(b) that the inclusion of a single amplitude does not reproduce the details of the data. Because of this, Belle repeated the fit with two BW amplitudes in the channel. This model fits the data well, as can be seen in Fig. 9(c); the significance of the two Z model relative to the single Z model is . The masses and widths of the two Zs are
A BaBar study of
decays did not confirm the Belle claim of resonances in the
channel [
66]. Figure 10(a) shows BaBar’s background-subtracted
distribution for events with
. The dashed curve shows the projection of the BaBar fit with no
resonances in the
channel. This fit obviously overshoots the data in the
GeV region and undershoots the data near
GeV. The red curve shows the result when two
resonance terms with the Belle mass and width values are added; this improves the agreement with the data, but not markedly. The BaBar report claims that, overall, the
distributions in the data [including those in the regions of
that are not shown in Fig. 10(a)] are adequately described by resonances in the
sector only, and the inclusion of
resonances does not signficantly improve the fit quality. Based on this they set 90% CL product branching fraction upper limits of [
66]
which are below, but not in strong contradiction with, the Belle measurements [
53]
For comparison, Fig. 10(b), from Ref. [
53], shows the Belle data with the same
requirement and the results of a fit with no
resonances (dashed blue curve) and the fit with the two
resonances described above. The Belle and BaBar data, and the results of their no
fits are qualitatively very similar, while the results of the fits that include
terms are quite different. This is because in Belle fits, the
amplitudes are coherent with those for the
channel and, as in the case of the
analysis, interference between the
and
amplitudes is very strong, in this case resulting in strong destructive interference below and above the peak region. A comparison of Figs. 10(a) and (b) clearly shows that by neglecting the possibility of interference between the
and
amplitudes, the BaBar analysis underestimates the strength of possible
and
signals in their data.
The Zc(3900) : The discovery and early measurements of the
were based on measurements of the initial state radiation process,
at
GeV. This reaction requires that either the incident
or
radiates a
GeV photon prior to annihilating, which results in a strong reduction in event rate. However, since the PEPII and KEKB
B-factories ran with such high luminosity (
), the measurements were feasible. A more efficient way to produce
mesons would be to run a high luminosity
collider as a “
factory,” i.e., at a cm energy of 4260 MeV, corresponding to the peak mass of the
. This was done at the upgraded, two-ring Beijing electon-positron collider (BEPCII) [
67] in 2013, and large numbers of
decays were detected in the new BESIII spectrometer [
68].
The first channel to be studied with these data was
, where a distinct peak, called the
, was seen near
MeV in the distribution of the larger of the two
invariant mass combinations in each event (
), as can be seen in Fig. 11(a) [
49]. A fit using a mass-independent-width BW function to represent the
mass peak yielded a mass and width of
MeV and
MeV, which is
MeV above the
(or
) threshold. The
was observed by Belle in isr data at about the same time [
50].
A subsequent BESIII study of the
systems produced in
final states in the same data sample found very strong near-threshold peaks in both the
and
invariant mass distributions [
69], as shown in Figs. 11(b) and (c), respectively. The curves in the two figures show the results of fits to the data with threshold-modified BW line shapes to represent the peaks. The average values of the mass and widths from these fits are used to determine the resonance pole position (
) with real and imaginary values of
MeV and
MeV.
Since the pole mass position is
lower than the
mass reported in Ref. [
49], BESIII cautiously named this
state the
. In the mass determinations of both the
and
, effects of possible interference with a coherent component of the background are ignored, which can bias the measurements by amounts comparable to the resonance widths, and this might account for the different mass values. In any case, we consider it highly likely that the
is the
in a different decay channel. If this is the case, the partial width for
decays is
times larger than that for
, which is small compared to open-charm vs. hidden-charm decay-width ratios for established charmonium states above the open-charm threshold, such as the
and
, where corresponding ratios are measured to be more than an order-of-magnitude larger [
13].
Since the signals are so strong, the JP quantum numbers can be determined from the dependence of its production on , the bachelor pion production angle relative to the beam direction in the cm system. For , should go as ; for it should follow and for it should be flat ( is forbidden by Parity). Figure 11d shows the efficiency-corrected signal yield as a function of , together with expectations for (dashed red), (dotted blue) and . The assignment is clearly preferred and the and assignments are ruled out with high confidence.
The Zc(4020): With data accumulated at the peaks of the
,
and nearby energies, BESIII made a study of
final states. Exclusive
decays were detected via the
transition, where the
was reconstructed in 16 exclusive hadronic decay modes. With these data, BESIII observed a distinct peak near 4020 MeV in the
distribution that is shown in Fig. 12(a). A fit to this peak, which the BESIII group called the
, with a signal BW function (assuming
) plus a smooth background, returns a
significance signal with a fitted mass of
MeV, about 5 MeV above
, and a width of
MeV [
51]. The product
is measured to be
pb at
MeV, where the second error reflects the uncertainty of
).
The inset in Fig. 12(a) shows the result of including a
term in the fit. In this case, a marginal
signal for
is seen to the left of the
peak. This translates into an upper limit on the product
of 11 pb. Since the product
is measured to be
pb [
49], this limit implies that the
decay channel is suppressed relative to that for
by at least a factor of five.
BESIII recently reported observation of the neutral member of the
isospin triplet [
70]. The
distribution for
events in the same data set used for the
, shown in Fig. 12(b), looks qualitatively like the
distribution with a distinct peak near
MeV. A fit to the data that includes a BW term with a width fixed at the value measured for the
and floating mass returns a mass of
MeV; this and the signal yield are in good agreement with expectations based on isospin symmetry.
A study of
events in the
GeV data sample using a partial reconstruction technique that only required the detection of the bachelor
, the
from the
decay and one
, either from the
or the
decay, to isolate the process and measure the
invariant mass [
52]. The signal for real
final states is the distinct peak near 2.15 MeV in the
recoil mass spectrum shown on Fig. 12(c). The measured
invariant mass distribution for events in the 2.15 MeV peak, shown as data points in Fig. 12(d), shows a strong near-threshold peaking behavior with a shape that cannot be described by a phase-space-like distribution, shown as a dash-dot blue curve, or by combinatoric background, which is determined from wrong-sign (WS) events in the data (i.e., events where the bachelor pion and charged
D meson have the same sign) that are shown as the shaded histogram. The solid black curve shows the results of a fit to the data points that includes an efficiency weighted
S-wave BW function, the WS background shape scaled to measured non-
background level under the signal peak in Fig. 12(d), and a phase-space term. The fit returns a
signal with mass and width
MeV and
MeV, values that are close to those measured for the
channel. Although BESIII cautiously calls this
signal the
, in the following we assume that this is another decay mode of the
.
From the numbers provided in Ref. [
52], we determine
pb. This implies that the partial width for
is larger than that for
, but only by a factor of
, not by the large factors that are characteristic of open charm decays of conventional charmonium.
There is no sign of in either Figs. 11(b) or (c), where and event signals in the and distributions, respectively, correspond to the product pb, about the same as the corresponding product for the signal mentioned in the previous paragraph. This absence of any evident signals for in Figs. 11(b) and (c) suggests that the partial width is considerably smaller than that for , which may have some relation to the ’s proximity to the threshold. However, until BESIII provides a limit on a signal at MeV, this effect cannot be quantified.
X(3915) The
is an
mass peak with
MeV with
MeV [
13] seen in
decays by both Belle [
71] and BaBar [
72,
73] [see Figs. 13(a) and (b)] and in the two-photon process
also by Belle [
74] and BaBar [
75] [Fig. 13(c)]
†. BaBar measured its
quantum numbers to be
. The PDG currently assigns this as the
charmonium level (i.e., the
), an assignment that has a number of problems [
77]:
i) The
member of the
multiplet, the
(
), was seen by Belle [
78] and confirmed by BaBar [
79] as a distinct peak in the
invariant mass distribution near 3930 MeV in
events. The mass, production rate and production angle dependence agree quite well with expectations for the
[see Figs. 14(a) and (b)], and there are no known reasons to doubt this assignment. The weighted averages of the Belle and BaBar mass and width measurements are
MeV and
MeV [
13]. With the
well established with a reliably known mass, the
assignment implies a
fine splitting of only
MeV, which is very small in comparison with the corresponding
splitting of
MeV [
13] and theoretical predictions for
that range from 69 MeV [
36] to 80 MeV [
76].
ii) There is no sign of
decay, which is expected to be a favored decay mode. Belle [
80] and BaBar [
81] have studied the process
and both groups see prominent signals for
, but no hint of a
mass peak near 3915 MeV [see Fig. 14(c)]. Since neither group reported a
limit, I formed my own conservative estimate of an upper bound by scaling the total number of Belle events in the two mass bins surrounding 3915 MeV in the upper panel of Fig. 14(c) to the
signal while assuming constant acceptance. This gives
, which strongly contradicts the theoretical expectation that the
decay channel should dominant [
76].
iii) Since branching fractions cannot exceed unity, the measured quantity
keV [
78,
79], translates to a
90% CL lower limit
keV. Using the assumption
[
13], which is valid for pure charmonium states, I infer a lower limit
keV that, when taken with the measured value
keV [
82], gives an upper limit
if
. The PDG value for the
total width of
MeV and the above-mentioned limit
imply an upper limit
MeV for the
assignment. This upper limit is below the range of theoretical predictions that range from 7 MeV [
83] to 187 MeV [
84].
iv) The average of the Belle and BaBar measurements for
production in
B meson decay is
. If I make the (reasonable?) assumption that
[
13], I find the
lower limit
, in strong contradiction to the 5.6%
upper limit established in the previous paragraph.
Some authors have identified another candidate for the
. Guo and Meissner [
77] propose that the broad background under the
peak in the
distribution in
events as seen in Fig. 14(a) is due to
. Their fits to BaBar and Belle data, shown as dashed curves Fig. 14(d), yield a “
” mass and width of
MeV and
MeV, which is in general agreement with charmonium model expectations. This fit is almost certainly biased because the authors do not consider contributions to the
signal from
decays where the
π or
γ from
decay is missed. Nevertheless, their suggestion that a broad and light
might be responsible for at least part of the measured
“background” should be carefully considered. With enough data, contributions from
and
can be sorted out from the relative rates for
,
and
final states and the shapes of their associated
pT distributions. This is a good candidate for a “day one” measurement for the BelleII experiment [
85].
Chao [
33] suggested that
may be the source of the broad peak in the
spectrum seen by Belle in
events [
32], as discussed above and shown in the upper panel of Fig. 5(b). The Belle group’s fit to this distribution yielded a broad signal with a peak mass at
MeV and a significance of
. This mass is closer to expectations for the
than that of the
. Belle is now investigating this reaction with about twice as much data than was used in the Ref. [
32] analysis.
Although these suggestions are not definitive, they, plus the arguments from the previous paragraph, show that the PDG’s assignment of the to the charmonium level is premature and possibly misleading.
If the
is not an ordinary
charmonium state, what is it? Molina and Oset proposed a molecule-like picture with states that are dynamically generated from vector-vector interactions. They find a
state near 3940 MeV with a 17 MeV width [
86] that is dominantly
and
. The
mass is below the threshold for decays to these final states and the authors find a strong decay to
plus a strong suppression of decays to
, consistent with what is seen experimentally. This paper also predicts other states, including some with isospin=1, but none of these can be as easily associated with any of the
XYZ peaks that are seen in experiment.
Y(4140) In 2009, the CDF group reported
evidence for a near-threshold peak in the
invariant mass distribution from
decays based on an analysis of a 2.7 fb
-1 data sample [
87]. CDF subsequently reproduced this signal with a larger, 6.0 fb
-1 data sample and with a significance that increased to more than
[
88] [see Fig. 15(a)]. The mass and width were reported as
MeV and
MeV. The CDF group’s fit, shown as a red curve in Fig. 15(a), includes a second structure with mass and width
MeV and
MeV, with a significance estimated to be
.
The existence of the
has been somewhat controversial because it was not seen in
decays by LHCb [
89], which set an upper limit on the
production rate in
B decays that is about a factor of two below the CDF group’s central value for the same quantity. Figure 15(b) shows the LHCb group’s
distribution as a histogram with expectations for the two peaks reported by CDF superimposed as blue dashed curves. While the agreement between the LHCb data and the CDF-inspired curves is pretty poor, there does seem to be excesses in the LHCb distribution in the vicinity of both of the CDF peaks. The excess near threshold is pretty broad and suggests that if there is a state decaying to
in that mass region, it may have a broader width than the CDF group’s measured
value.
This year, the CMS group published the
distribution in
shown in Fig. 15(c), where there are distinct signals near the positions of both of the CDF peaks [
90]. Their fit to the data, shown as red curves in the figure, give a
mass an width of
MeV and
MeV, which agree within errors with the CDF measurements. The estimated significance of the
peak is greater than
. Note that the central value of the CMS width measurement, while consistent with the CDF value, is higher by nearly a factor of two, and has a large positive-side error.
The fitted mass of the second peak, MeV, is about higher than the CDF value, while the fitted width, MeV, is in good agreement, albeit with large errors. The CMS paper also provides a plot that compares the invariant mass distribution for decays with phase-space expectations [see Fig. 16(a)], where there is some indication of structure around GeV. The CMS group warns that if such a structure actually exists, it could create a reflection peak in the distribution near GeV that could distort the measured parameters of the second mass peak. As was the case for the parameter extraction from decays, a better understanding of this second peak probably needs an experiment with a data sample that is large enough to support an amplitude analysis.
The BaBar group recently reported on a search for the
in
decays [
91]. Figure 16(b) shows their efficiency-corrected
distribution together with results of a fit that includes two resonances with the CDF group’s mass and width values. Although there are signs of signals both for the
and the
, the statistical significance in each case is less that
after systematic errors are considered.
The
shows up just above the
mass threshold and e.g., the
mass is just above the
mass threshold. This led to some speculation that the two states may be related: e.g., the
may be a
molecule and the
is its hidden charm counterpart
molecule [
92,
93]. In this case the
would have the same
quantum numbers as the
, namely
, and this implies that the
could be accessible in
fusion reactions. The
distribution from a Belle study of
near the
threshold is shown in Fig. 16(c), where there is no sign of the
but
evidence for a peak at
MeV with width
MeV [
94]. The mass value is
above that of the second peak seen by CDF and CMS in
decays and, so, if both observations are from real meson states, they are not likely to be from the same source. The absence of any events in the
region translates into the upper limit
eV for
, which is smaller, but not much smaller, than the measured value (
eV) of the corresponding quantity for the
signal discussed above. However, it is much lower than theoretical expectations for a
molecule:
eV for
or
eV for
[
94].
The LHCb results discussed here were based on an analysis of a fb-1 data sample, which is only about one tenth of their current total. Hopefully new results based on all of the available data will soon be available.
X(3872) The
was first seen in 2003 as a peak in the
invariant mass distribution in
decays [
95] as shown in Fig. 17(a). It is well established and has been seen and studied by a number of experiments [
96–
100]. The PDG average mass value,
MeV, is indistinguishable from that for the
MeV threshold [
13]; a recent result from LHCb is
MeV [
101]. It is also narrow, Belle has reported a 95% C.L. upper limit on its total width of
MeV [
102].
While LHCb and CDF have conclusively established the
quantum numbers as
[
103,
104], its isospin is less well understood. Both CDF [
105] and Belle [
102] have shown that the
system in
decays originates from
decay, which is consistent with the
assignment reported by LHCb. The decay
implies that either the
has isospin
or 0: if it has isospin zero, its decay to
is isospin violating; if it has
, it should have charged partners. Searches for narrow, charged partner states decaying to
by BaBar [
106] and Belle [
102] set branching ratio limits well below expectations for isospin conservation. However, these limits should probably be viewed with some caution because if charged partners of the neutral
exist and have masses that are even just a few MeV higher, their decays to
final states would probably be significantly stronger than those for their neutral partner; these higher rates could suppress the
decay branching fraction below isospin expectations and produce a significantly broader width. However, other evidence against
comes from observations by Belle [
107] and BaBar [
72,
73] of
decays with a branching fraction that is nearly equal to that for
decays; the PDG average is
[
13]. Since
MeV, and
MeV below
, the decay
can only proceed via the low energy tail of the
ω peak and is, therefore, kinematically suppressed. I estimate a suppression factor of
†. The fact that this strongly suppressed
final state is accessed at nearly the same rate as the
,
final state – which is also kinematically suppressed, but only by a factor that I estimate to be
– suggests that the
is (mostly) an isospin singlet and that the
decay mode violates isospin symmetry.
The
has also been seen to decay to
[
108–
110]. Since its
, the
couples to a
pair in an
S- and/or
D-wave. The
system is right at threshold and, so, the
S-wave should be dominant, in which case some very general universal theorems apply [
111–
113]. One consequence of these theorems is that, independently of its dynamical origin, the
should exist for some fraction of the time as a
molecule-like state (either bound or virtual) with size determined by its scattering length
, which in turn depends upon the mass difference
(
MeV) as
, where
μ is the
reduced mass. This, taken with the experimentally allowed range of
values, suggests that for the
configuration, the mean
D0-
separation is huge, of order
fm, and much larger than the extent of the
configuration, for which
MeV and
fm. The very different properties of the
and
configurations imply that the
isospin is not very well defined [
114].
The BESIII experiment recently reported the observation of the process
at cms energies in the region of the
peak [
115]. The
was detected via its
decay channel; a
invariant mass plot summed over the data at all of the energy points is shown in Fig. 18(a), where a
peak at the mass of the
is evident. Figure 18(b) shows the energy dependence of the
production rate where there is some indication that the observed signal is associated with the
. Assuming that
decays are the source of this signal, and using the PDG lower limit
[
13], we determine
which is substantial and suggestive of some commonality in the nature of the , and .
Various interpretations for the
have been proposed. The only viable candidate for a charmonium assignment is the
state, i.e., the
, which is the only charmonium level with the right quantum numbers and an expected mass that is anywhere near 3872 MeV. The measured mass is below the range of the theoretically expected values discussed in Ref. [
76], where a computation using a non-relativistic potential model (NR) gives 3925 MeV while that based on a relativized potential model (GI) [
36] gives 3953 MeV. Potential model calculations of masses of charmonium states that are above the open-charm thresholds at
and
do not explicitly take into account effects of virtual, but on-mass-shell
and
states and, so, it is not too surprising that both models miss the mass of the well measured multiplet partner
by a substantial amount: NR gives 3972 MeV and GI gives 3979 MeV, while the PDG average of measured values is
MeV lower at
MeV. In the absence of any computation that incorporates the measured
as input, I estimate a range of expected
mass values pegged to the
measurement to be
MeV by subtracting the NR and GI calculated
splittings, namely
MeV and
MeV, from the
measurement. The
mass is below this range, but not by much. The biggest problem with the
charmonium assignment for the
is the strength of the
discovery decay channel, which, for charmonium, is isospin- and OZI-violating and expected to be strongly suppressed.
The close match between the
mass and
– they are equal to within 1 part in
– suggests that there is some close relation between the
and the
system. In 1994, Törnqvist proposed the existence of deuteron-like
isoscalar states bound by pion exchange with
and
and mass near 3870 MeV that he called “deusons” [
116]. In August 2003, shortly after the
discovery was announced by Belle at the Fermilab Lepton-Photon 2003 meeting, he identified it with the
deuson predicted in his 1994 paper. Because of its proximity to the
threshold, the deuson wave function is predominantly
, and not a very pure isospin eigenstate as discussed above [
114], and this can account for the strong isospin violation. There has been a considerable number of subsequent reports that describe the
as a molecule [
118–
129], an idea that predates even Törnqvist’s 1994 paper [
130–
133]. However, the CDF group reported that only (
)% of their
signal are produced via
B meson decays; most of their observed signal is produced promptly in high energy
interactions [
134]. In addition, the D0 experiment showed that the many of the characteristics of
production in these high energy
collisions, such as the rapidity- and
pT-dependence of the inclusive production cross section, are very similar to those for the
. The LHCb [
99] and CMS [
135] experiments report similar characteristics for inclusive
production in
TeV proton-proton collisions. If the
is a large and fragile molecule with a miniscule binding energy, why would its production characteristics in high energy
and
collisions match those of the nearly point-like and tightly bound
state? This issue is discussed in detail in Ref. [
136], where the authors use the powerful software tools that successfully model particle production in high energy hadron colliders to show that the prompt production cross section for a loosely bound
molecule should be about two-orders-of-magnitude smaller than the production rates measured by CDF.
Both Belle [
138] and BaBar [
137] reported similar strengths for
decay to
final states; the average of their measured branching fractions correspond to a
partial width that is less than that for
by a factor of
. This is in good agreement with a calculation based on a molecular picture by Aceti, Molina and Oset [
139], where they find this ratio to be 0.18. In addition to
, this calculation includes
and
components in the
wave function. Interestingly, the authors find that the
/
partial width ratio is very sensitive to these extra terms: if only the
term is considered, the ratio becomes very much smaller, of order
. Since many calculations based on a molecule picture ignore the
and (especially) the
terms, their reliability may be questionable.
Swanson pointed out that the relative partial widths for the
and
decay channels would be a powerful diagnostic for the
[
140]. For a pure
charmonium state, he estimates that this ratio would be in the range 0.7–6.8, while for pure
molecular state the expectations are distinctly smaller, at
. Until recently, the situation with
was not very clear. BaBar reported
evidence for this mode at a rate that is
times that for
[
137]; Belle reported no signal and a 90% CL upper limit on this ratio of 2.1 [
138]. This year LHCb study of this mode measured a
signal for
, and a ratio relative to an
signal in the same data of
[
141], much higher than expectations for a pure
molecular state.
Maiani and collaborators advocate a QCD-type tetraquark structure (i.e., a
diquark and a
diantiquark, where
or
u) for the
[
142]. In their first paper on the subject, they predicted that the
would be one of two neutral states that differ in mass by
MeV, a value that is related to the
u- and
d-quark mass difference; one of the states was predicted to be produced in
and the other in
decays. They also predicted the existence of charged partner states,
, nearby in mass. BaBar [
106] and Belle [
102] studied these possibilities and found no evidence for different
mass differences in
and
B0 decays and put limits on
that are well below isospin-based predictions. However, the recent discovery of the
triplet has supplied the “missing” particles, albeit with different
G-parity and at somewhat higher masses. This revived interest in QCD-tetraquark ideas [
143]. Among other things, this model has a natural explanation for the
[
144] and, since QCD-tetraquarks are tightly bound, compact objects, their prompt production in high hadron collisons with properties can be expected to be similar to that for the
. On the other hand, Ref. [
143] proposed a second
Zc state at about 100 MeV below the
mass and contrasted this prediction with a molecule expectation for a second
Zc existence of another
near the
threshold. The subsequent observation by BESIII [
51] of the higher mass
near the
threshold clearly favors the molecule scheme.
QCD-hybrid mesons are color-octet quark-antiquark combinations with an excited gluon degree of freedom [
145]. While there is considerable literature that identifies the
as a charmonium hybrid, i.e., a
-gluon structure [
46,
47], there have been no suggestions that this idea may apply to the
as well. This may be partly due to the fact that LQCD calculations find the lowest
charmonium hybrid mass to be near 4400 MeV and far above that of the
[
146].
Hadrocharmonium is a model in which a
pair forms a tightly bound system embedded in a light mesonic cloud that it interacts with via QCD analogs of Van der Waals forces [
130,
147]. The
core states have wave functions that are closely related to conventional Quarkonium states. This would explain, for example, the dominance of
over
decays. The proponents of this model have not made any
-specific predictions.
The defects in all of the above-mentioned pictures for the
have inspired models that incorporate combinations of the different ideas. For example, a charmonium-molecular hybrid
† model by Takizawa and Takeuchi finds a specific
wave function [
148]:
which translates into about 6%
, 69% of isoscalar
and 26% isovector
. Hadronic production is hypothesized to proceed via the
core component and this could explain why
production properties are similar to those of the
. This calculation uses a high
input mass, namely 3950 MeV, which may result in an underestimate of the
component, but does not negate the basic idea. Note that similar numerical results are found in Ref. [
113].
There are two related states that are orthogonal to the one given in Eq. (2). Reference [
148] discusses one that is mostly
and probably should be considered to be the
charmonium state. This is pushed up in mass to well above both
thresholds and becomes wide and not easily identifiable. Presumably the other state would be dominantly isovector
, and this might be the
, the neutral
member of the
isospin triplet. If so, the residual
core and isoscalar
components may result in a measureable isospin violating differences between
and
decays.
The
has a long interesting story that we cannot do justice to in this brief report and, instead, refer the readers to a recent review [
149].
3.2.2 Bottomoniumlike mesons
Figure 19 indicates the recent status of the bottomonium and bottomoniumlike mesons. Here the beige boxes indicate the well established bottomonium mesons, the green boxes show those that were recently established, and the red and purple boxes indicate anomalous states that are discussed below.
The large
signal discovered in the charmonium mass region by BaBar motivated a Belle search for similar behavior in the bottomonium system [
150]. This uncovered anomalously large
production rates that peak around
GeV as shown in the upper panel of Fig. 20(a) [
151]. This peak energy is about
higher than that of the peak in the
cross section at
GeV that is usually associated with the conventional
bottomonium meson (and shown in the lower panel of Fig. 20(b). If the peak in the
cross section is attributed to
decays, it implies
(
) partial widths that are hundreds of times larger than theoretical predictions [
152], and the corresponding measured rates for the
[
13]. This suggests the presence of a new, non-
b-quark-sector equivalent of the
with mass around
GeV [
153] and referred to in the following as the
.
The large cross sections for () near the motivated Belle to take a large sample of data at this energy in order to investigate the source of this anomaly. By the end of Belle operations, a 121.4 fb-1 data sample had been accumulated near the peak of the ( GeV) and data taken in energy scans around the peak accounted for an additional sample of 12 fb-1. One of the first studies done with this data sample was an investigation of the inclusive missing-mass spectrum recoiling from pairs.
The upper right panel of Fig. 20 shows the distribution of masses recoiling against all of the
pairs in events collected near the peak of the
resonance [
154]. The combinatoric background is huge – there are typically
entries in each 1 MeV bin – and the statistical errors are tiny (
). The data were fit piece-wise with sixth-order polynomials, and the residuals from the fits are shown in the lower panel of Fig. 20(b), where, in addition to peaks at the
,
,
masses and some expected reflections, there are unambiguous signals for the
and
, the
and
bottomonium states. This was the first observation of these two elusive levels [
154]. One puzzle is that the
, (
) final states are produced at rates that are nearly the same as those for
(
), even though the
transition requires a heavy-quark spin flip that should result in a strong suppression. This motivated a more detailed investigation of these channels.
Figure 21(a) shows the
yields versus the maximum
invariant mass for
(upper) and
(lower), where it can be seen that all of the
events are concentrated in two
peaks near
MeV and and
MeV [
155]. Studies of fully reconstructed
, (
events in the same data sample found peaks at the same masses in the
distributions for all three
states; these are shown in the three center panels of Fig. 21. Here the fractions of
events in the two peaks are substantial –
for the
,
for the
and
for the
– but, unlike the case for the
channels, they do not account for all of the
event yield [
156]. Fitted values of the peak masses and widths in all five channels are consistent with each other; the weighted average mass and width values are
A study of
,
found a
signal for the neutral
isospin partner state with a mass
MeV and a production rate that is consistent with isospin-based expectations [
157].
The lower mass state is just
MeV above the
mass threshold and the higher mass state is only
MeV above
. Dalitz-plot analyses of the
final states establish
quantum number assignments for both states [
158,
159]. The close proximity of the
and
thresholds and the
quantum number assignment is suggestive of virtual
S-wave molecule-like states.
The
molecule picture is supported by a Belle study of
final states in the same data sample [
160], where
and
invariant mass peaks are seen at the
and
mass values, respectively, as shown in the right panels of Fig. 21. From these data, preliminary values of the branching fractions
and
are inferred. The
“fall apart” modes are stronger than the sum total of the
and
modes, but only by factors of
for the
and
for the
. The measured branching fraction for
is consistent with zero. This pattern, where
decays dominate for the
and
decays are dominant for the
are consistent with expectations for molecule-like structures.
3.3 Comments
Table 1 provides a tabulation of recently discovered mesons (and candidate mesons), together with observed production & decay channels, averages of mass and width measurements and the values when they are known. For simplicity, I assume the and are the same state and average the measured mass and width values, the and measurements are treated in the same way.
3.3.1 Molecules?
The recent BESIII findings, taken together with previous experimental results, establishes a concentration of charmoniumlike states crowding the
and
mass threshold regions and bottomoniumlike isospin triplets near the
and
thresholds, which are suggestive of molecule-like structures [
118–
129].
If we assume that the
and
are the same state, it corresponds to an isospin triplet with a pole mass that is about
15 MeV above the
threshold with
and a significant coupling to
. This is consistent with a virtual
S-wave
molecule of the form
. The
also has
and couples to
with mass right at the
threshold and seems to be an isospin singlet [
102]. This suggests an
S-wave
molecule of the form
. (Note that although they both have
, the
has even
C parity, while the
member of the
triplet must have odd
C parity.)
The observations (assuming they are the same state) establish the existence of another isospin triplet just above the threshold. If this is the charmed-sector equivalent of the , it also has and could be considered as a virtual molecule for which the component must have odd C parity. This suggests that there might be an -like, even C parity isospin singlet nearby, and labeled as in the lower part of the level diagram shown in the left panel of Fig. 22.
If the
exists with a mass that is below the
threshold and a relatively narrow width, it might have a significant branching fraction to
final states. If its mass is above
and it is relatively narrow, it might be accessible in
decays. BaBar has reported large branching fractions for
(
%) and
(
%) but did not publish any invariant mass distributions [
169].
The Zc mesons have a minimal four-quark structure of (, & ). The locations of the and the near the and thresholds and the similarity of the MeV mass splitting with the MeV mass difference indicates that configurations where form a and form a are important, as is the case for molecular pictures. The BaBar group has recently identified the excitations of the D and with masses MeV and MeV [1708]. An S-wave combination would have have and a “threshold” mass around 4480 MeV, very close to the Belle-LHCb average 19 MeV.
The charged
and
states that decay to
are less easy to associate with a threshold. We do not know their
JP – we do not even know if the two states have the same
JP values – but if the
-
system is in an
S-wave,
. We do know that their neutral
partner, which has not yet been seen, has to have even
C parity. If we assume
, a
would give the right quantum numbers and a nearby mass threshold for the
, where the
D1 is a
,
resonance with mass
MeV and width
MeV. One could imagine a situation where the
is the
C odd isosinglet and the
is the
C even isotriplet
molecular states
. However, the scenario where the
is a
molecule [
48] was examined by BESIII as part of their study of
[
69]. Since the
mass is
MeV below
MeV, a prominant
component of its wave function should show up as a distinct clustering of
invariant masses near their upper kinematic limit. BESIII reports no evidence for such clustering and, thus, no indication of a
component of the
. On the other hand, there are no interesting nearby
mass thresholds for the
, especially for
.
In the
b-quark-sector, the
Zb states are isospin triplets with
near the
and
threshold and suggestive of virtual
S-wave
and
molecules. Here we might expect
C-even equivalents of the
and
(labeled as
and
in the right panel of Fig. 22), but finding them may be difficult with existing data. The CMS group searched for a
b-quark version of the
in the inclusive
invariant mass distribution produced in proton-proton collisions at
TeV, but found no evidence for peaks other than those due to
and
to
transitions [
171]. However, if, as expected, the
b-quark-sector equivalent of the
has
, zero isospin, and is near the
mass threshold, the
decay mode, for which the
would have to originate from
, would violate isospin and be suppressed relative to decays to the isospin-conserving
final state. This is not the case for the
where the isospin-allowed
decay mode is kinematically suppressed: i.e.,
MeV, which is about one
ω natural width below its peak mass
MeV. In the
b-quark-sector,
MeV, which is well above
. Thus,
final states are probably more relevant than
for searches for
counterparts of the
and
. This would require studies of decay final states that contain a
, which may be difficult to do with existing LHC experiments, but could be done at BelleII [
85].
3.3.2 Tetraquarks?
Maiani and collaborators note that the
MeV mass difference is the same as
MeV, with not such a large error. This, together with the preference for the
to decay to
rather than
, suggests that in the
, configurations where the
c and
form a
are important. This is in line with QCD tetraquark expectations as discussed in Ref. [
144].
In Ref. [
143], which appeared shortly after the
discovery was announced, Maiani and collaborators proposed a test between the tetraquark and molecular model: their model predicted a second charged
Zc state with a mass that is about 100 MeV lower, while the molecular picture predicted a second state at higher mass, close to the
threshold. The BESIII group’s subsequent discovery of the
confirmed the molecular picture. However, the Ref. [
143] prediction of a lower mass partner state was based on a particular model for diquark-diantiquark spin-spin interactions. Perhaps modifications that incorporate measured properties of the
can fix this. The same paper also predicted that the
decay width of the
would be 4 MeV, and small compared to that for
, which they estimated to be
MeV. Subsequently the
decays have been seen, with a decay with that is
times larger than that for
[
69], not six times smaller
†.
One attractive feature of the tetraquark feature is that it can explain the large partial width for transitions such as
,
,
, etc., in a natural way. The corresponding transitions in the charmonium system are OZI-suppressed, and the partial widths are relatively small
keV. In molecular models, although OZI-suppression can be evaded, the
Q and
reside in different constituent mesons with small spatial overlap. In addition they have uncorrelated colors and spins. In contrast, tetraquarks are compact. The the
Q and
necessarily have a large overlap and tightly correlated color and spin and the presence of the additional light quarks eliminates OZI suppression. A tetraquark interpretation of the charged bottomoniumlike
and
states is advocated by Ali and collaborators [
172,
173].
3.3.3 QCD-hybrids?
Since
-gluon hybrid mesons cannot account for any of the charged
Z states, their role in explaining the
XYZ meson puzzles described here has to be limited. As mentioned above, there has been a number of papers that identify the
Y states as charmonium hybrids. In
hybrids, the
Q and
are in a relative
P-wave, which suppresses their
partial widths. The experimental 90% CL upper limit
eV [
45] is smaller than corresponding width for the nearby
state:
eV and about the same as that for the
state:
eV [
13]. For similar reasons, decays to
S-wave plus
P-wave open charmed mesons are supposed to be dominant. As mentioned above in the discussion related to the study of
in
decays, there is no strong evidence for subthreshold
decays in these final states [
69]. Thus, although there is a lot of theoretical enthusiasm for identifying the
Y states as
-gluon hybrids, there is not much experimental evidence to support this assignment. Perhaps theoretical analyses of the recent BESIII observations of strong decay widths for
&
[
49,
52] and the radiative transition
[
115] will clarify the situation.
3.3.4 Hadrocharmonium?
Voloshin points out that the
MeV mass difference between the
(measured in the
channel) and the
(or
) threshold is not that small [
147]. The momenta of the “constituent”
mesons in the
Zc restframe would be substantial,
MeV/c
†. Since
, the mesons would be in an
S-wave with no centrifugal barrier to hold them together, in which case, the total width
MeV
† seems too small. Also, in a
bound state, the spins of the
c and the
quarks would be uncorrelated and, thus, the
system should consist of equal amounts of
and
. This suggests that the decays
and
should occur at a similar rate, contrary to the observation reported in Ref. [
51]. As discussed above, BESIII measurements show that the
rate is suppressed relative to that for the
mode by at least a factor of five. While the hadrocharmonium model fixes the above problems, it, like the tetraquark model, predicts a lower mass partner state while BESIII found the
at higher mass. Also, the hadrocharmonium prediction for the
decay width is similar to the 4 MeV value predicted by the tetraquark model, and is in strong contradiction with experimental observatiions.
3.3.5 A unified model?
None of the models discussed above gives a compelling picture of all the observed data. Thus, in our current situation, we are forced to a attribute some of the observed states to one picture and others to a different scenario. In some cases, like the , mixtures of different models have been invoked. In all cases, these pictures accept the standard potential-model based quark model ideas and apply molecule or tetraquark, etc., ideas to those states where the conventional approach fails. Thus, molecular models work for near-threshold “exotic” states, tetraquarks for scalar mesons, -gluon hybrids for the Y states, etc. Since all these approaches have problems, the situation is not very satisfying.
An exception to these piecemeal approaches is an ambitious project by Friedmann that eschews potential model and non-relativistic quantum mechanics ideas altogether and, instead, attempts to build the spectrum of hadrons directly from QCD principles alone, using quark and diquark constituents on an equal footing [
174]. With this approach, Friedmann is able to categorize all of the established hadrons as designated by the PDG at the time of her publication, including many of the “exotic” ones listed above, in an elegant concise way. A striking feature of this scheme is that all of the states can be incorporated in her scheme without invoking any radial excitations. In conventional models, radial excitations are essential features but, with them, the model runs into lots of problems, especially with the categorization of the baryon spectrum. For example, the
,
“Roper” resonance, which defies any compelling classification in the quark model, is naturally accommodated in Freidmann’s scheme as a
state, where the two asymmetric, spin-zero diquarks (
) are in a relative
P-wave. The
, which is the quintessential radially excited meson in the quark model, is identified as a
pair in a
P-wave. Of course this is just a clasification scheme and it remains to be seen if a tetraquark picture of the
can reproduce the success of the charmonium model description of the
properties such as, for example, the ratio of
. Nevertheless, no one could accuse Friedmann of being a “prisoner of conventional thinking.”
†4 Summary
The QCD exotic states that are much preferred by theorists, such as pentaquarks, the
H-dibaryon, and meson hybrids with exotic
values continue to elude confirmation even in experiments with increasingly high levels of sensitivity. On the other hand, a candidate
bound state and a rich spectroscopy of quarkoniumlike states that do not fit into the remaining unassigned levels for
charmonium and
bottomonium states has emerged. No compelling theoretical picture has yet been found that provides a comprehensive description of what is seen, but, since at least some of these states are near
or
thresholds and couple to
S-wave combinations of these states, molecule-like configurations necessarily have to be important components of their wave functions [
112]. This has inspired a new field of “flavor chemistry” that is attracting considerable attention both by the experimental and theoretical hadron physics communities [
29,
30]. With the increased emphasis of the BESIII and LHC experiments on this subject and the imminent operation of BelleII [
85], the high luminosity reincarnation of Belle, and the future operation of the PANDA experiment at FAIR [
175], we can expect a continuous flow of interesting experimental results including, probably, many new surprises and, hopefully, new, groundbreaking insights into the long-distance behavior of QCD.