A high-capacity and long-lifespan SnO₂@K-MnO₂ cathode material for aqueous zinc-ion batteries

Abstract

Aqueous Zn//MnO₂ rechargeable zinc-ion batteries (ZIBs) possess potential applications in electrochemical energy storage due to their safety, low cost, and environmental friendliness. However, manganese dioxide as the cathode material has poor cycle stability and low conductivity. In this work, the SnO₂@K-MnO₂ (SMO) composite was prepared using the hydrothermal method followed by the treatment with SnCl₂ sensitization, and its electrochemical characteristics were examined using SMO as the cathode material for ZIBs. The reversible specific capacity reaches 298.2 mA·h·g⁻¹ at 0.5 A·g⁻¹, and an excellent capacity retention of 86% is realized after 200 cycles, together with a high discharge capacity of 105 mA·h·g⁻¹ at 10 A·g⁻¹ and a long-term cycling life of over 8000 cycles with no apparent capacity fade. This cathode exhibits a long cycle life up to 2000 cycles at 2 A·g⁻¹ with the mass loading of 5 mg·cm⁻², and the battery maintains the capacity of 80%. The reversible co-embedding mechanism of H⁺/Zn²⁺ in such a Zn//SMO battery was confirmed by XRD and SEM during the charge/discharge process. This work can enlighten and promote the development of advanced cathode materials for ZIBs.

Graphical abstract

Keywords

zinc ion battery / SnO₂@K-MnO₂ / cathode material / energy storage mechanism

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Authors’ contributions

Xiaoqing Jin: methodology, investigation, performing relevant experiments, and writing original draft; Yae Qi: experimental data checking and English checking; Yongyao Xia: supervision and writing review & editing.

Declaration of competing interests

The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

Acknowledgements

This work was partly supported by the Science and Technology Planning Project of Gansu Province (22JR5RG569) and the Faculty Research Grants Awarded by Principal’s Funds (CXTD2022008).

Data availability statement

Data will be made available on request.

Online appendix

Electronic supplementary material (ESM) can be found in the online version at https://doi.org/10.1007/s11706-024-0694-8 and https://journal.hep.com.cn/foms/EN/10.1007/s11706-024-0694-8 that includes Table S1 and Figs. S1–S9.

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