Preparation of a wearable K-PAN@CuS composite fabric with excellent photothermal/electrothermal properties

Abstract

Electrospun nanofibers with highly efficient photothermal/electrothermal performance are extremely popular because of their great potential in wearable heaters. However, the lack of necessary wearable properties such as high mechanical strength and quick response of electrospun micro/nanofibers seriously affects their practical application. In this work, a technical route combining electrospinning and surface modification technology is proposed. The 3-triethoxysilylpropylamine-polyacrylonitrile@copper sulfide (K-PAN@CuS) composite fabric was achieved by modifying the original electrospinning PAN fiber and subsequently loading CuS nanoparticles. The results show that the break strength of the K-PAN@CuS fabric was increased by 10 times compared to that of the original PAN@CuS fabric. Furthermore, the saturated temperature of the K-PAN@CuS fabric heater could reach 116 °C within 15 s at a relatively low voltage of 3 V and 120.3 °C within 10 s under an infrared therapy lamp (100 W). In addition, due to its excellent conductivity, such a unique structural design enables the fiber to be closely attached to the human skin and helps to monitor human movements. This K-PAN@CuS fabric shows great potential in wearable heaters, hyperthermia, all-weather thermal management, and in vitro physical therapy.

Graphical abstract

Keywords

electrospinning / strain sensor / electrothermal/photothermal conversion / CuS / wearable fabric

References

[1] Li S, Zhang Y, Wang Y, . Physical sensors for skin-inspired electronics.InfoMat, 2020, 2(1): 184–211

[2] Chao M, Wang Y, Ma D, . Wearable MXene nanocomposites-based strain sensor with tile-like stacked hierarchical microstructure for broad-range ultrasensitive sensing.Nano Energy, 2020, 78: 105187

[3] Agcayazi T, Chatterjee K, Bozkurt A, . Flexible interconnects for electronic textiles.Advanced Materials Technologies, 2018, 3(10): 1700277

[4] Lee S J, Kim C L . Highly flexible, stretchable, durable conductive electrode for human-body-attachable wearable sensor application.Polymer Testing, 2023, 122: 108018

[5] Wang B, Facchetti A . Mechanically flexible conductors for stretchable and wearable E-skin and E-textile devices.Advanced Materials, 2019, 31(28): 1901408

[6] Cai G, Yang M, Xu Z, . Flexible and wearable strain sensing fabrics.Chemical Engineering Journal, 2017, 325: 396–403

[7] He P, Pu H, Li X, . CNTs-coated TPU/ANF composite fiber with flexible conductive performance for joule heating, photothermal, and strain sensing.Journal of Applied Polymer Science, 2023, 140(13): e53668

[8] Wang S, Chen W, Wang L, . Multifunctional nanofiber membrane with anti-ultraviolet and thermal regulation fabricated by coaxial electrospinning.Journal of Industrial and Engineering Chemistry, 2022, 108: 449–455

[9] Wang H, Ma Y, Qu J, . Multifunctional PAN/Al–ZnO/Ag nanofibers for infrared stealth, self-cleaning, and antibacterial applications.ACS Applied Nano Materials, 2022, 5(1): 782–790

[10] Wu F, Tian Z, Hu P, . Lightweight and flexible PAN@PPy/Mxene films with outstanding electromagnetic interference shielding and joule heating performance.Nanoscale, 2022, 14(48): 18133–18142

[11] Qi H, Yang L, Tang X, . Electrospun light stimulus response-enhanced anisotropic conductive Janus membrane with up/down-conversion luminescence.Materials Chemistry Frontiers, 2022, 6(16): 2219–2232

[12] Liu Z, Tian B, Liu X, . Multifunctional nanofiber mat for high temperature flexible sensors based on electrospinning.Journal of Alloys and Compounds, 2023, 941: 168959

[13] Al-Hamry A, Lu T, Bai J, . Versatile sensing capabilities of layer-by-layer deposited polyaniline-reduced graphene oxide composite-based sensors.Sensors and Actuators B: Chemical, 2023, 390: 133988

[14] Liu B, Zhang Q, Huang Y, . Bifunctional flexible fabrics with excellent joule heating and electromagnetic interference shielding performance based on copper sulfide/glass fiber composites.Nanoscale, 2021, 13(44): 18558–18569

[15] Svyntkivska M, Makowski T, Shkyliuk I, . Electrically conductive crystalline polylactide nonwovens obtained by electrospinning and modification with multiwall carbon nanotubes.International Journal of Biological Macromolecules, 2023, 242: 124730

[16] Wang X, Li T Y, Geng W H, . Flexible wearable electronic fabrics with dual functions of efficient EMI shielding and electric heating for triboelectric nanogenerators.ACS Applied Materials & Interfaces, 2023, 15(18): 22762–22776

[17] Wang Y, Chen J, Shen Y, . Control of conductive and mechanical performances of poly(amide–imide) composite films utilizing synergistic effect of polyaniline and multi-walled carbon nanotube.Polymer Engineering and Science, 2019, 59(s2): E224–E230

[18] Xiong F, Yuan K, Aftab W, . Copper sulfide nanodisk-doped solid–solid phase change materials for full spectrum solar-thermal energy harvesting and storage.ACS Applied Materials & Interfaces, 2021, 13(1): 1377–1385

[19] Singh N . Copper(II) sulfide nanostructures and its nanohybrids: recent trends, future perspectives and current challenges.Frontiers of Materials Science, 2023, 17(3): 230632

[20] Kim M R, Hafez H A, Chai X, . Covellite CuS nanocrystals: realizing rapid microwave-assisted synthesis in air and unravelling the disappearance of their plasmon resonance after coupling with carbon nanotubes.Nanoscale, 2016, 8(26): 12946–12957

[21] Liu P, Li Y, Xu Y, . Stretchable and energy-efficient heating carbon nanotube fiber by designing a hierarchically helical structure.Small, 2018, 14(4): 1702926

[22] Jang H S, Jeon S K, Nahm S H . The manufacture of a transparent film heater by spinning multi-walled carbon nanotubes.Carbon, 2011, 49(1): 111–116

[23] Xue C H, Du M M, Guo X J, . Fabrication of superhydrophobic photothermal conversion fabric via layer-by-layer assembly of carbon nanotubes.Cellulose, 2021, 28(8): 5107–5121

[24] Zhao Y, Meng Y, Yu P, . Modified reduced graphene oxide-LDH/WPU nanohybrid coated nylon 6 fabrics for durable photothermal conversion performance.Applied Surface Science, 2023, 622: 156900

[25] Bhattacharjee S, Macintyre C R, Bahl P, . Reduced graphene oxide and nanoparticles incorporated durable electroconductive silk fabrics.Advanced Materials Interfaces, 2020, 7(20): 2000814

[26] Li H, Pan Y, Du Z . Self-reduction assisted MXene/silver composite tencel cellulose-based fabric with electrothermal conversion and NIR photothermal actuation.Cellulose, 2022, 29(15): 8427–8441

[27] Zhang Y, Su H, Li H, . Enhanced photovoltaic–pyroelectric coupled effect of BiFeO₃/Au/ZnO heterostructures.Nano Energy, 2021, 85: 105968

[28] Ly T N, Park S . Wearable strain sensor for human motion detection based on ligand-exchanged gold nanoparticles.Journal of Industrial and Engineering Chemistry, 2020, 82: 122–129

[29] Zhang Y, Ren H, Chen H, . Cotton fabrics decorated with conductive graphene nanosheet inks for flexible wearable heaters and strain sensors.ACS Applied Nano Materials, 2021, 4(9): 9709–9720

[30] Zhang H, Ji H, Chen J, . A multi-scale MXene coating method for preparing washable conductive cotton yarn and fabric.Industrial Crops and Products, 2022, 188: 115653

[31] Fan Z, Wang Y, Jeon J, . Enhancing multiwalled carbon nanotubes/poly(amide–imide) interfacial strength through grafting polar conjugated polymer on multiwalled carbon nanotubes.Surfaces and Interfaces, 2022, 32: 102130

[32] Xu Q, Wang X, Zhang Y, . Temperature-controlled wearable heater of durably conductive cotton fabric prepared by composite coatings of silver/MXene and polydimethylsiloxane.Applied Surface Science, 2023, 625: 157176

[33] Cheng D, Liu Y, Zhang Y, . Polydopamine-assisted deposition of CuS nanoparticles on cotton fabrics for photocatalytic and photothermal conversion performance.Cellulose, 2020, 27(14): 8443–8455

[34] Ren Y, Yan B, Wang P, . Construction of a rapid photothermal antibacterial silk fabric via QCS-guided in situ deposition of CuSNPs.ACS Sustainable Chemistry & Engineering, 2022, 10(6): 2192–2203

[35] Kim H J, Choi D I, Lee S, . Quick thermal response-transparent-wearable heater based on copper mesh/poly(vinyl alcohol) film.Advanced Engineering Materials, 2021, 23(10): 2100395

[36] Choi J, Byun M, Choi D . Transparent planar layer copper heaters for wearable electronics.Applied Surface Science, 2021, 559: 149895

[37] Kwon M, Kim H, Mohanty A K, . Molecular-level contact of graphene/silver nanowires through simultaneous dispersion for a highly stable wearable electrothermal heater.Advanced Materials Technologies, 2021, 6(9): 2100177

[38] Tan C, Dong Z, Li Y, . A high performance wearable strain sensor with advanced thermal management for motion monitoring.Nature Communications, 2020, 11(1): 3530

[39] Ma Z, Huang Q, Xu Q, . Permeable superelastic liquid-metal fibre mat enables biocompatible and monolithic stretchable electronics.Nature Materials, 2021, 20(6): 859–868

[40] Liu Z, Zheng Y, Jin L, . Highly breathable and stretchable strain sensors with insensitive response to pressure and bending.Advanced Functional Materials, 2021, 31(14): 2007622

[41] Gao Q, Kopera B A F, Zhu J, . Breathable and flexible polymer membranes with mechanoresponsive electric resistance.Advanced Functional Materials, 2020, 30(26): 1907555

[42] Hong H, Jung Y H, Lee J S, . Anisotropic thermal conductive composite by the guided assembly of boron nitride nanosheets for flexible and stretchable electronics.Advanced Functional Materials, 2019, 29(37): 1902575

[43] Cai Q, Scullion D, Gan W, . High thermal conductivity of high-quality monolayer boron nitride and its thermal expansion.Science Advances, 2019, 5(6): eaav0129

[44] Guo Y, Qiu H, Ruan K, . Hierarchically multifunctional polyimide composite films with strongly enhanced thermal conductivity.Nano-Micro Letters, 2022, 14(1): 26

[45] Chen H, Ginzburg V V, Yang J, . Thermal conductivity of polymer-based composites: fundamentals and applications.Progress in Polymer Science, 2016, 59: 41–85

[46] Burger N, Laachachi A, Ferriol M, . Review of thermal conductivity in composites: mechanisms, parameters and theory.Progress in Polymer Science, 2016, 61: 1–28

[47] Wen Z, Wang S, Bao Z, . Preparation and oil absorption performance of polyacrylonitrile fiber oil absorption material.Water, Air, and Soil Pollution, 2020, 231(4): 153

[48] Wang Y, Wang W, Liu B, . Preparation of durable antibacterial and electrically conductive polyacrylonitrile fibers by copper sulfide coating.Journal of Applied Polymer Science, 2017, 134(44): 45496

[49] Sun Y, Liu Y, Zheng Y, . Enhanced energy harvesting ability of ZnO/PAN hybrid piezoelectric nanogenerators.ACS Applied Materials & Interfaces, 2020, 12(49): 54936–54945

[50] Chae H G, Sreekumar T V, Uchida T, . A comparison of reinforcement efficiency of various types of carbon nanotubes in polyacrylonitrile fiber.Polymer, 2005, 46(24): 10925–10935

[51] Abdel-Mottaleb M M, Mohamed A, Karim S A, . Preparation, characterization, and mechanical properties of polyacrylonitrile (PAN)/graphene oxide (GO) nanofibers.Mechanics of Advanced Materials and Structures, 2020, 27(4): 346–351

[52] Hu S, Zheng Z, Tian Y, . Preparation and characterization of electrospun PAN–CuCl₂ composite nanofiber membranes with a special net structure for high-performance air filters.Polymers, 2022, 14(20): 4387

[53] Zhang Q, Liu D, Pan W, . Flexible stretchable electrothermally/photothermally dual-driven heaters from nano-embedded hierarchical Cu_xS-coated PET fabrics for all-weather wearable thermal management.Journal of Colloid and Interface Science, 2022, 624: 564–578

[54] Dong Y, Xu D, Yu H Y, . Highly sensitive, scrub-resistant, robust breathable wearable silk yarn sensors via interfacial multiple covalent reactions for health management.Nano Energy, 2023, 115: 108723

[55] Wang C, Li X, Gao E, . Carbonized silk fabric for ultrastretchable, highly sensitive, and wearable strain sensors.Advanced Materials, 2016, 28(31): 6640–6648

[56] He G, Wang L, Bao X, . Synergistic flame retardant weft-knitted alginate/viscose fabrics with MXene coating for multifunctional wearable heaters.Composites Part B: Engineering, 2022, 232: 109618

[57] Zhang T, Song B, Li X, . Multifunctional hydrophobic MXene-coated cotton fabrics for electro/photothermal conversion, electromagnetic interference shielding, and pressure sensing.ACS Applied Polymer Materials, 2023, 5(8): 6296–6306

[58] Yang Y, Zeng H, Zhou H, . Photothermal fabric based on in situ growth of CuO@Cu fractal dendrite fiber for personal thermal management.Advanced Engineering Materials, 2023, 25: 2300386

[59] Zhang T, Song B, Li X, . In-situ twisted spiral fiber with tree-ring like structure for joule heating, photothermal and humidity sensing.Polymer Testing, 2023, 127: 108173

[60] Li H, Wen H, Zhang Z, . Reverse thinking of the aggregation-induced emission principle: amplifying molecular motions to boost photothermal efficiency of nanofibers.Angewandte Chemie International Edition, 2020, 59(46): 20371–20375

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