Construction of mechanically robust superamphiphobic surfaces on fiber using large particles

Abstract

Superamphiphobic surfaces have attracted the attention of researchers because of their broad application prospects. Currently, superamphiphobicity is primarily achieved by minimizing the solid–liquid contact area. Over the past few decades, researchers have primarily focused on using physical deposition methods to construct superamphiphobic surfaces using fine-sized nanoparticles (< 100 nm). However, porous hollow SiO₂ particles (PH-SiO₂), which are typically large spheres, have a highly hierarchical structure and can provide lower solid–liquid contact fractions than those provided by fine-sized particles. In this study, we used PH-SiO₂ as building blocks and combined them with poly (dimethylsiloxane) to construct a mechanically robust coating on fiber by spray-coating. After chemical vapor deposition treatment, the coating exhibited excellent superamphiphobicity and could repel various liquids, covering a wide range of surface tensions (27.4–72.0 mN·m⁻¹).

Graphical abstract

Keywords

superamphiphobicity / solid–liquid contact area / SiO₂ / hierarchical structure / spray-coating / robustness

References

[1] Barthlott W, Neinhuis C . Purity of the sacred lotus, or escape from contamination in biological surfaces.Planta, 1997, 202(1): 1–8

[2] Guo Z, Liu W . Biomimic from the superhydrophobic plant leaves in nature: binary structure and unitary structure.Plant Science, 2007, 172(6): 1103–1112

[3] Feng L, Li S, Li Y, . Super-hydrophobic surfaces: from natural to artificial.Advanced Materials, 2002, 14(24): 1857–1860

[4] Chang J J, Martin A, Du C, . Heat-free biomimetic metal molding on soft substrates.Angewandte Chemie International Edition in English, 2020, 59(38): 16346–16351

[5] Cao M, Jin X, Peng Y, . Unidirectional wetting properties on multi-bioinspired magnetocontrollable slippery microcilia.Advanced Materials, 2017, 29(23): 1606869

[6] Gao X, Jiang L . Water-repellent legs of water striders.Nature, 2004, 432(7013): 36

[7] Dong S, Zhang X, Li Q, . Springtail-inspired superamphiphobic ordered nanohoodoo arrays with quasi-doubly reentrant structures.Small, 2020, 16(19): 2000779

[8] Gao X, Yan X, Yao X, . The dry-style antifogging properties of mosquito compound eyes and artificial analogues prepared by soft lithography.Advanced Materials, 2007, 19(17): 2213–2217

[9] Wong W S Y, Corrales T P, Naga A, . Microdroplet contaminants: when and why superamphiphobic surfaces are not self-cleaning.ACS Nano, 2020, 14(4): 3836–3846

[10] Yuan R, Wu S, Yu P, . Superamphiphobic and electroactive nanocomposite toward self-cleaning, antiwear, and anticorrosion coatings.ACS Applied Materials & Interfaces, 2016, 8(19): 12481–12493

[11] Chen L, Guo Z, Liu W . Biomimetic multi-functional superamphiphobic FOTS-TiO₂ particles beyond lotus leaf.ACS Applied Materials & Interfaces, 2016, 8(40): 27188–27198

[12] Sun Q, Wang D, Li Y, . Surface charge printing for programmed droplet transport.Nature Materials, 2019, 18(9): 936–941

[13] Dai H, Gao C, Sun J, . Controllable high-speed electrostatic manipulation of water droplets on a superhydrophobic surface.Advanced Materials, 2019, 31(43): 1905449

[14] Wu D, Zhang Z, Zhang Y, . High-performance unidirectional manipulation of microdroplets by horizontal vibration on femtosecond laser-induced slant microwall arrays.Advanced Materials, 2020, 32(48): 2005039

[15] Cui H R, Wang C L, Bi Y Z, . Biocompatible janus membrane with double self-healing ability for intelligent anticorrosion.Advanced Materials Interfaces, 2020, 7(7): 1901782–1901790

[16] Hegner K I, Wong W S Y, Vollmer D . Ultrafast bubble bursting by superamphiphobic coatings.Advanced Materials, 2021, 33(39): 2101855

[17] Hu B, Duan Z, Xu B, . Ultrafast self-propelled directional liquid transport on the pyramid-structured fibers with concave curved surfaces.Journal of the American Chemical Society, 2020, 142(13): 6111–6116

[18] Li Y, Huang J, Cheng J, . Enhanced movement of two-component droplets on a wedge-shaped Ag/Cu surface by a wettability gradient.ACS Applied Materials & Interfaces, 2021, 13(13): 15857–15865

[19] Cheng X Q, Jiao Y, Sun Z, . Constructing scalable superhydrophobic membranes for ultrafast water-oil separation.ACS Nano, 2021, 15(2): 3500–3508

[20] Ahn E, Kim T, Jeon Y, . A4 paper chemistry: synthesis of a versatile and chemically modifiable cellulose membrane.ACS Nano, 2020, 14(5): 6173–6180

[21] Lian Z, Xu J, Wang Z, . Nanosecond laser-induced underwater superoleophobic and underoil superhydrophobic mesh for oil/water separation.Langmuir, 2018, 34(9): 2981–2988

[22] Zhang S, Jiang G, Gao S, . Cupric phosphate nanosheets-wrapped inorganic membranes with superhydrophilic and outstanding anticrude oil-fouling property for oil/water separation.ACS Nano, 2018, 12(1): 795–803

[23] Teisala H, Butt H J . Hierarchical structures for superhydrophobic and superoleophobic surfaces.Langmuir, 2019, 35(33): 10689–10703

[24] Tuteja A, Choi W, Ma M, . Designing superoleophobic surfaces.Science, 2007, 318(5856): 1618–1622

[25] Wang D, Sun Q, Hokkanen M J, . Design of robust superhydrophobic surfaces.Nature, 2020, 582(7810): 55–59

[26] Bielinski A R, Boban M, He Y, . Rational design of hyperbranched nanowire systems for tunable superomniphobic surfaces enabled by atomic layer deposition.ACS Nano, 2017, 11(1): 478–489

[27] Wang T, Jia X, Lv C, . Multifunctional textiles based on three-dimensional hierarchically structured TiO₂ nanowires.ACS Applied Materials & Interfaces, 2021, 13(23): 27557–27566

[28] Wong W S Y, Liu G, Nasiri N, . Omnidirectional self-assembly of transparent superoleophobic nanotextures.ACS Nano, 2017, 11(1): 587–596

[29] Li X, Wang D, Tan Y, . Designing transparent micro/nano re-entrant-coordinated superamphiphobic surfaces with ultralow solid/liquid adhesion.ACS Applied Materials & Interfaces, 2019, 11(32): 29458–29465

[30] Chu D, Singh S C, Yong J, . Superamphiphobic surfaces with controllable adhesion fabricated by femtosecond laser bessel beam on PTFE.Advanced Materials Interfaces, 2019, 6(14): 1900550–1900558

[31] Ellinas K, Pujari S P, Dragatogiannis D A, . Plasma micro-nanotextured, scratch, water and hexadecane resistant, superhydrophobic, and superamphiphobic polymeric surfaces with perfluorinated monolayers.ACS Applied Materials & Interfaces, 2014, 6(9): 6510–6524

[32] Gnanappa A K, Papageorgiou D P, Gogolides E, . Hierarchical, plasma nanotextured, robust superamphiphobic polymeric surfaces structurally stabilized through a wetting-drying cycle.Plasma Processes and Polymers, 2012, 9(3): 304–315

[33] Peng S, Yang X, Tian D, . Chemically stable and mechanically durable superamphiphobic aluminum surface with a micro/nanoscale binary structure.ACS Applied Materials & Interfaces, 2014, 6(17): 15188–15197

[34] Starostin A, Valtsifer V, Strelnikov V, . Robust technique allowing the manufacture of superoleophobic (omniphobic) metallic surfaces.Advanced Engineering Materials, 2014, 16(9): 1127–1132

[35] Grynyov R, Bormashenko E, Whyman G, . Superoleophobic surfaces obtained via hierarchical metallic meshes.Langmuir, 2016, 32(17): 4134–4140

[36] Pan S, Guo R, Björnmalm M, . Coatings super-repellent to ultralow surface tension liquids.Nature Materials, 2018, 17(11): 1040–1047

[37] Li F, Wang Z, Huang S, . Flexible, durable, and unconditioned superoleophobic/superhydrophilic surfaces for controllable transport and oil‒water separation.Advanced Functional Materials, 2018, 28(20): 1706867–1706873

[38] Zhou X, Liu J, Liu W, . Fabrication of stretchable superamphiphobic surfaces with deformation-induced rearrangeable structures.Advanced Materials, 2022, 34(10): 2107901

[39] Pan S, Kota A K, Mabry J M, . Superomniphobic surfaces for effective chemical shielding.Journal of the American Chemical Society, 2013, 135(2): 578–581

[40] Schlaich C, Cuellar Camacho L, Yu L, . Surface-independent hierarchical coatings with superamphiphobic properties.ACS Applied Materials & Interfaces, 2016, 8(42): 29117–29127

[41] Wang T, Cai J, Wu Y, . Applicable superamphiphobic Ni/Cu surface with high liquid repellency enabled by the electrochemical-deposited dual-scale structure.ACS Applied Materials & Interfaces, 2019, 11(12): 11106–11111

[42] Jin H, Kettunen M, Laiho A, . Superhydrophobic and superoleophobic nanocellulose aerogel membranes as bioinspired cargo carriers on water and oil.Langmuir, 2011, 27(5): 1930–1934

[43] Liu M, Li J, Hou Y, . Inorganic adhesives for robust superwetting surfaces.ACS Nano, 2017, 11(1): 1113–1119

[44] Deng X, Mammen L, Butt H J, . Candle soot as a template for a transparent robust superamphiphobic coating.Science, 2012, 335(6064): 67–70

[45] Wang T, Lv C, Ji L, . Designing re-entrant geometry: construction of a superamphiphobic surface with large-sized particles.ACS Applied Materials & Interfaces, 2020, 12(43): 49155–49164

[46] Liu J, Ye L, Sun Y, . Elastic superhydrophobic and photocatalytic active films used as blood repellent dressing.Advanced Materials, 2020, 32(11): 1908008

[47] Gong Y, Xie L, Li H, . Sustainable and scalable production of monodisperse and highly uniform colloidal carbonaceous spheres using sodium polyacrylate as the dispersant.Chemical Communications, 2014, 50(84): 12633–12636

[48] Stöber W, Fink A, Bohn E . Controlled growth of monodisperse silica spheres in the micron size range.Journal of Colloid and Interface Science, 1968, 26(1): 62–69

[49] Ji L, Zheng H, Wei Y, . Temperature-controlled fabrication of Co‒Fe-based nanoframes for efficient oxygen evolution.Science China Materials, 2022, 65(2): 431–441

[50] Wei Y, Xu G, Wei Y, . Temperature-controlled synthesis of heterostructured Ru-Ru₂P nanoparticles embedded in carbon nanofibers for highly efficient hydrogen production.Science China Materials, 2022, 65(4): 2675–2684

[51] Kota A K, Kwon G, Tuteja A . The design and applications of superomniphobic surfaces.NPG Asia Materials, 2014, 6(7): e109

[52] Tuteja A, Choi W, Mckinley G H, . Design parameters for superhydrophobicity and superoleophobicity.MRS Bulletin, 2008, 33(8): 752–758

[53] Tuteja A, Choi W, Mabry J M, . Robust omniphobic surfaces.Proceedings of the National Academy of Sciences of the United States of America, 2008, 105(47): 18200–18205

[54] Choi W, Tuteja A, Chhatre S, . Fabrics with tunable oleophobicity.Advanced Materials, 2009, 21(21): 2190–2195

RIGHTS & PERMISSIONS

Higher Education Press