Anti-corrosive, weatherproof and self-healing polyurethane developed from hydrogenated hydroxyl-terminated polybutadiene toward surface-protective applications

Abstract

Self-healing polyurethane (PU) faces aging deterioration due to active dynamic bonds, which remain a challenging predicament for practical use. In this work, a novel strategy is developed to address this predicament by leveraging the hydrophobicity and gas barrier of hydrogenated hydroxyl-terminated polybutadiene (HHPB). The dynamic oxime-carbamate bonds derived from 2, 4-pentanedione dioxime (PDO) enable the elastomer to exhibit surface self-repairability upon applied mild heat and achieve ~99.5% mechanical self-healing efficiency. The mechanical properties remained nearly intact after 30-d exposure to thermal oxidation, xenon lamp, acids, bases, and salts. Gas permeability, positron annihilation lifetime spectroscopy (PALS), and contact angle measurements reveal the pivotal role of gas barrier, free volume, and hydrophobicity in blocking undesirable molecules and ions which effectively protects the elastomer from deterioration. HHPB-PU also exhibits excellent adhesion to steel substrate. The shear strength achieves (3.02 ± 0.42) MPa after heating at 80 °C for 4 h, and (3.06 ± 0.2) MPa after heating at 130 °C for 0.5 h. Regarding its outstanding anti-corrosive and weatherproof performances, this self-healable elastomer is a promising candidate in surface-protective applications.

Graphical abstract

Keywords

hydrogenated hydroxyl-terminated polybutadiene / hydrophobicity / anti-aging performance / self-healing / surface protection

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Disclosure of potential conflicts of interest

The authors declare that they have no conflict of interest.

Acknowledgements

This work was funded by China Postdoctoral Science Foundation (Grant No. 2019M652572) and Zhengzhou Major Collaborative Innovation Project (Zhengzhou University, Grant No.18XTZX12001).

Electronic supplementary information

Supplementary materials can be found in the online version at https://doi.org/10.1007/s11706-022-0598-4, which are associated with this work including Figs. S1–S7 and Tables S1–S3.

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