In-situ sugar-templated porous elastomer sensor with high sensitivity for wearables

Meng REN , Ying FANG , Yufan ZHANG , Heli DENG , Desuo ZHANG , Hong LIN , Yuyue CHEN , Jiaqing XIONG

Front. Mater. Sci. ›› 2022, Vol. 16 ›› Issue (2) : 220597

PDF (4929KB)
Front. Mater. Sci. ›› 2022, Vol. 16 ›› Issue (2) : 220597 DOI: 10.1007/s11706-022-0597-5
RESEARCH ARTICLE
RESEARCH ARTICLE

In-situ sugar-templated porous elastomer sensor with high sensitivity for wearables

Author information +
History +
PDF (4929KB)

Abstract

Fabrication of elastic pressure sensors with low cost, high sensitivity, and mechanical durability is important for wearables, electronic skins and soft robotics. Here, we develop high-sensitivity porous elastomeric sensors for piezoresistive and capacitive pressure detection. Specifically, a porous polydimethylsiloxane (PDMS) sponge embedded with conductive fillers of carbon nanotubes (CNTs) or reduced graphene oxide (rGO) was fabricated by an in-situ sugar template strategy. The sensor demonstrates sensitive deformation to applied pressure, exhibiting large and fast response in resistance or capacitance for detection of a wide range of pressure (0‒5 kPa). PDMS, as a high-elasticity framework, enables creation of sensors with high sensitivity, excellent stability, and durability for long-term usage. The highest sensitivities of 22.1 and 68.3 kPa−1 can be attained by devices with 5% CNTs and 4% rGO, respectively. The geometrics of the sponge sensor is tailorable using tableting technology for different applications. The sensors demonstrate finger motion detection and heart-rate monitoring in real-time, as well as a capacitive sensor array for identification of pressure and shape of placed objects, exhibiting good potential for wearables and human-machine interactions.

Graphical abstract

Keywords

porous elastomer / sugar template / wearable pressure sensor / graphene / carbon nanotube

Cite this article

Download citation ▾
Meng REN, Ying FANG, Yufan ZHANG, Heli DENG, Desuo ZHANG, Hong LIN, Yuyue CHEN, Jiaqing XIONG. In-situ sugar-templated porous elastomer sensor with high sensitivity for wearables. Front. Mater. Sci., 2022, 16(2): 220597 DOI:10.1007/s11706-022-0597-5

登录浏览全文

4963

注册一个新账户 忘记密码

References

[1]

Matsuhisa N , Kaltenbrunner M , Yokota T . . Printable elastic conductors with a high conductivity for electronic textile applications. Nature Communications, 2015, 6 : 7461

[2]

Katsigiannis S , Ramzan N . DREAMER: A database for emotion recognition through EEG and ECG signals from wireless low-cost off-the-shelf devices. IEEE Journal of Biomedical and Health Informatics, 2018, 22( 1): 98– 107

[3]

Geng W , Du Y , Jin W . . Gesture recognition by instantaneous surface EMG images. Scientific Reports, 2016, 6( 1): 36571

[4]

Deignan J , Mcbrearty M , Monedero J . . Wearable chemical sensors: characterization of ECG electrodes with electrochemical impedance spectroscopy. Exercise, 2016, 277( 5693): 189– 192

[5]

Xiong J , Chen J , Lee P S . Functional fibers and fabrics for soft robotics, wearables, and human-robot interface. Advanced Materials, 2020, 33( 19): 2002640

[6]

Kim J , Campbell A S , de Ávila B E . . Wearable biosensors for healthcare monitoring. Nature Biotechnology, 2019, 37( 4): 389– 406

[7]

Webb R C , Bonifas A P , Behnaz A . . Ultrathin conformal devices for precise and continuous thermal characterization of human skin. Nature Materials, 2013, 12( 10): 938– 944

[8]

Jang K I , Han S Y , Xu S . . Rugged and breathable forms of stretchable electronics with adherent composite substrates for transcutaneous monitoring. Nature Communications, 2014, 5( 1): 4779

[9]

Miyamoto A , Lee S , Cooray N F . . Inflammation-free, gas-permeable, lightweight, stretchable on-skin electronics with nanomeshes. Nature Nanotechnology, 2017, 12( 9): 907– 913

[10]

Kim J , Salvatore G A , Araki H . . Battery-free, stretchable optoelectronic systems for wireless optical characterization of the skin. Science Advances, 2016, 2( 8): e1600418

[11]

Xiong J , Cui P , Chen X . . Skin-touch-actuated textile-based triboelectric nanogenerator with black phosphorus for durable biomechanical energy harvesting. Nature Communications, 2018, 9( 1): 4280

[12]

Xiong J , Lin M F , Wang J . . Wearable all-fabric-based triboelectric generator for water energy harvesting. Advanced Energy Materials, 2017, 7( 21): 1701243

[13]

Hua Q , Sun J , Liu H . . Skin-inspired highly stretchable and conformable matrix networks for multifunctional sensing. Nature Communications, 2018, 9( 1): 244

[14]

Kim J , Kim M , Lee M S . . Wearable smart sensor systems integrated on soft contact lenses for wireless ocular diagnostics. Nature Communications, 2017, 8( 1): 14997

[15]

Lu N , Kim D H . Flexible and stretchable electronics paving the way for soft robotics. Soft Robotics, 2014, 1( 1): 53– 62

[16]

Schwartz G , Tee B C K , Mei J . . Flexible polymer transistors with high pressure sensitivity for application in electronic skin and health monitoring. Nature Communications, 2013, 4( 1): 1859

[17]

Wang C , Hwang D , Yu Z . . User-interactive electronic skin for instantaneous pressure visualization. Nature Materials, 2013, 12( 10): 899– 904

[18]

Wang C , Xia K , Zhang M . . An all-silk-derived dual-mode e-skin for simultaneous temperature–pressure detection. ACS Applied Materials & Interfaces, 2017, 9( 45): 39484– 39492

[19]

Wang Q , Jian M , Wang C . . Carbonized silk nanofiber membrane for transparent and sensitive electronic skin. Advanced Functional Materials, 2017, 27( 9): 1605657

[20]

Gao D , Wang J , Ai K . . Inkjet-printed iontronics for transparent, elastic, and strain-insensitive touch sensing matrix. Advanced Intelligent Systems, 2020, 2( 7): 2000088

[21]

Honda W , Harada S , Arie T . . Wearable, human-interactive, health-monitoring, wireless devices fabricated by macroscale printing techniques. Advanced Functional Materials, 2014, 24( 22): 3299– 3304

[22]

Tao L Q , Tian H , Liu Y . . An intelligent artificial throat with sound-sensing ability based on laser induced graphene. Nature Communications, 2017, 8( 1): 14579

[23]

Li Y , Samad Y A , Liao K . From cotton to wearable pressure sensor. Journal of Materials Chemistry A: Materials for Energy and Sustainability, 2015, 3( 5): 2181– 2187

[24]

Shi X , Zuo Y , Zhai P . . Large-area display textiles integrated with functional systems. Nature, 2021, 591( 7849): 240– 245

[25]

Chen X , Parida K , Wang J . . A stretchable and transparent nanocomposite nanogenerator for self-powered physiological monitoring. ACS Applied Materials & Interfaces, 2017, 9( 48): 42200– 42209

[26]

Fan W , He Q , Meng K . . Machine-knitted washable sensor array textile for precise epidermal physiological signal monitoring. Science Advances, 2020, 6( 11): eaay2840

[27]

Wu F , Chen S , Chen B . . Bioinspired universal flexible elastomer-based microchannels. Small, 2018, 14( 18): 1702170

[28]

Dagdeviren C , Su Y , Joe P . . Conformable amplified lead zirconate titanate sensors with enhanced piezoelectric response for cutaneous pressure monitoring. Nature Communications, 2014, 5( 1): 4496

[29]

Yan C , Wang J , Kang W . . Highly stretchable piezoresistive graphene-nanocellulose nanopaper for strain sensors. Advanced Materials, 2014, 26( 13): 2022– 2027

[30]

Liu H , Dong M Y , Huang W J . . Lightweight conductive graphene/thermoplastic polyurethane foams with ultrahigh compressibility for piezoresistive sensing. Journal of Materials Chemistry C: Materials for Optical and Electronic Devices, 2017, 5( 1): 73– 83

[31]

Cho S H , Lee S W , Yu S . . Micropatterned pyramidal ionic gels for sensing broad-range pressures with high sensitivity. ACS Applied Materials & Interfaces, 2017, 9( 11): 10128– 10135

[32]

Mannsfeld S C B , Tee B C K , Stoltenberg R M . . Highly sensitive flexible pressure sensors with microstructured rubber dielectric layers. Nature Materials, 2010, 9( 10): 859– 864

[33]

Li J , Fang L , Sun B . . Recent progress in flexible and stretchable piezoresistive sensors and their applications. Journal of the Electrochemical Society, 2020, 167( 3): 037561

[34]

Gong S , Lai D T H , Su B . . Highly stretchy black gold e-skin nanopatches as highly sensitive wearable biomedical sensors. Advanced Electronic Materials, 2015, 1( 4): 1400063

[35]

Shi J , Li X , Cheng H . . Graphene reinforced carbon nanotube networks for wearable strain sensors. Advanced Functional Materials, 2016, 26( 13): 2078– 2084

[36]

Jian M , Wang C , Wang Q . . Advanced carbon materials for flexible and wearable sensors. Science China Materials, 2017, 60( 11): 1026– 1062

[37]

Lee J , Kim S , Lee J . . A stretchable strain sensor based on a metal nanoparticle thin film for human motion detection. Nanoscale, 2014, 6( 20): 11932– 11939

[38]

Boland C S , Khan U , Ryan G . . Sensitive electromechanical sensors using viscoelastic graphene–polymer nanocomposites. Science, 2016, 354( 6317): 1257– 1260

[39]

Tee B C K , Chortos A , Dunn R R . . Tunable flexible pressure sensors using microstructured elastomer geometries for intuitive electronics. Advanced Functional Materials, 2014, 24( 34): 5427– 5434

[40]

Wang H , Xiang Z , Giorgia P . . Triboelectric liquid volume sensor for self-powered lab-on-chip applications. Nano Energy, 2016, 23 : 80– 88

[41]

Xiong J , Thangavel G , Wang J . . Self-healable sticky porous elastomer for gas–solid interacted power generation. Science Advances, 2020, 6( 29): eabb4246

[42]

Sun B , McCay R N , Goswami S . . Gas-permeable, multifuncationl on-skin electronics based on laser-induced porous graphene and sugar-templated ealstomer sponges. Advanced Materials, 2018, 30( 50): 1804327

[43]

Miller S , Bao Z . Fabrication of flexible pressure sensors with microstructured polydimethylsiloxane dielectrics using the breath figures method. Journal of Materials Research, 2015, 30( 23): 3584– 3594

[44]

Deng Z , Hu T , Lei Q . . Stimuli-responsive conductive nanocomposite hydrogels with high stretchability, self-healing, adhesiveness, and 3D printability for human motion sensing. ACS Applied Materials & Interfaces, 2019, 11( 7): 6796– 6808

[45]

Zhang L , Liu L , Liu C . . Photolithographic fabrication of graphene-based all-solid-state planar on-chip microsupercapacitors with ultrahigh power characteristics. Journal of Applied Physics, 2019, 126( 16): 164308

[46]

Tyagi P , Chaturvedi R , Gorhe N R . Macroporous poly(vinyl chloride)-polypyrrole composites with piezoresistive behaviour. Materials Letters, 2020, 280 : 128566

[47]

Wu S , Zhang J , Ladani R B . . Novel electrically conductive porous PDMS/carbon nanofiber composites for deformable strain sensors and conductors. ACS Applied Materials & Interfaces, 2017, 9( 16): 14207– 14215

[48]

Kim Y , Jang S , Oh J H . Fabrication of highly sensitive capacitive pressure sensors with porous PDMS dielectric layer via microwave treatment. Microelectronic Engineering, 2019, 215 : 111002

[49]

Kang S , Lee J , Lee S . . Highly sensitive pressure sensor based on bioinspired porous structure for real-time tactile sensing. Advanced Electronic Materials, 2016, 2( 12): 1600356

[50]

Long Y , Zhao X , Jiang X . . A porous graphene/polydimethylsiloxane composite by chemical foaming for simultaneous tensile and compressive strain sensing. FlatChem, 2018, 10 : 1– 7

[51]

Li Q , Duan T , Shao J . . Fabrication method for structured porous polydimethylsiloxane (PDMS). Journal of Materials Science, 2018, 53( 16): 11873– 11882

[52]

Mamunya Y P , Muzychenko Y V , Pissis P . . Percolation phenomena in polymers containing dispersed iron. Polymer Engineering and Science, 2002, 42( 1): 90– 100

[53]

Kou H , Zhang L , Tan Q . . Wireless flexible pressure sensor based on micro-patterned graphene/PDMS composite. Sensors and Actuators A: Physical, 2018, 277 : 150– 156

[54]

Al-Handarish Y , Omisore O M , Duan W . . Facile fabrication of 3D porous sponges coated with synergistic carbon black/multiwalled carbon nanotubes for tactile sensing applications. Nanomaterials, 2020, 10( 10): 1941

[55]

Park S W , Das P S , Park J Y . Development of wearable and flexible insole type capacitive pressure sensor for continuous gait signal analysis. Organic Electronics, 2018, 53 : 213– 220

[56]

Tang X , Wu C , Gan L . . Multilevel microstructured flexible pressure sensors with ultrahigh sensitivity and ultrawide pressure range for versatile electronic skins. Small, 2019, 15( 10): 1804559

RIGHTS & PERMISSIONS

Higher Education Press

AI Summary AI Mindmap
PDF (4929KB)

2037

Accesses

0

Citation

Detail

Sections
Recommended

AI思维导图

/