LaNiO3 modified with Ag nanoparticles as an efficient bifunctional electrocatalyst for rechargeable zinc--air batteries

Pengzhang LI, Chuanjin TIAN, Wei YANG, Wenyan ZHAO, Zhe LÜ

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Front. Mater. Sci. ›› 2019, Vol. 13 ›› Issue (3) : 277-287. DOI: 10.1007/s11706-019-0474-z
RESEARCH ARTICLE

LaNiO3 modified with Ag nanoparticles as an efficient bifunctional electrocatalyst for rechargeable zinc--air batteries

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Abstract

No-precious bifunctional catalysts with high electrochemical activities and stability were crucial to properties of rechargeable zinc–air batteries. Herein, LaNiO3 modified with Ag nanoparticles (Ag/LaNiO3) was prepared by the co-synthesis method and evaluated as the bifunctional oxygen catalyst for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER). Compared with LaNiO3, Ag/LaNiO3 demonstrated the enhanced catalytic activity towards ORR/OER as well as higher limited current density and lower onset potential. Moreover, the potential gap between ORR potential (at −3 mA·cm−2) and OER potential (at 5 mA·cm−2) was 1.16 V. The maximum power density of the primary zinc–air battery with Ag/LaNiO3 catalyst achieved 60 mW·cm−2. Furthermore, rechargeable zinc–air batteries operated reversible charge–discharge cycles for 150 cycles without noticeable performance deterioration, which showed its excellent bifunctional activity and cycling stability as oxygen electrocatalyst for rechargeable zinc–air batteries. These results indicated that Ag/LaNiO3 prepared by the co-synthesis method was a promising bifunctional catalyst for rechargeable zinc–air batteries.

Keywords

Ag/LaNiO3 / co-synthesis method / oxygen reduction reaction / oxygen evolution reaction / rechargeable zinc--air battery

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Pengzhang LI, Chuanjin TIAN, Wei YANG, Wenyan ZHAO, Zhe LÜ. LaNiO3 modified with Ag nanoparticles as an efficient bifunctional electrocatalyst for rechargeable zinc--air batteries. Front. Mater. Sci., 2019, 13(3): 277‒287 https://doi.org/10.1007/s11706-019-0474-z

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (Grant Nos. 51372057 and 21373071).

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2019 Higher Education Press and Springer-Verlag GmbH Germany, part of Springer Nature
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