Graphene-based bipolar plates for polymer electrolyte membrane fuel cells

Ram Sevak SINGH , Anurag GAUTAM , Varun RAI

Front. Mater. Sci. ›› 2019, Vol. 13 ›› Issue (3) : 217 -241.

PDF (3334KB)
Front. Mater. Sci. ›› 2019, Vol. 13 ›› Issue (3) : 217 -241. DOI: 10.1007/s11706-019-0465-0
REVIEW ARTICLE
REVIEW ARTICLE

Graphene-based bipolar plates for polymer electrolyte membrane fuel cells

Author information +
History +
PDF (3334KB)

Abstract

Bipolar plates (BPs) are a major component of polymer electrolyte membrane fuel cells (PEMFCs). BPs play a multifunctional character within a PEMFC stack. It is one of the most costly and critical part of the fuel cell, and hence the development of efficient and cost-effective BPs is of much interest for the fabrication of next-generation PEMFCs in future. Owing to high electrical conductivity and chemical inertness, graphene is an ideal candidate to be utilized in BPs. This paper reviews recent advances in the area of graphene-based BPs for PEMFC applications. Various aspects including the momentous functions of BPs in the PEMFC, favorable features of graphene-based BPs, performance evaluation of various reported BPs with their advantages and disadvantages, challenges at commercial level products and future prospects of frontier research in this direction are extensively documented.

Keywords

graphene / bipolar plate / polymer electrolyte membrane fuel cell / proton exchange membrane fuel cell

Cite this article

Download citation ▾
Ram Sevak SINGH, Anurag GAUTAM, Varun RAI. Graphene-based bipolar plates for polymer electrolyte membrane fuel cells. Front. Mater. Sci., 2019, 13(3): 217-241 DOI:10.1007/s11706-019-0465-0

登录浏览全文

4963

注册一个新账户 忘记密码

References

[1]

Wind J, Späh R, Kaiser W, . Metallic bipolar plates for PEM fuel cells. Journal of Power Sources, 2002, 105(2): 256–260

[2]

Bar-On I, Kirchain R, Roth R. Technical cost analysis for PEM fuel cells. Journal of Power Sources, 2002, 109(1): 71–75

[3]

Lv H, Mu S. Nano-ceramic support materials for low temperature fuel cell catalysts. Nanoscale, 2014, 6(10): 5063–5074

[4]

Wei M, Jiang M, Liu X, . Graphene-doped electrospun nanofiber membrane electrodes and proton exchange membrane fuel cell performance. Journal of Power Sources, 2016, 327: 384–393

[5]

Mehta V, Cooper J S. Review and analysis of PEM fuel cell design and manufacturing. Journal of Power Sources, 2003, 114(1): 32–53

[6]

Li X, Sabir I. Review of bipolar plates in PEM fuel cells: Flow-field designs. International Journal of Hydrogen Energy, 2005, 30(4): 359–371

[7]

Davies D, Adcock P, Turpin M, . Stainless steel as a bipolar plate material for solid polymer fuel cells. Journal of Power Sources, 2000, 86(1–2): 237–242

[8]

Busick D, Wilson M. Development of composite materials for PEFC bipolar plates. MRS Online Proceedings Library Archive, 1999, 575

[9]

Heinzel A, Mahlendorf F, Niemzig O, . Injection moulded low cost bipolar plates for PEM fuel cells. Journal of Power Sources, 2004, 131(1–2): 35–40

[10]

Borup R L, Vanderborgh N E. Design and testing criteria for bipolar plate materials for PEM fuel cell applications. MRS Online Proceedings Library Archive, 1995, 393

[11]

Lee S J, Huang C H, Lai J J, . Corrosion-resistant component for PEM fuel cells. Journal of Power Sources, 2004, 131(1–2): 162–168

[12]

Dundar F, Dur E, Mahabunphachai S, . Corrosion resistance characteristics of stamped and hydroformed proton exchange membrane fuel cell metallic bipolar plates. Journal of Power Sources, 2010, 195(11): 3546–3552

[13]

Jin C K, Kang C G. Fabrication by vacuum die casting and simulation of aluminum bipolar plates with micro-channels on both sides for proton exchange membrane (PEM) fuel cells. International Journal of Hydrogen Energy, 2012, 37(2): 1661–1676

[14]

Hung J C, Chang D H, Chuang Y. The fabrication of high-aspect-ratio micro-flow channels on metallic bipolar plates using die-sinking micro-electrical discharge machining. Journal of Power Sources, 2012, 198: 158–163

[15]

Deprez N, McLachlan D. The analysis of the electrical conductivity of graphite conductivity of graphite powders during compaction. Journal of Physics D: Applied Physics, 1988, 21(1): 101–107

[16]

Davies D, Adcock P, Turpin M, . Bipolar plate materials for solid polymer fuel cells. Journal of Applied Electrochemistry, 2000, 30(1): 101–105

[17]

Dhakate S, Mathur R, Kakati B, . Properties of graphite-composite bipolar plate prepared by compression molding technique for PEM fuel cell. International Journal of Hydrogen Energy, 2007, 32(17): 4537–4543

[18]

Roßberg K, Trapp V. Graphite-based bipolar plates. In: Vielstich W, Gasteiger H A, Lamm A, ., eds. Handbook of Fuel Cells — Fundamentals, Technology and Applications. John Wiley & Sons, Ltd., 2010

[19]

Cho E, Jeon U S, Ha H, . Characteristics of composite bipolar plates for polymer electrolyte membrane fuel cells. Journal of Power Sources, 2004, 125(2): 178–182

[20]

Kuan H C, Ma C C M, Chen K H, . Preparation, electrical, mechanical and thermal properties of composite bipolar plate for a fuel cell. Journal of Power Sources, 2004, 134(1): 7–17

[21]

Hodgson D, May B, Adcock P, . New lightweight bipolar plate system for polymer electrolyte membrane fuel cells. Journal of Power Sources, 2001, 96(1): 233–235

[22]

He D, Tang H, Kou Z, . Engineered graphene materials: synthesis and applications for polymer electrolyte membrane fuel cells. Advanced Materials, 2017, 29(20): 1601741

[23]

Hung Y, Tawfik H, El-Khatib K M, . Corrosion and contact resistance measurements of different bipolar plate material for polymer electrolyte membrane fuel cells. International Journal of Alternative Propulsion, 2008, 2(1): 72–85

[24]

Zhang D, Duan L, Guo L, . TiN-coated titanium as the bipolar plate for PEMFC by multi-arc ion plating. International Journal of Hydrogen Energy, 2011, 36(15): 9155–9161

[25]

Bi F, Peng L, Yi P, . Multilayered Zr–C/a-C film on stainless steel 316L as bipolar plates for proton exchange membrane fuel cells. Journal of Power Sources, 2016, 314: 58–65

[26]

Yi P, Zhang W, Bi F, . Enhanced corrosion resistance and interfacial conductivity of TiCx/a-C nanolayered coatings via synergy of substrate bias voltage for bipolar plates applications in PEMFCs. ACS Applied Materials & Interfaces, 2018, 10(22): 19087–19096

[27]

Jayaraj J, Kim Y, Kim K, . Corrosion studies on Fe-based amorphous alloys in simulated PEM fuel cell environment. Science and Technology of Advanced Materials, 2005, 6(3–4): 282–289

[28]

Zhang D, Wang Z, Huang K. Composite coatings with in situ formation for Fe–Ni–Cr alloy as bipolar plate of PEMFC. International Journal of Hydrogen Energy, 2013, 38(26): 11379–11391

[29]

Omrani M, Habibi M, Amrollahi R, . Improvement of corrosion and electrical conductivity of 316L stainless steel as bipolar plate by TiN nanoparticle implantation using plasma focus. International Journal of Hydrogen Energy, 2012, 37(19): 14676–14686

[30]

Yoon W, Huang X, Fazzino P, . Evaluation of coated metallic bipolar plates for polymer electrolyte membrane fuel cells. Journal of Power Sources, 2008, 179(1): 265–273

[31]

Wang S, Hou M, Zhao Q, . Ti/(Ti,Cr)N/CrN multilayer coated 316L stainless steel by arc ion plating as bipolar plates for proton exchange membrane fuel cells. Journal of Energy Chemistry, 2017, 26(1): 168–174

[32]

Feng K, Shen Y, Sun H, . Conductive amorphous carbon-coated 316L stainless steel as bipolar plates in polymer electrolyte membrane fuel cells. International Journal of Hydrogen Energy, 2009, 34(16): 6771–6777

[33]

Wang H, Sweikart M A, Turner J A. Stainless steel as bipolar plate material for polymer electrolyte membrane fuel cells. Journal of Power Sources, 2003, 115(2): 243–251

[34]

Silva R, Franchi D, Leone A, . Surface conductivity and stability of metallic bipolar plate materials for polymer electrolyte fuel cells. Electrochimica Acta, 2006, 51(17): 3592–3598

[35]

Joseph S, McClure J, Chianelli R, . Conducting polymer-coated stainless steel bipolar plates for proton exchange membrane fuel cells (PEMFC). International Journal of Hydrogen Energy, 2005, 30(12): 1339–1344

[36]

Wang L, Sun J, Kang B, . Electrochemical behaviour and surface conductivity of niobium carbide-modified austenitic stainless steel bipolar plate. Journal of Power Sources, 2014, 246: 775–782

[37]

Wang S H, Peng J, Lui W B, . Performance of the gold-plated titanium bipolar plates for the light weight PEM fuel cells. Journal of Power Sources, 2006, 162(1): 486–491

[38]

Gamburzev S, Appleby A J. Recent progress in performance improvement of the proton exchange membrane fuel cell (PEMFC). Journal of Power Sources, 2002, 107(1): 5–12

[39]

Kumar A, Reddy R G. Materials and design development for bipolar/end plates in fuel cells. Journal of Power Sources, 2004, 129(1): 62–67

[40]

Cho E, Jeon U S, Hong S A, . Performance of a 1 kW-class PEMFC stack using TiN-coated 316 stainless steel bipolar plates. Journal of Power Sources, 2005, 142(1–2): 177–183

[41]

Yi P, Peng L, Feng L, . Performance of a proton exchange membrane fuel cell stack using conductive amorphous carbon-coated 304 stainless steel bipolar plates. Journal of Power Sources, 2010, 195(20): 7061–7066

[42]

Lee Y H, Li S M, Tseng C J, . Graphene as corrosion protection for metal foam flow distributor in proton exchange membrane fuel cells. International Journal of Hydrogen Energy, 2017, 42(34): 22201–22207

[43]

Tseng C J, Tsai B T, Liu Z S, . A PEM fuel cell with metal foam as flow distributor. Energy Conversion and Management, 2012, 62: 14–21

[44]

Lee S J, Huang C H, Chen Y P. Investigation of PVD coating on corrosion resistance of metallic bipolar plates in PEM fuel cell. Journal of Materials Processing Technology, 2003, 140(1–3): 688–693

[45]

Gladczuk L, Joshi C, Patel A, . Corrosion-resistant tantalum coatings for PEM fuel cell bipolar plates. MRS Online Proceedings Library Archive, 2002, 756

[46]

Ma L, Warthesen S, Shores D A. Evaluation of materials for bipolar plates in PEMFCs. Journal of New Materials for Electrochemical Systems, 2000, 3(3): 221–228

[47]

Wang H, Turner J. Reviewing metallic PEMFC bipolar plates. Fuel Cells, 2010, 10(4): 510–519

[48]

Hentall P L, Lakeman J B, Mepsted G O, . New materials for polymer electrolyte membrane fuel cell current collectors. Journal of Power Sources, 1999, 80(1–2): 235–241

[49]

Hornung R, Kappelt G. Bipolar plate materials development using Fe-based alloys for solid polymer fuel cells. Journal of Power Sources, 1998, 72(1): 20–21

[50]

Scholta J, Rohland B, Trapp V, . Investigations on novel low-cost graphite composite bipolar plates. Journal of Power Sources, 1999, 84(2): 231–234

[51]

Scholta J, Berg N, Wilde P, . Development and performance of a 10 kW PEMFC stack. Journal of Power Sources, 2004, 127(1–2): 206–212

[52]

Besmann T M, Klett J W, Burchell T D. Carbon composite for a PEM fuel cell bipolar plate. MRS Online Proceedings Library Archive, 1997, 496

[53]

Cunningham N, Guay D, Dodelet J, . New materials and procedures to protect metallic PEM fuel cell bipolar plates. Journal of the Electrochemical Society, 2002, 149(7): A905–A911

[54]

Gautam A, Ram S. Shape-controlled silver metal of nanospheroids from a polymer-assisted autocombustion reaction in open air. Journal of Alloys and Compounds, 2008, 463(1–2): 428–434

[55]

Chang H, Koschany P, Lim C, . Materials and processes for light weight and high power density PEM fuel cells. Journal of New Materials for Electrochemical Systems, 2000, 3(1): 55–60

[56]

Tawfik H, Hung Y, Mahajan D. Metal bipolar plates for PEM fuel cell — a review. Journal of Power Sources, 2007, 163(2): 755–767

[57]

Brady M, Weisbrod K, Zawodzinski C, . Assessment of thermal nitridation to protect metal bipolar plates in polymer electrolyte membrane fuel cells. Electrochemical and Solid-State Letters, 2002, 5(11): A245–A247

[58]

Brady M P, Weisbrod K, Paulauskas I, . Preferential thermal nitridation to form pin-hole free Cr-nitrides to protect proton exchange membrane fuel cell metallic bipolar plates. Scripta Materialia, 2004, 50(7): 1017–1022

[59]

Li M, Luo S, Zeng C, . Corrosion behavior of TiN coated type 316 stainless steel in simulated PEMFC environments. Corrosion Science, 2004, 46(6): 1369–1380

[60]

Middelman E, Kout W, Vogelaar B, . Bipolar plates for PEM fuel cells. Journal of Power Sources, 2003, 118(1–2): 44–46

[61]

Taherian R. A review of composite and metallic bipolar plates in proton exchange membrane fuel cell: Materials, fabrication, and material selection. Journal of Power Sources, 2014, 265: 370–390

[62]

Hermann A, Chaudhuri T, Spagnol P. Bipolar plates for PEM fuel cells: A review. International Journal of Hydrogen Energy, 2005, 30(12): 1297–1302

[63]

Steele B C, Heinzel A. Materials for fuel-cell technologies. Nature, 2001, 414(6861): 345–352

[64]

Dihrab S S, Sopian K, Alghoul M, . Review of the membrane and bipolar plates materials for conventional and unitized regenerative fuel cells. Renewable & Sustainable Energy Reviews, 2009, 13(6–7): 1663–1668

[65]

Yuan X Z, Wang H, Zhang J, . Bipolar plates for PEM fuel cells-from materials to processing. Journal of New Materials for Electrochemical Systems, 2005, 8(4): 257

[66]

Iwan A, Malinowski M, Pasciak G. Polymer fuel cell components modified by graphene: Electrodes, electrolytes and bipolar plates. Renewable & Sustainable Energy Reviews, 2015, 49: 954–967

[67]

Geim A K, Novoselov K S. The rise of graphene. Nature Materials, 2007, 6(3): 183–191

[68]

Novoselov K S, Geim A K, Morozov S V, . Two-dimensional gas of massless Dirac fermions in graphene. Nature, 2005, 438(7065): 197–200

[69]

Singh R S, Nalla V, Chen W, . Laser patterning of epitaxial graphene for Schottky junction photodetectors. ACS Nano, 2011, 5(7): 5969–5975

[70]

Singh R S, Nalla V, Chen W, . Photoresponse in epitaxial graphene with asymmetric metal contacts. Applied Physics Letters, 2012, 100(9): 093116 (3 pages)

[71]

Singh R S, Wang X, Chen W, . Large room-temperature quantum linear magnetoresistance in multilayered epitaxial graphene: Evidence for two-dimensional magnetotransport. Applied Physics Letters, 2012, 101(18): 183105 (3 pages)

[72]

Singh R S, Li D, Xiong Q, . Anomalous photoresponse in the deep-ultraviolet due to resonant excitonic effects in oxygen plasma treated few-layer graphene. Carbon, 2016, 106: 330–335

[73]

Santoso I, Singh R S, Gogoi P K, . Tunable optical absorption and interactions in graphene via oxygen plasma. Physical Review B, 2014, 89(7): 075134

[74]

Wu Z S, Ren W, Gao L, . Synthesis of graphene sheets with high electrical conductivity and good thermal stability by hydrogen arc discharge exfoliation. ACS Nano, 2009, 3(2): 411–417

[75]

Peigney A, Laurent C, Flahaut E, . Specific surface area of carbon nanotubes and bundles of carbon nanotubes. Carbon, 2001, 39(4): 507–514

[76]

Lee C, Wei X, Kysar J W, . Measurement of the elastic properties and intrinsic strength of monolayer graphene. Science, 2008, 321(5887): 385–388

[77]

Balandin A A, Ghosh S, Bao W, . Superior thermal conductivity of single-layer graphene. Nano Letters, 2008, 8(3): 902–907

[78]

Williams J R, Dicarlo L, Marcus C M. Quantum Hall effect in a gate-controlled p–n junction of graphene. Science, 2007, 317(5838): 638–641

[79]

Novoselov K S, Geim A K, Morozov S V, . Electric field effect in atomically thin carbon films. Science, 2004, 306(5696): 666–669

[80]

Stankovich S, Dikin D A, Piner R D, . Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide. Carbon, 2007, 45(7): 1558–1565

[81]

Hernandez Y, Nicolosi V, Lotya M, . High-yield production of graphene by liquid-phase exfoliation of graphite. Nature Nanotechnology, 2008, 3(9): 563–568

[82]

Hummers W S, Offeman R E. Preparation of graphitic oxide. Journal of the American Chemical Society, 1958, 80(6): 1339

[83]

Choucair M, Thordarson P, Stride J A. Gram-scale production of graphene based on solvothermal synthesis and sonication. Nature Nanotechnology, 2009, 4(1): 30–33

[84]

Obraztsov A N. Chemical vapour deposition: Making graphene on a large scale. Nature Nanotechnology, 2009, 4(4): 212–213

[85]

Sutter P W, Flege J I, Sutter E A. Epitaxial graphene on ruthenium. Nature Materials, 2008, 7(5): 406–411

[86]

Kou Z, Meng T, Guo B, . A generic conversion strategy: From 2D metal carbides (MxCy) to M-self-doped graphene toward high-efficiency energy applications. Advanced Functional Materials, 2017, 27(8): 1604904

[87]

Amiinu I S, Zhang J, Kou Z, . Self-organized 3D porous graphene dual-doped with biomass-sponsored nitrogen and sulfur for oxygen reduction and evolution. ACS Applied Materials & Interfaces, 2016, 8(43): 29408–29418

[88]

He D, Kou Z, Xiong Y, . Simultaneous sulfonation and reduction of graphene oxide as highly efficient supports for metal nanocatalysts. Carbon, 2014, 66: 312–319

[89]

Kyhl L, Nielsen S F, Čabo A G, . Graphene as an anti-corrosion coating layer. Faraday Discussions, 2015, 180: 495–509

[90]

Zhang Y, Zhang H, Wang B, . Role of wrinkles in the corrosion of graphene domain-coated Cu surfaces. Applied Physics Letters, 2014, 104(14): 143110 (3 pages)

[91]

Xu W, Zhao K, Zhang L, . SnS2@graphene nanosheet arrays grown on carbon cloth as freestanding binder-free flexible anodes for advanced sodium batteries. Journal of Alloys and Compounds, 2016, 654: 357–362

[92]

Hsieh Y P, Hofmann M, Chang K W, . Complete corrosion inhibition through graphene defect passivation. ACS Nano, 2014, 8(1): 443–448

[93]

Wlasny I, Dabrowski P, Rogala M, . Role of graphene defects in corrosion of graphene-coated Cu(111) surface. Applied Physics Letters, 2013, 102(11): 111601 (3 pages)

[94]

Rozada R, Paredes J I, Villar-Rodil S, . Towards full repair of defects in reduced graphene oxide films by two-step graphitization. Nano Research, 2013, 6(3): 216–233

[95]

Li X, Cai W, An J, . Large-area synthesis of high-quality and uniform graphene films on copper foils. Science, 2009, 324(5932): 1312–1314

[96]

Prasai D, Tuberquia J C, Harl R R, . Graphene: corrosion-inhibiting coating. ACS Nano, 2012, 6(2): 1102–1108

[97]

Ye X, Lin Z, Zhang H, . Protecting carbon steel from corrosion by laser in situ grown graphene films. Carbon, 2015, 94: 326–334

[98]

Nazarova M, Stora T, Zhukov A, . Growth of graphene on tantalum and its protective properties. Carbon, 2018, 139: 29–34

[99]

Pu N W, Shi G N, Liu Y M, . Graphene grown on stainless steel as a high-performance and ecofriendly anti-corrosion coating for polymer electrolyte membrane fuel cell bipolar plates. Journal of Power Sources, 2015, 282: 248–256

[100]

Antunes R A, Oliveira M C L, Ett G, . Corrosion of metal bipolar plates for PEM fuel cells: a review. International Journal of Hydrogen Energy, 2010, 35(8): 3632–3647

[101]

Sudagar J, Lian J, Sha W. Electroless nickel, alloy, composite and nano coatings—A critical review. Journal of Alloys and Compounds, 2013, 571: 183–204

[102]

Stoot A C, Camilli L, Spiegelhauer S A, . Multilayer graphene for long-term corrosion protection of stainless steel bipolar plates for polymer electrolyte membrane fuel cell. Journal of Power Sources, 2015, 293: 846–851

[103]

Ren Y, Anisur M, Qiu W, . Degradation of graphene coated copper in simulated proton exchange membrane fuel cell environment: Electrochemical impedance spectroscopy study. Journal of Power Sources, 2017, 362: 366–372

[104]

Lee Y H, Noh S, Lee J H, . Durable graphene-coated bipolar plates for polymer electrolyte fuel cells. International Journal of Hydrogen Energy, 2017, 42(44): 27350–27353

[105]

Zheng Z, Liu Y, Bai Y, . Fabrication of biomimetic hydrophobic patterned graphene surface with ecofriendly anti-corrosion properties for Al alloy. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2016, 500: 64–71

[106]

Mišković-Stanković V, Jevremović I, Jung I, . Electrochemical study of corrosion behavior of graphene coatings on copper and aluminum in a chloride solution. Carbon, 2014, 75: 335–344

[107]

Kim Y J, Kim D H, Kim J S, . Electro and surface properties of graphene-modified stainless steel for PEMFC bipolar plates. Advanced Materials Research, 2014, 167–170

[108]

Staudenmaier L. Verfahren zur darstellung der graphitsäure. European Journal of Inorganic Chemistry, 1899, 32(2): 1394–1399 (in German)

[109]

Lv J, Tongxiang L, Chen W. The effects of molybdenum and reduced graphene oxide on corrosion resistance of amorphous nickel–phosphorus as bipolar plates in PEMFC environment. International Journal of Hydrogen Energy, 2016, 41(23): 9738–9745

[110]

Raghupathy Y, Kamboj A, Rekha M, . Copper–graphene oxide composite coatings for corrosion protection of mild steel in 3.5% NaCl. Thin Solid Films, 2017, 636: 107–115

[111]

Hirata M, Gotou T, Horiuchi S, . Thin-film particles of graphite oxide 1: High-yield synthesis and flexibility of the particles. Carbon, 2004, 42(14): 2929–2937

[112]

Jang H, Kim J H, Kang H, . Reduced graphene oxide as a protection layer for Al. Applied Surface Science, 2017, 407: 1–7

[113]

Pavan A S S, Ramanan S R. A study on corrosion resistant graphene films on low alloy steel. Applied Nanoscience, 2016, 6(8): 1175–1181

[114]

Liu Y, Zhang J, Li S, . Fabrication of a superhydrophobic graphene surface with excellent mechanical abrasion and corrosion resistance on an aluminum alloy substrate. RSC Advances, 2014, 4(85): 45389–45396

[115]

Liu J, Hua L, Li S, . Graphene dip coatings: An effective anticorrosion barrier on aluminum. Applied Surface Science, 2015, 327: 241–245

[116]

Berlia R, Kumar M K P, Srivastava C. Electrochemical behavior of Sn–graphene composite coating. RSC Advances, 2015, 5(87): 71413–71418

[117]

Liu C, Su F, Liang J. Producing cobalt–graphene composite coating by pulse electrodeposition with excellent wear and corrosion resistance. Applied Surface Science, 2015, 351: 889–896

[118]

Sadhir M H, Saranya M, Aravind M, . Comparison of in situ and ex situ reduced graphene oxide reinforced electroless nickel phosphorus nanocomposite coating. Applied Surface Science, 2014, 320: 171–176

[119]

Amani H, Mostafavi E, Arzaghi H, . Three-dimensional graphene foams: synthesis, properties, biocompatibility, biodegradability, and applications in tissue engineering. ACS Biomaterials Science & Engineering, 2019, 5(1): 193–214

[120]

Chen Z, Ren W, Gao L, . Three-dimensional flexible and conductive interconnected graphene networks grown by chemical vapour deposition. Nature Materials, 2011, 10(6): 424–428

[121]

Yavari F, Chen Z, Thomas A V, . High sensitivity gas detection using a macroscopic three-dimensional graphene foam network. Scientific Reports, 2011, 1(1): 166

[122]

Wang J K, Xiong G M, Zhu M, . Polymer-enriched 3D graphene foams for biomedical applications. ACS Applied Materials & Interfaces, 2015, 7(15): 8275–8283

[123]

Loeblein M, Bolker A, Tsang S H, . 3D graphene-infused polyimide with enhanced electrothermal performance for long-term flexible space applications. Small, 2015, 11(48): 6425–6434

[124]

Chen K, Shi L, Zhang Y, . Scalable chemical-vapour-deposition growth of three-dimensional graphene materials towards energy-related applications. Chemical Society Reviews, 2018, 47(9): 3018–3036

[125]

Wu Z S, Winter A, Chen L, . Three-dimensional nitrogen and boron co-doped graphene for high-performance all-solid-state supercapacitors. Advanced Materials, 2012, 24(37): 5130–5135

[126]

Sim Y, Kwak J, Kim S Y, . Formation of 3D graphene–Ni foam heterostructures with enhanced performance and durability for bipolar plates in a polymer electrolyte membrane fuel cell. Journal of Materials Chemistry A: Materials for Energy and Sustainability, 2018, 6(4): 1504–1512

[127]

Jiang X, Drzal L T. Exploring the potential of exfoliated graphene nanoplatelets as the conductive filler in polymeric nanocomposites for bipolar plates. Journal of Power Sources, 2012, 218: 297–306

[128]

Plengudomkit R, Okhawilai M, Rimdusit S. Highly filled graphene–benzoxazine composites as bipolar plates in fuel cell applications. Polymer Composites, 2016, 37(6): 1715–1727

[129]

Rimdusit S, Jubsilp C, Tiptipakorn S. Alloys and Composites of Polybenzoxazines: Properties and Applications. Springer, 2013

[130]

Onyu K, Yeetsorn R, Fowler M, . Evaluation of the possibility for using polypropylene/graphene composite as bipolar plate material instead of polypropylene/graphite composite. KMUTNB: International Journal of Applied Science and Technology, 2016, 9(2): 99–111

[131]

Adloo A, Sadeghi M, Masoomi M, . High performance polymeric bipolar plate based on polypropylene/graphite/graphene/nano-carbon black composites for PEM fuel cells. Renewable Energy, 2016, 99: 867–874

[132]

Kakati B K, Ghosh A, Verma A. Graphene reinforced composite bipolar plate for polymer electrolyte membrane fuel cell. In: American Society of Mechanical Engineers. ASME 2011 9th International Conference on Fuel Cell Science, Engineering and Technology collocated with ASME 2011 5th International Conference on Energy Sustainability, 2011, 301–307

[133]

Ghosh A, Goswami P, Mahanta P, . Effect of carbon fiber length and graphene on carbon–polymer composite bipolar plate for PEMFC. Journal of Solid State Electrochemistry, 2014, 18(12): 3427–3436

[134]

Jiang L, Syed J A, Lu H, . In-situ electrodeposition of conductive polypyrrole–graphene oxide composite coating for corrosion protection of 304SS bipolar plates. Journal of Alloys and Compounds, 2019, 770: 35–47

[135]

Singh B P, Nayak S, Nanda K K, . The production of a corrosion resistant graphene reinforced composite coating on copper by electrophoretic deposition. Carbon, 2013, 61: 47–56

[136]

Singh B P, Jena B K, Bhattacharjee S, . Development of oxidation and corrosion resistance hydrophobic graphene oxide–polymer composite coating on copper. Surface and Coatings Technology, 2013, 232: 475–481

RIGHTS & PERMISSIONS

Higher Education Press and Springer-Verlag GmbH Germany, part of Springer Nature

AI Summary AI Mindmap
PDF (3334KB)

1443

Accesses

0

Citation

Detail

Sections
Recommended

AI思维导图

/