Graphene-based bipolar plates for polymer electrolyte membrane fuel cells

Ram Sevak SINGH, Anurag GAUTAM, Varun RAI

PDF(3334 KB)
PDF(3334 KB)
Front. Mater. Sci. ›› 2019, Vol. 13 ›› Issue (3) : 217-241. DOI: 10.1007/s11706-019-0465-0
REVIEW ARTICLE
REVIEW ARTICLE

Graphene-based bipolar plates for polymer electrolyte membrane fuel cells

Author information +
History +

Abstract

Bipolar plates (BPs) are a major component of polymer electrolyte membrane fuel cells (PEMFCs). BPs play a multifunctional character within a PEMFC stack. It is one of the most costly and critical part of the fuel cell, and hence the development of efficient and cost-effective BPs is of much interest for the fabrication of next-generation PEMFCs in future. Owing to high electrical conductivity and chemical inertness, graphene is an ideal candidate to be utilized in BPs. This paper reviews recent advances in the area of graphene-based BPs for PEMFC applications. Various aspects including the momentous functions of BPs in the PEMFC, favorable features of graphene-based BPs, performance evaluation of various reported BPs with their advantages and disadvantages, challenges at commercial level products and future prospects of frontier research in this direction are extensively documented.

Keywords

graphene / bipolar plate / polymer electrolyte membrane fuel cell / proton exchange membrane fuel cell

Cite this article

Download citation ▾
Ram Sevak SINGH, Anurag GAUTAM, Varun RAI. Graphene-based bipolar plates for polymer electrolyte membrane fuel cells. Front. Mater. Sci., 2019, 13(3): 217‒241 https://doi.org/10.1007/s11706-019-0465-0

References

[1]
Wind J, Späh R, Kaiser W, . Metallic bipolar plates for PEM fuel cells. Journal of Power Sources, 2002, 105(2): 256–260
CrossRef Google scholar
[2]
Bar-On I, Kirchain R, Roth R. Technical cost analysis for PEM fuel cells. Journal of Power Sources, 2002, 109(1): 71–75
CrossRef Google scholar
[3]
Lv H, Mu S. Nano-ceramic support materials for low temperature fuel cell catalysts. Nanoscale, 2014, 6(10): 5063–5074
CrossRef Pubmed Google scholar
[4]
Wei M, Jiang M, Liu X, . Graphene-doped electrospun nanofiber membrane electrodes and proton exchange membrane fuel cell performance. Journal of Power Sources, 2016, 327: 384–393
CrossRef Google scholar
[5]
Mehta V, Cooper J S. Review and analysis of PEM fuel cell design and manufacturing. Journal of Power Sources, 2003, 114(1): 32–53
CrossRef Google scholar
[6]
Li X, Sabir I. Review of bipolar plates in PEM fuel cells: Flow-field designs. International Journal of Hydrogen Energy, 2005, 30(4): 359–371
CrossRef Google scholar
[7]
Davies D, Adcock P, Turpin M, . Stainless steel as a bipolar plate material for solid polymer fuel cells. Journal of Power Sources, 2000, 86(1–2): 237–242
CrossRef Google scholar
[8]
Busick D, Wilson M. Development of composite materials for PEFC bipolar plates. MRS Online Proceedings Library Archive, 1999, 575
CrossRef Google scholar
[9]
Heinzel A, Mahlendorf F, Niemzig O, . Injection moulded low cost bipolar plates for PEM fuel cells. Journal of Power Sources, 2004, 131(1–2): 35–40
CrossRef Google scholar
[10]
Borup R L, Vanderborgh N E. Design and testing criteria for bipolar plate materials for PEM fuel cell applications. MRS Online Proceedings Library Archive, 1995, 393
[11]
Lee S J, Huang C H, Lai J J, . Corrosion-resistant component for PEM fuel cells. Journal of Power Sources, 2004, 131(1–2): 162–168
CrossRef Google scholar
[12]
Dundar F, Dur E, Mahabunphachai S, . Corrosion resistance characteristics of stamped and hydroformed proton exchange membrane fuel cell metallic bipolar plates. Journal of Power Sources, 2010, 195(11): 3546–3552
CrossRef Google scholar
[13]
Jin C K, Kang C G. Fabrication by vacuum die casting and simulation of aluminum bipolar plates with micro-channels on both sides for proton exchange membrane (PEM) fuel cells. International Journal of Hydrogen Energy, 2012, 37(2): 1661–1676
CrossRef Google scholar
[14]
Hung J C, Chang D H, Chuang Y. The fabrication of high-aspect-ratio micro-flow channels on metallic bipolar plates using die-sinking micro-electrical discharge machining. Journal of Power Sources, 2012, 198: 158–163
CrossRef Google scholar
[15]
Deprez N, McLachlan D. The analysis of the electrical conductivity of graphite conductivity of graphite powders during compaction. Journal of Physics D: Applied Physics, 1988, 21(1): 101–107
CrossRef Google scholar
[16]
Davies D, Adcock P, Turpin M, . Bipolar plate materials for solid polymer fuel cells. Journal of Applied Electrochemistry, 2000, 30(1): 101–105
CrossRef Google scholar
[17]
Dhakate S, Mathur R, Kakati B, . Properties of graphite-composite bipolar plate prepared by compression molding technique for PEM fuel cell. International Journal of Hydrogen Energy, 2007, 32(17): 4537–4543
CrossRef Google scholar
[18]
Roßberg K, Trapp V. Graphite-based bipolar plates. In: Vielstich W, Gasteiger H A, Lamm A, ., eds. Handbook of Fuel Cells — Fundamentals, Technology and Applications. John Wiley & Sons, Ltd., 2010
[19]
Cho E, Jeon U S, Ha H, . Characteristics of composite bipolar plates for polymer electrolyte membrane fuel cells. Journal of Power Sources, 2004, 125(2): 178–182
CrossRef Google scholar
[20]
Kuan H C, Ma C C M, Chen K H, . Preparation, electrical, mechanical and thermal properties of composite bipolar plate for a fuel cell. Journal of Power Sources, 2004, 134(1): 7–17
CrossRef Google scholar
[21]
Hodgson D, May B, Adcock P, . New lightweight bipolar plate system for polymer electrolyte membrane fuel cells. Journal of Power Sources, 2001, 96(1): 233–235
CrossRef Google scholar
[22]
He D, Tang H, Kou Z, . Engineered graphene materials: synthesis and applications for polymer electrolyte membrane fuel cells. Advanced Materials, 2017, 29(20): 1601741
CrossRef Pubmed Google scholar
[23]
Hung Y, Tawfik H, El-Khatib K M, . Corrosion and contact resistance measurements of different bipolar plate material for polymer electrolyte membrane fuel cells. International Journal of Alternative Propulsion, 2008, 2(1): 72–85
CrossRef Google scholar
[24]
Zhang D, Duan L, Guo L, . TiN-coated titanium as the bipolar plate for PEMFC by multi-arc ion plating. International Journal of Hydrogen Energy, 2011, 36(15): 9155–9161
CrossRef Google scholar
[25]
Bi F, Peng L, Yi P, . Multilayered Zr–C/a-C film on stainless steel 316L as bipolar plates for proton exchange membrane fuel cells. Journal of Power Sources, 2016, 314: 58–65
CrossRef Google scholar
[26]
Yi P, Zhang W, Bi F, . Enhanced corrosion resistance and interfacial conductivity of TiCx/a-C nanolayered coatings via synergy of substrate bias voltage for bipolar plates applications in PEMFCs. ACS Applied Materials & Interfaces, 2018, 10(22): 19087–19096
CrossRef Google scholar
[27]
Jayaraj J, Kim Y, Kim K, . Corrosion studies on Fe-based amorphous alloys in simulated PEM fuel cell environment. Science and Technology of Advanced Materials, 2005, 6(3–4): 282–289
CrossRef Google scholar
[28]
Zhang D, Wang Z, Huang K. Composite coatings with in situ formation for Fe–Ni–Cr alloy as bipolar plate of PEMFC. International Journal of Hydrogen Energy, 2013, 38(26): 11379–11391
CrossRef Google scholar
[29]
Omrani M, Habibi M, Amrollahi R, . Improvement of corrosion and electrical conductivity of 316L stainless steel as bipolar plate by TiN nanoparticle implantation using plasma focus. International Journal of Hydrogen Energy, 2012, 37(19): 14676–14686
CrossRef Google scholar
[30]
Yoon W, Huang X, Fazzino P, . Evaluation of coated metallic bipolar plates for polymer electrolyte membrane fuel cells. Journal of Power Sources, 2008, 179(1): 265–273
CrossRef Google scholar
[31]
Wang S, Hou M, Zhao Q, . Ti/(Ti,Cr)N/CrN multilayer coated 316L stainless steel by arc ion plating as bipolar plates for proton exchange membrane fuel cells. Journal of Energy Chemistry, 2017, 26(1): 168–174
CrossRef Google scholar
[32]
Feng K, Shen Y, Sun H, . Conductive amorphous carbon-coated 316L stainless steel as bipolar plates in polymer electrolyte membrane fuel cells. International Journal of Hydrogen Energy, 2009, 34(16): 6771–6777
CrossRef Google scholar
[33]
Wang H, Sweikart M A, Turner J A. Stainless steel as bipolar plate material for polymer electrolyte membrane fuel cells. Journal of Power Sources, 2003, 115(2): 243–251
CrossRef Google scholar
[34]
Silva R, Franchi D, Leone A, . Surface conductivity and stability of metallic bipolar plate materials for polymer electrolyte fuel cells. Electrochimica Acta, 2006, 51(17): 3592–3598
CrossRef Google scholar
[35]
Joseph S, McClure J, Chianelli R, . Conducting polymer-coated stainless steel bipolar plates for proton exchange membrane fuel cells (PEMFC). International Journal of Hydrogen Energy, 2005, 30(12): 1339–1344
CrossRef Google scholar
[36]
Wang L, Sun J, Kang B, . Electrochemical behaviour and surface conductivity of niobium carbide-modified austenitic stainless steel bipolar plate. Journal of Power Sources, 2014, 246: 775–782
CrossRef Google scholar
[37]
Wang S H, Peng J, Lui W B, . Performance of the gold-plated titanium bipolar plates for the light weight PEM fuel cells. Journal of Power Sources, 2006, 162(1): 486–491
CrossRef Google scholar
[38]
Gamburzev S, Appleby A J. Recent progress in performance improvement of the proton exchange membrane fuel cell (PEMFC). Journal of Power Sources, 2002, 107(1): 5–12
CrossRef Google scholar
[39]
Kumar A, Reddy R G. Materials and design development for bipolar/end plates in fuel cells. Journal of Power Sources, 2004, 129(1): 62–67
CrossRef Google scholar
[40]
Cho E, Jeon U S, Hong S A, . Performance of a 1 kW-class PEMFC stack using TiN-coated 316 stainless steel bipolar plates. Journal of Power Sources, 2005, 142(1–2): 177–183
CrossRef Google scholar
[41]
Yi P, Peng L, Feng L, . Performance of a proton exchange membrane fuel cell stack using conductive amorphous carbon-coated 304 stainless steel bipolar plates. Journal of Power Sources, 2010, 195(20): 7061–7066
CrossRef Google scholar
[42]
Lee Y H, Li S M, Tseng C J, . Graphene as corrosion protection for metal foam flow distributor in proton exchange membrane fuel cells. International Journal of Hydrogen Energy, 2017, 42(34): 22201–22207
CrossRef Google scholar
[43]
Tseng C J, Tsai B T, Liu Z S, . A PEM fuel cell with metal foam as flow distributor. Energy Conversion and Management, 2012, 62: 14–21
CrossRef Google scholar
[44]
Lee S J, Huang C H, Chen Y P. Investigation of PVD coating on corrosion resistance of metallic bipolar plates in PEM fuel cell. Journal of Materials Processing Technology, 2003, 140(1–3): 688–693
CrossRef Google scholar
[45]
Gladczuk L, Joshi C, Patel A, . Corrosion-resistant tantalum coatings for PEM fuel cell bipolar plates. MRS Online Proceedings Library Archive, 2002, 756
CrossRef Google scholar
[46]
Ma L, Warthesen S, Shores D A. Evaluation of materials for bipolar plates in PEMFCs. Journal of New Materials for Electrochemical Systems, 2000, 3(3): 221–228
CrossRef Google scholar
[47]
Wang H, Turner J. Reviewing metallic PEMFC bipolar plates. Fuel Cells, 2010, 10(4): 510–519
CrossRef Google scholar
[48]
Hentall P L, Lakeman J B, Mepsted G O, . New materials for polymer electrolyte membrane fuel cell current collectors. Journal of Power Sources, 1999, 80(1–2): 235–241
CrossRef Google scholar
[49]
Hornung R, Kappelt G. Bipolar plate materials development using Fe-based alloys for solid polymer fuel cells. Journal of Power Sources, 1998, 72(1): 20–21
CrossRef Google scholar
[50]
Scholta J, Rohland B, Trapp V, . Investigations on novel low-cost graphite composite bipolar plates. Journal of Power Sources, 1999, 84(2): 231–234
CrossRef Google scholar
[51]
Scholta J, Berg N, Wilde P, . Development and performance of a 10 kW PEMFC stack. Journal of Power Sources, 2004, 127(1–2): 206–212
CrossRef Google scholar
[52]
Besmann T M, Klett J W, Burchell T D. Carbon composite for a PEM fuel cell bipolar plate. MRS Online Proceedings Library Archive, 1997, 496
CrossRef Google scholar
[53]
Cunningham N, Guay D, Dodelet J, . New materials and procedures to protect metallic PEM fuel cell bipolar plates. Journal of the Electrochemical Society, 2002, 149(7): A905–A911
CrossRef Google scholar
[54]
Gautam A, Ram S. Shape-controlled silver metal of nanospheroids from a polymer-assisted autocombustion reaction in open air. Journal of Alloys and Compounds, 2008, 463(1–2): 428–434
CrossRef Google scholar
[55]
Chang H, Koschany P, Lim C, . Materials and processes for light weight and high power density PEM fuel cells. Journal of New Materials for Electrochemical Systems, 2000, 3(1): 55–60
[56]
Tawfik H, Hung Y, Mahajan D. Metal bipolar plates for PEM fuel cell — a review. Journal of Power Sources, 2007, 163(2): 755–767
CrossRef Google scholar
[57]
Brady M, Weisbrod K, Zawodzinski C, . Assessment of thermal nitridation to protect metal bipolar plates in polymer electrolyte membrane fuel cells. Electrochemical and Solid-State Letters, 2002, 5(11): A245–A247
CrossRef Google scholar
[58]
Brady M P, Weisbrod K, Paulauskas I, . Preferential thermal nitridation to form pin-hole free Cr-nitrides to protect proton exchange membrane fuel cell metallic bipolar plates. Scripta Materialia, 2004, 50(7): 1017–1022
CrossRef Google scholar
[59]
Li M, Luo S, Zeng C, . Corrosion behavior of TiN coated type 316 stainless steel in simulated PEMFC environments. Corrosion Science, 2004, 46(6): 1369–1380
CrossRef Google scholar
[60]
Middelman E, Kout W, Vogelaar B, . Bipolar plates for PEM fuel cells. Journal of Power Sources, 2003, 118(1–2): 44–46
CrossRef Google scholar
[61]
Taherian R. A review of composite and metallic bipolar plates in proton exchange membrane fuel cell: Materials, fabrication, and material selection. Journal of Power Sources, 2014, 265: 370–390
CrossRef Google scholar
[62]
Hermann A, Chaudhuri T, Spagnol P. Bipolar plates for PEM fuel cells: A review. International Journal of Hydrogen Energy, 2005, 30(12): 1297–1302
CrossRef Google scholar
[63]
Steele B C, Heinzel A. Materials for fuel-cell technologies. Nature, 2001, 414(6861): 345–352
CrossRef Pubmed Google scholar
[64]
Dihrab S S, Sopian K, Alghoul M, . Review of the membrane and bipolar plates materials for conventional and unitized regenerative fuel cells. Renewable & Sustainable Energy Reviews, 2009, 13(6–7): 1663–1668
CrossRef Google scholar
[65]
Yuan X Z, Wang H, Zhang J, . Bipolar plates for PEM fuel cells-from materials to processing. Journal of New Materials for Electrochemical Systems, 2005, 8(4): 257
[66]
Iwan A, Malinowski M, Pasciak G. Polymer fuel cell components modified by graphene: Electrodes, electrolytes and bipolar plates. Renewable & Sustainable Energy Reviews, 2015, 49: 954–967
CrossRef Google scholar
[67]
Geim A K, Novoselov K S. The rise of graphene. Nature Materials, 2007, 6(3): 183–191
CrossRef Pubmed Google scholar
[68]
Novoselov K S, Geim A K, Morozov S V, . Two-dimensional gas of massless Dirac fermions in graphene. Nature, 2005, 438(7065): 197–200
[69]
Singh R S, Nalla V, Chen W, . Laser patterning of epitaxial graphene for Schottky junction photodetectors. ACS Nano, 2011, 5(7): 5969–5975
CrossRef Pubmed Google scholar
[70]
Singh R S, Nalla V, Chen W, . Photoresponse in epitaxial graphene with asymmetric metal contacts. Applied Physics Letters, 2012, 100(9): 093116 (3 pages)
CrossRef Google scholar
[71]
Singh R S, Wang X, Chen W, . Large room-temperature quantum linear magnetoresistance in multilayered epitaxial graphene: Evidence for two-dimensional magnetotransport. Applied Physics Letters, 2012, 101(18): 183105 (3 pages)
CrossRef Google scholar
[72]
Singh R S, Li D, Xiong Q, . Anomalous photoresponse in the deep-ultraviolet due to resonant excitonic effects in oxygen plasma treated few-layer graphene. Carbon, 2016, 106: 330–335
CrossRef Google scholar
[73]
Santoso I, Singh R S, Gogoi P K, . Tunable optical absorption and interactions in graphene via oxygen plasma. Physical Review B, 2014, 89(7): 075134
CrossRef Google scholar
[74]
Wu Z S, Ren W, Gao L, . Synthesis of graphene sheets with high electrical conductivity and good thermal stability by hydrogen arc discharge exfoliation. ACS Nano, 2009, 3(2): 411–417
CrossRef Pubmed Google scholar
[75]
Peigney A, Laurent C, Flahaut E, . Specific surface area of carbon nanotubes and bundles of carbon nanotubes. Carbon, 2001, 39(4): 507–514
CrossRef Google scholar
[76]
Lee C, Wei X, Kysar J W, . Measurement of the elastic properties and intrinsic strength of monolayer graphene. Science, 2008, 321(5887): 385–388
CrossRef Pubmed Google scholar
[77]
Balandin A A, Ghosh S, Bao W, . Superior thermal conductivity of single-layer graphene. Nano Letters, 2008, 8(3): 902–907
CrossRef Pubmed Google scholar
[78]
Williams J R, Dicarlo L, Marcus C M. Quantum Hall effect in a gate-controlled p–n junction of graphene. Science, 2007, 317(5838): 638–641
CrossRef Pubmed Google scholar
[79]
Novoselov K S, Geim A K, Morozov S V, . Electric field effect in atomically thin carbon films. Science, 2004, 306(5696): 666–669
CrossRef Pubmed Google scholar
[80]
Stankovich S, Dikin D A, Piner R D, . Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide. Carbon, 2007, 45(7): 1558–1565
CrossRef Google scholar
[81]
Hernandez Y, Nicolosi V, Lotya M, . High-yield production of graphene by liquid-phase exfoliation of graphite. Nature Nanotechnology, 2008, 3(9): 563–568
CrossRef Pubmed Google scholar
[82]
Hummers W S, Offeman R E. Preparation of graphitic oxide. Journal of the American Chemical Society, 1958, 80(6): 1339
CrossRef Google scholar
[83]
Choucair M, Thordarson P, Stride J A. Gram-scale production of graphene based on solvothermal synthesis and sonication. Nature Nanotechnology, 2009, 4(1): 30–33
CrossRef Pubmed Google scholar
[84]
Obraztsov A N. Chemical vapour deposition: Making graphene on a large scale. Nature Nanotechnology, 2009, 4(4): 212–213
CrossRef Pubmed Google scholar
[85]
Sutter P W, Flege J I, Sutter E A. Epitaxial graphene on ruthenium. Nature Materials, 2008, 7(5): 406–411
CrossRef Pubmed Google scholar
[86]
Kou Z, Meng T, Guo B, . A generic conversion strategy: From 2D metal carbides (MxCy) to M-self-doped graphene toward high-efficiency energy applications. Advanced Functional Materials, 2017, 27(8): 1604904
CrossRef Google scholar
[87]
Amiinu I S, Zhang J, Kou Z, . Self-organized 3D porous graphene dual-doped with biomass-sponsored nitrogen and sulfur for oxygen reduction and evolution. ACS Applied Materials & Interfaces, 2016, 8(43): 29408–29418
CrossRef Pubmed Google scholar
[88]
He D, Kou Z, Xiong Y, . Simultaneous sulfonation and reduction of graphene oxide as highly efficient supports for metal nanocatalysts. Carbon, 2014, 66: 312–319
CrossRef Google scholar
[89]
Kyhl L, Nielsen S F, Čabo A G, . Graphene as an anti-corrosion coating layer. Faraday Discussions, 2015, 180: 495–509
CrossRef Pubmed Google scholar
[90]
Zhang Y, Zhang H, Wang B, . Role of wrinkles in the corrosion of graphene domain-coated Cu surfaces. Applied Physics Letters, 2014, 104(14): 143110 (3 pages)
CrossRef Google scholar
[91]
Xu W, Zhao K, Zhang L, . SnS2@graphene nanosheet arrays grown on carbon cloth as freestanding binder-free flexible anodes for advanced sodium batteries. Journal of Alloys and Compounds, 2016, 654: 357–362
CrossRef Google scholar
[92]
Hsieh Y P, Hofmann M, Chang K W, . Complete corrosion inhibition through graphene defect passivation. ACS Nano, 2014, 8(1): 443–448
CrossRef Pubmed Google scholar
[93]
Wlasny I, Dabrowski P, Rogala M, . Role of graphene defects in corrosion of graphene-coated Cu(111) surface. Applied Physics Letters, 2013, 102(11): 111601 (3 pages)
CrossRef Google scholar
[94]
Rozada R, Paredes J I, Villar-Rodil S, . Towards full repair of defects in reduced graphene oxide films by two-step graphitization. Nano Research, 2013, 6(3): 216–233
CrossRef Google scholar
[95]
Li X, Cai W, An J, . Large-area synthesis of high-quality and uniform graphene films on copper foils. Science, 2009, 324(5932): 1312–1314
CrossRef Pubmed Google scholar
[96]
Prasai D, Tuberquia J C, Harl R R, . Graphene: corrosion-inhibiting coating. ACS Nano, 2012, 6(2): 1102–1108
CrossRef Pubmed Google scholar
[97]
Ye X, Lin Z, Zhang H, . Protecting carbon steel from corrosion by laser in situ grown graphene films. Carbon, 2015, 94: 326–334
CrossRef Google scholar
[98]
Nazarova M, Stora T, Zhukov A, . Growth of graphene on tantalum and its protective properties. Carbon, 2018, 139: 29–34
CrossRef Google scholar
[99]
Pu N W, Shi G N, Liu Y M, . Graphene grown on stainless steel as a high-performance and ecofriendly anti-corrosion coating for polymer electrolyte membrane fuel cell bipolar plates. Journal of Power Sources, 2015, 282: 248–256
CrossRef Google scholar
[100]
Antunes R A, Oliveira M C L, Ett G, . Corrosion of metal bipolar plates for PEM fuel cells: a review. International Journal of Hydrogen Energy, 2010, 35(8): 3632–3647
CrossRef Google scholar
[101]
Sudagar J, Lian J, Sha W. Electroless nickel, alloy, composite and nano coatings—A critical review. Journal of Alloys and Compounds, 2013, 571: 183–204
CrossRef Google scholar
[102]
Stoot A C, Camilli L, Spiegelhauer S A, . Multilayer graphene for long-term corrosion protection of stainless steel bipolar plates for polymer electrolyte membrane fuel cell. Journal of Power Sources, 2015, 293: 846–851
CrossRef Google scholar
[103]
Ren Y, Anisur M, Qiu W, . Degradation of graphene coated copper in simulated proton exchange membrane fuel cell environment: Electrochemical impedance spectroscopy study. Journal of Power Sources, 2017, 362: 366–372
CrossRef Google scholar
[104]
Lee Y H, Noh S, Lee J H, . Durable graphene-coated bipolar plates for polymer electrolyte fuel cells. International Journal of Hydrogen Energy, 2017, 42(44): 27350–27353
CrossRef Google scholar
[105]
Zheng Z, Liu Y, Bai Y, . Fabrication of biomimetic hydrophobic patterned graphene surface with ecofriendly anti-corrosion properties for Al alloy. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2016, 500: 64–71
CrossRef Google scholar
[106]
Mišković-Stanković V, Jevremović I, Jung I, . Electrochemical study of corrosion behavior of graphene coatings on copper and aluminum in a chloride solution. Carbon, 2014, 75: 335–344
CrossRef Google scholar
[107]
Kim Y J, Kim D H, Kim J S, . Electro and surface properties of graphene-modified stainless steel for PEMFC bipolar plates. Advanced Materials Research, 2014, 167–170
CrossRef Google scholar
[108]
Staudenmaier L. Verfahren zur darstellung der graphitsäure. European Journal of Inorganic Chemistry, 1899, 32(2): 1394–1399 (in German)
CrossRef Google scholar
[109]
Lv J, Tongxiang L, Chen W. The effects of molybdenum and reduced graphene oxide on corrosion resistance of amorphous nickel–phosphorus as bipolar plates in PEMFC environment. International Journal of Hydrogen Energy, 2016, 41(23): 9738–9745
CrossRef Google scholar
[110]
Raghupathy Y, Kamboj A, Rekha M, . Copper–graphene oxide composite coatings for corrosion protection of mild steel in 3.5% NaCl. Thin Solid Films, 2017, 636: 107–115
CrossRef Google scholar
[111]
Hirata M, Gotou T, Horiuchi S, . Thin-film particles of graphite oxide 1: High-yield synthesis and flexibility of the particles. Carbon, 2004, 42(14): 2929–2937
CrossRef Google scholar
[112]
Jang H, Kim J H, Kang H, . Reduced graphene oxide as a protection layer for Al. Applied Surface Science, 2017, 407: 1–7
CrossRef Google scholar
[113]
Pavan A S S, Ramanan S R. A study on corrosion resistant graphene films on low alloy steel. Applied Nanoscience, 2016, 6(8): 1175–1181
CrossRef Google scholar
[114]
Liu Y, Zhang J, Li S, . Fabrication of a superhydrophobic graphene surface with excellent mechanical abrasion and corrosion resistance on an aluminum alloy substrate. RSC Advances, 2014, 4(85): 45389–45396
CrossRef Google scholar
[115]
Liu J, Hua L, Li S, . Graphene dip coatings: An effective anticorrosion barrier on aluminum. Applied Surface Science, 2015, 327: 241–245
CrossRef Google scholar
[116]
Berlia R, Kumar M K P, Srivastava C. Electrochemical behavior of Sn–graphene composite coating. RSC Advances, 2015, 5(87): 71413–71418
CrossRef Google scholar
[117]
Liu C, Su F, Liang J. Producing cobalt–graphene composite coating by pulse electrodeposition with excellent wear and corrosion resistance. Applied Surface Science, 2015, 351: 889–896
CrossRef Google scholar
[118]
Sadhir M H, Saranya M, Aravind M, . Comparison of in situ and ex situ reduced graphene oxide reinforced electroless nickel phosphorus nanocomposite coating. Applied Surface Science, 2014, 320: 171–176
CrossRef Google scholar
[119]
Amani H, Mostafavi E, Arzaghi H, . Three-dimensional graphene foams: synthesis, properties, biocompatibility, biodegradability, and applications in tissue engineering. ACS Biomaterials Science & Engineering, 2019, 5(1): 193–214
CrossRef Google scholar
[120]
Chen Z, Ren W, Gao L, . Three-dimensional flexible and conductive interconnected graphene networks grown by chemical vapour deposition. Nature Materials, 2011, 10(6): 424–428
CrossRef Pubmed Google scholar
[121]
Yavari F, Chen Z, Thomas A V, . High sensitivity gas detection using a macroscopic three-dimensional graphene foam network. Scientific Reports, 2011, 1(1): 166
CrossRef Pubmed Google scholar
[122]
Wang J K, Xiong G M, Zhu M, . Polymer-enriched 3D graphene foams for biomedical applications. ACS Applied Materials & Interfaces, 2015, 7(15): 8275–8283
CrossRef Pubmed Google scholar
[123]
Loeblein M, Bolker A, Tsang S H, . 3D graphene-infused polyimide with enhanced electrothermal performance for long-term flexible space applications. Small, 2015, 11(48): 6425–6434
CrossRef Pubmed Google scholar
[124]
Chen K, Shi L, Zhang Y, . Scalable chemical-vapour-deposition growth of three-dimensional graphene materials towards energy-related applications. Chemical Society Reviews, 2018, 47(9): 3018–3036
CrossRef Pubmed Google scholar
[125]
Wu Z S, Winter A, Chen L, . Three-dimensional nitrogen and boron co-doped graphene for high-performance all-solid-state supercapacitors. Advanced Materials, 2012, 24(37): 5130–5135
CrossRef Pubmed Google scholar
[126]
Sim Y, Kwak J, Kim S Y, . Formation of 3D graphene–Ni foam heterostructures with enhanced performance and durability for bipolar plates in a polymer electrolyte membrane fuel cell. Journal of Materials Chemistry A: Materials for Energy and Sustainability, 2018, 6(4): 1504–1512
CrossRef Google scholar
[127]
Jiang X, Drzal L T. Exploring the potential of exfoliated graphene nanoplatelets as the conductive filler in polymeric nanocomposites for bipolar plates. Journal of Power Sources, 2012, 218: 297–306
CrossRef Google scholar
[128]
Plengudomkit R, Okhawilai M, Rimdusit S. Highly filled graphene–benzoxazine composites as bipolar plates in fuel cell applications. Polymer Composites, 2016, 37(6): 1715–1727
CrossRef Google scholar
[129]
Rimdusit S, Jubsilp C, Tiptipakorn S. Alloys and Composites of Polybenzoxazines: Properties and Applications. Springer, 2013
[130]
Onyu K, Yeetsorn R, Fowler M, . Evaluation of the possibility for using polypropylene/graphene composite as bipolar plate material instead of polypropylene/graphite composite. KMUTNB: International Journal of Applied Science and Technology, 2016, 9(2): 99–111
CrossRef Google scholar
[131]
Adloo A, Sadeghi M, Masoomi M, . High performance polymeric bipolar plate based on polypropylene/graphite/graphene/nano-carbon black composites for PEM fuel cells. Renewable Energy, 2016, 99: 867–874
CrossRef Google scholar
[132]
Kakati B K, Ghosh A, Verma A. Graphene reinforced composite bipolar plate for polymer electrolyte membrane fuel cell. In: American Society of Mechanical Engineers. ASME 2011 9th International Conference on Fuel Cell Science, Engineering and Technology collocated with ASME 2011 5th International Conference on Energy Sustainability, 2011, 301–307
[133]
Ghosh A, Goswami P, Mahanta P, . Effect of carbon fiber length and graphene on carbon–polymer composite bipolar plate for PEMFC. Journal of Solid State Electrochemistry, 2014, 18(12): 3427–3436
CrossRef Google scholar
[134]
Jiang L, Syed J A, Lu H, . In-situ electrodeposition of conductive polypyrrole–graphene oxide composite coating for corrosion protection of 304SS bipolar plates. Journal of Alloys and Compounds, 2019, 770: 35–47
CrossRef Google scholar
[135]
Singh B P, Nayak S, Nanda K K, . The production of a corrosion resistant graphene reinforced composite coating on copper by electrophoretic deposition. Carbon, 2013, 61: 47–56
CrossRef Google scholar
[136]
Singh B P, Jena B K, Bhattacharjee S, . Development of oxidation and corrosion resistance hydrophobic graphene oxide–polymer composite coating on copper. Surface and Coatings Technology, 2013, 232: 475–481
CrossRef Google scholar

Acknowledgements

The authors gratefully acknowledge the work of all researchers in this field that helped us compile this review.

RIGHTS & PERMISSIONS

2019 Higher Education Press and Springer-Verlag GmbH Germany, part of Springer Nature
AI Summary AI Mindmap
PDF(3334 KB)

Accesses

Citations

Detail

Sections
Recommended

/