A simple single-step approach towards synthesis of nanofluids containing cuboctahedral cuprous oxide particles using glucose reduction

U. Sandhya SHENOY, A. Nityananda SHETTY

Front. Mater. Sci. ›› 2018, Vol. 12 ›› Issue (1) : 74-82.

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PDF(308 KB)
Front. Mater. Sci. ›› 2018, Vol. 12 ›› Issue (1) : 74-82. DOI: 10.1007/s11706-018-0411-6
RESEARCH ARTICLE
RESEARCH ARTICLE

A simple single-step approach towards synthesis of nanofluids containing cuboctahedral cuprous oxide particles using glucose reduction

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Abstract

Enhancement of thermal properties of conventional heat transfer fluids has become one of the important technical challenges. Since nanofluids offer a promising help in this regard, development of simpler and hassle free routes for their synthesis is of utmost importance. Synthesis of nanofluids using a hassle free route with greener chemicals has been reported. The single-step chemical approach reported here overcomes the drawbacks of the two-step procedures in the synthesis of nanofluids. The resulting Newtonian nanofluids prepared contained cuboctahedral particles of cuprous oxide and exhibited a thermal conductivity of 2.852 W·m−1·K−1. Polyvinylpyrrolidone (PVP) used during the synthesis acted as a stabilizing agent rendering the nanofluid a stability of 9 weeks.

Keywords

cuprous oxide / nanofluids / thermal conductivity / viscosity

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U. Sandhya SHENOY, A. Nityananda SHETTY. A simple single-step approach towards synthesis of nanofluids containing cuboctahedral cuprous oxide particles using glucose reduction. Front. Mater. Sci., 2018, 12(1): 74‒82 https://doi.org/10.1007/s11706-018-0411-6

References

[1]
Shin D, Banerjee D. Specific heat of nanofluids synthesized by dispersing alumina nanoparticles in alkali salt eutectic. International Journal of Heat and Mass Transfer, 2014, 74: 210–214
CrossRef Google scholar
[2]
Chakraborty S, Sarkar I, Haldar K, . Synthesis of Cu–Al layered double hydroxide nanofluid and characterization of its thermal properties. Applied Clay Science, 2015, 107: 98–108
CrossRef Google scholar
[3]
Chopkar M, Das P K, Manna I. Synthesis and characterization of nanofluid for advanced heat transfer applications. Scripta Materialia, 2006, 55(6): 549–552
CrossRef Google scholar
[4]
Li Y, Zhou J, Tung S, . A review on development of nanofluid preparation and characterization. Powder Technology, 2009, 196(2): 89–101
CrossRef Google scholar
[5]
Li C C, Chang M H. Colloidal stability of CuO nanoparticles in alkanes via oleate modifications. Materials Letters, 2004, 58(30): 3903–3907
CrossRef Google scholar
[6]
Beck M P, Yuan Y, Warrier P, . The thermal conductivity of alumina nanofluids in water, ethylene glycol and ethylene glycol-water mixtures. Journal of Nanoparticle Research, 2010, 12(4): 1469–1477
CrossRef Google scholar
[7]
Eastman J A, Choi S U S, Li S, . Anomalously increased effective thermal conductivities of ethylene glycol based nanofluids containing copper nanoparticles. Applied Physics Letters, 2001, 78(6): 718–720
CrossRef Google scholar
[8]
Heo Y K, Bratescu M A, Aburaya D, . A phonon thermodynamics approach of gold nanofluids synthesized in solution Plasma. Applied Physics Letters, 2014, 104(11): 111902 (3 pages)
CrossRef Google scholar
[9]
Phuoc T X, Soong Y, Chyu M K. Synthesis of Ag-deionized water nanofluids using multi-beam laser ablation in liquids. Optics and Lasers in Engineering, 2007, 45(12): 1099–1106
CrossRef Google scholar
[10]
Lee G J, Kim C K, Lee M K, . Thermal conductivity enhancement of ZnO nanofluid using a one-step physical method. Thermochimica Acta, 2012, 542: 24–27
CrossRef Google scholar
[11]
Tavares J, Coulombe S. Dual plasma synthesis and characterization of a stable copper-ethylene glycol nanofluid. Powder Technology, 2011, 210(2): 132–142
CrossRef Google scholar
[12]
Zhao T, Sun R, Yu S, . Size controlled preparation of silver nanoparticles by a modified polyol method. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2010, 366(1–3): 197–202
CrossRef Google scholar
[13]
Zhu H T, Lin Y S, Yin Y S. A novel one-step chemical method for preparation of copper nanofluids. Journal of Colloid and Interface Science, 2004, 277(1): 100–103
CrossRef Pubmed Google scholar
[14]
Kumar A S, Meenakshi K S, Narashimhan B R V, . Synthesis and characterization of copper nanofluid by a novel one-step method. Materials Chemistry and Physics, 2009, 113(1): 57–62
CrossRef Google scholar
[15]
Shenoy U S, Shetty A N. Synthesis of copper nanofluids using ascorbic acid reduction method via one step solution phase approach. Journal of ASTM International, 2012, 9(5): 104416
CrossRef Google scholar
[16]
Shenoy U S, Shetty A N. Simple glucose reduction route for one step synthesis of copper nanofluids. Applied Nanoscience, 2014, 4(1): 47–54
CrossRef Google scholar
[17]
Shenoy U S, Shetty A N. Copper nanofluids: A facile synthetic approach. Journal of Nanoengineering and Nanomanufacturing, 2013, 3(1): 64–69
CrossRef Google scholar
[18]
Shenoy U S, Shetty A N. A facile ascorbic acid reduction method for solution phase single step synthesis of copper nanofluids. NanoTrends: A Journal of Nanotechnology and Its Applications, 2013, 14: 09734181
[19]
Shenoy U S, Shetty A N. A simple solution phase synthesis of copper nanofluids using single step glucose reduction method. Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry, 2013, 43(3): 343–348
CrossRef Google scholar
[20]
Shenoy U S, Shetty A N. A simple approach towards synthesis of nanofluids containing octahedral copper nanoparticles. Journal of Nanofluids, 2015, 4(4): 428–434
CrossRef Google scholar
[21]
Shenoy U S, Shetty A N. Direct synthesis of nanofluids containing novel hexagonal disc shaped copper nanoparticles. Journal of Nanofluids, 2017, 6(1): 11–17
CrossRef Google scholar
[22]
Shenoy U S, Shetty A N. A facile one step solution route to synthesize cuprous oxide nanofluid. Nanomaterials and Nanotechology, 2013, 3(5): 2013 (7 pages)
[23]
Song H C, Cho Y S, Huh Y D. Morphology controlled synthesis of Cu2O microcrystal. Materials Letters, 2008, 62(10–11): 1734–1736
CrossRef Google scholar
[24]
Pal J, Ganguly M, Mondal C, . Crystal plane dependent etching of cuprous oxide nanoparticles of varied shapes and their application in visible light photocatalysis. The Journal of Physical Chemistry C, 2013, 117(46): 24640–24653
CrossRef Google scholar
[25]
Zhang H, Liu F, Li B, . Microwave assisted synthesis of Cu2O microcrystals with systematic shape evolution from octahedral to cubic and their comparative photocatalytic activities. RSC Advances, 2014, 4(72): 38059–38063
CrossRef Google scholar
[26]
Wei X, Zhu H, Kong T, . Synthesis and thermal conductivity of Cu2O nanofluids. International Journal of Heat and Mass Transfer, 2009, 52(19–20): 4371–4374
CrossRef Google scholar
[27]
Murshed S M S, Leong K C, Yang C. Investigations of thermal conductivity and viscosity of nanofluid. International Journal of Thermal Sciences, 2008, 47(5): 560–568
CrossRef Google scholar
[28]
Sreeremya T S, Krishnan A, Satapathy L N, . Facile synthetic strategy of oleophilic zirconia nanoparticles allows preparation of highly stable thermo-conductive coolant. RSC Advances, 2014, 4(53): 28020–28028
CrossRef Google scholar
[29]
Yu W, Xie H, Chen L, . Investigation of thermal conductivity and viscosity of ethylene glycol based ZnO nanofluid. Thermochimica Acta, 2009, 491(1–2): 92–96
CrossRef Google scholar
[30]
Li D, Xie W, Fang W. Preparation and properties of copper-oil-based nanofluids. Nanoscale Research Letters, 2011, 6(1): 373 (7 pages)
CrossRef Pubmed Google scholar

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