Green synthesis of metal/C and metal oxide/C films by using natural membrane as support

Abstract

A protocol aiming at making use of the huge amount of naturally existing wastes such as defoliation, pericarp and egg shell for nanostructured composite materials was proposed. In this study, a green synthetic route using naturally existing membrane as support was developed for the synthesis of nanostructured and porous metal- or metal oxide-carbon composite films. Different metallic ions (Co²⁺, Ni²⁺, Fe³⁺, Mn²⁺ or Cu²⁺) can be easily adsorbed onto egg membranes and the followed calcination process results in the formation of Co/C, Ni/C, Fe₃O₄/C, MnO/C or Cu/Cu₂O/CuO/C composite films. The electrochemical studies demonstrate that such composite films would have potential applications in energy fields. This method would provide a general green concept for chemical synthesis and be beneficial to the global sustainable future.

Keywords

green synthesis / metal / metal oxide / composite / electrochemistry

References

[1] Raveendran P, Fu J, Wallen S L. Completely “green” synthesis and stabilization of metal nanoparticles. Journal of the American Chemical Society, 2003, 125(46): 13940–13941

[2] Lu Q, Gao F, Komarneni S. A green chemical approach to the synthesis of tellurium nanowires. Langmuir, 2005, 21(13): 6002–6005

[3] Venkataramanan N S, Matsui K, Kawanami H, . Green synthesis of titania nanowire composites on natural cellulose fibers. Green Chemistry, 2007, 9(1): 18–19

[4] Baruwati B, Polshettiwar V, Varma R S. Glutathione promoted expeditious green synthesis of silver nanoparticles in water using microwaves. Green Chemistry, 2009, 11(7): 926–930

[5] Xie J, Lee J Y, Wang D I C, . Silver nanoplates: from biological to biomimetic synthesis. ACS Nano, 2007, 1(5): 429–439

[6] Kumar A, Vemula P K, Ajayan P M, . Silver-nanoparticle-embedded antimicrobial paints based on vegetable oil. Nature Materials, 2008, 7(3): 236–241

[7] Kemp M M, Kumar A, Clement D, . Hyaluronan- and heparin-reduced silver nanoparticles with antimicrobial properties. Nanomedicine, 2009, 4(4): 421–429

[8] Shankar S S, Rai A, Ankamwar B, . Biological synthesis of triangular gold nanoprisms. Nature Materials, 2004, 3(7): 482–488

[9] Shenton W, Douglas T, Young M, . Inorganic–organic nanotube composites from template mineralization of tobacco mosaic virus. Advanced Materials, 1999, 11(3): 253–256

[10] Lee S W, Mao C, Flynn C E, . Ordering of quantum dots using genetically engineered viruses. Science, 2002, 296(5569): 892–895

[11] Jain N, Bhargava A, Majumdar S, . Extracellular biosynthesis and characterization of silver nanoparticles using Aspergillus flavus NJP08: a mechanism perspective. Nanoscale, 2011, 3(2): 635–641

[12] Mukherjee P, Ahmad A, Mandal D, . Fungus-mediated synthesis of silver nanoparticles and their immobilization in the mycelial matrix: a novel biological approach to nanoparticle synthesis. Nano Letters, 2001, 1(10): 515–519

[13] Mukherjee P, Ahmad A, Mandal D, . Bioreduction of AuCl4-<?Pub Caret?> ions by the Fungus, Verticillium sp. and surface trapping of the gold nanoparticles formed. Angewandte Chemie International Edition, 2001, 40(19): 3585–3588

[14] Thakkar K N, Mhatre S S, Parikh R Y. Biological synthesis of metallic nanoparticles. Nanomedicine, 2010, 6(2): 257–262

[15] Lin X B, Wu M, Wu D Y, . Platinum nanoparticles using wood nanomaterials: eco-friendly synthesis, shape control and catalytic activity for p-nitrophenol reduction. Green Chemistry, 2011, 13(2): 283–287

[16] Iravani S. Green synthesis of metal nanoparticles using plants. Green Chemistry, 2011, 13(10): 2638–2650

[17] Liu N, Huo K, McDowell M T, . Rice husks as a sustainable source of nanostructured silicon for high performance Li-ion battery anodes. Scientific Reports, 2013, 3: 1919 (7 pages)

[18] Winter M, Brodd R J. What are batteries, fuel cells, and supercapacitors? Chemical Reviews, 2004, 104(10): 4245–4269

[19] Arunachalam V S, Fleischer E L. Harnessing materials for energy. MRS Bulletin, 2008, 33(4): 261

[20] Armand M, Tarascon J M. Building better batteries. Nature, 2008, 451(7179): 652–657

[21] Jacobson M Z. Review of solutions to global warming, air pollution, and energy security. Energy Environment Science, 2009, 2(2): 148–173

[22] Baxter J, Bian Z X, Chen G, . Nanoscale design to enable the revolution in renewable energy. Energy & Environment Science, 2009, 2(6): 559–588

[23] Orilall M C, Wiesner U. Block copolymer based composition and morphology control in nanostructured hybrid materials for energy conversion and storage: solar cells, batteries, and fuel cells. Chemical Society Reviews, 2011, 40(2): 520–535

[24] Wallace G G, Chen J, Mozer A J, . Nanoelectrodes: energy conversion and storage. Materials Today, 2009, 12(6): 20–27

[25] O’Hayre R, Cha S W, Colella W, . Fuel Cell Fundamentals. New Jersey, USA: John Wiley & Sons, 2005

[26] He S, Lu C, Zhang S. Facile and efficient route to polyimide-TiO₂ nanocomposite coating onto carbon fiber. ACS Applied Materials & Interfaces, 2011, 3(12): 4744–4750

[27] Nam K W, Kim K B. A study of the preparation of NiO_x electrode via electrochemical route for supercapacitor applications and their charge storage mechanism. Journal of the Electrochemical Society, 2002, 149(3): A346–A354

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