Recent research situation in tin dioxide nanomaterials: synthesis, microstructures, and properties

Abstract

This review article summarizes the new research in solid-state physical chemistry understanding of the microstructure characteristics of semiconductor tin oxide thin films made in the last years in our group. The work mainly focuses on the fabrication technology of semiconductor tin oxides thin films by using pulsed laser deposition (PLD) as well as the application of this technology on new micro- and nanostructured materials. It is an interdisciplinary work that integrates the areas of physics, chemistry and materials science.

Keywords

tin dioxide / thin film / synthesis / microstructure / nanostructure / property

References

[1] Chopra K L, Major S, Pandya D K. Transparent conductors-A status review. Thin Solid Films , 1983, 102(1): 1–46
[2] Kohl D.The role of noble metals in the chemistry of solid-state gas sensors. Sensors and Actuators B: Chemical , 1990, 1(1–6): 158 –165
[3] Abello L, Bochu B, Gaskov A, . Structural characterization of nanocrystalline SnO₂ by X-ray and Raman spectroscopy. Journal of Solid State Chemistry , 1998, 135(1): 78–85
[4] Ansari S G, Boroojerdian P, Sainkar S R, . Grain size effects on H₂ gas sensitivity of thick film resistor using SnO₂ nanoparticles. Thin Solid Films , 1997, 295(1–2): 271–276
[5] Ferrere S, Zaban A, Gregg B A. Dye sensitization of nanocrystalline tin oxide by perylene derivatives. The Journal of Physical Chemistry B , 1997, 101(23): 4490–4493
[6] Varghese O K, Malhotra L K. Electrode-sample capacitance effect on ethanol sensitivity of nano-grained SnO₂ thin films. Sensors and Actuators B: Chemical , 1998, 53(1–2): 19–23
[7] He Y S, Campbell J C, Murphy R C, . Electrical and optical characterization of Sb:SnO₂. Journal of Materials Research , 1993, 8(12): 3131–3134
[8] Wang D, Wen S, Chen J, . Microstructure of SnO₂. Physical Review B , 1994, 49(20): 14282–14285
[9] Cirera A, Vilà A, Diéguez A, . Microwave processing for the low cost, mass production of undoped and in situ catalytic doped nanosized SnO₂ gas sensor powders. Sensors and Actuators B: Chemical , 2000, 64(1–3): 65–69
[10] Sekizawa K, Widjaja H, Maeda S, . Low temperature oxidation of methane over Pd catalyst supported on metal oxides. Catalysis Today , 2000, 59(1–2): 69–74
[11] Dai Z R, Gole J L, Stout J D, . Tin oxide nanowires, nanoribbons, and nanotubes. The Journal of Physical Chemistry B , 2002, 106(6): 1274–1279
[12] Liu Y, Zheng C, Wang W, . Synthesis and characterization of rutile SnO₂ nanorods. Advanced Materials , 2001, 13(24): 1883–1887
[13] Xu C K, Xu G D, Liu Y K, . Preparation and characterization of SnO₂ nanorods by thermal decomposition of SnC₂O₄ precursor. Scripta Materialia , 2002, 46(11): 789–794
[14] Pan Z W, Dai Z R, Wang Z L. Nanobelts of semiconducting oxides. Science , 2001, 291(5510): 1947–1949
[15] Dai Z R, Pan Z W, Wang Z L. Ultra-long single crystalline nanoribbons of tin oxide. Solid State Communications , 2001, 118(7): 351–354
[16] Hu J Q, Ma X L, Shang N G, . Large-scale rapid oxidation synthesis of SnO₂ nanoribbons. The Journal of Physical Chemistry B , 2002, 106(15): 3823–3826
[17] Maddalena A, Maschio R D, Dire S, . Electrical conductivity of tin oxide films prepared by the sol-gel method. Journal of Non-Crystalline Solids , 1990, 121(1–3): 365–369
[18] Shek C H, Lai J K L, Lin G M. Grain growth in nanocrystalline SnO₂ prepared by sol-gel route. Nanostructured Materials , 1999, 11(7): 887–893
[19] Ghoshtagore R N. Mechanism of CVD thin film SnO₂ formation. Journal of the Electrochemical Society , 1978, 125(1): 110–117
[20] Tarey R D, Raju T A. A method for the deposition of transparent conducting thin films of tin oxide. Thin Solid Films , 1985, 128(3–4): 181–189
[21] Minami T, Nanto H, Takata S. Highly conducting and transparent SnO₂ thin films prepared by RF magnetron sputtering on low-temperature substrates. Japanese Journal of Applied Physics , 1988, 27(1): L287–L289
[22] Zhu J J, Lu Z H, Aruna S T, . Sonochemical synthesis of SnO₂ nanoparticles and their preliminary study as Li insertion electrodes. Chemistry of Materials , 2000, 12(9): 2557–2566
[23] Schlosser V, Wind G. Electrical and optical properties of tin oxide layers prepared by physical vapor deposition. In: Solomon I, Equer B, Helm P, eds. Eighth E.C. Photovoltaic Solar Energy Conference: Proceedings of the International Conference, Held at Florence, Italy, May 9–13, 1988 . Dordrecht, the Netherlands: Kluwer Academic Publishers, 1988, 998
[24] Zhu X, Birringer R, Herr U, . X-ray diffraction studies of the structure of nanometer-sized crystalline materials. Physical Review B , 1987, 35(17): 9085–9090
[25] Schaefer H E, Würschum R, Birringer R, . Structure of nanometer-sized polycrystalline iron investigated by positron lifetime spectroscopy. Physical Review B , 1988, 38(14): 9545–9554
[26] Chrisey D B, Hubler G K. Pulsed Laser Deposition of Thin Films . New York: Wiley, 1994, 327
[27] Willmott P R, Huber J R. Pulsed laser vaporization and deposition. Reviews of Modern Physics , 2000, 72(1): 315–328
[28] Auciello O, Engemann J, eds. Multicomponent and Multilayered Thin Films for Advanced Microtechnologies: Techniques, Fundamentals, and Devices . The Netherlands: Kluwer Academic Publishers, 1993
[29] B?uerle D. Laser Processing and Chemistry . New York: Springer, 1996
[30] Chen Z W, Lai J K L, Shek C H, . Nucleation and growth of SnO₂ nanocrystallites prepared by pulsed laser deposition. Applied Physics A: Materials Science & Processing , 2005, 81(5): 959–962
[31] von Allmen M, Blatter A. Laser-Beam Interactions with Materials . New York: Springer, 1995
[32] Campbell C T, Parker S C, Starr D E. The effect of size-dependent nanoparticle energetics on catalyst sintering. Science , 2002, 298(5594): 811–814
[33] Merkle K L, Thompson L J, Phillipp F. Collective effects in grain boundary migration. Physical Review Letters , 2002, 88(22): 225501 (4 pages)
[34] Moldovan D, Yamakov V, Wolf D, . Scaling behavior of grain-rotation-induced grain growth. Physical Review Letters , 2002, 89(20): 206101 (4 pages)
[35] Penn R L, Banfield J F. Imperfect oriented attachment: dislocation generation in defect-free nanocrystals. Science , 1998, 281(5379): 969–971
[36] Leite E R, Giraldi T R, Pontes F M, . Crystal growth in colloidal tin oxide nanocrystals induced by coalescence at room temperature. Applied Physics Letters , 2003, 83(8): 1566–1568
[37] Leite E R, Weber I T, Longo E, . A new method to control particle size and particle size distribution of SnO₂ nanoparticles for gas sensor applications. Advanced Materials , 2000, 12(13): 965–968
[38] Leite E R, Maciel A P, Weber I T, . Development of metal oxide nanoparticles with high stability against particle growth using a metastable solid solution. Advanced Materials , 2002, 14(12): 905–908
[39] Musolino V, Dal Corso A, Selloni A. Initial stages of growth of copper on MgO(100): A first principles study. Physical Review Letters , 1999, 83(14): 2761–2764
[40] Hu M, Noda S, Komiyama H. A new insight into the growth mode of metals on TiO₂(110). Surface Science , 2002, 513(3): 530–538
[41] Bajt S, Stearns D G, Kearney P A. Investigation of the amorphous-to-crystalline transition in Mo/Si multilayers. Journal of Applied Physics , 2001, 90(2): 1017–1025
[42] Soler J M, Beltran M R, Michaelian K, . Metallic bonding and cluster structure. Physical Review B , 2000, 61(8): 5771–5780
[43] Hu M, Noda S, Tsuji Y, . Effect of interfacial interactions on the initial growth of Cu on clean SiO₂ and 3-mercaptopropyltrimethoxysilane-modified SiO₂ substrates. Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films , 2002, 20(3): 589–596
[44] Zuo J M, Li B Q. Nanostructure evolution during cluster growth: Ag on H-terminated Si(111) surfaces. Physical Review Letters , 2002, 88(25): 255502 (4 pages)
[45] Williams G, Coles G S V. Gas sensing properties of nanocrystalline metal oxide powders produced by a laser evaporation technique. Journal of Materials Chemistry , 1998, 8(7): 1657–1664
[46] Bruno L, Pijolat C, Lalauze R. Tin dioxide thin-film gas sensor prepared by chemical vapour deposition: Influence of grain size and thickness on the electrical properties. Sensors and Actuators B: Chemical , 1994, 18(1–3): 195–199
[47] Serventi A M, Dolbec R, El Khakani M A, . High-resolution transmission electron microscopy investigation of the nanostructure of undoped and Pt-doped nanocrystalline pulsed laser deposited SnO₂ thin films. Journal of Physics and Chemistry of Solids , 2003, 64(11): 2097–2103
[48] Chen Z W, Lai J K L, Shek C H, . Synthesis and structural characterization of rutile SnO₂ nanocrystals. Journal of Materials Research , 2003, 18(6): 1289–1292
[49] Chen Z W, Lai J K L, Shek C H, . Multifractal spectra of scanning electron microscope images of SnO₂ thin films prepared by pulsed laser deposition. Physics Letters A , 2005, 345(1–3): 218–223
[50] Chen Z W, Lai J K L, Shek C H. Insights into microstructural evolution from nanocrystalline SnO₂ thin films prepared by pulsed laser deposition. Physical Review B , 2004, 70(16): 165314 (7 pages)
[51] Chen Z W, Lai J K L, Shek C H. High-resolution transmission electron microscopy investigation of nanostructures in SnO₂ thin films prepared by pulsed laser deposition. Journal of Solid State Chemistry , 2005, 178(3): 892–896
[52] Chen Z W, Lai J K L, Shek C H. Mystery of porous SnO₂ thin film formation by pulsed delivery. Chemical Physics Letters , 2006, 422(1–3): 1–5
[53] Serventi A M, El Khakani M A, Saint-Jacques R G, . Highly textured nanostructure of pulsed laser deposited IrO₂ thin films as investigated by transmission electron microscopy. Journal of Materials Research , 2001, 16(08): 2336–2342
[54] Butty J, Peyghambarian N, Kao Y H, . Room temperature optical gain in sol-gel derived CdS quantum dots. Applied Physics Letters , 1996, 69(21): 3224–3226
[55] Chen Z W, Wang X P, Tan S, . Multifractal behavior of crystallization on Au/Ge bilayer films. Physical Review B , 2001, 63(16): 165413 (5 pages)
[56] Huang L J, Liu B X, Ding J R, . Multifractal characteristics of magnetic-microsphere aggregates in thin films. Physical Review B , 1989, 40(1): 858–861
[57] Li H, Ding Z, Wu Z. Multifractal behavior of the distribution of secondary-electron-emission sites on solid surfaces. Physical Review B , 1995, 51(19): 13554–13559
[58] Li H, Ding Z-J, Wu Z. Multifractal analysis of the spatial distribution of secondary-electron emission sites. Physical Review B , 1996, 53(24): 16631–16636
[59] Wang B, Wang Y, Wu Z. Multifractal behavior of solid-on-solid growth. Solid State Communications , 1995, 96(2): 69–72
[60] Ohta S, Honjo H. Growth probability distribution in irregular fractal-like crystal growth of ammonium chloride. Physical Review Letters , 1988, 60(7): 611–614
[61] Xu C, Tamaki J, Miura N, . Grain size effects on gas sensitivity of porous SnO₂-based elements. Sensors and Actuators B: Chemical , 1991, 3(2): 147–155
[62] Baumann T F, Kucheyev S O, Gash A E, . Facile synthesis of a crystalline, high-surface-area SnO₂ aerogel. Advanced Materials , 2005, 17(12): 1546–1548
[63] Cheng B, Russell J M, Shi W S, . Large-Scale, solution-phase growth of single-crystalline SnO₂ nanorods. Journal of the American Chemical Society , 2004, 126(19): 5972–5973
[64] Hu J Q, Bando Y, Liu Q L, . Laser-ablation growth and optical properties of wide and long single-crystal SnO₂ ribbons. Advanced Functional Materials , 2003, 13(6): 493–496
[65] McCarthy G, Welton J. X-ray diffraction data for SnO₂. An illustration of the new powder data evaluation methods. Journal of Materials Characterization , 1989, 4(03): 156–159
[66] Traylor J G, Smith H G, Nicklow R M, . Wilkinson, lattice dynamics of rutile. Physical Review B , 1971, 3(10): 3457–3472
[67] Peercy P S, Morosin B. Pressure and temperature dependences of the Raman-active phonons in SnO₂. Physical Review B , 1973, 7(6): 2779–2786
[68] Diéguez A, Romano-Rodríguez A, Vilà A, . The complete Raman spectrum of nanometric SnO₂ particles. Journal of Applied Physics , 2001, 90(3): 1550–1557
[69] Wang G H, Han M. Structure and properties of nanocrystalline materials. Progress in Physics , 1990, 10(3): 248–289
[70] Romanowski W. Equilibrium forms of very small metallic crystals. Surface Science , 1969, 18(2): 373–388
[71] Jones F H, Dixon R, Foord J S, . The surface structure of SnO₂(110)(4×1) revealed by scanning tunneling microscopy. Surface Science , 1997, 376(1–3): 367–373
[72] Pagnier T, Boulova M, Galerie A, . In situ coupled Raman and impedance measurements of the reactivity of nanocrystalline SnO₂ versus H₂S. Journal of Solid State Chemistry , 1999, 143(1): 86–94
[73] Hama T, Matsubara T. Self-consistent Einstein model and theory of anharmonic surface vibration. II Face-centered cubic lattice. Progress of Theoretical Physics , 1978, 59(5): 1407–1417
[74] Hayashi S, Yamamoto K. Amorphous-like Raman spectra of semiconductor microcrystals. Superlattices and Microstructures , 1986, 2(6): 581–585
[75] Dolbec R, El Khakani M A, Serventi A M, . Microstructure and physical properties of nanostructured tin oxide thin films grown by means of pulsed laser deposition. Thin Solid Films , 2002, 419(1–2): 230–236
[76] Greskovich C, Lay K W. Grain growth in very porous Al₂O₃ compacts. Journal of the American Ceramic Society , 1972, 55(3): 142–146
[77] Penn R L, Banfield J F. Morphology development and crystal growth in nanocrystalline aggregates under hydrothermal conditions: insights from titania. Geochimica et Cosmochimica Acta , 1999, 63(10): 1549–1557
[78] Oviedo J, Gillan M J. Energetics and structure of stoichiometric SnO₂ surfaces studied by first-principles calculations. Surface Science , 2000, 463(2): 93–101
[79] Slater B, Catlow C R A, Gay D H, . Study of surface segregation of antimony on SnO₂ surfaces by computer simulation techniques. The Journal of Physical Chemistry B , 1999, 103(48): 10644–10650