Bulk scale production of carbon nanofibers in an economical way

Ravindra RAJARAO, Badekai Ramachandra BHAT()

PDF(608 KB)
PDF(608 KB)
Front. Mater. Sci. ›› 2012, Vol. 6 ›› Issue (4) : 319-325. DOI: 10.1007/s11706-012-0183-3
RESEARCH ARTICLE
RESEARCH ARTICLE

Bulk scale production of carbon nanofibers in an economical way

  • Ravindra RAJARAO, Badekai Ramachandra BHAT()
Author information +
History +

Abstract

An economical route for the scalable production of carbon nanofibers (CNFs) on a sodium chloride support has been developed. CNFs have been synthesized by chemical vapor deposition (CVD) method by using metal formate as catalyst precursors at 680°C. Products were characterized by SEM, TEM, Raman spectroscopy and XRD method. By thermal analysis, the purity of the as grown products and purified products were determined. This method avoids calcination and reduction process which was employed in commercial catalysts such as metal oxide or nitrate. The problems such as detrimental effect, environmental and even cost have been overcome by using sodium chloride as support. The yield of CNFs up to 7800 wt.% relative to the nickel catalyst has been achieved in the growth time of 15 min. The advantage of this synthesis technique is the simplicity and use of easily available low cost precursors.

Keywords

metal formate / carbon nanofiber (CNF) / chemical vapor deposition (CVD) / high yield / sodium chloride support / environmental friendly route

Cite this article

Download citation ▾
Ravindra RAJARAO, Badekai Ramachandra BHAT. Bulk scale production of carbon nanofibers in an economical way. Front Mater Sci, 2012, 6(4): 319‒325 https://doi.org/10.1007/s11706-012-0183-3

References

[1] Oberlin A, Endo M, Koyama T. Filamentous growth of carbon through benzene decomposition. Journal of Crystal Growth , 1976, 32(3): 335–349
[2] Endo M, Oberlin A, Koyama T. High resolution electron microscopy of graphitizable carbon fiber prepared by benzene decomposition. Japanese Journal of Applied Physics , 1977, 16(9): 1519–1523
[3] Iijima S. Helical microtubules of graphitic carbon. Nature , 1991, 354(6348): 56–58
[4] Bachtold A, Hadley P, Nakanishi T, . Logic circuits with carbon nanotube transistors. Science , 2001, 294(5545): 1317–1320
[5] Chen Z, Zhang D, Wang X, . High-performance energy-storage architectures from carbon nanotubes and nanocrystal building blocks. Advanced Materials , 2012, 24(15): 2030–2036
[6] Sairanen E, Karinen R, Borghei M, . Preparation methods for multi-walled carbon nanotube supported palladium catalysts. ChemCatChem , doi: 10.1002/cctc.201200344
[7] Zanolli Z, Leghrib R, Felten A, . Gas sensing with Au-decorated carbon nanotubes. ACS Nano , 2011, 5(6): 4592–4599
[8] Nishijima H, Kamo S, Akita S, . Carbon-nanotube tips for scanning probe microscopy: Preparation by a controlled process and observation of deoxyribonucleic acid. Applied Physics Letters , 1999, 74(26): 4061–4063
[9] Viet N X, Ukita Y, Chikae M, . Fabrication of new single-walled carbon nanotubes microelectrode for electrochemical sensors application. Talanta , 2012, 91: 88–94
[10] Guillorn M A, Melechko A V, Merkulov V I, . Operation of a gated field emitter using an individual carbon nanofiber cathode. Applied Physics Letters , 2001, 79(21): 3506–3508
[11] Haque A, Mina F, Moshiul Alam A K M, . Multiwalled carbon nanotubes-reinforced isotactic polypropylene nanocomposites: Enhancement of crystallization and mechanical, thermal, and electrical properties. Polymer Composites , 2012, 33(7): 1094–1104
[12] Edwards A B, Garner C D, Roberts K J. In situ QXAFS study of the pyrolytic decomposition of nickel formate dihydrate. The Journal of Physical Chemistry B , 1997, 101(1): 20–26
[13] De Jesus J C, Gonzalez I, Quevedo A, . Thermal decomposition of nickel acetate tetrahydrate: an integrated study by TGA, QMS and XPS techniques. Journal of Molecular Catalysis A: Chemical , 2005, 228(1–2): 283–291
[14] Eklund P C, Holden J M, Jishi R A. Vibrational modes of carbon nanotubes; Spectroscopy and theory. Carbon , 1995, 33(7): 959–972
[15] Li W, Zhang H, Wang C, . Raman characterization of aligned carbon nanotubes produced by thermal decomposition of hydrocarbon vapor. Applied Physics Letters , 1997, 70(20): 2684–2686
[16] Porwal D, Mukhopadhyay K, Ram K, . Investigation of the synthesis strategy of CNTs from CCVD by thermal analysis. Thermochimica Acta , 2007, 463(1–2): 53–59
AI Summary AI Mindmap
PDF(608 KB)

Accesses

Citations

Detail

Sections
Recommended

/